9-(Triphenylphosphine-P)-arachno-6-thiadecaborane(11) Trichloromethane (1/1)

Cooke, P.A.; Holub, J.; Kennedy, J.D.; Štíbr, B.; Thornton-Pett, M.

doi:10.1107/S0108270197012389

9-(Triphenylphosphine-P)-arachno-6-thiadecaborane(11) Trichloromethane (1/1)

P. A. Cooke, J. Holub, J. D. Kennedy, B. Stíbr and M. Thornton-Pett

The title compound, C₁₈H₂₆B₉PS.CHCl₃ is shown to have an arachno ten-vertex {6-SB₉H₁₁} cluster structure with a PPh₃ ligand in the exo-9-position. The two bridging H atoms occupy asymmetric positions [average B-H_bridge values 1.21 (4) and 1.35 (4) Å] displaced away from the S atom.

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9-(Triphenylphosphine-P)-arachno-6-thiadecaborane(11) Trichloromethane (1/1)

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