Chelation of 2,6-Bis(hydroxymethyl)pyridine in cis-Dichloro(triphenylphosphine-P)[2-(oxymethylene-O)-6-(hydroxymethyl)pyridine-N]oxorhenium(V)–Water (2/1)

Gerber, T.I.A.; Perils, J.; Du Preez, J.G.H.; Bandoli, G.

doi:10.1107/S0108270196013030

Chelation of 2,6-Bis(hydroxymethyl)pyridine in cis-Dichloro(triphenylphosphine-P)[2-(oxymethylene-O)-6-(hydroxymethyl)pyridine-N]oxorhenium(V)-Water (2/1)

T. I. A. Gerber, J. Perils, J. G. H. Du Preez and G. Bandoli

The potentially terdentate dianionic ligand pyridine-2,6-bis(methanol) (H₂L) acts as a didentate monoanionic N,O^--donor in the title compound, dichloro(oxo)[pyridine-2,6-bis(methanolato)(1-)-N,O](triphenylphosphine-P)rhenium(V)-water (2/1), 2[ReCl₂O{C₅H₃N(CH₂O)(CH₂OH)}(PPh₃)].H₂O. The asymmetric unit contains two monomeric neutral independent and well separated [ReOCl₂(HL)(PPh₃)] moieties per water molecule.

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Chelation of 2,6-Bis(hydroxymethyl)pyridine in cis-Dichloro(triphenylphosphine-P)[2-(oxymethylene-O)-6-(hydroxymethyl)pyridine-N]oxorhenium(V)-Water (2/1)

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