A centrosymmetric polymorph of chloridotris(triphenyl­phosphine-κP)copper(I) at 150 K

This study characterizes a new polymorph of the title compound, [CuCl(C₁₈H₁₅P)₃], and analyses the influence of the extensive network of weak hydrogen-bonding inter­actions in the generation of this different crystal structure. The compound crystallizes in the centrosymmetric space group C2/c with two crystallographically independent mol­ecules per asymmetric unit, in contrast with the previously determined polymorph which crystallizes in the noncentrosymmetric space group P3 with three crystallographically independent mol­ecules in the asymmetric unit, each with crystallographically imposed C3 symmetry [Gill, Mayerle, Welcker, Lewis, Ucko, Barton, Stowens & Lippard (1976). Inorg. Chem. 15, 1155–1168]. The geometries of the two mol­ecules of the title compound are very similar, with each having an approximately tetra­hedral coordination around the central Cu atom and approximate C_s mol­ecular symmetry. The mol­ecules pack in chains parallel to the crystallographic b axis, connected by C—H...Cl and C—H...π(phenyl) hydrogen bonds.

S1. Comment

The phenomenon of polymorphism consists of the ability of a chemical substance to adopt more than one crystal structure. Different crystal structures of the same chemical material offer distinct physico-chemical properties (Day et al., 2006). The crystal structure of the title compound, (I), is an example of this. The compound has been determined in five different crystalline arrangements, either pure or in solvated forms. The first one determined was the noncentrosymmetric polymorph (Gill et al., 1976). In this structure, the compound is found in the trigonal space group P3 with three crystallographically independent molecules in the unit cell, each with crystallographically imposed C3 symmetry. The molecular packing is chiral, in which two of the three molecules possess (S) conformations and one an (R) conformation, using the `steering wheel' convention (Albano et al., 1971). The remaining four crystalline arrangements have been found with different solvates. Two, as acetone (Barron et al., 1997) or acetonitrile (Kraüter & Neumüller, 1996) solvates, are found in the centrosymmetric space group P1. The remaining two, both as tetrahydrofuran solvates, crystallize as two polymorphs, a noncentrosymmetric form in P6₃ (Folting et al., 1987) and a centrosymmetric form in P2₁/c (Carlson et al., 1996; Kraüter & Neumüller, 1996). This report presents the second known polymorph of the (pure) title compound.

The asymmetric unit of (I) contains two complete independent molecules, 1 and 2. The geometries of the two molecules are very similar; in both, the Cu atom has an approximately tetrahedral coordination geometry made up of three P atoms and one Cl atom. The average root-mean square deviation of the atomic positions for the five central atoms for the superposition of molecules 1 and 2 (atom pairs Cu1/Cu2, Cl1/Cl2, P1/P6, P2/P4 and P3/P5) is 0.078 Å using the quaternion transformation method (Mackay, 1984) in MOLFIT (PLATON; Spek, 2003). The arrangement of the phenyl rings, however, is different between the molecules. The angles about the Cu atom show a distortion, with Cl—Cu—P angles smaller than 108.86 (2)° and P—Cu—P angles larger than 111.18 (3)°, due to the 145° cone angle of the PPh₃ (Tollman, 1977) (Table 1). Steric hindrance between the triphenylphosphine ligands is also shown by smaller than usual C—P—C angles, with the smallest two, C311—P3—C321 = 99.87 (12)° and C611—P6—C631 = 99.69 (11)°, being significantly different from the average for C—P—C angles [103.5(1.7)° from 3638 observations in the Cambridge Structural Database (CSD, Version 5.28, November, 2007; Allen, 2002)]. The distances around the Cu atoms are close to the averages found in the CSD for similar tetrahedral ClCuP₃ compounds (256 observations): 2.32 (2) Å for Cu—Cl and 2.31 (2) Å for Cu—P distances. The phenyl rings of the PPh₃ ligands are arranged in a symmetric fashion, according to the approximate C_s molecular symmetry. One phenyl ring of each triphenylphosphine ligand points in the opposite direction to the Cl atom; the Cl—Cu—P—C torsion angles are about 180°, with the exception of Cl2—Cu2—P6—C621 (see Supplementary Material). The other two phenyl rings cradle the Cl atom, with space to accommodate the neighbouring Cl atom in the crystal packing (see below).

Chains of each molecule of (I), connected by weak non-classical hydrogen bonds, are formed by crystallographic unit-cell translations along the b axis. The molecules pack in a head-to-tail fashion where the Cl atom `head' fits into the spaces between the phenyl rings of the triphenylphosphine ligands of its own molecule and those of neighbouring ones. The interactions generate a network of weak non-classical hydrogen bonds between the molecules, making the packing arrangement interesting (Steiner & Desiraju, 1998; Desiraju & Steiner, 1999; Desiraju, 2002; Steiner, 2002; Brammer, 2004). The hydrogen bonding between the Cl atoms and the H atoms of the neighbouring phenyl groups is shown as filled dashed lines in Fig. 2 and details are given in Table 2. Both atoms Cl1 and Cl2 each participate in five C—H···n hydrogen bonds (n is a lone pair), with three intramolecular and two intermolecular interactions, with the Cl···H distances ranging from 2.61 to 2.93 Å. The sum of the radii is 2.95 Å (Bondi, 1964). Hydrogen bonds of the type C—H···n, where n is in this case the lone pair of the Cl atom, have been identified as influencing molecular packing (Balamurugan et al., 2004). Hydrogen bonds involving the Cl—M moiety are fairly strong, of the same order as those with Cl^- interactions (Aullón et al., 1998). Additionally, C—H···π(C₆H₅) hydrogen bonds are observed, shown as unfilled dashed lines in Fig. 2, with distances ranging from 2.70 to 2.93 Å to the ring centroid (Table 2). These weak bonds are of the order of 5 kJ mol^-1 (Tsuzuki et al., 2000). The directionality of the hydrogen bonds distinguishes them from simple van der Waals interactions (Steiner & Desiraju, 1998). Fig. 3 shows a view of the interactions.

S2. Experimental

The title compound was synthesized by the dissolution of [Cu{P(C₆H₅)₃}₃Cl] [Quantity?] in a mixture of methanol and acetone (1:1 v/v) [Quantity?] followed by filtration. Colourless single crystals of (I) were obtained by evaporation of the solution at room temperature.

S3. Refinement

All H atoms were refined using a riding model, with C—H = 0.93 Å and U_iso(H) = 1.2U_eq(C).

Computing details

Data collection: APEX2 (Bruker, 2006), COSMO (Bruker, 2006) and BIS (Bruker, 2006); cell refinement: SAINT (Bruker, 2006); data reduction: SAINT (Bruker, 2006), XPREP (Bruker, 2006) and SADABS (Bruker, 2006); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: DIAMOND (Brandenburg, 2007); software used to prepare material for publication: SHELXL97 (Sheldrick, 2008).

Figures

	Fig. 1. A view of the molecular structures of (a) molecule 1 and (b) molecule 2 of (I), showing the atom-labelling schemes. Displacement ellipsoids are drawn at the 50% probability level and H atoms are shown as small spheres of arbitrary radii.
	Fig. 2. A close-up view of the hydrogen-bond interactions of (a) molecule 1 and (b) molecule 2 of (I). C—H···Cl interactions are indicated with filled dashed lines and C—H···π interactions by unfilled dashed lines. Cg21 is the centroid of the ring C211–C216, Cg51 of ring C511–C516, Cg23 of ring C231–C236 and Cg13 of ring C131–C136. [Symmetry codes: (i) x, y + 1, z; (ii) -x + 3/2, y + 1/2, -z + 1/2; (iii) -x + 1/2, -y + 1/2, -z; (iv) -x + 3/2, y - 1/2, -z + 1/2; (v) -x+1, y, -z + 1/2; (vi) -x + 1, -y + 1, -z; (vii) x, y -1, z.]
	Fig. 3. Molecule interactions along the crystallographic b direction.

chloridotris(triphenylphosphine-κP)copper(I)

Crystal data

[CuCl(C18H15)3]	F(000) = 7360
Mr = 885.80	Dx = 1.339 Mg m^−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 9812 reflections
a = 43.253 (3) Å	θ = 2.2–27.0°
b = 9.9863 (8) Å	µ = 0.71 mm^−1
c = 44.354 (3) Å	T = 150 K
β = 113.496 (4)°	Block, colourless
V = 17570 (2) Å^3	0.32 × 0.16 × 0.13 mm
Z = 16

Data collection

Bruker X8 Kappa APEXII CCD area-detector diffractometer	25640 independent reflections
Radiation source: fine-focus sealed tube	17309 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.075
ϕ and ω scans	θmax = 30.1°, θmin = 1.7°
Absorption correction: gaussian [XPREP (Bruker, 2006) was used to perform the Gaussian numeric absorption correction based on the face-indexed crystal size; SADABS (Bruker, 2006) was used to perform further processing]	h = −60→60
Tmin = 0.844, Tmax = 0.927	k = −13→14
191602 measured reflections	l = −62→62

