Two precatalysts for application in asymmetric homogeneous hydrogen­ation

The title compounds, [(1R,1′R,2R,2′R)-2,2′-bis­(di­phenyl­phos­phanyl)-1,1′-di­cyclo­pentane](η⁴-norborna­diene)rhodium(I) tetra­fluorido­borate, [Rh(C₃₄H₃₆P₂)(C₇H₈)]BF₄, (I), and [(1R,1′R,2R,2′R)-2,2′-bis­(di­phenyl­phosphanyl)-1,1′-di­cyclo­pen­tane][η⁴-(Z,Z)-cyclo­octa-1,5-diene]rhodium(I) tetra­fluorido­borate di­chloro­methane mono­solvate, [Rh(C₃₄H₃₆P₂)(C₈H₁₂)]BF₄·CH₂Cl₂, (II), are applied as precatalysts in asymmetric homogeneous hydrogenation, e.g. in the reduction of de­hydro­amino acids, affording excellent enantio­meric excesses [Zhu, Cao, Jiang & Zhang (1997). J. Am. Chem. Soc. 119, 1799–1800].

S1. Introduction

One of our main inter­ests lies in the field of homogeneous asymmetric catalysis, with a special focus on asymmetric hydrogenation promoted by chiral rhodium bis­phosphine complexes. Relevant ligands in this context are shown in Scheme 1. Besides the well known chiral ligands which form five-membered ring chelates, e.g. DIPAMP {1,2-bis­[(2-meth­oxy­phenyl)(phenyl)­phosphanyl]ethane; Knowles et al., 1972} or ChiraPHOS [(2S,3S)-2,3-bis­(di­phenyl­phosphanyl)butane; Fryzuk & Bosnich, 1977], there are many established ligands which give rise to larger seven-membered-ring chelates, e.g. DIOP [4,5-bis­(di­phenyl­phosphanyl)-2,2-di­methyl-1,3-dioxolane; Kagan & Dang, 1972] or BINAP [2,2'-bis­(di­phenyl­phosphanyl)-1,1'-bi­naphthalene; Miyashita et al., 1980]. While the former possess rather stiff backbones, seven-membered ring chelates are more flexible and can adopt several conformations.

Recently, Zhang et al. [Reference?] developed a novel ligand, BICP [systematic name: 2,2'-bis­(di­phenyl­phosphanyl)-1,1'-bi­cyclo­pentane] (Scheme 1), which is able to coordinate to rhodium affording a seven-membered chelate complex. The authors reported that the resulting chelate has reduced conformational freedom because of the two cyclo­pentane rings in the ligand backbone. Additionally, they calculated (MM2) that the four stereogenic centres in the rhodium–BICP complex di­ctate the orientation of the phenyl groups in alternate sterically hindered and non-hindered quadrants. The preferred conformation adopted by the ligand in the metal complex should be a skewed seven-membered ring (Zhu et al., 1997). Such a conformation should result in higher enanti­oselectivity. However, the first structures of rhodium–BICP complexes (Scheme 2), viz. [Rh(BICP)(nbd)]BF₄ (ndb is norbornadiene), (I), and [Rh(BICP)(cod)]BF₄ (cod is cyclo­octa-1,5-diene), (II), which we present in this article, suggest that this assumption is not correct.

S2. Experimental

All manipulations were carried out using standard Schlenk techniques under argon. NMR spectra were recorded on a Bruker ARX-300 spectrometer. Hydrogen consumptions were monitored using the device described by Drexler et al. (2007).

S2.1. Synthesis and crystallization

The cationic complexes [Rh(BICP)(nbd)]BF₄, (I), and [Rh(BICP)(cod)]BF₄, (II), were prepared by reaction of [Rh(diolefin)(acac)] (acac is acetyl­acetate) and BICP, followed by addition of HBF₄ to the resulting solution, according to a modification of a previously published procedure (Schrock & Osborn, 1971).

For the preparation of [Rh(BICP)(cod)]BF₄, (I), a dry argon-flushed Schlenk tube was charged with Rh(cod)(acac) (97.2 mg, 0.313 mmol) and tetra­hydro­furan (THF, 10 ml). A solution of BICP (158 mg, 0.313 mmol) in THF (10 ml) was added dropwise at 273 K. After stirring for 30 min at room temperature, 39 µl of an 8 M solution of HBF₄ in Et₂O were added. The resulting mixture was stirred for 1 h. Upon addition of Et₂O, complex (I) precipitated. It was filtered off and washed with Et₂O. Crystals suitable for X-ray analysis were grown by slow diffusion of n-hexane into a CH₂Cl₂ solution.

For the preparation of [Rh(BICP)(nbd)]BF₄, (II), a dry argon-flushed Schlenk tube was charged with Rh(nbd)(acac) (92.1 mg, 0.313 mmol) and THF (10 ml). A solution of BICP (158 mg, 0.313 mmol) in THF (10 ml) was added dropwise at 273 K. After stirring for 30 min at room temperature, 39 µl of a 8 M solution of HBF₄ in Et₂O were added. The resulting mixture was stirred for 1 h. Upon addition of Et₂O, complex (II) precipitated. It was filtered off and washed with Et₂O. Crystals suitable for X-ray analysis were grown by slow diffusion of Et2O into the THF solution.

Spectroscopic analysis: ³¹P NMR (MeOH-d₄, 298 K, 121 MHz, δ, p.p.m.): (I), 26.0 (d, J_P—Rh = 141.2 Hz); (II) 28.9 (d, J_P—Rh = 150.9 Hz).

S2.2. Refinement

Crystal data, data collection and structure refinement details are summarized in Table 1. All H atoms were placed in idealized positions, with C—H = 0.93–0.98 (CH) and 0.97 Å (CH₂), and were refined using a riding model, with U_iso(H) = 1.2U_eq(C). The absolute configuration indicators 2R,2'R and 1R,1'R for (I) and (II) were determined using 5782 and 4694 Friedel pairs, resectively, in the refinement. The Flack parameters (Flack, 1983) at convergence were -0.032 (18) for (I) and -0.015 (5) for (II).

The anisotropic displacement parameters of atom C51 and neighbouring C atoms C52 and C55 in (I) were restrained to be more equal in the U_ij components.

After refinement of the BF₄^- anion in (II), residual electron density and large anisotropic displacement parameters for the F atoms indicated an alternative orientation for this group. The occupancy of the alternative orientations was refined and their sum was constrained to unity; refinement converged for a ratio of 0.655 (11):0.345 (11) between the major and minor orientations. The disordered BF₄^- anion in (II) was constrained by similarity constraints to resemble an ideal tetra­hedron.

S3. Structural commentary

The title compounds, (I) and (II), crystallize in the noncentrosymmetric space group P2₁ as red crystals. Compound (I) contains two cations and two anions in the asymmetric unit. The cationic complex of rhodium(I) coordinates to a BICP ligand and a bidentate h²,h²-coordinated norborna-2,5-diene. The unit cell of (II) contains one cation, one anion and a cocrystallized di­chloro­methane molecule per unit cell. The metal centre is coordinated by the BICP and the h²,h²-coordinated cyclo­octa-1,5-diene. The intra­molecular P—Rh—P bite angles are 94.25 (7) and 94.88 (7)° for nbd, and 91.85 (2)° for cod. The dihedral angles between the P/Rh/P and C_M/Rh/C_M planes (C_M is the centroid of the double bond) are 9.5 (2) and 11.2 (2)° for nbd, and 14.2 (1)° for cod. These values and the bond lengths and angles in the coordination environments (Table 2) are in the same ranges as for related rhodium complexes of BINAP (Preetz et al., 2010).

S4. Discussion

In the three independent cations in (I) and (II), we consistently found that all C atoms should be located in or above the P—Rh—P plane (Fig. 3a and Table 3). This means strong deviations from the ideal skew conformation. Nevertheless, the rhodium–BICP complexes afforded very good enanti­oselectivities in the asymmetric hydrogenation of standard substrates (Zhu et al., 1997). In contrast, in almost all examined X-ray structures of rhodium complexes containing BINAP, a ligand with a less flexible backbone (all sp₂ C atoms), we found a skew conformation (Preetz et al., 2010, 2011) (Fig. 3b). In such complexes, the C atoms are arranged symmetrically above and below the P—Rh—P plane (Table 3). However, asymmetric hydrogenation of standard substrates with rhodium–BINAP complexes as catalysts leads to poor enanti­oselectivities (Preetz et al., 2010).

Catalytic hydrogenations of cod and nbd, respectively, with [Rh(BICP)(nbd)]BF₄ or [Rh(BICP)(cod)]BF₄ have been carried out in MeOH according to Preetz et al. (2008) and Heller et al. (2007). Fig. 4 shows the hydrogen consumption curves for the catalytic hydrogenation of a ca 100-fold excess of cod and nbd. Pseudo-rate constants were determined from the slope of the hydrogen consumption from the linear part of the curve, which represents the hydrogenation of the first double bond of the diolefin. For the hydrogenation of nbd, we obtained 2.225 min^-1, and for cod 0.056 min^-1. This gives a ratio of k'_2nnbd/k'_2cod of 39.7. The rate constants are slightly lower than those we found for other seven-membered rhodium complexes (Meißner et al., 2014).

Related literature

For related literature, see: Drexler et al. (2007); Flack (1983); Fryzuk & Bosnich (1977); Heller et al. (2007); Kagan & Dang (1972); Knowles et al. (1972); Meißner, Alberico, Drexler, Baumann & Heller (2014); Miyashita et al. (1980); Preetz et al. (2008, 2010, 2011); Schrock & Osborn (1971); Zhu et al. (1997).

Computing details

Data collection: X-AREA (Stoe & Cie, 2005) for RhBICPnbdBF4; APEX2 (Bruker, 2009) for RhBICPcodBF4. Cell refinement: X-AREA (Stoe & Cie, 2005) for RhBICPnbdBF4; SAINT (Bruker, 2009) for RhBICPcodBF4. Data reduction: X-RED32 (Stoe & Cie, 2005) for RhBICPnbdBF4; SAINT (Bruker, 2009) for RhBICPcodBF4. For both compounds, program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures

	Fig. 1. A view of the cations of [Rh(BICP)(nbd)]BF4, (I), showing the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level and H atoms have been omitted for clarity. The relative orientation of the two molecules in the plot does not reflect their true orientation in the asymmetric unit.
	Fig. 2. A view of the cation of [Rh(BICP)(cod)]BF4, (II), showing the atom-labelling scheme. Displacement ellipsoids are drawn at the 30% probability level and H atoms have been omitted for clarity.
	Fig. 3. Extract of molecular structures from X-ray diffraction analysis showing the seven-membered chelates of (a) [Rh(BICP)(cod)]BF4, (II) (pronounced deviation from skew conformation), and (b) [Rh(BINAP)(thf)2]BF4 (thf is tetrahydrofuran; skew conformation) (Preetz et al., 2011). The figure was prepared using SCHAKAL (Keller & Pierrard, 1999).
	Fig. 4. Hydrogen consumption for the hydrogenation of a 100-fold excess of cod (red) and nbd (green) {standard conditions: 0.01 mmol [Rh(BICP)(diolefine)]BF4, 1.0 mmol cod or nbd, 15 ml MeOH 298 K and 1.01 bar overall pressure (1 bar = 100000 Pa)}.

(RhBICPnbdBF4) [(1R,1'R,2R,2'R)-2,2'-Bis(diphenylphosphanyl)-1,1'-dicyclopentane](η⁴-norbornadiene)rhodium(I) tetrafluoroborate

Crystal data

[Rh(C34H36P2)(C7H8)]BF4	F(000) = 1624
Mr = 788.42	Dx = 1.483 Mg m^−3
Monoclinic, P21	Mo Kα radiation, λ = 0.71073 Å
a = 10.002 (2) Å	Cell parameters from 16122 reflections
b = 9.0293 (18) Å	θ = 2.0–26.8°
c = 39.251 (8) Å	µ = 0.63 mm^−1
β = 95.17 (3)°	T = 200 K
V = 3530.4 (12) Å^3	Prism, red
Z = 4	0.34 × 0.28 × 0.25 mm

Data collection

Stoe IPDS 2 diffractometer	12426 independent reflections
Radiation source: fine-focus sealed tube	7748 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.087
Detector resolution: 6.67 pixels mm^-1	θmax = 25.0°, θmin = 1.6°
rotation method scans	h = −11→11
Absorption correction: numerical (X-SHAPE; Stoe & Cie, 2005)	k = −10→10
Tmin = 0.453, Tmax = 0.897	l = −46→45
38678 measured reflections

