Structure of the {U13} polyoxo cluster U13O8Clx(MeO)38–x (x = 2.3, MeO = methoxide)

Fichter, S.; Radoske, T.; Ikeda-Ohno, A.

doi:10.1107/S2056989021007623

Acta Crystallographica Section E
Acta Crystallographica
Section ECRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 3
Cubic coordination polyhedra of uranium (dark purple polyhedra) in different compounds: (a) bulk UO₂ (Cooper, 1982

), (b) the {U₃₈} cluster (Falaise et al., 2013c

), and (c) the {U₁₃} cluster (I). The structure of I is drawn as [U₁₃(μ₄-O_oxo)₈Cl₆(MeO)₃₂] in order to omit the disorder between chloride and methoxide anions for clarity. Colour code: carbon, black; oxygen, red; chlorine, light green; uranium, dark purple. Hydrogen atoms are omitted for clarity in (b) and (c).

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 77| Part 8| August 2021| Pages 847-852

https://doi.org/10.1107/S2056989021007623

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