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.052	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.137	H-atom parameters constrained
S = 1.02	w = 1/[σ^2(Fo^2) + (0.0583P)^2 + 28.227P] where P = (Fo^2 + 2Fc^2)/3
25640 reflections	(Δ/σ)max = 0.003
1063 parameters	Δρmax = 1.28 e Å^−3
0 restraints	Δρmin = −0.72 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Cu1	0.633442 (7)	0.14830 (3)	0.230168 (7)	0.01984 (7)
Cu2	0.365921 (7)	0.46499 (3)	0.024394 (7)	0.01951 (7)
Cl1	0.646620 (17)	−0.07635 (6)	0.232458 (17)	0.02958 (14)
Cl2	0.344425 (16)	0.25841 (6)	0.030176 (16)	0.02639 (13)
P1	0.633530 (16)	0.21965 (6)	0.180356 (16)	0.02104 (13)
P2	0.676264 (16)	0.23879 (6)	0.276342 (16)	0.02049 (13)
P3	0.580164 (17)	0.14105 (7)	0.231017 (16)	0.02357 (14)
P4	0.368129 (17)	0.57126 (6)	0.071620 (16)	0.02106 (13)
P5	0.324664 (16)	0.53809 (6)	−0.025757 (16)	0.01983 (13)
P6	0.419925 (16)	0.43443 (6)	0.025437 (16)	0.02078 (13)
C111	0.62341 (6)	0.3960 (2)	0.17004 (6)	0.0246 (5)
C112	0.60884 (7)	0.4441 (3)	0.13796 (7)	0.0321 (6)
H112	0.6033	0.3839	0.1200	0.039*
C113	0.60244 (8)	0.5798 (3)	0.13219 (8)	0.0399 (7)
H113	0.5921	0.6118	0.1102	0.048*
C114	0.61096 (8)	0.6691 (3)	0.15814 (9)	0.0422 (8)
H114	0.6068	0.7621	0.1540	0.051*
C115	0.62547 (8)	0.6229 (3)	0.18998 (8)	0.0427 (8)
H115	0.6313	0.6838	0.2078	0.051*
C116	0.63155 (7)	0.4870 (3)	0.19588 (7)	0.0329 (6)
H116	0.6414	0.4554	0.2179	0.039*
C121	0.67328 (7)	0.1986 (3)	0.17529 (6)	0.0252 (5)
C122	0.68644 (7)	0.2966 (3)	0.16126 (7)	0.0303 (6)
H122	0.6748	0.3791	0.1542	0.036*
C123	0.71639 (7)	0.2740 (3)	0.15757 (7)	0.0359 (7)
H123	0.7255	0.3417	0.1485	0.043*
C124	0.73311 (8)	0.1525 (3)	0.16716 (7)	0.0403 (7)
H124	0.7533	0.1361	0.1641	0.048*
C125	0.72020 (7)	0.0556 (3)	0.18122 (7)	0.0380 (7)
H125	0.7317	−0.0273	0.1878	0.046*
C126	0.69063 (7)	0.0784 (3)	0.18577 (7)	0.0307 (6)
H126	0.6823	0.0123	0.1960	0.037*
C131	0.60350 (7)	0.1327 (2)	0.14403 (6)	0.0243 (5)
C132	0.61322 (9)	0.0452 (3)	0.12523 (7)	0.0401 (7)
H132	0.6365	0.0307	0.1304	0.048*
C133	0.58884 (10)	−0.0224 (3)	0.09849 (8)	0.0515 (10)
H133	0.5957	−0.0814	0.0855	0.062*
C134	0.55521 (9)	−0.0038 (3)	0.09101 (8)	0.0463 (9)
H134	0.5389	−0.0517	0.0733	0.056*
C135	0.54503 (8)	0.0851 (3)	0.10924 (7)	0.0424 (8)
H135	0.5217	0.1003	0.1038	0.051*
C136	0.56913 (7)	0.1514 (3)	0.13552 (7)	0.0338 (6)
H136	0.5620	0.2114	0.1481	0.041*
C211	0.71766 (6)	0.2452 (2)	0.27394 (6)	0.0223 (5)
C212	0.72173 (7)	0.3221 (3)	0.24928 (7)	0.0282 (6)
H212	0.7032	0.3712	0.2342	0.034*
C213	0.75261 (7)	0.3271 (3)	0.24672 (7)	0.0335 (6)
H213	0.7552	0.3815	0.2303	0.040*
C214	0.77959 (7)	0.2537 (3)	0.26782 (7)	0.0336 (6)
H214	0.8007	0.2576	0.2660	0.040*
C215	0.77563 (7)	0.1743 (3)	0.29155 (8)	0.0358 (7)
H215	0.7940	0.1219	0.3058	0.043*
C216	0.74500 (7)	0.1708 (3)	0.29469 (7)	0.0298 (6)
H216	0.7427	0.1167	0.3113	0.036*
C221	0.68661 (6)	0.1549 (2)	0.31605 (6)	0.0235 (5)
C222	0.68946 (7)	0.0157 (3)	0.31730 (7)	0.0302 (6)
H222	0.6860	−0.0332	0.2979	0.036*
C223	0.69733 (7)	−0.0518 (3)	0.34688 (7)	0.0359 (7)
H223	0.6998	−0.1464	0.3476	0.043*
C224	0.70162 (8)	0.0180 (3)	0.37513 (7)	0.0393 (7)
H224	0.7067	−0.0285	0.3952	0.047*
C225	0.69850 (8)	0.1555 (3)	0.37404 (7)	0.0393 (7)
H225	0.7013	0.2037	0.3934	0.047*
C226	0.69132 (7)	0.2239 (3)	0.34474 (7)	0.0313 (6)
H226	0.6896	0.3187	0.3443	0.038*
C231	0.66711 (6)	0.4101 (2)	0.28489 (6)	0.0241 (5)
C232	0.68572 (7)	0.5228 (3)	0.28360 (7)	0.0288 (6)
H232	0.7059	0.5124	0.2802	0.035*
C233	0.67457 (8)	0.6506 (3)	0.28729 (7)	0.0357 (7)
H233	0.6872	0.7268	0.2860	0.043*
C234	0.64576 (8)	0.6679 (3)	0.29266 (7)	0.0408 (7)
H234	0.6382	0.7555	0.2947	0.049*
C235	0.62765 (8)	0.5567 (3)	0.29509 (8)	0.0385 (7)
H235	0.6082	0.5678	0.2997	0.046*
C236	0.63799 (7)	0.4290 (3)	0.29074 (7)	0.0323 (6)
H236	0.6251	0.3535	0.2918	0.039*
C311	0.57677 (7)	0.0492 (3)	0.26550 (7)	0.0274 (6)
C312	0.54724 (9)	−0.0104 (4)	0.26361 (9)	0.0616 (11)
H312	0.5275	−0.0045	0.2439	0.074*
C313	0.54615 (9)	−0.0789 (5)	0.29040 (9)	0.0693 (13)
H313	0.5256	−0.1183	0.2889	0.083*
C314	0.57441 (8)	−0.0904 (3)	0.31900 (8)	0.0424 (8)
H314	0.5737	−0.1390	0.3371	0.051*
C315	0.60356 (8)	−0.0309 (4)	0.32101 (8)	0.0439 (8)
H315	0.6232	−0.0365	0.3408	0.053*
C316	0.60454 (8)	0.0378 (3)	0.29422 (7)	0.0394 (7)
H316	0.6251	0.0779	0.2959	0.047*
C321	0.54728 (7)	0.0558 (3)	0.19646 (7)	0.0291 (6)
C322	0.51542 (7)	0.1087 (3)	0.17939 (7)	0.0365 (7)
H322	0.5100	0.1948	0.1850	0.044*
C323	0.49128 (8)	0.0362 (4)	0.15406 (8)	0.0434 (8)
H323	0.4695	0.0732	0.1424	0.052*
C324	0.49881 (8)	−0.0886 (3)	0.14581 (8)	0.0438 (8)
H324	0.4823	−0.1384	0.1287	0.053*
C325	0.53049 (9)	−0.1404 (3)	0.16252 (8)	0.0482 (8)
H325	0.5357	−0.2266	0.1568	0.058*
C326	0.55496 (8)	−0.0692 (3)	0.18761 (7)	0.0377 (7)
H326	0.5769	−0.1058	0.1987	0.045*
C331	0.56187 (7)	0.3057 (3)	0.23191 (7)	0.0290 (6)
C332	0.54994 (10)	0.3451 (4)	0.25502 (9)	0.0595 (11)
H332	0.5484	0.2821	0.2704	0.071*
C333	0.54006 (12)	0.4775 (4)	0.25579 (10)	0.0740 (14)
H333	0.5319	0.5035	0.2719	0.089*
C334	0.54188 (9)	0.5706 (4)	0.23405 (8)	0.0521 (9)
H334	0.5351	0.6604	0.2349	0.062*
C335	0.55354 (9)	0.5329 (3)	0.21123 (8)	0.0453 (8)
H335	0.5548	0.5966	0.1959	0.054*
C336	0.56371 (8)	0.4013 (3)	0.21010 (7)	0.0370 (7)
H336	0.5721	0.3767	0.1940	0.044*
C411	0.33075 (7)	0.5587 (2)	0.08127 (6)	0.0235 (5)
C412	0.30018 (7)	0.5213 (3)	0.05674 (7)	0.0282 (6)
H412	0.2989	0.5028	0.0353	0.034*
C413	0.27159 (7)	0.5106 (3)	0.06315 (7)	0.0351 (6)
H413	0.2508	0.4848	0.0461	0.042*
C414	0.27300 (8)	0.5374 (3)	0.09434 (8)	0.0359 (7)
H414	0.2532	0.5313	0.0987	0.043*
C415	0.30363 (8)	0.5732 (3)	0.11922 (7)	0.0336 (6)
H415	0.3049	0.5906	0.1407	0.040*
C416	0.33221 (7)	0.5835 (3)	0.11275 (7)	0.0290 (6)
H416	0.3531	0.6077	0.1299	0.035*
C421	0.37929 (6)	0.7485 (2)	0.07604 (6)	0.0222 (5)
C422	0.36332 (7)	0.8472 (2)	0.08682 (7)	0.0275 (6)
H422	0.3456	0.8232	0.0933	0.033*
C423	0.37311 (7)	0.9810 (3)	0.08823 (7)	0.0327 (6)
H423	0.3617	1.0477	0.0951	0.039*
C424	0.39935 (7)	1.0169 (3)	0.07961 (7)	0.0348 (7)
H424	0.4061	1.1080	0.0809	0.042*
C425	0.41574 (7)	0.9205 (3)	0.06919 (8)	0.0353 (7)
H425	0.4341	0.9446	0.0637	0.042*
C426	0.40522 (7)	0.7881 (3)	0.06675 (7)	0.0322 (6)
H426	0.4159	0.7229	0.0586	0.039*
C431	0.40043 (7)	0.4990 (3)	0.10905 (6)	0.0270 (6)
