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Figure 3
Schematic packing diagram. The bulky fluorido­carboxyl­ate anions are represented by octa­hedra, the cation positions are given by dot-centered circles, and the closest anion⋯cation contacts are indicated by dashed lines. The distorted fcc-packing of the bulky anions can easily be recognized. Note the offset of the cations from the centers of the tetra­hedral inter­sticial regions that are indicated by eight translucent circular areas. With respect to the primitive unit cell, this offset is along [101] or in the reverse direction and to a lesser extent along [010] or in the reverse direction. Thus, each cation is significantly closer to one of the four anions establishing a tetra­hedral hole than to the other three.

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890
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