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.046	H-atom parameters constrained
wR(F^2) = 0.103	w = 1/[σ^2(Fo^2) + (0.0481P)^2] where P = (Fo^2 + 2Fc^2)/3
S = 0.83	(Δ/σ)max = 0.002
12426 reflections	Δρmax = 2.80 e Å^−3
883 parameters	Δρmin = −1.09 e Å^−3
13 restraints	Absolute structure: Flack (1983), with 5782 Friedel pairs
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: −0.03 (3)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Rh1	0.18661 (9)	0.65107 (6)	0.36836 (3)	0.0266 (4)
Rh2	0.30267 (9)	0.01815 (6)	0.13129 (3)	0.0267 (4)
P1	0.1097 (3)	0.7273 (3)	0.41955 (7)	0.0278 (7)
P2	0.0173 (3)	0.7703 (3)	0.33469 (7)	0.0265 (6)
P3	0.3821 (3)	0.0920 (3)	0.08043 (7)	0.0261 (7)
P4	0.4662 (2)	0.1403 (3)	0.16557 (6)	0.0265 (6)
C1	0.0943 (10)	0.9246 (10)	0.4237 (3)	0.032 (3)
H1	0.1867	0.9538	0.4311	0.038*
C2	0.0158 (11)	0.9947 (11)	0.4516 (3)	0.038 (3)
H2A	0.0580	0.9714	0.4742	0.046*
H2B	−0.0760	0.9587	0.4499	0.046*
C3	0.0193 (17)	1.1637 (13)	0.4449 (4)	0.056 (4)
H3A	−0.0700	1.2058	0.4446	0.067*
H3B	0.0776	1.2131	0.4625	0.067*
C4	0.0736 (12)	1.1798 (11)	0.4100 (3)	0.037 (3)
H4A	0.1671	1.2099	0.4127	0.044*
H4B	0.0228	1.2540	0.3965	0.044*
C5	0.0596 (9)	1.0285 (10)	0.3925 (2)	0.029 (2)
H5	0.1276	1.0181	0.3762	0.035*
C6	−0.0811 (10)	1.0109 (10)	0.3738 (2)	0.032 (2)
H6	−0.1459	1.0235	0.3909	0.038*
C7	−0.1144 (13)	1.1272 (11)	0.3460 (3)	0.039 (3)
H7A	−0.0395	1.1399	0.3322	0.047*
H7B	−0.1339	1.2218	0.3562	0.047*
C8	−0.2376 (12)	1.0694 (11)	0.3241 (3)	0.041 (3)
H8A	−0.3182	1.1180	0.3305	0.049*
H8B	−0.2290	1.0889	0.3001	0.049*
C9	−0.2454 (11)	0.9041 (12)	0.3304 (3)	0.041 (3)
H9A	−0.2469	0.8503	0.3090	0.049*
H9B	−0.3261	0.8800	0.3412	0.049*
C10	−0.1169 (10)	0.8623 (10)	0.3545 (3)	0.027 (2)
H10	−0.1465	0.7934	0.3716	0.032*
C11	0.2231 (11)	0.6788 (10)	0.4565 (3)	0.027 (3)
C12	0.3420 (10)	0.7604 (11)	0.4639 (3)	0.037 (3)
H12	0.3604	0.8403	0.4501	0.044*
C13	0.4320 (11)	0.7231 (12)	0.4914 (3)	0.043 (3)
H13	0.5103	0.7779	0.4958	0.051*
C14	0.4072 (12)	0.6076 (14)	0.5119 (3)	0.047 (3)
H14	0.4675	0.5849	0.5306	0.056*
C15	0.2924 (10)	0.5232 (13)	0.5050 (3)	0.047 (3)
H15	0.2761	0.4428	0.5189	0.056*
C16	0.2018 (11)	0.5592 (11)	0.4774 (3)	0.037 (3)
H16	0.1251	0.5018	0.4729	0.044*
C17	−0.0444 (10)	0.6340 (11)	0.4284 (3)	0.026 (3)
C18	−0.1097 (12)	0.6655 (14)	0.4581 (4)	0.039 (3)
H18	−0.0754	0.7379	0.4733	0.047*
C19	−0.2262 (11)	0.5875 (12)	0.4646 (3)	0.045 (3)
H19	−0.2670	0.6042	0.4846	0.054*
C20	−0.2804 (11)	0.4845 (12)	0.4406 (3)	0.051 (3)
H20	−0.3603	0.4368	0.4441	0.061*
C21	−0.2165 (10)	0.4531 (11)	0.4118 (3)	0.039 (3)
H21	−0.2502	0.3810	0.3965	0.046*
C22	−0.1020 (10)	0.5305 (11)	0.4063 (3)	0.033 (2)
H22	−0.0614	0.5112	0.3863	0.040*
C23	0.0807 (10)	0.9028 (10)	0.3052 (3)	0.030 (2)
C24	0.2079 (10)	0.9672 (10)	0.3130 (3)	0.034 (2)
H24	0.2626	0.9350	0.3320	0.041*
C25	0.2510 (12)	1.0779 (12)	0.2926 (3)	0.045 (3)
H25	0.3353	1.1195	0.2980	0.054*
C26	0.1740 (14)	1.1280 (14)	0.2648 (4)	0.044 (3)
H26	0.2036	1.2063	0.2521	0.053*
C27	0.0503 (12)	1.0616 (11)	0.2554 (3)	0.043 (3)
H27	0.0001	1.0914	0.2355	0.052*
C28	0.0021 (11)	0.9522 (10)	0.2754 (3)	0.035 (2)
H28	−0.0818	0.9106	0.2694	0.042*
C29	−0.0683 (11)	0.6342 (12)	0.3067 (3)	0.031 (3)
C30	−0.1788 (9)	0.5533 (10)	0.3169 (3)	0.031 (2)
H30	−0.2161	0.5786	0.3370	0.037*
C31	−0.2317 (10)	0.4368 (11)	0.2973 (3)	0.037 (3)
H31	−0.3064	0.3868	0.3039	0.044*
C32	−0.1761 (11)	0.3939 (13)	0.2682 (3)	0.044 (3)
H32	−0.2104	0.3124	0.2559	0.053*
C33	−0.0678 (11)	0.4723 (11)	0.2572 (3)	0.040 (3)
H33	−0.0310	0.4451	0.2372	0.048*
C34	−0.0167 (11)	0.5895 (12)	0.2761 (3)	0.038 (3)
H34	0.0550	0.6417	0.2685	0.045*
C35	0.3088 (10)	0.5967 (12)	0.3257 (3)	0.034 (2)
H35	0.3007	0.6473	0.3035	0.041*
C36	0.2341 (10)	0.4744 (10)	0.3333 (3)	0.034 (2)
H36	0.1661	0.4309	0.3167	0.040*
C37	0.3215 (9)	0.3803 (10)	0.3586 (3)	0.030 (2)
H37	0.2961	0.2761	0.3606	0.036*
C38	0.3230 (11)	0.4761 (10)	0.3915 (3)	0.039 (3)
H38	0.3156	0.4345	0.4143	0.047*
C39	0.3978 (10)	0.5989 (11)	0.3856 (3)	0.036 (3)
H39	0.4503	0.6535	0.4038	0.043*
C40	0.4421 (11)	0.5801 (12)	0.3487 (3)	0.041 (3)
H40	0.5179	0.6408	0.3428	0.049*
C41	0.4603 (10)	0.4114 (11)	0.3474 (3)	0.037 (3)
H41A	0.4718	0.3749	0.3247	0.044*
H41B	0.5321	0.3757	0.3636	0.044*
C51	0.3959 (11)	0.3065 (12)	0.0764 (3)	0.035 (2)
H51	0.3047	0.3374	0.0682	0.042*
C52	0.4810 (11)	0.3575 (10)	0.0479 (3)	0.039 (3)
H52A	0.4409	0.3298	0.0254	0.047*
H52B	0.5721	0.3199	0.0512	0.047*
C53	0.4748 (16)	0.5283 (14)	0.0540 (4)	0.051 (4)
H53A	0.5643	0.5704	0.0561	0.061*
H53B	0.4223	0.5762	0.0351	0.061*
C54	0.4091 (12)	0.5487 (11)	0.0869 (3)	0.036 (3)
H54A	0.3145	0.5715	0.0821	0.043*
H54B	0.4517	0.6287	0.1003	0.043*
C55	0.4279 (10)	0.3961 (10)	0.1069 (3)	0.031 (2)
H55	0.3577	0.3847	0.1225	0.037*
C56	0.5651 (10)	0.3805 (11)	0.1263 (3)	0.032 (2)
H56	0.6310	0.3938	0.1096	0.039*
C57	0.5925 (13)	0.5020 (11)	0.1530 (3)	0.036 (3)
H57A	0.5162	0.5139	0.1664	0.043*
H57B	0.6093	0.5956	0.1420	0.043*
C58	0.7166 (12)	0.4526 (12)	0.1759 (3)	0.044 (3)
H58A	0.7076	0.4782	0.1995	0.052*
H58B	0.7968	0.4995	0.1688	0.052*
C59	0.7239 (11)	0.2831 (12)	0.1715 (3)	0.041 (3)
H59A	0.7180	0.2341	0.1933	0.049*
H59B	0.8080	0.2554	0.1627	0.049*
C60	0.6037 (10)	0.2374 (10)	0.1458 (3)	0.033 (2)
H60	0.6384	0.1687	0.1294	0.040*
C61	0.2710 (10)	0.0427 (11)	0.0430 (3)	0.029 (3)
C62	0.1501 (10)	0.1202 (10)	0.0356 (3)	0.036 (3)
H62	0.1289	0.1979	0.0497	0.043*
C63	0.0621 (12)	0.0829 (13)	0.0076 (3)	0.047 (3)
H63	−0.0173	0.1359	0.0032	0.056*
C64	0.0911 (13)	−0.0325 (15)	−0.0137 (4)	0.051 (3)
H64	0.0328	−0.0553	−0.0328	0.062*
C65	0.2068 (11)	−0.1133 (14)	−0.0064 (3)	0.049 (3)
H65	0.2257	−0.1928	−0.0202	0.058*
C66	0.2959 (11)	−0.0757 (11)	0.0218 (3)	0.040 (3)
H66	0.3736	−0.1313	0.0265	0.048*
C67	0.5387 (11)	−0.0008 (11)	0.0727 (3)	0.029 (3)
C68	0.5900 (9)	−0.1046 (10)	0.0966 (3)	0.031 (2)
H68	0.5473	−0.1226	0.1163	0.037*
C69	0.7098 (11)	−0.1833 (11)	0.0904 (3)	0.044 (3)
H69	0.7446	−0.2537	0.1061	0.053*
C70	0.7736 (11)	−0.1558 (11)	0.0617 (3)	0.046 (3)
H70	0.8520	−0.2063	0.0579	0.055*
C71	0.7205 (11)	−0.0528 (13)	0.0383 (3)	0.045 (3)
H71	0.7638	−0.0357	0.0187	0.053*
C72	0.6057 (12)	0.0258 (12)	0.0430 (3)	0.036 (3)
H72	0.5726	0.0953	0.0269	0.043*
C73	0.3976 (10)	0.2754 (11)	0.1937 (3)	0.032 (2)
C74	0.2725 (10)	0.3388 (10)	0.1840 (3)	0.032 (2)
H74	0.2207	0.3015	0.1651	0.038*
C75	0.2241 (11)	0.4564 (11)	0.2021 (3)	0.038 (3)
H75	0.1406	0.4969	0.1951	0.046*
C76	0.2979 (14)	0.5134 (13)	0.2301 (4)	0.048 (4)
H76	0.2672	0.5952	0.2415	0.057*
C77	0.4221 (12)	0.4456 (12)	0.2414 (3)	0.044 (3)
H77	0.4720	0.4802	0.2609	0.053*
C78	0.4681 (11)	0.3291 (11)	0.2234 (3)	0.036 (3)
H78	0.5488	0.2844	0.2313	0.044*
C79	0.5514 (11)	0.0102 (12)	0.1952 (3)	0.033 (3)
C80	0.4961 (11)	−0.0329 (11)	0.2250 (3)	0.035 (3)
H80	0.4192	0.0149	0.2309	0.042*
C81	0.5503 (12)	−0.1422 (12)	0.2458 (3)	0.043 (3)
H81	0.5118	−0.1654	0.2658	0.052*
C82	0.6620 (11)	−0.2187 (11)	0.2372 (3)	0.043 (3)
H82	0.6978	−0.2949	0.2512	0.051*
C83	0.7208 (11)	−0.1804 (11)	0.2075 (3)	0.042 (3)
H83	0.7971	−0.2298	0.2017	0.051*
C84	0.6656 (11)	−0.0696 (10)	0.1868 (3)	0.036 (3)
H84	0.7042	−0.0464	0.1668	0.044*
C85	0.1797 (11)	−0.0375 (12)	0.1737 (3)	0.035 (3)
H85	0.1880	0.0130	0.1959	0.042*
C86	0.2537 (11)	−0.1596 (10)	0.1664 (3)	0.033 (2)
H86	0.3212	−0.2028	0.1832	0.040*
C87	0.1707 (10)	−0.2530 (11)	0.1405 (3)	0.035 (2)
H87	0.1970	−0.3569	0.1383	0.042*
