Synthesis, crystal structure and Hirshfeld analysis of trans-bis­(2-{1-[(6R,S)-3,5,5,6,8,8-hexa­methyl-5,6,7,8-tetra­hydronaphthalen-2-yl]ethyl­idene}-N-methyl­hydrazinecarbo­thio­amidato-κ2N2,S)palladium(II) ethanol monosolvate

Melo, A.P.L. de; Bresolin, L.; Tirloni, B.; Farias, R.L. de; Oliveira, A.B. de

doi:10.1107/S2056989023009908

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 10
Crystal structure section of the trans-bis[cinnamaldehyde 4-phenylthiosemicarbazonato-κ²N²S]palladium(II) complex viewed along [010] (Melo et al., 2023b

). The H⋯S intra- and intermolecular hydrogen bonds are drawn as dashed lines, forming rings of graph-set motifs R₂²(8) and S(5). The molecules are connected into mono-periodic hydrogen-bonded ribbons along [001]. [Symmetry codes: (#i) x, −y + $[{1\over 2}]$ , z + $[{1\over 2}]$ ; (#ii) x, −y + $[{1\over 2}]$ , z − $[{1\over 2}]$ .]

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 79| Part 12| December 2023| Pages 1166-1172

https://doi.org/10.1107/S2056989023009908

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