Synthesis and structure of (NH4)12[Mo36O112(OH)4(H2O)10], the first example of the [Mo36O112]8− molybdate anion cluster to bear a charge of 12−

Gaur, R.S.; Brock, S.L.; Ward, C.L.

doi:10.1107/S2056989026010388

Figure 4
Polyhedral views of (NH₄)₁₂[Mo₃₆O₁₁₂(OH)₄(H₂O)₁₀]·26H₂O projected along the b (left) and a (right) axes, illustrating the extensive hydrogen-bonding network surrounding the isopolymolybdate anions and the internal cavity occupied by two water molecules and two ammonium cations. Molybdenum polyhedra are shown in teal, with O atoms in red, N atoms in blue, and H atoms in white.

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ISSN: 2056-9890

Volume 82| Part 11| November 2026|

https://doi.org/10.1107/S2056989026010388

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