Λ-Tris(1,10-phenanthroline-N,N')ruthenium(II) Bis(hexafluorophosphate)–Acetonitrile–Diethyl Ether (1/1/0.5)

Maloney, D.J.; MacDonnell, F.M.

doi:10.1107/S0108270197001091

Λ-Tris(1,10-phenanthroline-N,N')ruthenium(II) Bis(hexafluorophosphate)–Acetonitrile–Diethyl Ether (1/1/0.5)

The title compound was obtained from a solution of the resolved compound as an acetonitrile 0.5 diethyl ether solvate, [Ru(C₁₂H₈N₂)₃](PF₆)₂.CH₃CN.0.5(CH₃CH₂)₂O. The cations possess idealized D₃ symmetry with three bidentate phenanthroline ligands arranged about each Ru^II center in a propeller-like fashion. Assignment of the appropriate polar space group corroborates the absolute configuration of the compound with chemical and circular dichroism data.

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Λ-Tris(1,10-phenanthroline-N,N')ruthenium(II) Bis(hexafluorophosphate)–Acetonitrile–Diethyl Ether (1/1/0.5)

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	Crystallographic Information File (CIF) Contains datablocks phen, global
	Structure factor file (CIF format) Contains datablock phen
	Portable Document Format (PDF) file Supplementary material