C88	0.1655 (10)	−0.1565 (10)	0.1081 (3)	0.036 (3)
H88	0.1722	−0.1970	0.0851	0.043*
C89	0.0906 (10)	−0.0322 (13)	0.1144 (3)	0.040 (3)
H89	0.0382	0.0233	0.0963	0.048*
C90	0.0467 (12)	−0.0514 (13)	0.1508 (3)	0.043 (3)
H90	−0.0290	0.0089	0.1570	0.052*
C91	0.0290 (10)	−0.2222 (13)	0.1515 (3)	0.045 (3)
H91A	0.0164	−0.2601	0.1741	0.054*
H91B	−0.0421	−0.2573	0.1350	0.054*
B1	0.5125 (13)	0.0297 (16)	0.3946 (4)	0.046 (3)
F1	0.4698 (8)	0.0156 (13)	0.3601 (2)	0.090 (3)
F2	0.5735 (8)	−0.0958 (8)	0.4075 (2)	0.081 (3)
F3	0.4022 (7)	0.0648 (10)	0.4122 (2)	0.077 (2)
F4	0.6041 (8)	0.1456 (9)	0.3975 (3)	0.071 (3)
B2	0.9696 (14)	0.3904 (16)	0.1064 (4)	0.049 (3)
F5	0.8890 (9)	0.5118 (9)	0.1004 (3)	0.073 (3)
F6	1.0871 (7)	0.4084 (10)	0.0911 (2)	0.080 (3)
F7	0.9044 (9)	0.2694 (9)	0.0926 (3)	0.094 (3)
F8	1.0017 (7)	0.3704 (13)	0.1408 (2)	0.097 (3)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Rh1	0.0296 (5)	0.0254 (7)	0.0245 (9)	0.0028 (4)	0.0013 (5)	−0.0001 (4)
Rh2	0.0298 (5)	0.0250 (7)	0.0251 (9)	−0.0023 (4)	0.0021 (5)	−0.0003 (4)
P1	0.0302 (15)	0.0250 (14)	0.0285 (18)	−0.0018 (11)	0.0040 (13)	−0.0023 (11)
P2	0.0285 (14)	0.0256 (13)	0.0249 (16)	0.0018 (11)	0.0003 (12)	0.0005 (11)
P3	0.0281 (14)	0.0246 (14)	0.0253 (17)	0.0009 (10)	0.0018 (12)	−0.0011 (11)
P4	0.0295 (13)	0.0242 (13)	0.0258 (16)	−0.0007 (12)	0.0017 (11)	0.0024 (13)
C1	0.028 (5)	0.021 (5)	0.047 (7)	−0.003 (4)	0.005 (5)	0.007 (5)
C2	0.053 (7)	0.038 (6)	0.024 (6)	0.005 (5)	0.006 (5)	−0.002 (5)
C3	0.104 (12)	0.021 (6)	0.044 (10)	0.009 (6)	0.016 (9)	0.002 (5)
C4	0.052 (7)	0.022 (6)	0.034 (7)	−0.005 (5)	−0.009 (5)	−0.007 (5)
C5	0.039 (5)	0.024 (4)	0.025 (5)	0.003 (5)	0.005 (4)	0.008 (5)
C6	0.045 (6)	0.023 (4)	0.027 (6)	0.009 (5)	0.001 (4)	0.002 (5)
C7	0.056 (7)	0.021 (6)	0.038 (8)	−0.001 (5)	−0.009 (6)	0.000 (5)
C8	0.048 (7)	0.033 (5)	0.039 (7)	0.011 (5)	−0.001 (6)	0.006 (5)
C9	0.039 (6)	0.047 (6)	0.036 (7)	0.005 (5)	−0.002 (5)	0.002 (5)
C10	0.034 (6)	0.020 (5)	0.025 (6)	0.006 (4)	−0.004 (5)	−0.004 (4)
C11	0.035 (6)	0.022 (5)	0.025 (7)	0.004 (4)	0.001 (5)	−0.004 (5)
C12	0.039 (6)	0.031 (5)	0.039 (7)	−0.006 (5)	0.000 (5)	0.004 (5)
C13	0.036 (6)	0.041 (6)	0.048 (8)	−0.001 (5)	−0.012 (6)	0.002 (6)
C14	0.037 (7)	0.061 (8)	0.042 (8)	0.018 (6)	0.000 (6)	0.007 (7)
C15	0.040 (6)	0.053 (6)	0.049 (7)	0.014 (6)	0.009 (5)	0.022 (7)
C16	0.032 (6)	0.038 (6)	0.039 (7)	0.001 (4)	0.000 (5)	0.007 (5)
C17	0.029 (5)	0.019 (5)	0.028 (7)	−0.004 (4)	−0.006 (5)	0.007 (4)
C18	0.037 (7)	0.040 (7)	0.040 (9)	−0.001 (5)	0.007 (6)	0.005 (6)
C19	0.036 (6)	0.046 (6)	0.056 (8)	0.001 (5)	0.017 (6)	0.008 (6)
C20	0.029 (6)	0.059 (8)	0.064 (9)	−0.015 (5)	0.001 (6)	0.021 (6)
C21	0.030 (6)	0.034 (5)	0.051 (8)	−0.008 (4)	−0.004 (5)	0.007 (5)
C22	0.044 (6)	0.035 (5)	0.023 (5)	0.003 (5)	0.010 (5)	0.003 (5)
C23	0.038 (6)	0.026 (5)	0.026 (6)	0.001 (4)	0.003 (5)	−0.003 (4)
C24	0.036 (6)	0.032 (5)	0.034 (6)	−0.004 (4)	0.004 (5)	0.000 (4)
C25	0.053 (7)	0.040 (6)	0.043 (8)	−0.013 (5)	0.015 (6)	−0.007 (6)
C26	0.061 (8)	0.037 (7)	0.036 (8)	−0.004 (6)	0.017 (6)	0.008 (6)
C27	0.059 (7)	0.039 (6)	0.032 (7)	0.006 (5)	0.009 (6)	0.007 (5)
C28	0.043 (6)	0.030 (5)	0.031 (6)	0.001 (4)	0.003 (5)	−0.004 (5)
C29	0.029 (6)	0.034 (6)	0.028 (7)	0.000 (5)	−0.006 (5)	0.000 (5)
C30	0.025 (5)	0.032 (6)	0.036 (6)	0.000 (4)	0.003 (5)	0.004 (4)
C31	0.030 (6)	0.035 (5)	0.045 (7)	−0.005 (4)	−0.005 (5)	0.001 (5)
C32	0.047 (7)	0.037 (5)	0.047 (7)	0.002 (5)	−0.011 (5)	−0.017 (5)
C33	0.043 (7)	0.041 (6)	0.036 (7)	0.002 (5)	0.003 (5)	−0.008 (5)
C34	0.033 (6)	0.047 (6)	0.032 (7)	0.002 (5)	0.000 (5)	0.000 (5)
C35	0.036 (6)	0.042 (6)	0.025 (6)	0.007 (5)	−0.001 (5)	−0.004 (5)
C36	0.032 (6)	0.029 (5)	0.039 (7)	0.010 (4)	−0.001 (5)	−0.009 (4)
C37	0.018 (5)	0.029 (5)	0.043 (7)	0.001 (4)	0.007 (5)	0.000 (5)
C38	0.046 (7)	0.037 (6)	0.035 (7)	0.019 (5)	0.005 (5)	0.004 (5)
C39	0.036 (6)	0.033 (5)	0.037 (7)	−0.002 (5)	−0.008 (5)	0.005 (5)
C40	0.029 (6)	0.045 (6)	0.048 (8)	−0.001 (5)	0.008 (5)	0.005 (5)
C41	0.026 (5)	0.040 (6)	0.044 (7)	0.007 (5)	−0.001 (5)	0.001 (5)
C51	0.033 (5)	0.055 (6)	0.018 (5)	0.000 (5)	0.004 (4)	0.024 (5)
C52	0.054 (6)	0.036 (6)	0.028 (6)	−0.003 (5)	0.007 (5)	0.003 (5)
C53	0.082 (10)	0.037 (8)	0.034 (9)	−0.005 (6)	0.011 (8)	−0.007 (6)
C54	0.047 (7)	0.019 (5)	0.043 (8)	0.003 (5)	0.013 (6)	−0.014 (5)
C55	0.038 (5)	0.025 (5)	0.029 (6)	0.002 (4)	0.004 (4)	0.000 (4)
C56	0.035 (6)	0.031 (5)	0.030 (6)	−0.009 (5)	0.003 (5)	0.003 (5)
C57	0.055 (7)	0.019 (5)	0.033 (7)	−0.008 (5)	−0.005 (6)	−0.008 (5)
C58	0.051 (7)	0.040 (6)	0.038 (7)	−0.007 (5)	−0.004 (6)	−0.005 (5)
C59	0.041 (6)	0.038 (6)	0.041 (7)	−0.014 (5)	−0.006 (5)	−0.001 (5)
C60	0.030 (5)	0.028 (5)	0.039 (7)	0.001 (4)	−0.006 (5)	−0.013 (5)
C61	0.028 (5)	0.029 (6)	0.031 (7)	0.003 (4)	0.005 (5)	0.004 (5)
C62	0.036 (6)	0.024 (5)	0.046 (7)	0.003 (4)	−0.005 (5)	−0.007 (4)
C63	0.035 (6)	0.048 (7)	0.056 (9)	−0.001 (5)	−0.006 (6)	0.003 (6)
C64	0.050 (8)	0.062 (8)	0.041 (8)	−0.019 (7)	0.002 (6)	−0.003 (7)
C65	0.039 (6)	0.064 (7)	0.043 (8)	−0.010 (6)	0.003 (6)	−0.032 (6)
C66	0.033 (6)	0.032 (6)	0.053 (8)	0.000 (4)	−0.002 (5)	−0.004 (5)
C67	0.030 (6)	0.023 (5)	0.033 (7)	0.003 (4)	0.003 (5)	−0.005 (5)
C68	0.028 (5)	0.018 (4)	0.045 (7)	0.006 (4)	−0.009 (5)	−0.004 (5)
C69	0.044 (7)	0.035 (6)	0.052 (8)	0.015 (5)	−0.003 (6)	−0.007 (5)
C70	0.031 (6)	0.046 (7)	0.061 (9)	0.011 (5)	0.006 (6)	−0.008 (6)
C71	0.036 (6)	0.056 (7)	0.045 (8)	−0.002 (5)	0.015 (6)	−0.007 (6)
C72	0.045 (7)	0.030 (6)	0.032 (8)	0.004 (5)	0.002 (6)	0.004 (5)
C73	0.034 (6)	0.033 (5)	0.028 (6)	−0.004 (4)	0.003 (5)	0.000 (5)
C74	0.038 (6)	0.032 (5)	0.026 (6)	0.000 (4)	0.004 (5)	−0.002 (4)
C75	0.037 (6)	0.038 (5)	0.041 (7)	0.005 (5)	0.009 (5)	0.005 (5)
C76	0.062 (8)	0.036 (6)	0.047 (9)	0.005 (6)	0.019 (7)	0.002 (6)
C77	0.055 (7)	0.047 (6)	0.031 (7)	−0.009 (6)	0.004 (6)	−0.004 (5)
C78	0.033 (6)	0.043 (6)	0.033 (7)	−0.006 (4)	0.005 (5)	−0.002 (5)
C79	0.028 (5)	0.034 (6)	0.038 (8)	0.004 (5)	−0.003 (5)	0.000 (5)
C80	0.040 (6)	0.027 (5)	0.038 (7)	−0.002 (4)	0.004 (5)	0.009 (5)
C81	0.055 (7)	0.048 (6)	0.026 (6)	−0.007 (5)	−0.005 (5)	0.009 (5)
C82	0.047 (7)	0.033 (5)	0.045 (7)	0.002 (5)	−0.010 (6)	0.004 (5)
C83	0.042 (6)	0.036 (6)	0.048 (8)	0.006 (5)	−0.004 (6)	0.000 (5)
C84	0.042 (6)	0.031 (5)	0.036 (6)	−0.001 (5)	0.003 (5)	0.001 (5)
C85	0.042 (7)	0.036 (6)	0.027 (7)	−0.009 (5)	0.006 (5)	−0.005 (5)
C86	0.045 (6)	0.033 (5)	0.022 (6)	−0.005 (5)	0.004 (5)	0.009 (4)
C87	0.038 (6)	0.031 (5)	0.035 (7)	0.001 (4)	0.006 (5)	−0.001 (5)
C88	0.036 (6)	0.033 (6)	0.038 (7)	−0.013 (4)	−0.006 (5)	0.001 (5)
C89	0.023 (5)	0.046 (6)	0.049 (8)	−0.005 (5)	−0.006 (5)	0.003 (6)
C90	0.039 (7)	0.045 (6)	0.045 (8)	0.002 (5)	0.002 (6)	0.003 (6)
C91	0.027 (6)	0.049 (6)	0.063 (9)	−0.012 (5)	0.015 (5)	0.004 (6)
B1	0.042 (7)	0.043 (7)	0.051 (9)	−0.009 (7)	−0.005 (6)	−0.007 (7)
F1	0.061 (5)	0.159 (9)	0.049 (5)	0.003 (6)	−0.006 (4)	−0.021 (6)
F2	0.085 (6)	0.043 (4)	0.110 (7)	−0.004 (4)	−0.013 (5)	0.021 (5)
F3	0.045 (4)	0.121 (7)	0.066 (6)	0.002 (4)	0.011 (4)	0.010 (5)
F4	0.067 (6)	0.054 (5)	0.091 (8)	−0.021 (5)	−0.003 (5)	0.011 (4)
B2	0.049 (8)	0.049 (8)	0.049 (9)	0.007 (7)	−0.006 (7)	−0.008 (7)
F5	0.069 (6)	0.068 (6)	0.079 (8)	0.034 (5)	−0.005 (5)	−0.012 (5)
F6	0.045 (4)	0.126 (7)	0.072 (6)	0.003 (5)	0.020 (4)	−0.012 (5)
F7	0.089 (6)	0.053 (5)	0.134 (9)	−0.006 (5)	−0.015 (6)	−0.013 (5)
F8	0.040 (4)	0.200 (11)	0.050 (5)	0.018 (6)	−0.005 (4)	0.034 (6)

