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In racemic (α-ferrocenylphenacyl)triphenylphosphonium iodide,[Fe(C
5H
5)(C
31H
25OP)], the cations are involved in C-H

I
− interactions with short C

I distances of 3.836 (7), 3.932 (7) and 3.995 (7) Å.
Supporting information
 | Crystallographic Information File (CIF) Contains datablocks global, I |
 | Structure factor file (CIF format) Contains datablock 95103 |
CCDC reference: 126926

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