Figure 9
Packing diagram for 3 (only major component shown) showing the complex three-dimensional array of hydrogen bonding involving
R22(8),
R44(12) and
R44(20) rings propagating in the a-axis direction between the the 4-nitrophenyl group of one cation with the piperazinium ring of an adjacent cation (symmetry code: − x, − y, 1 − z, involving O1iii and O2iii; Table 4), two cations and two anions in adjacent asymmetric units (−x, −y, 1 − z, involving O7i), and two cations and two anions in adjacent asymmetric units (symmetry code: − − x, + y, − z, involving O4iv) . |