An Exopolyhedral Cyclized Platinaundecaborane: [(PPh3)(PhCOS)PtB10H9(PPh3)].1.5CHCl3

Hu, C.-H.; Dou, J.-M.; Yao, H.-J.; Wei, J.-D.; Jin, R.-S.; Sun, J.; Zheng, P.-J.

doi:10.1107/S0108270198010452

An Exopolyhedral Cyclized Platinaundecaborane: [(PPh₃)(PhCOS)PtB₁₀H₉(PPh₃)].1.5CHCl₃

C.-H. Hu, J.-M. Dou, H.-J. Yao, J.-D. Wei, R.-S. Jin, J. Sun and P.-J. Zheng

The title platinaundecaborane species, 7,11-(μ-thiobenzoate-S:O)-7,10-bis(triphenylphosphine-P)-8:9-μH-7-platina-nido-undecaborane-chloroform (1/1.5), has a nido-type {PtB₁₀} cage with a five-membered Pt–S–C–O–B ring. Of the two PPh₃ ligands, one is bound to the Pt atom and the other to a B atom.

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An Exopolyhedral Cyclized Platinaundecaborane: [(PPh₃)(PhCOS)PtB₁₀H₉(PPh₃)].1.5CHCl₃

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	Crystallographic Information File (CIF) Contains datablocks pts3, I
	Structure factor file (CIF format) Contains datablock pts3