Crystal structure of (μ-hydrogen di­sulfato)-μ-oxido-bis­[(4,4′-di-tert-butyl-2,2′-bi­pyridine)­oxidovanadium(IV/V)] aceto­nitrile monosolvate

Kodama, S.; Hashiguchi, T.; Nomoto, A.

doi:10.1107/S2056989023009040

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 1
Crystal structure of [V₂O₂(μ-O)(μ-H(SO₄)₂)(4,4′-^tBubpy)₂] (V₂) with numbered atoms. Ellipsoids are shown at the 50% probability level. Side view (top) and front view (bottom). The hydrogen atoms of 4,4′-^tBubpy ligands are omitted for clarity. Symmetry code: (i) −x + $[{5\over 4}]$ , y, −z + $[{5\over 4}]$ . The hydrogen atom of H(SO₄)₂^3– ligand is located at two positions (H6 and H6ⁱ) with 0.5 occupancy. Selected interatomic distances (Å): V1—O1 1.5932 (14), V1—O2 1.8268 (7), V1—O3 1.9692 (12), V1—O5ⁱ 2.2827 (12), V1—N1 2.1077 (14), V1—N2 2.1399 (14), S1—O3 1.5098 (12), S1—O4 1.4391 (13), S1—O5 1.4654 (13), S1—O6 1.5066 (13), O6⋯O6ⁱ 2.480 (2).

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 79| Part 11| November 2023| Pages 1055-1058

https://doi.org/10.1107/S2056989023009040

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