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Figure 4
Local environment of the O1-centred hydroxonium ion, showing four selected O1⋯Br contacts with bromide ions of neighbouring Pb–Br layers. Dashed lines indicate O1⋯Br contacts associated with possible O—H⋯Br hydrogen-bonding; hydrogen atom positions remain undetermined. [Symmetry codes: (i) 1 − x, y, Mathematical equation − z; (ii) x − Mathematical equation, y + Mathematical equation, z - 1/2; (iii) x, 1 − y, Mathematical equation − z.]

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