C432	0.39652 (8)	0.3645 (3)	0.11548 (7)	0.0357 (7)
H432	0.3779	0.3147	0.1008	0.043*
C433	0.42005 (10)	0.3041 (3)	0.14336 (8)	0.0485 (9)
H433	0.4173	0.2129	0.1479	0.058*
C434	0.44744 (10)	0.3757 (4)	0.16451 (8)	0.0525 (10)
H434	0.4635	0.3339	0.1835	0.063*
C435	0.45141 (9)	0.5088 (4)	0.15788 (8)	0.0473 (8)
H435	0.4704	0.5578	0.1723	0.057*
C436	0.42797 (7)	0.5705 (3)	0.13050 (7)	0.0343 (6)
H436	0.4306	0.6621	0.1263	0.041*
C511	0.28122 (6)	0.5230 (2)	−0.02893 (6)	0.0207 (5)
C512	0.26020 (6)	0.6338 (2)	−0.03248 (6)	0.0244 (5)
H512	0.2682	0.7214	−0.0336	0.029*
C513	0.22774 (7)	0.6161 (3)	−0.03432 (7)	0.0308 (6)
H513	0.2138	0.6919	−0.0362	0.037*
C514	0.21538 (7)	0.4885 (3)	−0.03350 (7)	0.0286 (6)
H514	0.1930	0.4770	−0.0351	0.034*
C515	0.23587 (7)	0.3778 (3)	−0.03032 (7)	0.0292 (6)
H515	0.2274	0.2903	−0.0299	0.035*
C516	0.26858 (7)	0.3947 (3)	−0.02779 (6)	0.0266 (5)
H516	0.2826	0.3186	−0.0252	0.032*
C521	0.32577 (6)	0.7130 (2)	−0.03780 (6)	0.0229 (5)
C522	0.33156 (6)	0.8109 (3)	−0.01382 (7)	0.0263 (5)
H522	0.3359	0.7846	0.0081	0.032*
C523	0.33115 (7)	0.9468 (3)	−0.02121 (7)	0.0319 (6)
H523	0.3348	1.0122	−0.0046	0.038*
C524	0.32543 (7)	0.9856 (3)	−0.05289 (8)	0.0360 (7)
H524	0.3250	1.0780	−0.0582	0.043*
C525	0.32036 (8)	0.8896 (3)	−0.07692 (8)	0.0377 (7)
H525	0.3168	0.9161	−0.0986	0.045*
C526	0.32046 (7)	0.7539 (3)	−0.06936 (7)	0.0296 (6)
H526	0.3169	0.6888	−0.0860	0.035*
C531	0.32183 (6)	0.4413 (2)	−0.06197 (6)	0.0243 (5)
C532	0.29156 (8)	0.4184 (4)	−0.08850 (7)	0.0464 (8)
H532	0.2714	0.4573	−0.0887	0.056*
C533	0.29020 (9)	0.3401 (4)	−0.11464 (8)	0.0556 (10)
H533	0.2691	0.3239	−0.1323	0.067*
C534	0.31902 (9)	0.2853 (3)	−0.11539 (8)	0.0442 (8)
H534	0.3180	0.2332	−0.1337	0.053*
C536	0.35075 (7)	0.3848 (3)	−0.06286 (7)	0.0303 (6)
H536	0.3719	0.3993	−0.0451	0.036*
C535	0.34914 (8)	0.3070 (3)	−0.08947 (8)	0.0386 (7)
H535	0.3692	0.2685	−0.0896	0.046*
C611	0.45717 (6)	0.4790 (3)	0.06232 (6)	0.0237 (5)
C612	0.46732 (7)	0.3926 (3)	0.08925 (7)	0.0314 (6)
H612	0.4539	0.3168	0.0888	0.038*
C613	0.49666 (7)	0.4162 (3)	0.11649 (7)	0.0364 (7)
H613	0.5038	0.3548	0.1343	0.044*
C614	0.51576 (8)	0.5288 (3)	0.11792 (7)	0.0391 (7)
H614	0.5361	0.5443	0.1366	0.047*
C615	0.50528 (7)	0.6183 (3)	0.09231 (7)	0.0366 (7)
H615	0.5179	0.6975	0.0937	0.044*
C616	0.47630 (7)	0.5938 (3)	0.06435 (7)	0.0290 (6)
H616	0.4695	0.6554	0.0466	0.035*
C621	0.42736 (6)	0.5306 (2)	−0.00631 (6)	0.0221 (5)
C622	0.40925 (7)	0.6491 (2)	−0.01710 (7)	0.0269 (5)
H622	0.3946	0.6790	−0.0073	0.032*
C623	0.41250 (7)	0.7240 (3)	−0.04219 (7)	0.0324 (6)
H623	0.3994	0.8027	−0.0500	0.039*
C624	0.43470 (8)	0.6839 (3)	−0.05571 (7)	0.0360 (7)
H624	0.4375	0.7364	−0.0723	0.043*
C625	0.45299 (8)	0.5666 (3)	−0.04490 (8)	0.0384 (7)
H625	0.4681	0.5384	−0.0544	0.046*
C626	0.44934 (7)	0.4904 (3)	−0.02044 (7)	0.0336 (6)
H626	0.4619	0.4101	−0.0133	0.040*
C631	0.43195 (6)	0.2644 (2)	0.01838 (6)	0.0246 (5)
C632	0.40668 (7)	0.1725 (3)	0.00174 (7)	0.0297 (6)
H632	0.3837	0.1954	−0.0041	0.036*
C633	0.41519 (8)	0.0470 (3)	−0.00633 (8)	0.0397 (7)
H633	0.3978	−0.0150	−0.0179	0.048*
C634	0.44846 (7)	0.0113 (3)	0.00216 (8)	0.0371 (7)
H634	0.4540	−0.0742	−0.0037	0.045*
C635	0.47364 (7)	0.1010 (3)	0.01926 (7)	0.0345 (6)
H635	0.4966	0.0767	0.0253	0.041*
C636	0.46576 (7)	0.2260 (3)	0.02763 (7)	0.0302 (6)
H636	0.4833	0.2864	0.0397	0.036*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Cu1	0.02097 (16)	0.01698 (13)	0.02166 (16)	−0.00021 (11)	0.00858 (12)	0.00041 (11)
Cu2	0.02002 (15)	0.01699 (13)	0.02229 (16)	−0.00060 (11)	0.00923 (13)	−0.00083 (11)
Cl1	0.0351 (4)	0.0175 (3)	0.0362 (4)	0.0016 (2)	0.0143 (3)	−0.0017 (2)
Cl2	0.0258 (3)	0.0169 (3)	0.0382 (4)	−0.0017 (2)	0.0146 (3)	0.0018 (2)
P1	0.0229 (3)	0.0190 (3)	0.0210 (3)	−0.0002 (2)	0.0085 (3)	0.0010 (2)
P2	0.0225 (3)	0.0169 (3)	0.0206 (3)	−0.0011 (2)	0.0071 (3)	−0.0003 (2)
P3	0.0204 (3)	0.0273 (3)	0.0236 (3)	0.0012 (3)	0.0095 (3)	0.0039 (3)
P4	0.0235 (3)	0.0177 (3)	0.0220 (3)	0.0017 (2)	0.0091 (3)	−0.0010 (2)
P5	0.0185 (3)	0.0199 (3)	0.0207 (3)	0.0003 (2)	0.0075 (3)	0.0002 (2)
P6	0.0181 (3)	0.0200 (3)	0.0244 (3)	−0.0003 (2)	0.0086 (3)	−0.0005 (2)
C111	0.0245 (13)	0.0206 (11)	0.0284 (14)	−0.0009 (10)	0.0102 (11)	0.0032 (10)
C112	0.0363 (16)	0.0263 (13)	0.0310 (15)	−0.0014 (11)	0.0105 (13)	0.0062 (11)
C113	0.0412 (18)	0.0323 (15)	0.0441 (18)	0.0000 (13)	0.0147 (15)	0.0160 (13)
C114	0.0396 (18)	0.0239 (14)	0.062 (2)	0.0006 (12)	0.0195 (16)	0.0099 (14)
C115	0.050 (2)	0.0210 (13)	0.051 (2)	−0.0046 (13)	0.0145 (16)	−0.0076 (13)
C116	0.0379 (17)	0.0224 (13)	0.0318 (15)	0.0010 (11)	0.0071 (13)	−0.0010 (11)
C121	0.0263 (14)	0.0281 (13)	0.0210 (13)	0.0000 (10)	0.0093 (11)	−0.0019 (10)
C122	0.0312 (15)	0.0340 (14)	0.0258 (14)	−0.0025 (11)	0.0113 (12)	0.0017 (11)
C123	0.0306 (16)	0.0489 (17)	0.0302 (15)	−0.0038 (13)	0.0142 (13)	0.0072 (13)
C124	0.0279 (16)	0.061 (2)	0.0352 (17)	0.0067 (14)	0.0159 (14)	0.0063 (15)
C125	0.0316 (16)	0.0480 (18)	0.0353 (17)	0.0117 (13)	0.0142 (14)	0.0090 (13)
C126	0.0289 (15)	0.0331 (14)	0.0315 (15)	0.0040 (11)	0.0135 (12)	0.0052 (12)
C131	0.0306 (14)	0.0194 (11)	0.0201 (12)	−0.0016 (10)	0.0071 (11)	0.0026 (9)
C132	0.0471 (19)	0.0309 (15)	0.0329 (16)	0.0094 (13)	0.0059 (14)	−0.0063 (12)
C133	0.071 (3)	0.0301 (16)	0.0341 (18)	0.0168 (15)	0.0011 (17)	−0.0093 (13)
C134	0.057 (2)	0.0267 (14)	0.0331 (17)	−0.0116 (14)	−0.0051 (16)	0.0032 (12)
C135	0.0367 (17)	0.055 (2)	0.0310 (16)	−0.0174 (15)	0.0090 (14)	0.0090 (14)
C136	0.0325 (16)	0.0453 (17)	0.0238 (14)	−0.0108 (13)	0.0114 (12)	−0.0013 (12)
C211	0.0237 (13)	0.0198 (11)	0.0234 (13)	−0.0048 (9)	0.0093 (11)	−0.0051 (9)
C212	0.0285 (14)	0.0272 (13)	0.0288 (14)	−0.0035 (10)	0.0112 (12)	−0.0021 (11)
C213	0.0349 (16)	0.0351 (15)	0.0354 (16)	−0.0104 (12)	0.0191 (13)	−0.0042 (12)
C214	0.0288 (15)	0.0349 (15)	0.0402 (17)	−0.0063 (12)	0.0171 (13)	−0.0127 (12)
C215	0.0285 (15)	0.0371 (15)	0.0403 (17)	0.0041 (12)	0.0122 (13)	−0.0008 (13)
C216	0.0280 (14)	0.0279 (13)	0.0333 (15)	0.0001 (11)	0.0122 (12)	0.0031 (11)
C221	0.0220 (13)	0.0237 (12)	0.0233 (13)	−0.0006 (10)	0.0075 (11)	0.0019 (10)
C222	0.0359 (16)	0.0261 (13)	0.0253 (14)	−0.0036 (11)	0.0086 (12)	0.0024 (11)
C223	0.0362 (17)	0.0308 (14)	0.0352 (16)	−0.0053 (12)	0.0085 (13)	0.0112 (12)
