Figure 1
The single-crystal X-ray structure of DyIIINa(3-OHben)4[12-MCMn(III)N(shi)-4](H2O)4·10DMA, 1, (a) top view with only the metal atoms and shi3− ligands labeled for clarity and (b) side view with only the metal atoms and axial ligands labeled for clarity. The displacement ellipsoids are drawn at the 50% probability level. For clarity, hydrogen atoms, solvent molecules, and disorder have been omitted. Color scheme: purple – DyIII, green – MnIII, yellow – Na+, red – oxygen, blue – nitrogen, and gray – carbon. All figures were generated with the program Mercury (Macrae et al., 2020). [Symmetry codes: (i) +x, −y + , +z; (ii) −x + , −y + , +z; (iii) −x + , +y, +z.] |