An Additional Isomer of the Neutral Dicarbollide Analogue of Ferrocene [Fe{C2B9H10(SMe2)}2]

Plesek, J.; Stíbr, B.; Cooke, P.A.; Kennedy, J.D.; McGrath, T.D.; Thornton-Pett, M.

doi:10.1107/S0108270197012742

An Additional Isomer of the Neutral Dicarbollide Analogue of Ferrocene [Fe{C₂B₉H₁₀(SMe₂)}₂]

J. Plesek, B. Stíbr, P. A. Cooke, J. D. Kennedy, T. D. McGrath and M. Thornton-Pett

The title compound, 8,8'-bis(dimethyl sulfido)-3,3'-ferra-commo-bis[3,1,2-ferradicarba-closo- dodecaborane(11)], has the expected overall geometry in which two {FeC₂B₉} icosahedra are linked via a common Fe atom; additionally, the whole cluster has crystallographically imposed C₂ symmetry. The structure is compared with those of its geometric isomers and of some related compounds.

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An Additional Isomer of the Neutral Dicarbollide Analogue of Ferrocene [Fe{C₂B₉H₁₀(SMe₂)}₂]

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	Crystallographic Information File (CIF) Contains datablocks bs8, global
	Structure factor file (CIF format) Contains datablock bs8