C224	0.0349 (17)	0.0522 (19)	0.0258 (15)	−0.0045 (14)	0.0069 (13)	0.0138 (13)
C225	0.0412 (18)	0.0529 (19)	0.0202 (14)	−0.0006 (14)	0.0085 (13)	0.0009 (13)
C226	0.0347 (16)	0.0302 (14)	0.0260 (14)	0.0008 (11)	0.0087 (12)	0.0001 (11)
C231	0.0279 (14)	0.0198 (11)	0.0207 (13)	−0.0006 (10)	0.0057 (11)	−0.0028 (9)
C232	0.0367 (16)	0.0230 (12)	0.0269 (14)	0.0000 (11)	0.0130 (12)	0.0010 (10)
C233	0.0546 (19)	0.0182 (12)	0.0327 (16)	0.0011 (12)	0.0158 (14)	0.0010 (11)
C234	0.056 (2)	0.0279 (14)	0.0325 (16)	0.0109 (13)	0.0112 (15)	−0.0051 (12)
C235	0.0390 (17)	0.0359 (16)	0.0399 (17)	0.0092 (13)	0.0150 (14)	−0.0071 (13)
C236	0.0328 (16)	0.0281 (13)	0.0338 (16)	0.0008 (11)	0.0109 (13)	−0.0044 (11)
C311	0.0212 (13)	0.0330 (14)	0.0298 (14)	0.0005 (10)	0.0121 (11)	0.0063 (11)
C312	0.0361 (19)	0.104 (3)	0.042 (2)	−0.020 (2)	0.0118 (16)	0.025 (2)
C313	0.042 (2)	0.113 (4)	0.052 (2)	−0.025 (2)	0.0171 (19)	0.030 (2)
C314	0.0462 (19)	0.0476 (18)	0.0431 (19)	0.0048 (15)	0.0282 (16)	0.0165 (15)
C315	0.0331 (17)	0.063 (2)	0.0325 (17)	0.0033 (15)	0.0093 (14)	0.0177 (15)
C316	0.0284 (16)	0.0515 (18)	0.0363 (17)	−0.0066 (13)	0.0109 (13)	0.0126 (14)
C321	0.0239 (14)	0.0332 (14)	0.0301 (15)	−0.0030 (11)	0.0108 (12)	0.0090 (11)
C322	0.0268 (15)	0.0443 (17)	0.0379 (17)	0.0006 (12)	0.0122 (13)	0.0042 (13)
C323	0.0244 (16)	0.059 (2)	0.0385 (18)	−0.0035 (14)	0.0033 (14)	0.0055 (15)
C324	0.0345 (17)	0.0485 (19)	0.0369 (18)	−0.0183 (14)	0.0022 (14)	0.0054 (14)
C325	0.052 (2)	0.0315 (16)	0.0437 (19)	−0.0057 (14)	0.0006 (16)	0.0029 (14)
C326	0.0370 (17)	0.0309 (14)	0.0336 (16)	−0.0002 (12)	0.0018 (13)	0.0050 (12)
C331	0.0225 (13)	0.0377 (14)	0.0270 (14)	0.0065 (11)	0.0102 (11)	0.0026 (11)
C332	0.085 (3)	0.062 (2)	0.053 (2)	0.044 (2)	0.049 (2)	0.0267 (18)
C333	0.107 (4)	0.074 (3)	0.066 (3)	0.058 (3)	0.061 (3)	0.023 (2)
C334	0.063 (2)	0.0459 (19)	0.0422 (19)	0.0292 (17)	0.0154 (18)	−0.0003 (15)
C335	0.060 (2)	0.0337 (16)	0.0407 (18)	0.0124 (15)	0.0189 (17)	0.0037 (14)
C336	0.0494 (19)	0.0294 (14)	0.0355 (16)	0.0057 (13)	0.0206 (15)	0.0017 (12)
C411	0.0283 (14)	0.0189 (11)	0.0266 (13)	0.0020 (9)	0.0146 (11)	0.0009 (9)
C412	0.0304 (15)	0.0299 (13)	0.0239 (14)	0.0013 (11)	0.0104 (12)	−0.0002 (11)
C413	0.0285 (15)	0.0427 (16)	0.0341 (16)	−0.0011 (12)	0.0123 (13)	0.0009 (13)
C414	0.0355 (17)	0.0359 (15)	0.0432 (18)	0.0038 (12)	0.0230 (15)	0.0029 (13)
C415	0.0424 (17)	0.0346 (14)	0.0305 (15)	0.0009 (12)	0.0214 (14)	−0.0011 (12)
C416	0.0320 (15)	0.0298 (13)	0.0249 (14)	−0.0006 (11)	0.0111 (12)	−0.0013 (11)
C421	0.0216 (12)	0.0194 (11)	0.0212 (12)	0.0035 (9)	0.0041 (10)	−0.0014 (9)
C422	0.0299 (14)	0.0219 (12)	0.0308 (14)	0.0017 (10)	0.0121 (12)	−0.0022 (10)
C423	0.0335 (16)	0.0213 (12)	0.0409 (17)	0.0028 (11)	0.0121 (13)	−0.0043 (11)
C424	0.0381 (17)	0.0195 (12)	0.0390 (17)	−0.0014 (11)	0.0072 (14)	−0.0007 (11)
C425	0.0308 (15)	0.0295 (14)	0.0458 (18)	−0.0083 (12)	0.0156 (14)	−0.0008 (13)
C426	0.0349 (16)	0.0245 (13)	0.0407 (17)	0.0016 (11)	0.0188 (14)	−0.0018 (12)
C431	0.0329 (15)	0.0253 (12)	0.0237 (13)	0.0084 (11)	0.0121 (12)	0.0005 (10)
C432	0.0466 (18)	0.0274 (14)	0.0337 (16)	0.0113 (12)	0.0166 (14)	0.0038 (12)
C433	0.072 (3)	0.0362 (17)	0.0404 (19)	0.0244 (17)	0.0259 (19)	0.0125 (14)
C434	0.063 (2)	0.060 (2)	0.0274 (17)	0.0347 (19)	0.0102 (17)	0.0087 (15)
C435	0.044 (2)	0.057 (2)	0.0300 (17)	0.0164 (16)	0.0032 (15)	−0.0040 (15)
C436	0.0374 (17)	0.0334 (14)	0.0261 (15)	0.0086 (12)	0.0064 (13)	−0.0014 (11)
C511	0.0215 (12)	0.0218 (11)	0.0173 (12)	0.0000 (9)	0.0061 (10)	0.0007 (9)
C512	0.0217 (13)	0.0230 (12)	0.0281 (14)	−0.0016 (10)	0.0096 (11)	−0.0017 (10)
C513	0.0250 (14)	0.0300 (13)	0.0396 (16)	0.0031 (11)	0.0150 (13)	−0.0018 (12)
C514	0.0206 (13)	0.0360 (14)	0.0290 (14)	−0.0020 (11)	0.0098 (11)	0.0006 (11)
C515	0.0277 (14)	0.0276 (13)	0.0298 (15)	−0.0044 (11)	0.0089 (12)	0.0048 (11)
C516	0.0249 (14)	0.0225 (12)	0.0291 (14)	0.0012 (10)	0.0071 (11)	0.0018 (10)
C521	0.0172 (12)	0.0239 (12)	0.0284 (14)	0.0006 (9)	0.0098 (11)	0.0037 (10)
C522	0.0242 (13)	0.0265 (12)	0.0286 (14)	−0.0025 (10)	0.0109 (11)	−0.0006 (10)
C523	0.0295 (15)	0.0251 (13)	0.0430 (17)	−0.0056 (11)	0.0164 (13)	−0.0017 (12)
C524	0.0298 (15)	0.0263 (13)	0.0502 (19)	−0.0014 (11)	0.0143 (14)	0.0097 (13)
C525	0.0401 (17)	0.0367 (15)	0.0351 (16)	−0.0012 (13)	0.0138 (14)	0.0134 (13)
C526	0.0314 (15)	0.0318 (14)	0.0251 (14)	0.0008 (11)	0.0108 (12)	0.0054 (11)
C531	0.0234 (13)	0.0254 (12)	0.0248 (13)	−0.0012 (10)	0.0105 (11)	−0.0013 (10)
C532	0.0303 (17)	0.075 (2)	0.0288 (16)	0.0069 (16)	0.0067 (14)	−0.0136 (16)
C533	0.040 (2)	0.089 (3)	0.0303 (18)	−0.0051 (19)	0.0055 (15)	−0.0197 (18)
C534	0.058 (2)	0.0477 (18)	0.0315 (17)	−0.0042 (16)	0.0231 (16)	−0.0121 (14)
C536	0.0268 (14)	0.0305 (13)	0.0346 (15)	0.0000 (11)	0.0131 (12)	−0.0019 (11)
C535	0.0431 (18)	0.0370 (15)	0.0443 (18)	0.0054 (13)	0.0266 (16)	−0.0051 (13)
C611	0.0206 (13)	0.0270 (12)	0.0242 (13)	0.0022 (10)	0.0096 (11)	−0.0009 (10)
C612	0.0286 (15)	0.0335 (14)	0.0308 (15)	0.0007 (11)	0.0104 (12)	0.0020 (11)
C613	0.0336 (16)	0.0449 (17)	0.0249 (15)	0.0079 (13)	0.0057 (13)	0.0036 (12)
C614	0.0293 (16)	0.0529 (19)	0.0298 (16)	−0.0012 (14)	0.0062 (13)	−0.0102 (14)
C615	0.0293 (15)	0.0387 (16)	0.0385 (17)	−0.0106 (12)	0.0101 (13)	−0.0120 (13)
C616	0.0275 (14)	0.0271 (13)	0.0318 (15)	−0.0005 (11)	0.0111 (12)	−0.0002 (11)
C621	0.0187 (12)	0.0247 (12)	0.0232 (13)	−0.0033 (9)	0.0088 (10)	−0.0025 (10)
C622	0.0261 (14)	0.0252 (12)	0.0324 (15)	−0.0019 (10)	0.0147 (12)	−0.0007 (11)
C623	0.0406 (17)	0.0234 (12)	0.0320 (15)	−0.0052 (11)	0.0130 (13)	0.0028 (11)
C624	0.0486 (19)	0.0347 (15)	0.0271 (15)	−0.0131 (13)	0.0177 (14)	−0.0022 (12)
C625	0.0472 (19)	0.0414 (16)	0.0402 (17)	−0.0053 (14)	0.0317 (15)	−0.0045 (13)
C626	0.0322 (16)	0.0347 (14)	0.0404 (17)	0.0023 (12)	0.0211 (14)	−0.0018 (12)
C631	0.0246 (13)	0.0220 (11)	0.0281 (14)	0.0020 (10)	0.0115 (11)	0.0017 (10)
C632	0.0249 (14)	0.0278 (13)	0.0395 (16)	−0.0010 (10)	0.0161 (13)	−0.0055 (11)
C633	0.0333 (16)	0.0299 (14)	0.061 (2)	−0.0064 (12)	0.0241 (16)	−0.0162 (14)
C634	0.0367 (17)	0.0258 (13)	0.054 (2)	0.0039 (12)	0.0237 (15)	−0.0091 (13)
C635	0.0273 (15)	0.0334 (14)	0.0439 (18)	0.0053 (12)	0.0155 (13)	−0.0026 (13)
C636	0.0229 (14)	0.0291 (13)	0.0360 (16)	0.0015 (11)	0.0090 (12)	−0.0032 (11)

