Crystal structure of 1-[(4-methyl­phen­yl)sulfon­yl]-2-phenyl­azetidine

In the crystal structure of 2-phenyl-N-tosyl­azetidine, there are three close con­tacts stabilizing the supra­molecular structure.

Synthesis, structure and computational study of 1-acetyl-3-(3,5-di­chloro­phen­yl)thio­urea

In the crystal, C—H⋯Cl and double-acceptor N—H⋯S and C—H⋯S hydrogen bonds link the mol­ecules into infinite chains parallel to the the b axis.

Crystal structure and Hirshfeld analysis of di-μ-bromido-bis­[(1-{[dimeth­yl(phenyl­thio­meth­yl)sil­yl]meth­yl}piperidine-κ²N,S)copper(I)] and di-μ-iodido-bis­[(1-{[dimeth­yl(phenyl­thio­meth­yl)sil­yl]meth­yl}piperidine-κ²N,S)copper(I)]

The dinuclear S,N-chelate title complexes feature a halide-bridged rhomboid-shaped Cu(μ₂-X)Cu (X = I, Br) core with Cu⋯Cu contacts of 2.8249 (5) and 2.7631 (6) Å, respectively. The two isostructural complexes crystallize in the triclinic space group P1 with half mol­ecule in the asymmetric unit.

Synthesis and crystal structure of di­bromido­bis­[1-butyl-4-(pyridin-2-yl)-1,2,4-triazol-5-yl­idene]palladium(II)

The synthesis and crystal structure of di­bromido­bis­[1-butyl-4-(pyridin-2-yl)-1,2,4-triazol-5-yl­idene]palladium(II) are presented

Lamellar crystal structure of the trigonal mixed-metal phosphate RbCoFe(PO₄)₂

In the title compound, all the cations occupy tetra­hedral sites, with the exception of rubidium, whose coordination number is twelve. The three types of tetra­hedra are linked at their vertices to form double layers stacked along the c-axis direction. The planes occupied by the rubidium ions are sandwiched between these layers.

Crystal structure and Hirshfeld surface analysis of (benzo[4,5]imidazo[2,1-b]thia­zol-2-yl)(4-chlorophen­yl)methanone

The title compound crystallizes in the monoclinic space group P2₁/c with two conformationally similar mol­ecules (Z′ = 2) in the asymmetric unit. The fused thia­zolo[3,2-a]benzimidazole framework is essentially planar, while the 4-chloro­benzoyl ring is inclined by ∼53° to the thia­zole ring in both mol­ecules. The crystal packing is consolidated by C—H⋯N hydrogen bonds, C—H⋯π contacts, and π–π stacking inter­actions, forming a three-dimensional supra­molecular framework.

Synthesis and structure of 1,1-bis­(furan-2-ylmethyl)-3-phenyl­urea

The asymmetric unit of the title compound contains two mol­ecules, A and B, with one furan ring in each mol­ecule showing ‘flip' rotational disorder. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into separate infinite ⋯A⋯A⋯A⋯ and ⋯B⋯B⋯B⋯ chains propagating along the c-axis direction.

Synthesis and structure of catena-poly[[[aquazinc(II)]-μ-2-({[amino­(sulfanid­yl)methyl­idene]amino}­imino)-2-phenyl­acetato-κ⁴O,N,S:O′] monohydrate]

The title Zn^II compound is a mono-periodic coordination polymer in which the doubly deprotonated phenyl­glyoxylic acid thio­semicarbazone ligand chelates one Zn^II ion through O, N and S donors and bridges to the next through its second carboxyl­ate O atom.

Crystal structure and Hirshfeld surface analysis of 3-(2,6-di­chloro­phen­yl)-1,5-bis­(thio­phen-2-yl)pentane-1,5-dione

In the crystal of the title compound, mol­ecules are linked by inter­molecular C—H⋯O hydrogen bonds, forming a square-ring around a fourfold rotation axis parallel to the c-axis. In addition, C—H⋯π and π-π- inter­actions connect mol­ecules, forming a three-dimensional network.

Syntheses and structures of trans-di­aqua­bis­(propane-1,3-di­amine-κ²N,N′)nickel(II) salts of two isomeric naphthalene­disulfonates

Two new layered structures of trans-di­aquabis(propane-1,3-di­amine)­nickel(II) complexes with isomeric naphthalene­disulfonate counter-ions are presented.

Synthesis and structure of (NH₄)₁₂[Mo₃₆O₁₁₂(OH)₄(H₂O)₁₀], the first example of the [Mo₃₆O₁₁₂]⁸⁻ molybdate anion cluster to bear a charge of 12−

The single-crystal X-ray structure of (NH₄)₁₂[Mo₃₆O₁₁₂(OH)₄(H₂O)₁₀]·26H₂O reveals a new ammonium Mo₃₆ isopolymolybdate polymorph containing a 12− charged cluster whose formulation is supported by Mo—OH—Mo bond-distance analysis.

Crystal structure and Hirshfeld surface analysis of 3-(4-meth­oxy­phen­yl)-2-[(thio­phen-2-yl)carbon­yl]acrylo­nitrile

In the title crystal, mol­ecular pairs are connected by C—H⋯N contacts, producing R₂²(16) motifs parallel to the (001) plane. Mol­ecules are linked by C—O⋯π and π–π inter­actions, forming layers parallel to the (100) plane. These layers are connected by C—H⋯N inter­actions.