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Figure 9
Packing diagram for 3 (only major component shown) showing the complex three-dimensional array of hydrogen bonding involving R22(8), R44(12) and R44(20) rings propagating in the a-axis direction between the the 4-nitro­phenyl group of one cation with the piperazinium ring of an adjacent cation (symmetry code: [{1\over 2}] − x, [{1\over 2}] − y, 1 − z, involving O1iii and O2iii; Table 4[link]), two cations and two anions in adjacent asymmetric units (−x, −y, 1 − z, involving O7i), and two cations and two anions in adjacent asymmetric units (symmetry code: −[{1\over 2}] − x, [{1\over 2}] + y, [{1\over 2}] − z, involving O4iv) .

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890
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