Bis(η6-toluene)thallium(I) 7,8,9,10,11,12-Hexabromo-closo-1-carbadodecaborate: a Halocarborane-Bridged Dimer with Heavy Metal–Arene Interactions

Mathur, R.S.; Drovetskaya, T.; Reed, C.A.

doi:10.1107/S010827019700320X

Bis(η⁶-toluene)thallium(I) 7,8,9,10,11,12-Hexabromo-closo-1-carbadodecaborate: a Halocarborane-Bridged Dimer with Heavy Metal–Arene Interactions

R. S. Mathur, T. Drovetskaya and C. A. Reed

The title compound, [Tl(C₇H₈)₂](CB₁₁H₆Br₆), shows Tl⁺ having η⁶ interactions with two toluene molecules and dative interactions with two Br atoms of one carborane anion and one Br atom of a neighboring anion.

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Bis(η⁶-toluene)thallium(I) 7,8,9,10,11,12-Hexabromo-closo-1-carbadodecaborate: a Halocarborane-Bridged Dimer with Heavy Metal–Arene Interactions

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	Crystallographic Information File (CIF) Contains datablocks global, I
	Structure factor file (CIF format) Contains datablock ra2