Geometric parameters (Å, º)

Rh1—C36	2.187 (9)	C38—C39	1.369 (14)
Rh1—C39	2.210 (10)	C38—H38	0.9800
Rh1—C35	2.216 (11)	C39—C40	1.561 (16)
Rh1—C38	2.226 (10)	C39—H39	0.9800
Rh1—P2	2.317 (3)	C40—C41	1.536 (15)
Rh1—P1	2.319 (3)	C40—H40	0.9800
Rh2—C86	2.199 (9)	C41—H41A	0.9700
Rh2—C89	2.212 (10)	C41—H41B	0.9700
Rh2—C85	2.214 (11)	C51—C55	1.456 (15)
Rh2—C88	2.230 (10)	C51—C52	1.534 (13)
Rh2—P4	2.304 (3)	C51—H51	0.9800
Rh2—P3	2.312 (3)	C52—C53	1.562 (15)
P1—C1	1.797 (10)	C52—H52A	0.9700
P1—C11	1.813 (12)	C52—H52B	0.9700
P1—C17	1.818 (10)	C53—C54	1.512 (18)
P2—C29	1.813 (12)	C53—H53A	0.9700
P2—C10	1.813 (10)	C53—H53B	0.9700
P2—C23	1.819 (10)	C54—C55	1.587 (14)
P3—C61	1.817 (12)	C54—H54A	0.9700
P3—C67	1.824 (11)	C54—H54B	0.9700
P3—C51	1.950 (11)	C55—C56	1.516 (14)
P4—C79	1.811 (12)	C55—H55	0.9800
P4—C73	1.820 (10)	C56—C57	1.523 (14)
P4—C60	1.859 (11)	C56—C60	1.532 (14)
C1—C2	1.540 (14)	C56—H56	0.9800
C1—C5	1.558 (13)	C57—C58	1.532 (16)
C1—H1	0.9800	C57—H57A	0.9700
C2—C3	1.549 (15)	C57—H57B	0.9700
C2—H2A	0.9700	C58—C59	1.543 (15)
C2—H2B	0.9700	C58—H58A	0.9700
C3—C4	1.525 (19)	C58—H58B	0.9700
C3—H3A	0.9700	C59—C60	1.553 (14)
C3—H3B	0.9700	C59—H59A	0.9700
C4—C5	1.531 (13)	C59—H59B	0.9700
C4—H4A	0.9700	C60—H60	0.9800
C4—H4B	0.9700	C61—C66	1.389 (14)
C5—C6	1.536 (13)	C61—C62	1.404 (14)
C5—H5	0.9800	C62—C63	1.384 (15)
C6—C7	1.529 (15)	C62—H62	0.9300
C6—C10	1.567 (13)	C63—C64	1.383 (18)
C6—H6	0.9800	C63—H63	0.9300
C7—C8	1.529 (16)	C64—C65	1.376 (17)
C7—H7A	0.9700	C64—H64	0.9300
C7—H7B	0.9700	C65—C66	1.399 (15)
C8—C9	1.517 (16)	C65—H65	0.9300
C8—H8A	0.9700	C66—H66	0.9300
C8—H8B	0.9700	C67—C68	1.390 (15)
C9—C10	1.572 (14)	C67—C72	1.417 (17)
C9—H9A	0.9700	C68—C69	1.433 (14)
C9—H9B	0.9700	C68—H68	0.9300
C10—H10	0.9800	C69—C70	1.369 (16)
C11—C16	1.384 (14)	C69—H69	0.9300
C11—C12	1.407 (14)	C70—C71	1.378 (16)
C12—C13	1.384 (15)	C70—H70	0.9300
C12—H12	0.9300	C71—C72	1.376 (16)
C13—C14	1.353 (16)	C71—H71	0.9300
C13—H13	0.9300	C72—H72	0.9300
C14—C15	1.384 (16)	C73—C78	1.396 (14)
C14—H14	0.9300	C73—C74	1.397 (14)
C15—C16	1.387 (15)	C74—C75	1.390 (14)
C15—H15	0.9300	C74—H74	0.9300
C16—H16	0.9300	C75—C76	1.368 (18)
C17—C22	1.366 (15)	C75—H75	0.9300
C17—C18	1.416 (17)	C76—C77	1.419 (17)
C18—C19	1.404 (16)	C76—H76	0.9300
C18—H18	0.9300	C77—C78	1.368 (14)
C19—C20	1.398 (17)	C77—H77	0.9300
C19—H19	0.9300	C78—H78	0.9300
C20—C21	1.374 (16)	C79—C80	1.393 (17)
C20—H20	0.9300	C79—C84	1.414 (15)
C21—C22	1.376 (14)	C80—C81	1.360 (14)
C21—H21	0.9300	C80—H80	0.9300
C22—H22	0.9300	C81—C82	1.380 (15)
C23—C24	1.407 (14)	C81—H81	0.9300
C23—C28	1.420 (14)	C82—C83	1.398 (15)
C24—C25	1.374 (14)	C82—H82	0.9300
C24—H24	0.9300	C83—C84	1.372 (14)
C25—C26	1.355 (18)	C83—H83	0.9300
C25—H25	0.9300	C84—H84	0.9300
C26—C27	1.394 (17)	C85—C86	1.372 (14)
C26—H26	0.9300	C85—C90	1.541 (16)
C27—C28	1.375 (14)	C85—H85	0.9800
C27—H27	0.9300	C86—C87	1.511 (14)
C28—H28	0.9300	C86—H86	0.9800
C29—C34	1.407 (16)	C87—C88	1.541 (14)
C29—C30	1.413 (15)	C87—C91	1.544 (14)
C30—C31	1.381 (14)	C87—H87	0.9800
C30—H30	0.9300	C88—C89	1.384 (14)
C31—C32	1.368 (16)	C88—H88	0.9800
C31—H31	0.9300	C89—C90	1.545 (16)
C32—C33	1.395 (16)	C89—H89	0.9800
C32—H32	0.9300	C90—C91	1.553 (16)
C33—C34	1.365 (14)	C90—H90	0.9800
C33—H33	0.9300	C91—H91A	0.9700
C34—H34	0.9300	C91—H91B	0.9700
C35—C36	1.381 (14)	B1—F2	1.363 (16)
C35—C40	1.550 (15)	B1—F1	1.388 (16)
C35—H35	0.9800	B1—F4	1.388 (15)
C36—C37	1.522 (14)	B1—F3	1.391 (15)
C36—H36	0.9800	B2—F7	1.360 (16)
C37—C41	1.519 (13)	B2—F5	1.369 (15)
C37—C38	1.551 (14)	B2—F8	1.370 (16)
C37—H37	0.9800	B2—F6	1.377 (16)
C36—Rh1—C39	77.4 (4)	C39—C38—H38	123.4
C36—Rh1—C35	36.6 (4)	C37—C38—H38	123.4
C39—Rh1—C35	66.9 (4)	Rh1—C38—H38	123.4
C36—Rh1—C38	65.1 (4)	C38—C39—C40	105.8 (9)
C39—Rh1—C38	35.9 (4)	C38—C39—Rh1	72.7 (6)
C35—Rh1—C38	77.9 (4)	C40—C39—Rh1	94.7 (6)
C36—Rh1—P2	99.7 (3)	C38—C39—H39	123.4
C39—Rh1—P2	154.5 (3)	C40—C39—H39	123.4
C35—Rh1—P2	95.5 (3)	Rh1—C39—H39	123.4
C38—Rh1—P2	162.1 (3)	C41—C40—C35	100.1 (9)
C36—Rh1—P1	150.4 (3)	C41—C40—C39	100.5 (9)
C39—Rh1—P1	100.4 (3)	C35—C40—C39	103.3 (8)
C35—Rh1—P1	165.7 (3)	C41—C40—H40	116.8
C38—Rh1—P1	95.5 (3)	C35—C40—H40	116.8
P2—Rh1—P1	94.25 (10)	C39—C40—H40	116.8
C86—Rh2—C89	77.1 (4)	C37—C41—C40	93.4 (8)
C86—Rh2—C85	36.2 (4)	C37—C41—H41A	113.0
C89—Rh2—C85	66.2 (4)	C40—C41—H41A	113.0
C86—Rh2—C88	65.0 (4)	C37—C41—H41B	113.0
C89—Rh2—C88	36.3 (4)	C40—C41—H41B	113.0
C85—Rh2—C88	77.5 (4)	H41A—C41—H41B	110.4
C86—Rh2—P4	99.8 (3)	C55—C51—C52	109.6 (9)
C89—Rh2—P4	152.3 (3)	C55—C51—P3	119.8 (7)
C85—Rh2—P4	94.8 (3)	C52—C51—P3	113.9 (7)
C88—Rh2—P4	162.8 (3)	C55—C51—H51	103.8
C86—Rh2—P3	149.8 (3)	C52—C51—H51	103.8
C89—Rh2—P3	101.2 (3)	P3—C51—H51	103.8
C85—Rh2—P3	166.3 (3)	C51—C52—C53	98.8 (9)
C88—Rh2—P3	95.6 (3)	C51—C52—H52A	112.0
P4—Rh2—P3	94.88 (10)	C53—C52—H52A	112.0
C1—P1—C11	102.7 (5)	C51—C52—H52B	112.0
C1—P1—C17	111.1 (5)	C53—C52—H52B	112.0
C11—P1—C17	102.4 (5)	H52A—C52—H52B	109.7
C1—P1—Rh1	114.3 (4)	C54—C53—C52	106.1 (10)
C11—P1—Rh1	112.9 (4)	C54—C53—H53A	110.5
C17—P1—Rh1	112.4 (4)	C52—C53—H53A	110.5
C29—P2—C10	104.1 (5)	C54—C53—H53B	110.5
C29—P2—C23	103.4 (5)	C52—C53—H53B	110.5
C10—P2—C23	106.6 (4)	H53A—C53—H53B	108.7
C29—P2—Rh1	108.2 (4)	C53—C54—C55	105.9 (9)
C10—P2—Rh1	120.0 (3)	C53—C54—H54A	110.5
C23—P2—Rh1	113.0 (3)	C55—C54—H54A	110.5
C61—P3—C67	103.0 (5)	C53—C54—H54B	110.5
C61—P3—C51	102.7 (5)	C55—C54—H54B	110.5
C67—P3—C51	112.0 (5)	H54A—C54—H54B	108.7
C61—P3—Rh2	113.3 (4)	C51—C55—C56	119.0 (9)
C67—P3—Rh2	112.2 (4)	C51—C55—C54	93.9 (8)
C51—P3—Rh2	112.9 (3)	C56—C55—C54	113.1 (9)
C79—P4—C73	103.1 (5)	C51—C55—H55	109.9
C79—P4—C60	104.6 (5)	C56—C55—H55	109.9
C73—P4—C60	105.7 (4)	C54—C55—H55	109.9
C79—P4—Rh2	109.4 (4)	C55—C56—C57	112.2 (9)
C73—P4—Rh2	112.8 (3)	C55—C56—C60	120.4 (8)
C60—P4—Rh2	119.7 (3)	C57—C56—C60	104.1 (9)
C2—C1—C5	102.8 (7)	C55—C56—H56	106.4
C2—C1—P1	121.7 (7)	C57—C56—H56	106.4
C5—C1—P1	122.7 (8)	C60—C56—H56	106.4
C2—C1—H1	102.0	C56—C57—C58	106.2 (9)
C5—C1—H1	102.0	C56—C57—H57A	110.5
P1—C1—H1	102.0	C58—C57—H57A	110.5
C1—C2—C3	105.3 (9)	C56—C57—H57B	110.5
C1—C2—H2A	110.7	C58—C57—H57B	110.5
C3—C2—H2A	110.7	H57A—C57—H57B	108.7
C1—C2—H2B	110.7	C57—C58—C59	105.5 (9)
C3—C2—H2B	110.7	C57—C58—H58A	110.6
H2A—C2—H2B	108.8	C59—C58—H58A	110.6
C4—C3—C2	105.2 (10)	C57—C58—H58B	110.6
C4—C3—H3A	110.7	C59—C58—H58B	110.6
C2—C3—H3A	110.7	H58A—C58—H58B	108.8
C4—C3—H3B	110.7	C58—C59—C60	107.1 (9)
C2—C3—H3B	110.7	C58—C59—H59A	110.3
H3A—C3—H3B	108.8	C60—C59—H59A	110.3
C3—C4—C5	107.1 (9)	C58—C59—H59B	110.3
C3—C4—H4A	110.3	C60—C59—H59B	110.3
C5—C4—H4A	110.3	H59A—C59—H59B	108.6
C3—C4—H4B	110.3	C56—C60—C59	104.2 (8)
C5—C4—H4B	110.3	C56—C60—P4	116.3 (7)
H4A—C4—H4B	108.6	C59—C60—P4	114.3 (8)
C4—C5—C6	110.5 (8)	C56—C60—H60	107.2
C4—C5—C1	100.3 (8)	C59—C60—H60	107.2
C6—C5—C1	116.3 (8)	P4—C60—H60	107.2
C4—C5—H5	109.8	C66—C61—C62	117.2 (10)
C6—C5—H5	109.8	C66—C61—P3	122.8 (8)
C1—C5—H5	109.8	C62—C61—P3	119.8 (8)
C7—C6—C5	113.6 (8)	C63—C62—C61	121.1 (10)
C7—C6—C10	102.6 (8)	C63—C62—H62	119.5
C5—C6—C10	118.6 (8)	C61—C62—H62	119.5
C7—C6—H6	107.1	C64—C63—C62	120.6 (11)
C5—C6—H6	107.1	C64—C63—H63	119.7
C10—C6—H6	107.1	C62—C63—H63	119.7
C6—C7—C8	106.2 (8)	C65—C64—C63	119.5 (12)
C6—C7—H7A	110.5	C65—C64—H64	120.3
C8—C7—H7A	110.5	C63—C64—H64	120.3
C6—C7—H7B	110.5	C64—C65—C66	120.0 (11)
C8—C7—H7B	110.5	C64—C65—H65	120.0
H7A—C7—H7B	108.7	C66—C65—H65	120.0
C9—C8—C7	107.2 (9)	C61—C66—C65	121.6 (10)
C9—C8—H8A	110.3	C61—C66—H66	119.2
C7—C8—H8A	110.3	C65—C66—H66	119.2
C9—C8—H8B	110.3	C68—C67—C72	119.7 (10)
C7—C8—H8B	110.3	C68—C67—P3	117.9 (9)
H8A—C8—H8B	108.5	C72—C67—P3	122.3 (9)
C8—C9—C10	106.4 (9)	C67—C68—C69	118.9 (11)
C8—C9—H9A	110.4	C67—C68—H68	120.5
C10—C9—H9A	110.4	C69—C68—H68	120.5
C8—C9—H9B	110.4	C70—C69—C68	120.6 (10)
C10—C9—H9B	110.4	C70—C69—H69	119.7
H9A—C9—H9B	108.6	C68—C69—H69	119.7
C6—C10—C9	103.0 (7)	C69—C70—C71	119.4 (10)
C6—C10—P2	117.0 (7)	C69—C70—H70	120.3
C9—C10—P2	116.7 (7)	C71—C70—H70	120.3
C6—C10—H10	106.4	C72—C71—C70	122.4 (11)
C9—C10—H10	106.4	C72—C71—H71	118.8
P2—C10—H10	106.4	C70—C71—H71	118.8
C16—C11—C12	117.4 (10)	C71—C72—C67	119.0 (11)
C16—C11—P1	123.0 (8)	C71—C72—H72	120.5
C12—C11—P1	119.6 (8)	C67—C72—H72	120.5
C13—C12—C11	120.7 (10)	C78—C73—C74	117.2 (9)
C13—C12—H12	119.7	C78—C73—P4	123.4 (8)
C11—C12—H12	119.7	C74—C73—P4	119.1 (8)
C14—C13—C12	120.7 (11)	C75—C74—C73	121.2 (10)
C14—C13—H13	119.6	C75—C74—H74	119.4
C12—C13—H13	119.6	C73—C74—H74	119.4
C13—C14—C15	120.1 (12)	C76—C75—C74	120.8 (11)
C13—C14—H14	119.9	C76—C75—H75	119.6
C15—C14—H14	119.9	C74—C75—H75	119.6
C14—C15—C16	119.6 (11)	C75—C76—C77	118.8 (11)
C14—C15—H15	120.2	C75—C76—H76	120.6
C16—C15—H15	120.2	C77—C76—H76	120.6
C11—C16—C15	121.4 (11)	C78—C77—C76	119.8 (11)
C11—C16—H16	119.3	C78—C77—H77	120.1
C15—C16—H16	119.3	C76—C77—H77	120.1
C22—C17—C18	117.5 (10)	C77—C78—C73	122.0 (11)
C22—C17—P1	120.8 (9)	C77—C78—H78	119.0
