9,12-Dibromo-3,3-bis(triphenylphosphine-P)-1,2-dicarba-3-hydrido-3-rhoda-closo-dodecaborane–Dichloromethane (1/1)

McEneaney, P.A.; Spalding, T.R.; Meehan, P.R.; Ferguson, G.

doi:10.1107/S0108270197003715

9,12-Dibromo-3,3-bis(triphenylphosphine-P)-1,2-dicarba-3-hydrido-3-rhoda-closo-dodecaborane-Dichloromethane (1/1)

P. A. McEneaney, T. R. Spalding, P. R. Meehan and G. Ferguson

In the title complex, [RhH(C₂B₉H₉Br₂)(C₁₈H₁₅P)₂].CH₂Cl₂, the rhodacarborane molecule adopts a closed icosahedral RhC₂B₉-cage geometry with adjacent Rh and C atoms. Principal distances include, Rh-P 2.345 (2) and 2.276 (2) Å, Rh-C 2.289 (8) and 2.241 (8) Å, B-Br 1.974 (9) and 1.980 (9)Å

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9,12-Dibromo-3,3-bis(triphenylphosphine-P)-1,2-dicarba-3-hydrido-3-rhoda-closo-dodecaborane-Dichloromethane (1/1)

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	Crystallographic Information File (CIF) Contains datablocks global, 96962
	Structure factor file (CIF format) Contains datablock AB-1472