Dibromobis(η5-pentamethylcyclopentadienyl)thorium(IV)

Rabinovich, D.; Schimek, G.L.; Pennington, W.T.; Nielsen, J.B.; Abney, K.D.

doi:10.1107/S0108270197010056

Dibromobis(η⁵-pentamethylcyclopentadienyl)thorium(IV)

D. Rabinovich, G. L. Schimek, W. T. Pennington, J. B. Nielsen and K. D. Abney

The title compound, [ThBr₂(η⁵-C₁₀H₁₅)₂] or Cp^*₂ThBr₂ [Cp^* = η⁵-C₅(CH₃)₅], presents a pseudo-tetrahedral `bent-metallocene' geometry in the solid state, with the Th atom binding to two pentamethylcyclopentadienyl ligands and two bromide ligands. The Th–Br bond length is 2.800 (2) Å, whereas the Th–C distances are in the range 2.77 (1)–2.782 (9) Å.

Read article Similar articles

Subscribe to Acta Crystallographica Section C: Structural Chemistry

The full text of this article is available to subscribers to the journal.

Information on subscribing
Sample issue
Purchase subscription
Reduced-price subscriptions
If you have already subscribed, you may need to register

If you have already registered and are using a computer listed in your registration details, please email [email protected] for assistance.

Buy online

You may purchase this article in PDF and/or HTML formats. For purchasers in the European Community who do not have a VAT number, VAT will be added at the local rate. Payments to the IUCr are handled by WorldPay, who will accept payment by credit card in several currencies. To purchase the article, please complete the form below (fields marked * are required), and then click on `Continue'.

E-mail address*
Repeat e-mail address* (for error checking)

Format*	PDF (US $40)
In order for VAT to be shown for your country javascript needs to be enabled.

VAT number (non-UK EC countries only)
Country*

Terms and conditions of use
Contact us

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Text
		Plain Text

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Text
		Plain Text

Search IUCr Journals		doi		Advanced search
Author		volume	page

Dibromobis(η⁵-pentamethylcyclopentadienyl)thorium(IV)

Supporting information

Subscribe to Acta Crystallographica Section C: Structural Chemistry

Buy online

	Crystallographic Information File (CIF) Contains datablock BD0618
	Structure factor file (CIF format) Supplementary material