C18—C17—P1	121.7 (9)	C73—C78—H78	119.0
C19—C18—C17	120.0 (12)	C80—C79—C84	116.3 (10)
C19—C18—H18	120.0	C80—C79—P4	121.4 (8)
C17—C18—H18	120.0	C84—C79—P4	121.6 (10)
C20—C19—C18	119.3 (12)	C81—C80—C79	122.6 (11)
C20—C19—H19	120.4	C81—C80—H80	118.7
C18—C19—H19	120.4	C79—C80—H80	118.7
C21—C20—C19	120.7 (10)	C80—C81—C82	120.4 (11)
C21—C20—H20	119.7	C80—C81—H81	119.8
C19—C20—H20	119.7	C82—C81—H81	119.8
C20—C21—C22	118.7 (10)	C81—C82—C83	119.3 (10)
C20—C21—H21	120.6	C81—C82—H82	120.4
C22—C21—H21	120.6	C83—C82—H82	120.4
C17—C22—C21	123.8 (10)	C84—C83—C82	119.8 (10)
C17—C22—H22	118.1	C84—C83—H83	120.1
C21—C22—H22	118.1	C82—C83—H83	120.1
C24—C23—C28	118.3 (9)	C83—C84—C79	121.6 (11)
C24—C23—P2	119.5 (8)	C83—C84—H84	119.2
C28—C23—P2	122.1 (8)	C79—C84—H84	119.2
C25—C24—C23	119.8 (10)	C86—C85—C90	105.5 (9)
C25—C24—H24	120.1	C86—C85—Rh2	71.3 (6)
C23—C24—H24	120.1	C90—C85—Rh2	95.2 (7)
C26—C25—C24	121.8 (11)	C86—C85—H85	123.7
C26—C25—H25	119.1	C90—C85—H85	123.7
C24—C25—H25	119.1	Rh2—C85—H85	123.7
C25—C26—C27	119.7 (11)	C85—C86—C87	108.3 (9)
C25—C26—H26	120.1	C85—C86—Rh2	72.5 (6)
C27—C26—H26	120.1	C87—C86—Rh2	97.2 (6)
C28—C27—C26	120.4 (11)	C85—C86—H86	122.2
C28—C27—H27	119.8	C87—C86—H86	122.2
C26—C27—H27	119.8	Rh2—C86—H86	122.2
C27—C28—C23	119.9 (10)	C86—C87—C88	102.5 (8)
C27—C28—H28	120.1	C86—C87—C91	100.0 (9)
C23—C28—H28	120.1	C88—C87—C91	99.6 (9)
C34—C29—C30	116.8 (10)	C86—C87—H87	117.2
C34—C29—P2	121.5 (9)	C88—C87—H87	117.2
C30—C29—P2	121.1 (9)	C91—C87—H87	117.2
C31—C30—C29	120.3 (10)	C89—C88—C87	106.8 (10)
C31—C30—H30	119.9	C89—C88—Rh2	71.1 (6)
C29—C30—H30	119.9	C87—C88—Rh2	95.1 (6)
C32—C31—C30	121.1 (10)	C89—C88—H88	123.3
C32—C31—H31	119.4	C87—C88—H88	123.3
C30—C31—H31	119.4	Rh2—C88—H88	123.3
C31—C32—C33	120.0 (10)	C88—C89—C90	106.2 (10)
C31—C32—H32	120.0	C88—C89—Rh2	72.6 (6)
C33—C32—H32	120.0	C90—C89—Rh2	95.2 (7)
C34—C33—C32	119.2 (11)	C88—C89—H89	123.2
C34—C33—H33	120.4	C90—C89—H89	123.2
C32—C33—H33	120.4	Rh2—C89—H89	123.2
C33—C34—C29	122.6 (11)	C85—C90—C89	103.1 (9)
C33—C34—H34	118.7	C85—C90—C91	99.5 (9)
C29—C34—H34	118.7	C89—C90—C91	99.8 (10)
C36—C35—C40	104.5 (9)	C85—C90—H90	117.2
C36—C35—Rh1	70.6 (6)	C89—C90—H90	117.2
C40—C35—Rh1	94.9 (7)	C91—C90—H90	117.2
C36—C35—H35	124.1	C87—C91—C90	93.7 (8)
C40—C35—H35	124.1	C87—C91—H91A	113.0
Rh1—C35—H35	124.1	C90—C91—H91A	113.0
C35—C36—C37	107.3 (9)	C87—C91—H91B	113.0
C35—C36—Rh1	72.9 (6)	C90—C91—H91B	113.0
C37—C36—Rh1	98.1 (7)	H91A—C91—H91B	110.4
C35—C36—H36	122.2	F2—B1—F1	112.0 (12)
C37—C36—H36	122.2	F2—B1—F4	109.0 (10)
Rh1—C36—H36	122.2	F1—B1—F4	107.0 (12)
C41—C37—C36	101.2 (8)	F2—B1—F3	110.7 (11)
C41—C37—C38	101.3 (8)	F1—B1—F3	108.5 (10)
C36—C37—C38	101.2 (7)	F4—B1—F3	109.5 (11)
C41—C37—H37	116.8	F7—B2—F5	108.7 (11)
C36—C37—H37	116.8	F7—B2—F8	110.3 (13)
C38—C37—H37	116.8	F5—B2—F8	111.0 (12)
C39—C38—C37	106.1 (9)	F7—B2—F6	108.6 (11)
C39—C38—Rh1	71.4 (6)	F5—B2—F6	110.1 (12)
C37—C38—Rh1	95.6 (6)	F8—B2—F6	108.2 (11)
C11—P1—C1—C2	−71.5 (9)	C38—C37—C41—C40	−52.2 (10)
C17—P1—C1—C2	37.4 (10)	C35—C40—C41—C37	−53.5 (10)
Rh1—P1—C1—C2	165.9 (8)	C39—C40—C41—C37	52.2 (10)
C11—P1—C1—C5	153.7 (8)	C55—C51—C52—C53	−39.7 (12)
C17—P1—C1—C5	−97.5 (9)	P3—C51—C52—C53	−177.0 (8)
Rh1—P1—C1—C5	31.0 (9)	C51—C52—C53—C54	8.4 (13)
C5—C1—C2—C3	−34.2 (12)	C52—C53—C54—C55	21.2 (13)
P1—C1—C2—C3	−176.5 (9)	C52—C51—C55—C56	−68.3 (12)
C1—C2—C3—C4	11.0 (14)	P3—C51—C55—C56	66.1 (11)
C2—C3—C4—C5	17.1 (14)	C52—C51—C55—C54	50.8 (10)
C3—C4—C5—C6	85.6 (11)	P3—C51—C55—C54	−174.7 (7)
C3—C4—C5—C1	−37.7 (12)	C53—C54—C55—C51	−42.4 (11)
C2—C1—C5—C4	43.6 (10)	C53—C54—C55—C56	81.5 (12)
P1—C1—C5—C4	−174.5 (7)	C51—C55—C56—C57	168.6 (9)
C2—C1—C5—C6	−75.4 (10)	C54—C55—C56—C57	59.8 (12)
P1—C1—C5—C6	66.4 (11)	C51—C55—C56—C60	−68.4 (13)
C4—C5—C6—C7	60.2 (11)	C54—C55—C56—C60	−177.2 (9)
C1—C5—C6—C7	173.5 (9)	C55—C56—C57—C58	167.0 (9)
C4—C5—C6—C10	−179.2 (9)	C60—C56—C57—C58	35.3 (12)
C1—C5—C6—C10	−65.8 (12)	C56—C57—C58—C59	−21.9 (13)
C5—C6—C7—C8	164.9 (9)	C57—C58—C59—C60	0.4 (13)
C10—C6—C7—C8	35.6 (11)	C55—C56—C60—C59	−161.1 (9)
C6—C7—C8—C9	−19.7 (13)	C57—C56—C60—C59	−34.3 (11)
C7—C8—C9—C10	−4.3 (12)	C55—C56—C60—P4	−34.2 (12)
C7—C6—C10—C9	−37.3 (10)	C57—C56—C60—P4	92.6 (9)
C5—C6—C10—C9	−163.4 (8)	C58—C59—C60—C56	20.9 (11)
C7—C6—C10—P2	92.1 (9)	C58—C59—C60—P4	−107.1 (9)
C5—C6—C10—P2	−34.0 (11)	C79—P4—C60—C56	−165.0 (8)
C8—C9—C10—C6	25.9 (11)	C73—P4—C60—C56	−56.6 (8)
C8—C9—C10—P2	−103.8 (9)	Rh2—P4—C60—C56	72.0 (8)
C29—P2—C10—C6	−166.1 (7)	C79—P4—C60—C59	−43.5 (8)
C23—P2—C10—C6	−57.2 (8)	C73—P4—C60—C59	65.0 (8)
Rh1—P2—C10—C6	72.8 (8)	Rh2—P4—C60—C59	−166.4 (6)
C29—P2—C10—C9	−43.5 (9)	C67—P3—C61—C66	18.4 (11)
C23—P2—C10—C9	65.4 (8)	C51—P3—C61—C66	134.9 (10)
Rh1—P2—C10—C9	−164.6 (6)	Rh2—P3—C61—C66	−103.0 (9)
C1—P1—C11—C16	135.2 (9)	C67—P3—C61—C62	−165.5 (9)
C17—P1—C11—C16	19.8 (10)	C51—P3—C61—C62	−49.0 (10)
Rh1—P1—C11—C16	−101.3 (9)	Rh2—P3—C61—C62	73.1 (9)
C1—P1—C11—C12	−48.0 (9)	C66—C61—C62—C63	−2.2 (16)
C17—P1—C11—C12	−163.3 (9)	P3—C61—C62—C63	−178.5 (9)
Rh1—P1—C11—C12	75.6 (9)	C61—C62—C63—C64	0.3 (18)
C16—C11—C12—C13	−1.2 (16)	C62—C63—C64—C65	1.8 (19)
P1—C11—C12—C13	−178.2 (9)	C63—C64—C65—C66	−1.8 (19)
C11—C12—C13—C14	−0.2 (18)	C62—C61—C66—C65	2.2 (17)
C12—C13—C14—C15	1.4 (19)	P3—C61—C66—C65	178.4 (9)
C13—C14—C15—C16	−1.1 (18)	C64—C65—C66—C61	−0.2 (18)
C12—C11—C16—C15	1.5 (16)	C61—P3—C67—C68	−120.5 (9)
P1—C11—C16—C15	178.4 (9)	C51—P3—C67—C68	129.8 (8)
C14—C15—C16—C11	−0.4 (17)	Rh2—P3—C67—C68	1.7 (9)
C1—P1—C17—C22	130.2 (9)	C61—P3—C67—C72	57.3 (10)
C11—P1—C17—C22	−120.8 (9)	C51—P3—C67—C72	−52.4 (11)
Rh1—P1—C17—C22	0.7 (10)	Rh2—P3—C67—C72	179.4 (8)
C1—P1—C17—C18	−49.6 (11)	C72—C67—C68—C69	−0.4 (15)
C11—P1—C17—C18	59.4 (10)	P3—C67—C68—C69	177.4 (8)
Rh1—P1—C17—C18	−179.1 (8)	C67—C68—C69—C70	0.7 (16)
C22—C17—C18—C19	2.4 (17)	C68—C69—C70—C71	−0.9 (17)
P1—C17—C18—C19	−177.9 (9)	C69—C70—C71—C72	0.8 (18)
C17—C18—C19—C20	−3.3 (18)	C70—C71—C72—C67	−0.5 (18)
C18—C19—C20—C21	3.7 (17)	C68—C67—C72—C71	0.3 (17)
C19—C20—C21—C22	−3.2 (16)	P3—C67—C72—C71	−177.4 (9)
C18—C17—C22—C21	−1.9 (16)	C79—P4—C73—C78	41.5 (10)
P1—C17—C22—C21	178.3 (8)	C60—P4—C73—C78	−68.0 (9)
C20—C21—C22—C17	2.4 (16)	Rh2—P4—C73—C78	159.4 (7)
C29—P2—C23—C24	−142.0 (8)	C79—P4—C73—C74	−144.0 (8)
C10—P2—C23—C24	108.6 (8)	C60—P4—C73—C74	106.5 (8)
Rh1—P2—C23—C24	−25.3 (9)	Rh2—P4—C73—C74	−26.1 (9)
C29—P2—C23—C28	42.6 (9)	C78—C73—C74—C75	3.7 (14)
C10—P2—C23—C28	−66.8 (9)	P4—C73—C74—C75	−171.1 (8)
Rh1—P2—C23—C28	159.3 (7)	C73—C74—C75—C76	−0.1 (16)
C28—C23—C24—C25	1.9 (14)	C74—C75—C76—C77	−3.0 (17)
P2—C23—C24—C25	−173.7 (8)	C75—C76—C77—C78	2.5 (17)
C23—C24—C25—C26	0.2 (17)	C76—C77—C78—C73	1.2 (16)
C24—C25—C26—C27	−3.2 (19)	C74—C73—C78—C77	−4.3 (15)
C25—C26—C27—C28	4.3 (18)	P4—C73—C78—C77	170.4 (8)
C26—C27—C28—C23	−2.2 (16)	C73—P4—C79—C80	39.7 (10)
C24—C23—C28—C27	−0.8 (14)	C60—P4—C79—C80	150.0 (9)
P2—C23—C28—C27	174.6 (8)	Rh2—P4—C79—C80	−80.6 (10)
C10—P2—C29—C34	149.5 (9)	C73—P4—C79—C84	−150.3 (9)
C23—P2—C29—C34	38.3 (10)	C60—P4—C79—C84	−39.9 (10)
Rh1—P2—C29—C34	−81.8 (10)	Rh2—P4—C79—C84	89.4 (9)
C10—P2—C29—C30	−39.7 (10)	C84—C79—C80—C81	2.1 (17)
C23—P2—C29—C30	−150.9 (9)	P4—C79—C80—C81	172.6 (9)
Rh1—P2—C29—C30	89.0 (9)	C79—C80—C81—C82	−2.0 (17)
C34—C29—C30—C31	−0.3 (15)	C80—C81—C82—C83	1.5 (16)
P2—C29—C30—C31	−171.5 (8)	C81—C82—C83—C84	−1.2 (16)
C29—C30—C31—C32	2.3 (16)	C82—C83—C84—C79	1.4 (17)
C30—C31—C32—C33	−2.9 (17)	C80—C79—C84—C83	−1.8 (16)
C31—C32—C33—C34	1.5 (17)	P4—C79—C84—C83	−172.3 (8)
C32—C33—C34—C29	0.5 (17)	C90—C85—C86—C87	−1.7 (11)
C30—C29—C34—C33	−1.1 (16)	Rh2—C85—C86—C87	−92.0 (7)
P2—C29—C34—C33	170.0 (8)	C90—C85—C86—Rh2	90.3 (8)
C40—C35—C36—C37	−3.3 (11)	C85—C86—C87—C88	69.2 (10)
Rh1—C35—C36—C37	−93.3 (7)	Rh2—C86—C87—C88	−4.6 (8)
C40—C35—C36—Rh1	90.1 (7)	C85—C86—C87—C91	−33.0 (10)
C35—C36—C37—C41	−32.0 (10)	Rh2—C86—C87—C91	−106.9 (7)
Rh1—C36—C37—C41	−106.5 (7)	C86—C87—C88—C89	−67.2 (10)
C35—C36—C37—C38	72.1 (9)	C91—C87—C88—C89	35.4 (10)
Rh1—C36—C37—C38	−2.4 (7)	C86—C87—C88—Rh2	4.6 (8)
C41—C37—C38—C39	34.1 (10)	C91—C87—C88—Rh2	107.2 (7)
C36—C37—C38—C39	−69.9 (10)	C87—C88—C89—C90	−0.8 (11)
C41—C37—C38—Rh1	106.4 (7)	Rh2—C88—C89—C90	−90.4 (7)
C36—C37—C38—Rh1	2.4 (7)	C87—C88—C89—Rh2	89.7 (7)
C37—C38—C39—C40	0.5 (10)	C86—C85—C90—C89	−67.0 (11)
Rh1—C38—C39—C40	−90.1 (7)	Rh2—C85—C90—C89	5.0 (9)
C37—C38—C39—Rh1	90.6 (7)	C86—C85—C90—C91	35.5 (11)
C36—C35—C40—C41	36.9 (11)	Rh2—C85—C90—C91	107.5 (8)
Rh1—C35—C40—C41	108.1 (8)	C88—C89—C90—C85	68.3 (10)
C36—C35—C40—C39	−66.5 (10)	Rh2—C89—C90—C85	−5.0 (9)
Rh1—C35—C40—C39	4.7 (8)	C88—C89—C90—C91	−33.9 (10)
C38—C39—C40—C41	−34.5 (10)	Rh2—C89—C90—C91	−107.3 (7)
Rh1—C39—C40—C41	−107.8 (7)	C86—C87—C91—C90	51.5 (10)
C38—C39—C40—C35	68.6 (10)	C88—C87—C91—C90	−53.1 (10)
Rh1—C39—C40—C35	−4.7 (8)	C85—C90—C91—C87	−52.5 (10)
C36—C37—C41—C40	51.7 (10)	C89—C90—C91—C87	52.7 (10)

