Figure 3
[Pd(HL)2]2+ cations of (I) joined by aromatic stacking between triazole and benzene rings of the centrosymmetrically related ligands (black dashed lines) and intermolecular C15—H15A⋯N3ii and C15—H15C⋯O3iii interactions forming rings with
R44(18) and
R22(12) graph-set motifs (blue dashed lines). H atoms not involved in hydrogen bonding have been omitted for clarity. [Symmetry codes: (ii) −x + 1, −y + 1, −z + 1; (iii) −x + 1, −y, −z + 1.] |