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Figure 5
Time-resolved SAXS data for azobenzene amphiphile mixtures of (a1) 95:5 DPPC:1 and (b1) 80:20 DPPC:2 from the trans state (blue) to the cis state (red) after illuminating the sample for the given number of seconds. In addition to the measured scattering data, the Gaussian curves belonging to the fitted lamellar (blue), Pn3m (red/grey solid lines) and Im3m (grey dotted lines) phases for the trans state at 0 s are shown underneath the data in panel (b1) (the fits for the cis state are shown in Fig. S11). (a2) Fitted values of the d spacing for 95:5 and 97.5:2.5 DPPC:1. (b2) Comparison of the intensity of the lamellar phase 100 and 200 peaks and Pn3m 110 peak [marked by arrows in panel (b1)] of 80:20 DPPC:2 for the trans to cis (t-c) and cis to trans (c-t) isomerization. |
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