(1,3-Butadiynyl-C1)(η5-cyclopentadienyl)(triphenylphosphine-P)nickel(II)

Gallagher, J.F.; Butler, P.; Manning, A.R.

doi:10.1107/S0108270197016478

(1,3-Butadiynyl-C¹)(η⁵-cyclopentadienyl)(triphenylphosphine-P)nickel(II)

J. F. Gallagher, P. Butler and A. R. Manning

The title compound, [Ni(Cp)(PPh₃)(C [triple bond]

C—C

C—H)] or [Ni(C₄H)(C₅H₅)(C₁₈H₁₅P)], has metal–ligand dimensions of Ni—P 2.1410 (4), Ni—C 1.8383 (15) Å and P—Ni—C 93.47 (5)°, and principal alkyne dimensions of C [triple bond]

C 1.212 (2) and 1.187 (3) Å, and C [triple bond]

C—C 177.94 (19) and 179.5 (2)°. Intra- and intermolecular C—H

C interactions are present with the shortest C

C distance being 3.198 Å.

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(1,3-Butadiynyl-C¹)(η⁵-cyclopentadienyl)(triphenylphosphine-P)nickel(II)

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	Crystallographic Information File (CIF) Contains datablocks global, I
	Structure factor file (CIF format) Contains datablock 9754psis