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Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890

December 2026 issue

Early view articles

Journal cover

early career research


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The crystal structure for (R)-3-fluoro­pyrrolidine hydro­chloride, C4H9FN+·Cl−, is presented. It features an extended hydrogen-bonded arrangement linking the ammonium N—H groups with the chloride anions.

research communications


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The title compound features a nearly planar thia­zolo[3,2-a]benzimidazole core and a twisted 4-(tri­fluoro­meth­yl)phenyl ring, which subtends a dihedral angle of 52.6 (2)° with the thia­zole ring. The crystal packing is governed by C—H⋯N hydrogen-bonded chains, C—F⋯π and π–π contacts, with Hirshfeld and energy-framework analyses showing substantial dispersion-driven consolidation.

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The crystal structure of (H3O)Pb2Br5 contains an extended two-periodic Pb—Br network extending parallel to the ab plane, with hydroxonium ions embedded between neighbouring layers. O⋯Br contacts suggest possible O—H⋯Br hydrogen bonding.

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Reactions of cyclo­hexane-1,3-dione dioxime in the presence of nickel(II) salts yield a hydro­carbazole oxime cation, isolated as a nitrate salt and as a hydrated chloride co-crystal with cyclo­hexane-1,2,3-trione 1,3-dioxime. The two structures show different proton arrangements and hydrogen-bonding environments.