Geometric parameters (Å, º)

Cu1—Cl1	2.3070 (7)	C325—H325	0.9500
Cu1—P3	2.3208 (7)	C326—H326	0.9500
Cu1—P1	2.3228 (7)	C331—C332	1.376 (4)
Cu1—P2	2.3274 (7)	C331—C336	1.384 (4)
Cu2—P4	2.3159 (7)	C332—C333	1.395 (5)
Cu2—Cl2	2.3187 (6)	C332—H332	0.9500
Cu2—P6	2.3378 (7)	C333—C334	1.365 (5)
Cu2—P5	2.3453 (7)	C333—H333	0.9500
P1—C111	1.828 (2)	C334—C335	1.352 (5)
P1—C121	1.833 (3)	C334—H334	0.9500
P1—C131	1.835 (3)	C335—C336	1.393 (4)
P2—C231	1.830 (2)	C335—H335	0.9500
P2—C211	1.837 (3)	C336—H336	0.9500
P2—C221	1.837 (3)	C411—C412	1.388 (4)
P3—C331	1.833 (3)	C411—C416	1.394 (4)
P3—C321	1.833 (3)	C412—C413	1.379 (4)
P3—C311	1.839 (3)	C412—H412	0.9500
P4—C421	1.824 (2)	C413—C414	1.386 (4)
P4—C411	1.834 (3)	C413—H413	0.9500
P4—C431	1.838 (3)	C414—C415	1.391 (4)
P5—C521	1.832 (2)	C414—H414	0.9500
P5—C511	1.834 (3)	C415—C416	1.380 (4)
P5—C531	1.836 (3)	C415—H415	0.9500
P6—C611	1.835 (3)	C416—H416	0.9500
P6—C621	1.836 (3)	C421—C422	1.393 (3)
P6—C631	1.839 (3)	C421—C426	1.397 (4)
C111—C112	1.392 (4)	C422—C423	1.396 (4)
C111—C116	1.393 (4)	C422—H422	0.9500
C112—C113	1.386 (4)	C423—C424	1.382 (4)
C112—H112	0.9500	C423—H423	0.9500
C113—C114	1.385 (5)	C424—C425	1.379 (4)
C113—H113	0.9500	C424—H424	0.9500
C114—C115	1.377 (5)	C425—C426	1.389 (4)
C114—H114	0.9500	C425—H425	0.9500
C115—C116	1.387 (4)	C426—H426	0.9500
C115—H115	0.9500	C431—C436	1.389 (4)
C116—H116	0.9500	C431—C432	1.397 (4)
C121—C126	1.394 (4)	C432—C433	1.388 (4)
C121—C122	1.397 (4)	C432—H432	0.9500
C122—C123	1.387 (4)	C433—C434	1.382 (5)
C122—H122	0.9500	C433—H433	0.9500
C123—C124	1.389 (4)	C434—C435	1.387 (5)
C123—H123	0.9500	C434—H434	0.9500
C124—C125	1.384 (4)	C435—C436	1.378 (4)
C124—H124	0.9500	C435—H435	0.9500
C125—C126	1.390 (4)	C436—H436	0.9500
C125—H125	0.9500	C511—C512	1.401 (3)
C126—H126	0.9500	C511—C516	1.402 (3)
C131—C132	1.384 (4)	C512—C513	1.384 (4)
C131—C136	1.393 (4)	C512—H512	0.9500
C132—C133	1.406 (4)	C513—C514	1.388 (4)
C132—H132	0.9500	C513—H513	0.9500
C133—C134	1.369 (5)	C514—C515	1.389 (4)
C133—H133	0.9500	C514—H514	0.9500
C134—C135	1.386 (5)	C515—C516	1.384 (4)
C134—H134	0.9500	C515—H515	0.9500
C135—C136	1.384 (4)	C516—H516	0.9500
C135—H135	0.9500	C521—C526	1.387 (4)
C136—H136	0.9500	C521—C522	1.393 (4)
C211—C216	1.389 (4)	C522—C523	1.394 (4)
C211—C212	1.404 (4)	C522—H522	0.9500
C212—C213	1.386 (4)	C523—C524	1.381 (4)
C212—H212	0.9500	C523—H523	0.9500
C213—C214	1.380 (4)	C524—C525	1.385 (4)
C213—H213	0.9500	C524—H524	0.9500
C214—C215	1.382 (4)	C525—C526	1.395 (4)
C214—H214	0.9500	C525—H525	0.9500
C215—C216	1.387 (4)	C526—H526	0.9500
C215—H215	0.9500	C531—C532	1.386 (4)
C216—H216	0.9500	C531—C536	1.387 (4)
C221—C226	1.389 (4)	C532—C533	1.381 (4)
C221—C222	1.395 (3)	C532—H532	0.9500
C222—C223	1.391 (4)	C533—C534	1.374 (5)
C222—H222	0.9500	C533—H533	0.9500
C223—C224	1.380 (4)	C534—C535	1.368 (4)
C223—H223	0.9500	C534—H534	0.9500
C224—C225	1.379 (4)	C536—C535	1.391 (4)
C224—H224	0.9500	C536—H536	0.9500
C225—C226	1.389 (4)	C535—H535	0.9500
C225—H225	0.9500	C611—C612	1.394 (4)
C226—H226	0.9500	C611—C616	1.396 (4)
C231—C236	1.396 (4)	C612—C613	1.379 (4)
C231—C232	1.398 (4)	C612—H612	0.9500
C232—C233	1.397 (4)	C613—C614	1.382 (4)
C232—H232	0.9500	C613—H613	0.9500
C233—C234	1.370 (4)	C614—C615	1.372 (4)
C233—H233	0.9500	C614—H614	0.9500
C234—C235	1.388 (4)	C615—C616	1.389 (4)
C234—H234	0.9500	C615—H615	0.9500
C235—C236	1.390 (4)	C616—H616	0.9500
C235—H235	0.9500	C621—C626	1.391 (4)
C236—H236	0.9500	C621—C622	1.394 (3)
C311—C316	1.363 (4)	C622—C623	1.393 (4)
C311—C312	1.381 (4)	C622—H622	0.9500
C312—C313	1.388 (5)	C623—C624	1.379 (4)
C312—H312	0.9500	C623—H623	0.9500
C313—C314	1.371 (5)	C624—C625	1.388 (4)
C313—H313	0.9500	C624—H624	0.9500
C314—C315	1.365 (4)	C625—C626	1.385 (4)
C314—H314	0.9500	C625—H625	0.9500
C315—C316	1.387 (4)	C626—H626	0.9500
C315—H315	0.9500	C631—C632	1.392 (4)
C316—H316	0.9500	C631—C636	1.406 (4)
C321—C322	1.385 (4)	C632—C633	1.393 (4)
C321—C326	1.388 (4)	C632—H632	0.9500
C322—C323	1.394 (4)	C633—C634	1.381 (4)
C322—H322	0.9500	C633—H633	0.9500
C323—C324	1.373 (5)	C634—C635	1.381 (4)
C323—H323	0.9500	C634—H634	0.9500
C324—C325	1.373 (5)	C635—C636	1.383 (4)
C324—H324	0.9500	C635—H635	0.9500
C325—C326	1.388 (4)	C636—H636	0.9500
Cl1—Cu1—P3	101.44 (3)	C324—C325—C326	121.2 (3)
Cl1—Cu1—P1	104.25 (3)	C324—C325—H325	119.4
P3—Cu1—P1	113.78 (3)	C326—C325—H325	119.4
Cl1—Cu1—P2	104.05 (3)	C325—C326—C321	119.7 (3)
P3—Cu1—P2	116.41 (3)	C325—C326—H326	120.2
P1—Cu1—P2	114.54 (3)	C321—C326—H326	120.2
P4—Cu2—Cl2	100.45 (3)	C332—C331—C336	117.9 (3)
P4—Cu2—P6	111.18 (3)	C332—C331—P3	124.4 (2)
Cl2—Cu2—P6	108.86 (2)	C336—C331—P3	117.3 (2)
P4—Cu2—P5	117.17 (2)	C331—C332—C333	119.9 (3)
Cl2—Cu2—P5	101.23 (2)	C331—C332—H332	120.0
P6—Cu2—P5	115.84 (3)	C333—C332—H332	120.0
C111—P1—C121	102.85 (12)	C334—C333—C332	121.6 (3)
C111—P1—C131	102.75 (12)	C334—C333—H333	119.2
C121—P1—C131	102.03 (12)	C332—C333—H333	119.2
C111—P1—Cu1	116.26 (9)	C335—C334—C333	118.9 (3)
C121—P1—Cu1	116.03 (9)	C335—C334—H334	120.5
C131—P1—Cu1	114.90 (8)	C333—C334—H334	120.5
C231—P2—C211	106.02 (11)	C334—C335—C336	120.5 (3)
C231—P2—C221	102.58 (11)	C334—C335—H335	119.8
C211—P2—C221	101.60 (11)	C336—C335—H335	119.8
C231—P2—Cu1	112.55 (8)	C331—C336—C335	121.2 (3)
C211—P2—Cu1	114.50 (8)	C331—C336—H336	119.4
C221—P2—Cu1	118.09 (8)	C335—C336—H336	119.4
C331—P3—C321	103.70 (13)	C412—C411—C416	118.8 (2)
C331—P3—C311	104.56 (12)	C412—C411—P4	119.24 (19)
C321—P3—C311	99.87 (12)	C416—C411—P4	122.0 (2)
C331—P3—Cu1	114.36 (9)	C413—C412—C411	120.8 (3)
