Crystal structures of six complexes of phosphane chalcogenides R1R2R3PE (R = tert-butyl or isopropyl, E = S or Se) with the metal halides MX2 (M = Pd or Pt, X = Cl or Br), two halochalcogenyl­phospho­nium derivatives (tBu2iPrPEBr)2[Pd2Br6] and one hydrolysis product

Upmann, D.; Jones, P.G.

doi:10.1107/S2056989025000805

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 13
The packing of compound 2, showing the short three-centre contacts H63A⋯(Pd1, Se1) (dashed lines). The view direction is parallel to the ac plane, and the region y ≃ 0.25 is depicted. Note that neighbouring molecules are connected by the c glide operator and not by translation, despite their very similar orientation.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 81| Part 3| March 2025|

https://doi.org/10.1107/S2056989025000805

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