Dichlorobis[1-methyl-3-(prop-2-enyl)imidazole-2(3H)-thione-S]zinc(II)

Williams, D.J.; Ly, T.A.; Mudge, J.W.; Pennington, W.T.; Schimek, G.L.

doi:10.1107/S0108270196013984

Dichlorobis[1-methyl-3-(prop-2-enyl)imidazole-2(3H)-thione-S]zinc(II)

D. J. Williams, T. A. Ly, J. W. Mudge, W. T. Pennington and G. L. Schimek

The crystal structure of the title compound, [ZnCl₂(C₇H₁₀N₂S)₂], shows a discrete molecular structure with tetrahedral geometry around the zinc ion. The mean Zn-Cl and Zn-S distances are 2.259 (4) and 2.372 (4) Å, respectively. Bond angles around the zinc ion range from 102.8 (1) to 113.7 (1)°. Ring distances and angles in the ligand compare favorably with literature values of analogous compounds, and the mean C-S bond distance of 1.71 (1) Å is close to the average distance of 1.72 Å observed for several dialkylimidazolethione complexes of main group and transition metal halides.

Read article Similar articles

Subscribe to Acta Crystallographica Section C: Structural Chemistry

The full text of this article is available to subscribers to the journal.

Information on subscribing
Sample issue
Purchase subscription
Reduced-price subscriptions
If you have already subscribed, you may need to register

If you have already registered and are using a computer listed in your registration details, please email support@iucr.org for assistance.

Buy online

You may purchase this article in PDF and/or HTML formats. For purchasers in the European Community who do not have a VAT number, VAT will be added at the local rate. Payments to the IUCr are handled by WorldPay, who will accept payment by credit card in several currencies. To purchase the article, please complete the form below (fields marked * are required), and then click on `Continue'.

E-mail address*
Repeat e-mail address* (for error checking)

Format*	PDF (US $40)
In order for VAT to be shown for your country javascript needs to be enabled.

VAT number (non-UK EC countries only)
Country*

Terms and conditions of use
Contact us

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Text
		Plain Text

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Text
		Plain Text

Search IUCr Journals		doi		Advanced search
Author		volume	page

Dichlorobis[1-methyl-3-(prop-2-enyl)imidazole-2(3H)-thione-S]zinc(II)

Supporting information

Subscribe to Acta Crystallographica Section C: Structural Chemistry

Buy online

	Crystallographic Information File (CIF) Contains datablock BD0437
	Structure factor file (CIF format) Supplementary material