C321—P3—Cu1	116.46 (9)	C413—C412—H412	119.6
C311—P3—Cu1	115.98 (9)	C411—C412—H412	119.6
C421—P4—C411	105.14 (11)	C412—C413—C414	120.3 (3)
C421—P4—C431	102.15 (12)	C412—C413—H413	119.9
C411—P4—C431	100.70 (12)	C414—C413—H413	119.9
C421—P4—Cu2	117.10 (8)	C413—C414—C415	119.4 (3)
C411—P4—Cu2	117.23 (9)	C413—C414—H414	120.3
C431—P4—Cu2	112.30 (8)	C415—C414—H414	120.3
C521—P5—C511	101.61 (11)	C416—C415—C414	120.2 (3)
C521—P5—C531	104.29 (12)	C416—C415—H415	119.9
C511—P5—C531	100.40 (11)	C414—C415—H415	119.9
C521—P5—Cu2	118.35 (8)	C415—C416—C411	120.5 (3)
C511—P5—Cu2	114.58 (8)	C415—C416—H416	119.7
C531—P5—Cu2	115.22 (9)	C411—C416—H416	119.7
C611—P6—C621	101.36 (11)	C422—C421—C426	117.8 (2)
C611—P6—C631	99.69 (12)	C422—C421—P4	125.3 (2)
C621—P6—C631	101.81 (11)	C426—C421—P4	116.86 (18)
C611—P6—Cu2	120.06 (8)	C421—C422—C423	120.7 (3)
C621—P6—Cu2	113.31 (8)	C421—C422—H422	119.7
C631—P6—Cu2	117.74 (8)	C423—C422—H422	119.7
C112—C111—C116	118.6 (2)	C424—C423—C422	120.3 (3)
C112—C111—P1	123.7 (2)	C424—C423—H423	119.9
C116—C111—P1	117.8 (2)	C422—C423—H423	119.9
C113—C112—C111	120.1 (3)	C425—C424—C423	120.0 (3)
C113—C112—H112	119.9	C425—C424—H424	120.0
C111—C112—H112	119.9	C423—C424—H424	120.0
C114—C113—C112	120.6 (3)	C424—C425—C426	119.6 (3)
C114—C113—H113	119.7	C424—C425—H425	120.2
C112—C113—H113	119.7	C426—C425—H425	120.2
C115—C114—C113	119.9 (3)	C425—C426—C421	121.5 (3)
C115—C114—H114	120.1	C425—C426—H426	119.2
C113—C114—H114	120.1	C421—C426—H426	119.2
C114—C115—C116	119.7 (3)	C436—C431—C432	119.6 (3)
C114—C115—H115	120.1	C436—C431—P4	123.5 (2)
C116—C115—H115	120.1	C432—C431—P4	116.8 (2)
C115—C116—C111	121.1 (3)	C433—C432—C431	119.7 (3)
C115—C116—H116	119.5	C433—C432—H432	120.2
C111—C116—H116	119.5	C431—C432—H432	120.2
C126—C121—C122	119.4 (2)	C434—C433—C432	120.3 (3)
C126—C121—P1	117.7 (2)	C434—C433—H433	119.8
C122—C121—P1	122.9 (2)	C432—C433—H433	119.8
C123—C122—C121	120.3 (3)	C433—C434—C435	119.9 (3)
C123—C122—H122	119.9	C433—C434—H434	120.1
C121—C122—H122	119.9	C435—C434—H434	120.1
C122—C123—C124	120.2 (3)	C436—C435—C434	120.3 (3)
C122—C123—H123	119.9	C436—C435—H435	119.8
C124—C123—H123	119.9	C434—C435—H435	119.8
C125—C124—C123	119.6 (3)	C435—C436—C431	120.2 (3)
C125—C124—H124	120.2	C435—C436—H436	119.9
C123—C124—H124	120.2	C431—C436—H436	119.9
C124—C125—C126	120.7 (3)	C512—C511—C516	118.7 (2)
C124—C125—H125	119.6	C512—C511—P5	122.89 (18)
C126—C125—H125	119.6	C516—C511—P5	118.37 (19)
C125—C126—C121	119.8 (3)	C513—C512—C511	120.2 (2)
C125—C126—H126	120.1	C513—C512—H512	119.9
C121—C126—H126	120.1	C511—C512—H512	119.9
C132—C131—C136	118.0 (3)	C512—C513—C514	120.5 (2)
C132—C131—P1	123.3 (2)	C512—C513—H513	119.7
C136—C131—P1	118.7 (2)	C514—C513—H513	119.7
C131—C132—C133	120.4 (3)	C513—C514—C515	119.8 (2)
C131—C132—H132	119.8	C513—C514—H514	120.1
C133—C132—H132	119.8	C515—C514—H514	120.1
C134—C133—C132	120.4 (3)	C516—C515—C514	120.1 (2)
C134—C133—H133	119.8	C516—C515—H515	119.9
C132—C133—H133	119.8	C514—C515—H515	119.9
C133—C134—C135	120.0 (3)	C515—C516—C511	120.6 (2)
C133—C134—H134	120.0	C515—C516—H516	119.7
C135—C134—H134	120.0	C511—C516—H516	119.7
C136—C135—C134	119.3 (3)	C526—C521—C522	118.1 (2)
C136—C135—H135	120.3	C526—C521—P5	124.2 (2)
C134—C135—H135	120.3	C522—C521—P5	117.67 (19)
C135—C136—C131	121.9 (3)	C521—C522—C523	121.5 (3)
C135—C136—H136	119.0	C521—C522—H522	119.3
C131—C136—H136	119.0	C523—C522—H522	119.3
C216—C211—C212	118.1 (2)	C524—C523—C522	119.5 (3)
C216—C211—P2	122.33 (19)	C524—C523—H523	120.2
C212—C211—P2	119.5 (2)	C522—C523—H523	120.2
C213—C212—C211	120.5 (3)	C523—C524—C525	119.8 (3)
C213—C212—H212	119.7	C523—C524—H524	120.1
C211—C212—H212	119.7	C525—C524—H524	120.1
C214—C213—C212	120.5 (3)	C524—C525—C526	120.2 (3)
C214—C213—H213	119.8	C524—C525—H525	119.9
C212—C213—H213	119.8	C526—C525—H525	119.9
C213—C214—C215	119.6 (3)	C521—C526—C525	120.8 (3)
C213—C214—H214	120.2	C521—C526—H526	119.6
C215—C214—H214	120.2	C525—C526—H526	119.6
C214—C215—C216	120.3 (3)	C532—C531—C536	117.8 (3)
C214—C215—H215	119.9	C532—C531—P5	122.7 (2)
C216—C215—H215	119.9	C536—C531—P5	119.5 (2)
C215—C216—C211	121.0 (3)	C533—C532—C531	121.1 (3)
C215—C216—H216	119.5	C533—C532—H532	119.5
C211—C216—H216	119.5	C531—C532—H532	119.5
C226—C221—C222	118.6 (2)	C534—C533—C532	120.7 (3)
C226—C221—P2	122.91 (19)	C534—C533—H533	119.6
C222—C221—P2	118.5 (2)	C532—C533—H533	119.6
C223—C222—C221	120.3 (3)	C535—C534—C533	119.1 (3)
C223—C222—H222	119.8	C535—C534—H534	120.4
C221—C222—H222	119.8	C533—C534—H534	120.4
C224—C223—C222	120.4 (3)	C531—C536—C535	120.7 (3)
C224—C223—H223	119.8	C531—C536—H536	119.6
C222—C223—H223	119.8	C535—C536—H536	119.6
C225—C224—C223	119.7 (3)	C534—C535—C536	120.6 (3)
C225—C224—H224	120.2	C534—C535—H535	119.7
C223—C224—H224	120.2	C536—C535—H535	119.7
C224—C225—C226	120.3 (3)	C612—C611—C616	118.5 (2)
C224—C225—H225	119.8	C612—C611—P6	118.6 (2)
C226—C225—H225	119.8	C616—C611—P6	122.9 (2)
C221—C226—C225	120.7 (3)	C613—C612—C611	120.7 (3)
C221—C226—H226	119.7	C613—C612—H612	119.7
C225—C226—H226	119.7	C611—C612—H612	119.7
C236—C231—C232	118.4 (2)	C612—C613—C614	120.2 (3)
C236—C231—P2	116.75 (19)	C612—C613—H613	119.9
C232—C231—P2	124.6 (2)	C614—C613—H613	119.9
C233—C232—C231	120.0 (3)	C615—C614—C613	119.8 (3)
C233—C232—H232	120.0	C615—C614—H614	120.1
C231—C232—H232	120.0	C613—C614—H614	120.1
C234—C233—C232	121.1 (3)	C614—C615—C616	120.5 (3)
C234—C233—H233	119.5	C614—C615—H615	119.8
C232—C233—H233	119.5	C616—C615—H615	119.8
C233—C234—C235	119.5 (3)	C615—C616—C611	120.2 (3)
C233—C234—H234	120.2	C615—C616—H616	119.9
