Synthesis, crystal structure and Hirshfeld analysis of a crystalline compound comprising a 1/1 mixture of 1-[(1R,4S)- and 1-[(1S,4R)-1,7,7-trimethyl-2-oxobi­cyclo[2.2.1]heptan-3-yl­idene]hydrazinecarbo­thio­amide

Pires, F.C.; Bresolin, L.; Gervini, V.C.; Tirloni, B.; Bof de Oliveira, A.

doi:10.1107/S2056989019016980

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 4
Section of the crystal structure of the title compound showing the H⋯S and H⋯O intermolecular interactions for the (1R)-camphor thiosemicarbazone molecule. H⋯S interactions connect the (1R)- and (1S)- isomers and the graph-set motifs for the hydrogen-bonding interactions (dashed lines) in the crystal packing are R₂²(8) and R₂¹ (7). The H⋯O interaction connects two (1R)-isomers.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 76| Part 1| January 2020| Pages 115-120

https://doi.org/10.1107/S2056989019016980

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