Figure 9
(a) Section of the molecular arrangement of α-JTSC (Orsoni et al., 2020). The three crystallographically independent molecules are A-, B-, and C-labelled. They are linked by pairs of N—H⋯S interactions, with rings of graph-set motif
R22(8), into two independent mono-periodic hydrogen-bonded ribbons along [100]. [Symmetry codes: (i) x + 1, y, z; (ii) x − 1, y, z; (iii) −x + 1, −y, −z + 1; (iv) −x, −y, −z + 1.] (b) Section of the molecular arrangement of β-JTSC (Oliveira et al., 2023b). The molecules are connected by pairs of N—H⋯S and C—H⋯S intermolecular interactions, with rings of graph-set motifs
R22(8) and
R21(7), into mono-periodic hydrogen-bonded ribbons along [010]. Disorder is not shown for clarity. [Symmetry codes: (i) −x + 1, y + , −z + ; (ii) −x + 1, y − , −z + .] |