Crystal structure of μ3-tetra­thio­anti­monato-tris[(cyclam)zinc(II)] tetra­thio­anti­monate aceto­nitrile disolvate dihydrate showing Zn disorder over the cyclam ring planes (cyclam = 1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)

Näther, C.; Danker, F.; Bensch, W.

doi:10.1107/S2056989022003759

Acta Crystallographica Section E
Acta Crystallographica
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Figure 4
Crystal structure of the title compound showing the [(Zn-cyclam)₃(SbS₄)₂] substructure with disorder of the Zn²⁺ cations (A), and assuming that an equivalent amount of [Zn(cyclam)₃(SbS₄)]³⁺ and [SbS₄]³⁻ (B) or [Zn(cyclam)SbS₄]⁻ and [(Zn(cyclam))₂(SbS₄)]⁺ units are present (C).

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 78| Part 5| May 2022| Pages 490-495

https://doi.org/10.1107/S2056989022003759

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