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Figure 9
(a) Section of the mol­ecular arrangement of α-JTSC (Orsoni et al., 2020BB28). The three crystallographically independent mol­ecules are A-, B-, and C-labelled. They are linked by pairs of N—H⋯S inter­actions, with rings of graph-set motif R22(8), into two independent mono-periodic hydrogen-bonded ribbons along [100]. [Symmetry codes: (i) x + 1, y, z; (ii) x − 1, y, z; (iii) −x + 1, −y, −z + 1; (iv) −x, −y, −z + 1.] (b) Section of the mol­ecular arrangement of β-JTSC (Oliveira et al., 2023bBB27). The mol­ecules are connected by pairs of N—H⋯S and C—H⋯S inter­molecular inter­actions, with rings of graph-set motifs R22(8) and R21(7), into mono-periodic hydrogen-bonded ribbons along [010]. Disorder is not shown for clarity. [Symmetry codes: (i) −x + 1, y + [{1\over 2}], −z + [{1\over 2}]; (ii) −x + 1, y − [{1\over 2}], −z + [{1\over 2}].]

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