Synthesis, crystal structure and Hirshfeld analysis of trans-bis­{(2E)-N-phenyl-2-[(2E)-3-phenyl-2-propen-1-yl­idene]hydrazinecarbo­thio­amidato-κ2N1,S}palladium(II)

Melo, A.P.L. de; Martins, B.B.; Bresolin, L.; Tirloni, B.; Oliveira, A.B. de

doi:10.1107/S2056989023008654

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 8
The Hirshfeld surface two-dimensional fingerprint plot for the Ni^II coordination compound (Song et al., 2014

) showing the (a) H⋯H, (b) H⋯C/C⋯H, (c) H⋯N/N⋯H and (d) H⋯S/S⋯·H contacts in detail (cyan dots). The contributions of the interactions to the crystal cohesion amount to 47.4, 27.6, 7.0 and 6.5%, respectively. The d_i (x-axis) and the d_e (y-axis) values are the closest internal and external distances from given points on the Hirshfeld surface (in Å).

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 79| Part 11| November 2023| Pages 993-998

https://doi.org/10.1107/S2056989023008654

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