K2Mn(VO3)4, a New Three-Dimensional Potassium Manganese(II) Polyvanadate

Liao, J.-H.; Sigala, C.; Guyomard, D.; Piffard, Y.

doi:10.1107/S0108270195012509

K₂Mn(VO₃)₄, a New Three-Dimensional Potassium Manganese(II) Polyvanadate

J.-H. Liao, C. Sigala, D. Guyomard and Y. Piffard

The structure of potassium manganese(II) polyvanadate, K₂Mn(VO₃)₄, is comprised of VO₄ tetrahedra and MnO₆ octahedra. Parallel zigzag polyvanadate (VO₃)_n^n- chains of corner-sharing VO₄ tetrahedra are cross-linked by separate MnO₆ octahedra to form a three-dimensional structure with K⁺ cations situated in void space.

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K₂Mn(VO₃)₄, a New Three-Dimensional Potassium Manganese(II) Polyvanadate

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