The crystal structures determination and Hirshfeld surface analysis of N-(4-bromo-3-meth­oxy­phen­yl)- and N-{[3-bromo-1-(phenyl­sulfon­yl)-1H-indol-2-yl]meth­yl}- derivatives of N-{[3-bromo-1-(phenylsulfon­yl)-1H-indol-2-yl]meth­yl}benzene­sulfonamide

Madhan, S.; NizamMohideen, M.; Pavunkumar, V.; MohanaKrishnan, A.K.

doi:10.1107/S2056989024009587

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 4
(a) Projection of the structure of II on the ab plane, showing the assembly of centrosymmetric C—H⋯O-bonded dimers and their integration into the three-dimensional framework. An individual dimer is colored red and its principal interactions C27—H⋯O1^iv, C13—H⋯O3ⁱ, C14—H⋯O4ⁱ and C35—H⋯Cg(C16–C21)^vi are labeled as 1–4, respectively. Two subconnectivities, which are orthogonal to the drawing plane, are marked with gray strips and they are detailed in the projections on the ac plane: (b) phenylsulfonyl layer; (c) π–π and C–H⋯O interactions between the molecules of II. [Symmetry codes: (i) x − $[{1\over 2}]$ , −y + $[{1\over 2}]$ , z − $[{1\over 2}]$ ; (ii) x + 1, y, z; (iii) x + $[{1\over 2}]$ , −y + $[{1\over 2}]$ , z − $[{1\over 2}]$ ; (iv) −x + 1, −y + 1, −z + 1; (vi) x − $[{1\over 2}]$ , −y − $[{1\over 2}]$ , z − $[{1\over 2}]$ ; (vii) x − 1, y, z − 1.]

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 80| Part 11| November 2024| Pages 1110-1117

https://doi.org/10.1107/S2056989024009587

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