(RhBICPcodBF4) [(1R,1'R,2R,2'R)-2,2'-Bis(diphenylphosphanyl)-1,1'-dicyclopentane][η⁴-(Z,Z)-cycloocta-1,5-diene]rhodium(I) tetrafluoroborate dichloromethane monosolvate

Crystal data

[Rh(C34H36P2)(C8H12)]BF4·CH2Cl2	F(000) = 916
Mr = 889.39	Dx = 1.499 Mg m^−3
Monoclinic, P21	Mo Kα radiation, λ = 0.71073 Å
a = 10.2285 (2) Å	Cell parameters from 9728 reflections
b = 13.9823 (3) Å	θ = 2.9–33.4°
c = 14.5131 (4) Å	µ = 0.70 mm^−1
β = 108.2650 (12)°	T = 150 K
V = 1971.06 (8) Å^3	Part of prism, red
Z = 2	0.38 × 0.34 × 0.16 mm

Data collection

Bruker APEXII CCD area-detector diffractometer	9780 independent reflections
Radiation source: sealed tube	9496 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.034
Detector resolution: 8.3333 pixels mm^-1	θmax = 28.3°, θmin = 2.1°
φ and ω scans	h = −13→13
Absorption correction: multi-scan (SADABS; Bruker, 2008)	k = −18→18
Tmin = 0.670, Tmax = 0.749	l = −19→19
64265 measured reflections

