Synthesis, crystal structure and Hirshfeld analysis of a crystalline compound comprising a 1/1 mixture of 1-[(1R,4S)- and 1-[(1S,4R)-1,7,7-trimethyl-2-oxobi­cyclo[2.2.1]heptan-3-yl­idene]hydrazinecarbo­thio­amide

Pires, F.C.; Bresolin, L.; Gervini, V.C.; Tirloni, B.; Bof de Oliveira, A.

doi:10.1107/S2056989019016980

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 8
Hirshfeld surface two-dimensional fingerprint plot for the title compound showing (a) H⋯H, (b) H⋯S/S⋯H, (c) H⋯N/N⋯H and (d) H⋯O/O⋯H contacts in detail (cyan dots). The contributions of the interactions to the crystal packing amount to 55.0, 22.0, 8.9 and 8.4%, respectively. The d_e and d_i values are the closest external and internal distances (values in Å) from given points on the Hirshfeld surface.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 76| Part 1| January 2020| Pages 115-120

https://doi.org/10.1107/S2056989019016980

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