The Secondary Explosive Tetraammine-cis-bis(5-nitro-2H-tetrazolato-N2)cobalt(III) Perchlorate at 293 and 213 K

Morosin, B.; Dunn, R.G.; Assink, R.; Massis, T.M.; Fronabarger, J.; Duesler, E.N.

doi:10.1107/S0108270197007634

The Secondary Explosive Tetraammine-cis-bis(5-nitro-2H-tetrazolato-N²)cobalt(III) Perchlorate at 293 and 213 K

B. Morosin, R. G. Dunn, R. Assink, T. M. Massis, J. Fronabarger and E. N. Duesler

For the title compound, (OC-6-22)-[Co(CN₅O₂)₂(NH₃)₄]ClO₄, the structure determination confirms the cis relationship of the two ring ligands deduced from NMR and shows that these ligands involve N-2 bonding to the Co atom. The accompanying low temperature study suggests several O atoms of the ClO₄^- ion are slightly disordered rather than having large thermal displacements.

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The Secondary Explosive Tetraammine-cis-bis(5-nitro-2H-tetrazolato-N²)cobalt(III) Perchlorate at 293 and 213 K

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	Crystallographic Information File (CIF) Contains datablocks 1, 2, default
	Structure factor file (CIF format) Contains datablock 1
	Structure factor file (CIF format) Contains datablock 2