C235—C234—H234	120.2	C611—C616—H616	119.9
C234—C235—C236	120.1 (3)	C626—C621—C622	118.8 (2)
C234—C235—H235	120.0	C626—C621—P6	123.7 (2)
C236—C235—H235	120.0	C622—C621—P6	117.46 (19)
C235—C236—C231	120.9 (3)	C623—C622—C621	120.5 (2)
C235—C236—H236	119.6	C623—C622—H622	119.7
C231—C236—H236	119.6	C621—C622—H622	119.7
C316—C311—C312	118.0 (3)	C624—C623—C622	120.1 (3)
C316—C311—P3	119.1 (2)	C624—C623—H623	120.0
C312—C311—P3	122.9 (2)	C622—C623—H623	120.0
C311—C312—C313	120.5 (3)	C623—C624—C625	119.6 (3)
C311—C312—H312	119.8	C623—C624—H624	120.2
C313—C312—H312	119.8	C625—C624—H624	120.2
C314—C313—C312	120.8 (3)	C626—C625—C624	120.5 (3)
C314—C313—H313	119.6	C626—C625—H625	119.8
C312—C313—H313	119.6	C624—C625—H625	119.8
C315—C314—C313	118.9 (3)	C625—C626—C621	120.4 (3)
C315—C314—H314	120.5	C625—C626—H626	119.8
C313—C314—H314	120.5	C621—C626—H626	119.8
C314—C315—C316	120.2 (3)	C632—C631—C636	118.7 (2)
C314—C315—H315	119.9	C632—C631—P6	118.89 (19)
C316—C315—H315	119.9	C636—C631—P6	122.3 (2)
C311—C316—C315	121.7 (3)	C631—C632—C633	119.8 (3)
C311—C316—H316	119.2	C631—C632—H632	120.1
C315—C316—H316	119.2	C633—C632—H632	120.1
C322—C321—C326	119.1 (3)	C634—C633—C632	121.1 (3)
C322—C321—P3	123.5 (2)	C634—C633—H633	119.5
C326—C321—P3	117.4 (2)	C632—C633—H633	119.5
C321—C322—C323	120.3 (3)	C635—C634—C633	119.3 (3)
C321—C322—H322	119.8	C635—C634—H634	120.3
C323—C322—H322	119.8	C633—C634—H634	120.3
C324—C323—C322	120.3 (3)	C634—C635—C636	120.6 (3)
C324—C323—H323	119.8	C634—C635—H635	119.7
C322—C323—H323	119.8	C636—C635—H635	119.7
C325—C324—C323	119.3 (3)	C635—C636—C631	120.5 (3)
C325—C324—H324	120.3	C635—C636—H636	119.8
C323—C324—H324	120.3	C631—C636—H636	119.8
Cl1—Cu1—P1—C111	179.32 (10)	C311—P3—C321—C322	101.1 (2)
P3—Cu1—P1—C111	69.71 (10)	Cu1—P3—C321—C322	−133.2 (2)
P2—Cu1—P1—C111	−67.64 (10)	C331—P3—C321—C326	174.5 (2)
Cl1—Cu1—P1—C121	−59.55 (10)	C311—P3—C321—C326	−77.8 (2)
P3—Cu1—P1—C121	−169.16 (9)	Cu1—P3—C321—C326	47.9 (2)
P2—Cu1—P1—C121	53.49 (10)	C326—C321—C322—C323	1.1 (4)
Cl1—Cu1—P1—C131	59.29 (10)	P3—C321—C322—C323	−177.8 (2)
P3—Cu1—P1—C131	−50.31 (10)	C321—C322—C323—C324	0.1 (5)
P2—Cu1—P1—C131	172.33 (9)	C322—C323—C324—C325	−0.7 (5)
Cl1—Cu1—P2—C231	−168.27 (9)	C323—C324—C325—C326	0.1 (5)
P3—Cu1—P2—C231	−57.61 (10)	C324—C325—C326—C321	1.1 (5)
P1—Cu1—P2—C231	78.58 (9)	C322—C321—C326—C325	−1.7 (4)
Cl1—Cu1—P2—C211	70.57 (9)	P3—C321—C326—C325	177.3 (2)
P3—Cu1—P2—C211	−178.78 (9)	C321—P3—C331—C332	106.3 (3)
P1—Cu1—P2—C211	−42.58 (9)	C311—P3—C331—C332	2.1 (3)
Cl1—Cu1—P2—C221	−49.01 (10)	Cu1—P3—C331—C332	−125.8 (3)
P3—Cu1—P2—C221	61.65 (10)	C321—P3—C331—C336	−81.3 (2)
P1—Cu1—P2—C221	−162.16 (9)	C311—P3—C331—C336	174.5 (2)
Cl1—Cu1—P3—C331	176.61 (10)	Cu1—P3—C331—C336	46.6 (3)
P1—Cu1—P3—C331	−72.07 (10)	C336—C331—C332—C333	0.3 (6)
P2—Cu1—P3—C331	64.45 (10)	P3—C331—C332—C333	172.7 (3)
Cl1—Cu1—P3—C321	−62.34 (10)	C331—C332—C333—C334	0.0 (7)
P1—Cu1—P3—C321	48.98 (10)	C332—C333—C334—C335	0.1 (7)
P2—Cu1—P3—C321	−174.50 (9)	C333—C334—C335—C336	−0.4 (6)
Cl1—Cu1—P3—C311	54.75 (10)	C332—C331—C336—C335	−0.6 (5)
P1—Cu1—P3—C311	166.07 (10)	P3—C331—C336—C335	−173.5 (3)
P2—Cu1—P3—C311	−57.41 (10)	C334—C335—C336—C331	0.6 (5)
Cl2—Cu2—P4—C421	−173.13 (9)	C421—P4—C411—C412	114.3 (2)
P6—Cu2—P4—C421	71.78 (9)	C431—P4—C411—C412	−139.8 (2)
P5—Cu2—P4—C421	−64.63 (10)	Cu2—P4—C411—C412	−17.7 (2)
Cl2—Cu2—P4—C411	−46.75 (9)	C421—P4—C411—C416	−66.8 (2)
P6—Cu2—P4—C411	−161.84 (9)	C431—P4—C411—C416	39.0 (2)
P5—Cu2—P4—C411	61.75 (9)	Cu2—P4—C411—C416	161.13 (18)
Cl2—Cu2—P4—C431	69.14 (10)	C416—C411—C412—C413	1.0 (4)
P6—Cu2—P4—C431	−45.95 (10)	P4—C411—C412—C413	179.9 (2)
P5—Cu2—P4—C431	177.64 (10)	C411—C412—C413—C414	0.0 (4)
P4—Cu2—P5—C521	60.44 (10)	C412—C413—C414—C415	−0.9 (4)
Cl2—Cu2—P5—C521	168.50 (9)	C413—C414—C415—C416	0.8 (4)
P6—Cu2—P5—C521	−73.97 (9)	C414—C415—C416—C411	0.2 (4)
P4—Cu2—P5—C511	−59.44 (9)	C412—C411—C416—C415	−1.1 (4)
Cl2—Cu2—P5—C511	48.61 (9)	P4—C411—C416—C415	−180.0 (2)
P6—Cu2—P5—C511	166.15 (9)	C411—P4—C421—C422	4.0 (3)
P4—Cu2—P5—C531	−175.22 (9)	C431—P4—C421—C422	−100.7 (2)
Cl2—Cu2—P5—C531	−67.17 (9)	Cu2—P4—C421—C422	136.2 (2)
P6—Cu2—P5—C531	50.37 (9)	C411—P4—C421—C426	−173.7 (2)
P4—Cu2—P6—C611	5.38 (10)	C431—P4—C421—C426	81.5 (2)
Cl2—Cu2—P6—C611	−104.37 (10)	Cu2—P4—C421—C426	−41.6 (2)
P5—Cu2—P6—C611	142.41 (10)	C426—C421—C422—C423	0.0 (4)
P4—Cu2—P6—C621	−114.44 (9)	P4—C421—C422—C423	−177.8 (2)
Cl2—Cu2—P6—C621	135.81 (9)	C421—C422—C423—C424	−1.4 (4)
P5—Cu2—P6—C621	22.60 (9)	C422—C423—C424—C425	0.8 (4)
P4—Cu2—P6—C631	126.99 (10)	C423—C424—C425—C426	1.4 (5)
Cl2—Cu2—P6—C631	17.23 (10)	C424—C425—C426—C421	−2.9 (5)
P5—Cu2—P6—C631	−95.98 (10)	C422—C421—C426—C425	2.2 (4)
C121—P1—C111—C112	79.7 (2)	P4—C421—C426—C425	−179.9 (2)
C131—P1—C111—C112	−26.0 (3)	C421—P4—C431—C436	−8.4 (3)
Cu1—P1—C111—C112	−152.4 (2)	C411—P4—C431—C436	−116.6 (2)
C121—P1—C111—C116	−98.7 (2)	Cu2—P4—C431—C436	117.9 (2)
C131—P1—C111—C116	155.6 (2)	C421—P4—C431—C432	172.0 (2)
Cu1—P1—C111—C116	29.3 (2)	C411—P4—C431—C432	63.8 (2)
C116—C111—C112—C113	−0.6 (4)	Cu2—P4—C431—C432	−61.7 (2)
P1—C111—C112—C113	−179.0 (2)	C436—C431—C432—C433	0.5 (4)
C111—C112—C113—C114	1.2 (5)	P4—C431—C432—C433	−180.0 (2)
C112—C113—C114—C115	−1.0 (5)	C431—C432—C433—C434	−0.8 (5)
C113—C114—C115—C116	0.2 (5)	C432—C433—C434—C435	0.1 (5)
C114—C115—C116—C111	0.4 (5)	C433—C434—C435—C436	0.8 (5)
C112—C111—C116—C115	−0.2 (4)	C434—C435—C436—C431	−1.0 (5)
P1—C111—C116—C115	178.3 (2)	C432—C431—C436—C435	0.4 (4)
C111—P1—C121—C126	171.2 (2)	P4—C431—C436—C435	−179.1 (2)
