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organic compounds
The stereochemistry of 2,2′-diaminodiphenyl disulfide hemihydrate, C12H12N2S2.0.5H2O, differs significantly from that of the corresponding anhydrous compound. The conformational difference is a consequence of the O—H
N and N—HO intermolecular hydrogen bonding between the C12H12N2S2 and water molecules. The molecule is characterized by a skewed central moiety with a C—S—S—C torsion angle of 75.2 (1)°.
N and N—HO intermolecular hydrogen bonding between the C12H12N2S2 and water molecules. The molecule is characterized by a skewed central moiety with a C—S—S—C torsion angle of 75.2 (1)°.
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