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Figure 8
Schematic representation of the MIL-125(Ti) framework obtained from SPED and oriented along the crystallographic a axis (a). Overview of the octahedral and tetrahedral cavities (b) alongside the SBU composing the network (c). Comparison of fraction of the polymeric repeating unit (d, e), the crystal packing oriented along the crystallographic b axis (f, g) and the structure overlay oriented along the crystallographic c axis (h) between the crystal structure obtained from serial ED (d, f) and the reported structure from PXRD analysis (e.g. Dan-Hardi et al., 2009View full citation). In the structure overlay, the serial ED structure is represented in blue while the PXRD structure is in red. Carbon atoms are represented as black sticks, oxygen atoms as red spheres and Ti(IV) centres as blue polyhedra, while hydrogen atoms have been omitted for clarity.

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