Refinement

Refinement on F^2	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.020	w = 1/[σ^2(Fo^2) + (0.0228P)^2 + 0.6524P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.048	(Δ/σ)max = 0.001
S = 1.04	Δρmax = 0.46 e Å^−3
9780 reflections	Δρmin = −0.46 e Å^−3
524 parameters	Absolute structure: Flack x determined using 4470 quotients [(I+)-(I-)]/[(I+)+(I-)] (Parsons et al., 2013)
25 restraints	Absolute structure parameter: −0.015 (5)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Rh1	0.41617 (2)	0.24643 (2)	0.23220 (2)	0.01403 (4)
P1	0.44955 (6)	0.38414 (4)	0.15326 (4)	0.01486 (11)
P2	0.32514 (6)	0.33385 (4)	0.33545 (4)	0.01515 (12)
C1	0.2886 (2)	0.44676 (18)	0.09159 (18)	0.0168 (5)
H1	0.2450	0.4052	0.0340	0.020*
C2	0.2935 (3)	0.54545 (19)	0.0459 (2)	0.0240 (5)
H2A	0.3411	0.5422	−0.0038	0.029*
H2B	0.3402	0.5932	0.0958	0.029*
C3	0.1399 (3)	0.5693 (2)	0.0001 (2)	0.0307 (6)
H3A	0.1079	0.5509	−0.0692	0.037*
H3B	0.1239	0.6387	0.0052	0.037*
C4	0.0631 (3)	0.5114 (2)	0.05753 (19)	0.0240 (5)
H4A	−0.0010	0.4654	0.0142	0.029*
H4B	0.0094	0.5547	0.0859	0.029*
C5	0.1737 (2)	0.45702 (18)	0.13946 (18)	0.0182 (5)
H5	0.1378	0.3921	0.1475	0.022*
C6	0.2084 (2)	0.51101 (18)	0.23624 (18)	0.0190 (5)
H6	0.2452	0.5749	0.2256	0.023*
C7	0.0824 (3)	0.5299 (2)	0.26988 (19)	0.0265 (6)
H7A	0.0208	0.5782	0.2281	0.032*
H7B	0.0296	0.4704	0.2690	0.032*
C8	0.1447 (3)	0.5672 (3)	0.3732 (2)	0.0368 (7)
H8A	0.0828	0.5537	0.4122	0.044*
H8B	0.1600	0.6371	0.3729	0.044*
C9	0.2820 (3)	0.51438 (19)	0.41508 (19)	0.0225 (5)
H9A	0.2743	0.4652	0.4622	0.027*
H9B	0.3557	0.5598	0.4487	0.027*
C10	0.3153 (2)	0.46676 (17)	0.32827 (17)	0.0174 (4)
H10	0.4082	0.4903	0.3296	0.021*
C11	0.5253 (3)	0.36461 (16)	0.05541 (17)	0.0176 (4)
C12	0.4464 (3)	0.34150 (18)	−0.03916 (18)	0.0213 (5)
H12	0.3488	0.3425	−0.0568	0.026*
C13	0.5098 (3)	0.31695 (19)	−0.1077 (2)	0.0262 (6)
H13	0.4552	0.3017	−0.1720	0.031*
C14	0.6517 (3)	0.31456 (19)	−0.0830 (2)	0.0281 (6)
H14	0.6944	0.2966	−0.1299	0.034*
C15	0.7317 (3)	0.3384 (2)	0.0105 (2)	0.0261 (5)
H15	0.8292	0.3376	0.0276	0.031*
C16	0.6685 (3)	0.36342 (19)	0.07889 (19)	0.0224 (5)
H16	0.7237	0.3800	0.1427	0.027*
C17	0.5785 (3)	0.46552 (19)	0.2293 (2)	0.0196 (5)
C18	0.6139 (3)	0.55152 (19)	0.1928 (2)	0.0254 (5)
H18	0.5669	0.5703	0.1280	0.030*
C19	0.7174 (3)	0.6090 (2)	0.2516 (2)	0.0318 (6)
H19	0.7415	0.6670	0.2268	0.038*
C20	0.7860 (3)	0.5815 (2)	0.3469 (3)	0.0352 (7)
H20	0.8550	0.6218	0.3875	0.042*
C21	0.7543 (3)	0.4965 (2)	0.3822 (2)	0.0332 (6)
H21	0.8024	0.4775	0.4469	0.040*
C22	0.6515 (3)	0.4379 (2)	0.3232 (2)	0.0241 (6)
H22	0.6312	0.3786	0.3476	0.029*
C23	0.1518 (2)	0.29339 (17)	0.32712 (18)	0.0176 (5)
C24	0.0960 (3)	0.30752 (19)	0.40233 (19)	0.0234 (5)
H24	0.1515	0.3335	0.4623	0.028*
C25	−0.0400 (3)	0.2839 (2)	0.3901 (2)	0.0293 (6)
H25	−0.0771	0.2940	0.4416	0.035*
C26	−0.1221 (2)	0.2456 (3)	0.30310 (19)	0.0303 (5)
H26	−0.2159	0.2311	0.2944	0.036*
C27	−0.0669 (3)	0.22856 (18)	0.2291 (2)	0.0258 (6)
H27	−0.1224	0.2009	0.1700	0.031*
C28	0.0692 (2)	0.2518 (2)	0.24073 (16)	0.0202 (4)
H28	0.1067	0.2393	0.1897	0.024*
C29	0.4253 (3)	0.31440 (18)	0.46317 (17)	0.0188 (5)
C30	0.4031 (3)	0.2339 (2)	0.51345 (17)	0.0243 (6)
H30	0.3275	0.1929	0.4840	0.029*
C31	0.4907 (3)	0.2131 (2)	0.6064 (2)	0.0315 (6)
H31	0.4744	0.1583	0.6399	0.038*
C32	0.6012 (3)	0.2723 (2)	0.6496 (2)	0.0374 (8)
H32	0.6629	0.2569	0.7118	0.045*
C33	0.6217 (3)	0.3540 (2)	0.6021 (2)	0.0334 (7)
H33	0.6957	0.3958	0.6330	0.040*
C34	0.5352 (3)	0.3753 (2)	0.50993 (19)	0.0254 (5)
H34	0.5503	0.4317	0.4781	0.030*
C35	0.3424 (3)	0.10766 (18)	0.28107 (19)	0.0219 (5)
H35	0.2788	0.1167	0.3205	0.026*
C36	0.4785 (3)	0.12082 (18)	0.33184 (19)	0.0225 (5)
H36	0.4950	0.1373	0.4016	0.027*
C37	0.5979 (3)	0.0692 (2)	0.3135 (2)	0.0266 (6)
H37A	0.6012	0.0029	0.3380	0.032*
H37B	0.6846	0.1013	0.3508	0.032*
C38	0.5891 (3)	0.0663 (2)	0.2059 (2)	0.0246 (5)
H38A	0.6833	0.0608	0.2012	0.029*
H38B	0.5373	0.0084	0.1758	0.029*
C39	0.5198 (3)	0.15355 (18)	0.14924 (18)	0.0206 (5)
H39	0.5794	0.1897	0.1183	0.025*
C40	0.3812 (3)	0.16018 (18)	0.09964 (18)	0.0203 (5)
H40	0.3600	0.1992	0.0390	0.024*
C41	0.2727 (3)	0.0869 (2)	0.0978 (2)	0.0264 (6)
H41A	0.2748	0.0366	0.0503	0.032*
H41B	0.1813	0.1181	0.0748	0.032*
C42	0.2889 (3)	0.03933 (19)	0.1964 (2)	0.0273 (6)
H42A	0.1986	0.0139	0.1964	0.033*
H42B	0.3532	−0.0153	0.2051	0.033*
B1	0.0439 (9)	0.2767 (5)	0.8985 (5)	0.0265 (18)	0.655 (11)
F1	0.0418 (9)	0.2732 (4)	0.9927 (4)	0.0296 (18)	0.655 (11)
F2	0.0856 (6)	0.3668 (3)	0.8796 (2)	0.0447 (14)	0.655 (11)
F3	0.1349 (4)	0.2099 (4)	0.8855 (4)	0.0404 (11)	0.655 (11)
F4	−0.0847 (6)	0.2592 (5)	0.8351 (7)	0.0529 (16)	0.655 (11)
B1'	0.0096 (12)	0.2837 (7)	0.8886 (8)	0.021 (3)	0.345 (11)
F1'	0.0293 (16)	0.2713 (9)	0.9855 (7)	0.050 (6)	0.345 (11)
F2'	−0.0189 (16)	0.3785 (4)	0.8658 (5)	0.061 (4)	0.345 (11)
F3'	0.1247 (8)	0.2579 (10)	0.8660 (7)	0.062 (3)	0.345 (11)
F4'	−0.1010 (10)	0.2309 (8)	0.8354 (12)	0.041 (3)	0.345 (11)
C51	0.0206 (7)	0.3922 (4)	0.6660 (4)	0.0879 (19)
H51A	−0.0537	0.3548	0.6200	0.106*
H51B	0.0158	0.3807	0.7322	0.106*
Cl1	0.18126 (13)	0.35195 (8)	0.65983 (7)	0.0593 (3)
Cl2	−0.00589 (15)	0.51239 (9)	0.63875 (12)	0.0863 (5)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Rh1	0.01564 (7)	0.01289 (7)	0.01393 (7)	0.00028 (8)	0.00518 (5)	0.00058 (8)
P1	0.0155 (3)	0.0143 (3)	0.0161 (3)	0.0000 (2)	0.0069 (2)	0.0004 (2)
P2	0.0151 (3)	0.0168 (3)	0.0137 (3)	−0.0004 (2)	0.0047 (2)	−0.0003 (2)
C1	0.0172 (11)	0.0164 (11)	0.0175 (11)	0.0025 (9)	0.0067 (9)	0.0036 (9)
C2	0.0301 (14)	0.0199 (12)	0.0260 (13)	0.0041 (10)	0.0142 (11)	0.0075 (10)
C3	0.0354 (15)	0.0245 (13)	0.0306 (14)	0.0082 (11)	0.0080 (12)	0.0098 (11)
C4	0.0203 (12)	0.0278 (13)	0.0219 (12)	0.0073 (10)	0.0037 (9)	0.0032 (10)
C5	0.0155 (11)	0.0190 (11)	0.0199 (12)	0.0024 (9)	0.0054 (9)	0.0028 (9)
C6	0.0198 (11)	0.0189 (11)	0.0203 (12)	0.0032 (9)	0.0094 (9)	0.0012 (9)
C7	0.0239 (13)	0.0326 (14)	0.0259 (13)	0.0104 (11)	0.0118 (11)	0.0045 (11)
C8	0.0373 (16)	0.0470 (18)	0.0293 (15)	0.0190 (14)	0.0151 (13)	−0.0020 (13)
C9	0.0243 (12)	0.0222 (12)	0.0235 (12)	−0.0002 (10)	0.0111 (10)	−0.0055 (10)
C10	0.0176 (11)	0.0171 (11)	0.0189 (11)	0.0003 (9)	0.0075 (9)	−0.0022 (9)
C11	0.0237 (11)	0.0129 (10)	0.0195 (11)	0.0006 (9)	0.0118 (9)	0.0012 (8)
C12	0.0257 (12)	0.0184 (11)	0.0220 (12)	0.0006 (10)	0.0106 (10)	0.0013 (9)
C13	0.0394 (16)	0.0214 (12)	0.0204 (12)	0.0023 (11)	0.0133 (11)	−0.0014 (10)
C14	0.0417 (16)	0.0227 (12)	0.0294 (14)	0.0045 (11)	0.0249 (13)	0.0013 (10)
C15	0.0259 (13)	0.0260 (13)	0.0325 (14)	0.0034 (10)	0.0181 (11)	0.0024 (11)
C16	0.0228 (12)	0.0234 (12)	0.0241 (12)	0.0002 (10)	0.0116 (10)	0.0001 (10)
C17	0.0156 (11)	0.0203 (12)	0.0254 (13)	−0.0022 (9)	0.0103 (10)	−0.0055 (10)
C18	0.0244 (13)	0.0213 (12)	0.0343 (14)	−0.0020 (10)	0.0149 (11)	−0.0022 (11)
C19	0.0234 (13)	0.0223 (13)	0.0552 (19)	−0.0062 (11)	0.0203 (13)	−0.0072 (13)
C20	0.0187 (13)	0.0304 (15)	0.054 (2)	−0.0030 (11)	0.0075 (12)	−0.0128 (14)
C21	0.0187 (12)	0.0390 (16)	0.0363 (16)	0.0005 (11)	0.0005 (11)	−0.0095 (13)
C22	0.0179 (13)	0.0254 (13)	0.0288 (14)	0.0003 (10)	0.0067 (11)	−0.0017 (11)
C23	0.0158 (11)	0.0174 (11)	0.0196 (11)	−0.0010 (9)	0.0056 (9)	0.0016 (9)
C24	0.0221 (12)	0.0277 (13)	0.0222 (12)	−0.0023 (10)	0.0095 (10)	−0.0014 (10)
C25	0.0266 (14)	0.0338 (13)	0.0330 (15)	−0.0022 (11)	0.0172 (12)	0.0000 (11)
C26	0.0186 (10)	0.0309 (12)	0.0430 (14)	−0.0019 (16)	0.0119 (9)	0.0021 (18)
C27	0.0203 (11)	0.0236 (18)	0.0295 (12)	−0.0022 (9)	0.0020 (9)	−0.0018 (10)
C28	0.0208 (10)	0.0188 (10)	0.0202 (9)	0.0012 (13)	0.0055 (8)	0.0007 (13)
C29	0.0180 (11)	0.0263 (12)	0.0121 (10)	0.0017 (9)	0.0048 (9)	−0.0019 (9)
C30	0.0257 (11)	0.0299 (16)	0.0179 (10)	0.0047 (11)	0.0077 (9)	0.0035 (11)
C31	0.0373 (16)	0.0401 (15)	0.0190 (12)	0.0125 (12)	0.0116 (12)	0.0071 (11)
C32	0.0346 (15)	0.058 (2)	0.0164 (12)	0.0151 (13)	0.0029 (11)	−0.0017 (12)
C33	0.0250 (13)	0.0476 (18)	0.0234 (14)	0.0032 (13)	0.0016 (11)	−0.0113 (12)
C34	0.0216 (12)	0.0316 (14)	0.0219 (12)	−0.0006 (11)	0.0051 (10)	−0.0060 (10)
C35	0.0268 (13)	0.0163 (11)	0.0262 (13)	0.0016 (9)	0.0133 (10)	0.0061 (10)
C36	0.0303 (13)	0.0185 (11)	0.0200 (12)	0.0058 (10)	0.0098 (10)	0.0050 (9)
C37	0.0275 (15)	0.0259 (14)	0.0273 (14)	0.0078 (11)	0.0096 (12)	0.0062 (11)
C38	0.0285 (14)	0.0202 (13)	0.0275 (14)	0.0063 (11)	0.0123 (11)	0.0017 (10)
C39	0.0260 (13)	0.0171 (11)	0.0218 (12)	0.0018 (10)	0.0118 (10)	0.0001 (9)
C40	0.0277 (13)	0.0173 (11)	0.0160 (11)	−0.0009 (10)	0.0068 (9)	−0.0021 (9)
C41	0.0303 (14)	0.0189 (13)	0.0262 (14)	−0.0051 (11)	0.0033 (11)	−0.0035 (11)
C42	0.0305 (14)	0.0188 (12)	0.0342 (15)	−0.0055 (10)	0.0123 (12)	−0.0002 (11)
B1	0.017 (3)	0.033 (4)	0.027 (3)	−0.003 (2)	0.004 (2)	−0.002 (2)
F1	0.038 (3)	0.025 (3)	0.022 (3)	−0.006 (2)	0.004 (2)	−0.0013 (18)
F2	0.064 (3)	0.0354 (18)	0.0335 (16)	−0.0154 (18)	0.0143 (16)	−0.0002 (12)
F3	0.0322 (18)	0.049 (2)	0.040 (2)	0.0099 (19)	0.0124 (15)	−0.0108 (19)
F4	0.027 (2)	0.070 (4)	0.054 (3)	−0.010 (2)	0.002 (2)	−0.018 (3)
B1'	0.012 (7)	0.025 (5)	0.023 (6)	0.002 (4)	0.001 (5)	−0.009 (4)
F1'	0.044 (7)	0.070 (11)	0.052 (9)	−0.001 (6)	0.035 (7)	−0.009 (6)
F2'	0.125 (12)	0.022 (3)	0.042 (4)	0.012 (4)	0.036 (5)	0.005 (3)
F3'	0.033 (4)	0.088 (9)	0.071 (6)	0.020 (5)	0.027 (4)	0.011 (6)
F4'	0.019 (3)	0.051 (6)	0.041 (5)	−0.010 (3)	−0.009 (3)	−0.024 (4)
C51	0.131 (5)	0.067 (3)	0.089 (4)	0.026 (3)	0.068 (4)	0.026 (3)
Cl1	0.0856 (8)	0.0492 (5)	0.0404 (5)	0.0018 (5)	0.0158 (5)	0.0047 (4)
Cl2	0.0818 (9)	0.0478 (6)	0.1018 (10)	0.0025 (6)	−0.0108 (7)	−0.0102 (6)

Geometric parameters (Å, º)