C131—P1—C121—C126	−82.5 (2)	C521—P5—C511—C512	−12.3 (2)
Cu1—P1—C121—C126	43.2 (2)	C531—P5—C511—C512	−119.4 (2)
C111—P1—C121—C122	−9.4 (3)	Cu2—P5—C511—C512	116.5 (2)
C131—P1—C121—C122	96.9 (2)	C521—P5—C511—C516	167.6 (2)
Cu1—P1—C121—C122	−137.4 (2)	C531—P5—C511—C516	60.5 (2)
C126—C121—C122—C123	0.5 (4)	Cu2—P5—C511—C516	−63.6 (2)
P1—C121—C122—C123	−178.9 (2)	C516—C511—C512—C513	0.9 (4)
C121—C122—C123—C124	1.4 (4)	P5—C511—C512—C513	−179.2 (2)
C122—C123—C124—C125	−1.7 (5)	C511—C512—C513—C514	−1.6 (4)
C123—C124—C125—C126	0.2 (5)	C512—C513—C514—C515	1.0 (4)
C124—C125—C126—C121	1.7 (5)	C513—C514—C515—C516	0.4 (4)
C122—C121—C126—C125	−2.0 (4)	C514—C515—C516—C511	−1.0 (4)
P1—C121—C126—C125	177.4 (2)	C512—C511—C516—C515	0.4 (4)
C111—P1—C131—C132	122.4 (2)	P5—C511—C516—C515	−179.5 (2)
C121—P1—C131—C132	16.0 (3)	C511—P5—C521—C526	−95.8 (2)
Cu1—P1—C131—C132	−110.4 (2)	C531—P5—C521—C526	8.3 (3)
C111—P1—C131—C136	−60.1 (2)	Cu2—P5—C521—C526	137.8 (2)
C121—P1—C131—C136	−166.5 (2)	C511—P5—C521—C522	82.7 (2)
Cu1—P1—C131—C136	67.1 (2)	C531—P5—C521—C522	−173.3 (2)
C136—C131—C132—C133	−0.2 (4)	Cu2—P5—C521—C522	−43.7 (2)
P1—C131—C132—C133	177.3 (2)	C526—C521—C522—C523	1.8 (4)
C131—C132—C133—C134	−0.8 (5)	P5—C521—C522—C523	−176.8 (2)
C132—C133—C134—C135	1.9 (5)	C521—C522—C523—C524	−1.1 (4)
C133—C134—C135—C136	−1.8 (5)	C522—C523—C524—C525	−0.4 (4)
C134—C135—C136—C131	0.8 (4)	C523—C524—C525—C526	1.0 (4)
C132—C131—C136—C135	0.2 (4)	C522—C521—C526—C525	−1.1 (4)
P1—C131—C136—C135	−177.4 (2)	P5—C521—C526—C525	177.4 (2)
C231—P2—C211—C216	120.5 (2)	C524—C525—C526—C521	−0.3 (4)
C221—P2—C211—C216	13.7 (2)	C521—P5—C531—C532	−83.1 (3)
Cu1—P2—C211—C216	−114.8 (2)	C511—P5—C531—C532	21.8 (3)
C231—P2—C211—C212	−62.9 (2)	Cu2—P5—C531—C532	145.5 (2)
C221—P2—C211—C212	−169.7 (2)	C521—P5—C531—C536	98.8 (2)
Cu1—P2—C211—C212	61.8 (2)	C511—P5—C531—C536	−156.2 (2)
C216—C211—C212—C213	−2.4 (4)	Cu2—P5—C531—C536	−32.6 (2)
P2—C211—C212—C213	−179.2 (2)	C536—C531—C532—C533	1.1 (5)
C211—C212—C213—C214	1.7 (4)	P5—C531—C532—C533	−177.0 (3)
C212—C213—C214—C215	0.3 (4)	C531—C532—C533—C534	−1.6 (6)
C213—C214—C215—C216	−1.5 (4)	C532—C533—C534—C535	1.4 (6)
C214—C215—C216—C211	0.8 (4)	C532—C531—C536—C535	−0.5 (4)
C212—C211—C216—C215	1.2 (4)	P5—C531—C536—C535	177.7 (2)
P2—C211—C216—C215	177.8 (2)	C533—C534—C535—C536	−0.9 (5)
C231—P2—C221—C226	−10.0 (3)	C531—C536—C535—C534	0.4 (5)
C211—P2—C221—C226	99.6 (2)	C621—P6—C611—C612	−157.4 (2)
Cu1—P2—C221—C226	−134.3 (2)	C631—P6—C611—C612	−53.1 (2)
C231—P2—C221—C222	169.2 (2)	Cu2—P6—C611—C612	77.0 (2)
C211—P2—C221—C222	−81.2 (2)	C621—P6—C611—C616	21.0 (2)
Cu1—P2—C221—C222	44.9 (2)	C631—P6—C611—C616	125.2 (2)
C226—C221—C222—C223	−0.9 (4)	Cu2—P6—C611—C616	−104.6 (2)
P2—C221—C222—C223	179.9 (2)	C616—C611—C612—C613	−3.7 (4)
C221—C222—C223—C224	1.5 (4)	P6—C611—C612—C613	174.7 (2)
C222—C223—C224—C225	−0.8 (5)	C611—C612—C613—C614	2.5 (4)
C223—C224—C225—C226	−0.4 (5)	C612—C613—C614—C615	0.7 (5)
C222—C221—C226—C225	−0.4 (4)	C613—C614—C615—C616	−2.6 (5)
P2—C221—C226—C225	178.8 (2)	C614—C615—C616—C611	1.2 (4)
C224—C225—C226—C221	1.1 (5)	C612—C611—C616—C615	1.9 (4)
C211—P2—C231—C236	−174.5 (2)	P6—C611—C616—C615	−176.5 (2)
C221—P2—C231—C236	−68.4 (2)	C611—P6—C621—C626	79.3 (2)
Cu1—P2—C231—C236	59.6 (2)	C631—P6—C621—C626	−23.3 (3)
C211—P2—C231—C232	10.3 (3)	Cu2—P6—C621—C626	−150.7 (2)
C221—P2—C231—C232	116.5 (2)	C611—P6—C621—C622	−102.1 (2)
Cu1—P2—C231—C232	−115.6 (2)	C631—P6—C621—C622	155.3 (2)
C236—C231—C232—C233	−1.6 (4)	Cu2—P6—C621—C622	27.9 (2)
P2—C231—C232—C233	173.5 (2)	C626—C621—C622—C623	1.6 (4)
C231—C232—C233—C234	1.0 (4)	P6—C621—C622—C623	−177.1 (2)
C232—C233—C234—C235	1.2 (5)	C621—C622—C623—C624	−2.5 (4)
C233—C234—C235—C236	−2.6 (5)	C622—C623—C624—C625	2.0 (4)
C234—C235—C236—C231	2.0 (4)	C623—C624—C625—C626	−0.6 (5)
C232—C231—C236—C235	0.2 (4)	C624—C625—C626—C621	−0.2 (5)
P2—C231—C236—C235	−175.3 (2)	C622—C621—C626—C625	−0.3 (4)
C331—P3—C311—C316	−100.9 (3)	P6—C621—C626—C625	178.3 (2)
C321—P3—C311—C316	152.0 (2)	C611—P6—C631—C632	154.0 (2)
Cu1—P3—C311—C316	26.0 (3)	C621—P6—C631—C632	−102.1 (2)
C331—P3—C311—C312	79.7 (3)	Cu2—P6—C631—C632	22.4 (2)
C321—P3—C311—C312	−27.4 (3)	C611—P6—C631—C636	−29.5 (2)
Cu1—P3—C311—C312	−153.4 (3)	C621—P6—C631—C636	74.4 (2)
C316—C311—C312—C313	0.3 (6)	Cu2—P6—C631—C636	−161.09 (19)
P3—C311—C312—C313	179.8 (3)	C636—C631—C632—C633	−2.1 (4)
C311—C312—C313—C314	−0.9 (7)	P6—C631—C632—C633	174.6 (2)
C312—C313—C314—C315	1.4 (7)	C631—C632—C633—C634	0.6 (5)
C313—C314—C315—C316	−1.2 (6)	C632—C633—C634—C635	0.8 (5)
C312—C311—C316—C315	−0.2 (5)	C633—C634—C635—C636	−0.5 (5)
P3—C311—C316—C315	−179.7 (3)	C634—C635—C636—C631	−1.0 (4)
C314—C315—C316—C311	0.6 (5)	C632—C631—C636—C635	2.3 (4)
C331—P3—C321—C322	−6.7 (3)	P6—C631—C636—C635	−174.2 (2)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C115—H115···Cl1^i	0.95	2.61	3.469 (3)	151
C214—H214···Cl1^ii	0.95	2.80	3.619 (3)	146
C126—H126···Cl1	0.95	2.79	3.667 (3)	154
C222—H222···Cl1	0.95	2.75	3.589 (3)	148
C326—H326···Cl1	0.95	2.80	3.659 (3)	151
C432—H432···Cl2	0.95	2.93	3.704 (3)	139
C514—H514···Cl2^iii	0.95	2.91	3.619 (3)	132
C516—H516···Cl2	0.95	2.88	3.535 (3)	127
C523—H523···Cl2^i	0.95	2.84	3.764 (3)	164
C632—H632···Cl2	0.95	2.77	3.505 (4)	135
C125—H125···Cg21^iv	0.95	2.80	3.668 (3)	152
C412—H412···Cg51	0.95	2.89	3.648 (3)	138
C415—H415···Cg23^v	0.95	2.93	3.748 (3)	146
C624—H624···Cg13^vi	0.95	2.70	3.579 (3)	154

Symmetry codes: (i) x, y+1, z; (ii) −x+3/2, y+1/2, −z+1/2; (iii) −x+1/2, −y+1/2, −z; (iv) −x+3/2, y−1/2, −z+1/2; (v) −x+1, y, −z+1/2; (vi) −x+1, −y+1, −z.