Rh1—C40	2.203 (2)	C21—C22	1.395 (4)
Rh1—C36	2.237 (2)	C21—H21	0.9500
Rh1—C39	2.250 (2)	C22—H22	0.9500
Rh1—C35	2.274 (2)	C23—C24	1.396 (4)
Rh1—P1	2.3198 (6)	C23—C28	1.400 (3)
Rh1—P2	2.3411 (6)	C24—C25	1.385 (4)
P1—C17	1.828 (3)	C24—H24	0.9500
P1—C1	1.832 (2)	C25—C26	1.386 (4)
P1—C11	1.839 (2)	C25—H25	0.9500
P2—C23	1.829 (2)	C26—C27	1.382 (4)
P2—C29	1.835 (2)	C26—H26	0.9500
P2—C10	1.862 (2)	C27—C28	1.388 (3)
C1—C2	1.538 (3)	C27—H27	0.9500
C1—C5	1.548 (3)	C28—H28	0.9500
C1—H1	1.0000	C29—C30	1.398 (4)
C2—C3	1.539 (4)	C29—C34	1.404 (4)
C2—H2A	0.9900	C30—C31	1.396 (4)
C2—H2B	0.9900	C30—H30	0.9500
C3—C4	1.542 (4)	C31—C32	1.382 (5)
C3—H3A	0.9900	C31—H31	0.9500
C3—H3B	0.9900	C32—C33	1.384 (5)
C4—C5	1.558 (3)	C32—H32	0.9500
C4—H4A	0.9900	C33—C34	1.386 (4)
C4—H4B	0.9900	C33—H33	0.9500
C5—C6	1.535 (3)	C34—H34	0.9500
C5—H5	1.0000	C35—C36	1.368 (4)
C6—C7	1.537 (3)	C35—C42	1.517 (4)
C6—C10	1.564 (3)	C35—H35	1.0000
C6—H6	1.0000	C36—C37	1.512 (4)
C7—C8	1.526 (4)	C36—H36	1.0000
C7—H7A	0.9900	C37—C38	1.537 (4)
C7—H7B	0.9900	C37—H37A	0.9900
C8—C9	1.534 (4)	C37—H37B	0.9900
C8—H8A	0.9900	C38—C39	1.517 (4)
C8—H8B	0.9900	C38—H38A	0.9900
C9—C10	1.554 (3)	C38—H38B	0.9900
C9—H9A	0.9900	C39—C40	1.378 (4)
C9—H9B	0.9900	C39—H39	1.0000
C10—H10	1.0000	C40—C41	1.505 (4)
C11—C12	1.395 (3)	C40—H40	1.0000
C11—C16	1.396 (3)	C41—C42	1.539 (4)
C12—C13	1.390 (4)	C41—H41A	0.9900
C12—H12	0.9500	C41—H41B	0.9900
C13—C14	1.383 (4)	C42—H42A	0.9900
C13—H13	0.9500	C42—H42B	0.9900
C14—C15	1.388 (4)	B1—F4	1.370 (7)
C14—H14	0.9500	B1—F3	1.372 (7)
C15—C16	1.388 (4)	B1—F1	1.375 (6)
C15—H15	0.9500	B1—F2	1.385 (6)
C16—H16	0.9500	B1'—F3'	1.366 (8)
C17—C22	1.388 (4)	B1'—F1'	1.367 (8)
C17—C18	1.406 (4)	B1'—F4'	1.369 (8)
C18—C19	1.388 (4)	B1'—F2'	1.374 (8)
C18—H18	0.9500	C51—Cl2	1.728 (5)
C19—C20	1.395 (5)	C51—Cl1	1.765 (6)
C19—H19	0.9500	C51—H51A	0.9900
C20—C21	1.374 (5)	C51—H51B	0.9900
C20—H20	0.9500
C40—Rh1—C36	94.02 (9)	C20—C19—H19	120.0
C40—Rh1—C39	36.03 (9)	C21—C20—C19	120.3 (3)
C36—Rh1—C39	78.83 (9)	C21—C20—H20	119.9
C40—Rh1—C35	80.00 (10)	C19—C20—H20	119.9
C36—Rh1—C35	35.28 (10)	C20—C21—C22	120.0 (3)
C39—Rh1—C35	86.13 (9)	C20—C21—H21	120.0
C40—Rh1—P1	91.82 (7)	C22—C21—H21	120.0
C36—Rh1—P1	156.16 (7)	C17—C22—C21	120.7 (3)
C39—Rh1—P1	92.74 (7)	C17—C22—H22	119.7
C35—Rh1—P1	167.60 (7)	C21—C22—H22	119.7
C40—Rh1—P2	148.93 (7)	C24—C23—C28	118.6 (2)
C36—Rh1—P2	94.93 (7)	C24—C23—P2	122.04 (19)
C39—Rh1—P2	173.07 (7)	C28—C23—P2	119.21 (18)
C35—Rh1—P2	90.49 (7)	C25—C24—C23	120.4 (2)
P1—Rh1—P2	91.85 (2)	C25—C24—H24	119.8
C17—P1—C1	111.44 (12)	C23—C24—H24	119.8
C17—P1—C11	99.20 (11)	C24—C25—C26	120.4 (3)
C1—P1—C11	103.04 (11)	C24—C25—H25	119.8
C17—P1—Rh1	114.12 (9)	C26—C25—H25	119.8
C1—P1—Rh1	112.90 (8)	C27—C26—C25	119.7 (2)
C11—P1—Rh1	114.90 (8)	C27—C26—H26	120.1
C23—P2—C29	104.10 (11)	C25—C26—H26	120.1
C23—P2—C10	105.71 (11)	C26—C27—C28	120.2 (2)
C29—P2—C10	101.99 (11)	C26—C27—H27	119.9
C23—P2—Rh1	111.59 (8)	C28—C27—H27	119.9
C29—P2—Rh1	111.16 (8)	C27—C28—C23	120.5 (2)
C10—P2—Rh1	120.71 (8)	C27—C28—H28	119.8
C2—C1—C5	104.02 (19)	C23—C28—H28	119.8
C2—C1—P1	119.55 (18)	C30—C29—C34	118.2 (2)
C5—C1—P1	121.17 (17)	C30—C29—P2	121.06 (19)
C2—C1—H1	103.1	C34—C29—P2	120.5 (2)
C5—C1—H1	103.1	C31—C30—C29	120.8 (3)
P1—C1—H1	103.1	C31—C30—H30	119.6
C1—C2—C3	102.3 (2)	C29—C30—H30	119.6
C1—C2—H2A	111.3	C32—C31—C30	120.0 (3)
C3—C2—H2A	111.3	C32—C31—H31	120.0
C1—C2—H2B	111.3	C30—C31—H31	120.0
C3—C2—H2B	111.3	C31—C32—C33	119.9 (3)
H2A—C2—H2B	109.2	C31—C32—H32	120.0
C2—C3—C4	106.0 (2)	C33—C32—H32	120.0
C2—C3—H3A	110.5	C32—C33—C34	120.5 (3)
C4—C3—H3A	110.5	C32—C33—H33	119.8
C2—C3—H3B	110.5	C34—C33—H33	119.8
C4—C3—H3B	110.5	C33—C34—C29	120.6 (3)
H3A—C3—H3B	108.7	C33—C34—H34	119.7
C3—C4—C5	107.3 (2)	C29—C34—H34	119.7
C3—C4—H4A	110.2	C36—C35—C42	124.7 (2)
C5—C4—H4A	110.2	C36—C35—Rh1	70.87 (15)
C3—C4—H4B	110.2	C42—C35—Rh1	110.81 (17)
C5—C4—H4B	110.2	C36—C35—H35	114.2
H4A—C4—H4B	108.5	C42—C35—H35	114.2
C6—C5—C1	117.8 (2)	Rh1—C35—H35	114.2
C6—C5—C4	111.3 (2)	C35—C36—C37	125.6 (3)
C1—C5—C4	100.04 (19)	C35—C36—Rh1	73.85 (14)
C6—C5—H5	109.1	C37—C36—Rh1	110.08 (17)
C1—C5—H5	109.1	C35—C36—H36	113.4
C4—C5—H5	109.1	C37—C36—H36	113.4
C5—C6—C7	113.5 (2)	Rh1—C36—H36	113.4
C5—C6—C10	119.1 (2)	C36—C37—C38	113.5 (2)
C7—C6—C10	103.20 (19)	C36—C37—H37A	108.9
C5—C6—H6	106.8	C38—C37—H37A	108.9
C7—C6—H6	106.8	C36—C37—H37B	108.9
C10—C6—H6	106.8	C38—C37—H37B	108.9
C8—C7—C6	103.7 (2)	H37A—C37—H37B	107.7
C8—C7—H7A	111.0	C39—C38—C37	113.4 (2)
C6—C7—H7A	111.0	C39—C38—H38A	108.9
C8—C7—H7B	111.0	C37—C38—H38A	108.9
C6—C7—H7B	111.0	C39—C38—H38B	108.9
H7A—C7—H7B	109.0	C37—C38—H38B	108.9
C7—C8—C9	105.9 (2)	H38A—C38—H38B	107.7
C7—C8—H8A	110.6	C40—C39—C38	124.5 (2)
C9—C8—H8A	110.6	C40—C39—Rh1	70.13 (14)
C7—C8—H8B	110.6	C38—C39—Rh1	113.11 (17)
C9—C8—H8B	110.6	C40—C39—H39	113.8
H8A—C8—H8B	108.7	C38—C39—H39	113.8
C8—C9—C10	106.9 (2)	Rh1—C39—H39	113.8
C8—C9—H9A	110.3	C39—C40—C41	126.6 (2)
C10—C9—H9A	110.3	C39—C40—Rh1	73.84 (15)
C8—C9—H9B	110.3	C41—C40—Rh1	107.76 (17)
C10—C9—H9B	110.3	C39—C40—H40	113.6
H9A—C9—H9B	108.6	C41—C40—H40	113.6
C9—C10—C6	104.50 (19)	Rh1—C40—H40	113.6
C9—C10—P2	113.83 (17)	C40—C41—C42	114.4 (2)
C6—C10—P2	116.97 (17)	C40—C41—H41A	108.6
C9—C10—H10	107.0	C42—C41—H41A	108.6
C6—C10—H10	107.0	C40—C41—H41B	108.6
P2—C10—H10	107.0	C42—C41—H41B	108.6
C12—C11—C16	118.5 (2)	H41A—C41—H41B	107.6
C12—C11—P1	122.69 (19)	C35—C42—C41	112.8 (2)
C16—C11—P1	118.51 (19)	C35—C42—H42A	109.0
C13—C12—C11	120.3 (2)	C41—C42—H42A	109.0
C13—C12—H12	119.8	C35—C42—H42B	109.0
C11—C12—H12	119.8	C41—C42—H42B	109.0
C14—C13—C12	120.6 (3)	H42A—C42—H42B	107.8
C14—C13—H13	119.7	F4—B1—F3	109.7 (5)
C12—C13—H13	119.7	F4—B1—F1	110.5 (5)
C13—C14—C15	119.8 (2)	F3—B1—F1	109.6 (5)
C13—C14—H14	120.1	F4—B1—F2	108.6 (6)
C15—C14—H14	120.1	F3—B1—F2	109.1 (5)
C14—C15—C16	119.8 (3)	F1—B1—F2	109.3 (5)
C14—C15—H15	120.1	F3'—B1'—F1'	110.7 (7)
C16—C15—H15	120.1	F3'—B1'—F4'	110.1 (7)
C15—C16—C11	121.1 (2)	F1'—B1'—F4'	109.9 (7)
C15—C16—H16	119.5	F3'—B1'—F2'	109.3 (7)
C11—C16—H16	119.5	F1'—B1'—F2'	108.8 (7)
C22—C17—C18	119.0 (2)	F4'—B1'—F2'	108.0 (7)
C22—C17—P1	119.0 (2)	Cl2—C51—Cl1	112.4 (3)
C18—C17—P1	121.8 (2)	Cl2—C51—H51A	109.1
C19—C18—C17	120.0 (3)	Cl1—C51—H51A	109.1
C19—C18—H18	120.0	Cl2—C51—H51B	109.1
C17—C18—H18	120.0	Cl1—C51—H51B	109.1
C18—C19—C20	120.0 (3)	H51A—C51—H51B	107.9
C18—C19—H19	120.0
C17—P1—C1—C2	42.8 (2)	C11—P1—C17—C18	56.0 (2)
C11—P1—C1—C2	−62.6 (2)	Rh1—P1—C17—C18	178.71 (18)
Rh1—P1—C1—C2	172.81 (17)	C22—C17—C18—C19	−2.1 (4)
C17—P1—C1—C5	−89.1 (2)	P1—C17—C18—C19	−176.7 (2)
C11—P1—C1—C5	165.40 (19)	C17—C18—C19—C20	−0.2 (4)
Rh1—P1—C1—C5	40.9 (2)	C18—C19—C20—C21	1.8 (4)
C5—C1—C2—C3	−42.9 (3)	C19—C20—C21—C22	−1.1 (5)
P1—C1—C2—C3	178.05 (19)	C18—C17—C22—C21	2.8 (4)
C1—C2—C3—C4	24.5 (3)	P1—C17—C22—C21	177.6 (2)
C2—C3—C4—C5	2.2 (3)	C20—C21—C22—C17	−1.3 (4)
C2—C1—C5—C6	−77.3 (3)	C29—P2—C23—C24	36.3 (2)
P1—C1—C5—C6	60.9 (3)	C10—P2—C23—C24	−70.7 (2)
C2—C1—C5—C4	43.4 (2)	Rh1—P2—C23—C24	156.30 (19)
P1—C1—C5—C4	−178.45 (18)	C29—P2—C23—C28	−147.4 (2)
C3—C4—C5—C6	97.6 (2)	C10—P2—C23—C28	105.6 (2)
C3—C4—C5—C1	−27.6 (3)	Rh1—P2—C23—C28	−27.4 (2)
C1—C5—C6—C7	171.5 (2)	C28—C23—C24—C25	−2.3 (4)
C4—C5—C6—C7	56.9 (3)	P2—C23—C24—C25	174.0 (2)
C1—C5—C6—C10	−66.7 (3)	C23—C24—C25—C26	0.2 (5)
C4—C5—C6—C10	178.7 (2)	C24—C25—C26—C27	1.7 (5)
C5—C6—C7—C8	170.4 (2)	C25—C26—C27—C28	−1.5 (5)
C10—C6—C7—C8	40.1 (3)	C26—C27—C28—C23	−0.6 (5)
C6—C7—C8—C9	−33.8 (3)	C24—C23—C28—C27	2.5 (4)
C7—C8—C9—C10	14.1 (3)	P2—C23—C28—C27	−174.0 (2)
C8—C9—C10—C6	10.7 (3)	C23—P2—C29—C30	38.2 (2)
C8—C9—C10—P2	−118.1 (2)	C10—P2—C29—C30	148.0 (2)
C5—C6—C10—C9	−158.0 (2)	Rh1—P2—C29—C30	−82.1 (2)
C7—C6—C10—C9	−31.1 (3)	C23—P2—C29—C34	−148.0 (2)
C5—C6—C10—P2	−31.1 (3)	C10—P2—C29—C34	−38.2 (2)
C7—C6—C10—P2	95.7 (2)	Rh1—P2—C29—C34	91.8 (2)
C23—P2—C10—C9	64.62 (19)	C34—C29—C30—C31	−2.1 (4)
C29—P2—C10—C9	−43.9 (2)	P2—C29—C30—C31	171.8 (2)
Rh1—P2—C10—C9	−167.68 (14)	C29—C30—C31—C32	−0.2 (4)
C23—P2—C10—C6	−57.5 (2)	C30—C31—C32—C33	2.4 (4)
C29—P2—C10—C6	−166.08 (17)	C31—C32—C33—C34	−2.3 (4)
Rh1—P2—C10—C6	70.19 (19)	C32—C33—C34—C29	0.0 (4)
C17—P1—C11—C12	−152.6 (2)	C30—C29—C34—C33	2.2 (4)
C1—P1—C11—C12	−38.0 (2)	P2—C29—C34—C33	−171.8 (2)
Rh1—P1—C11—C12	85.3 (2)	C42—C35—C36—C37	−0.9 (4)
C17—P1—C11—C16	34.0 (2)	Rh1—C35—C36—C37	−103.4 (3)
C1—P1—C11—C16	148.6 (2)	C42—C35—C36—Rh1	102.6 (2)
Rh1—P1—C11—C16	−88.1 (2)	C35—C36—C37—C38	47.0 (4)
C16—C11—C12—C13	0.7 (4)	Rh1—C36—C37—C38	−37.1 (3)
P1—C11—C12—C13	−172.7 (2)	C36—C37—C38—C39	32.1 (3)
C11—C12—C13—C14	0.4 (4)	C37—C38—C39—C40	−92.0 (3)
C12—C13—C14—C15	−1.1 (4)	C37—C38—C39—Rh1	−10.9 (3)
C13—C14—C15—C16	0.8 (4)	C38—C39—C40—C41	4.6 (4)
C14—C15—C16—C11	0.3 (4)	Rh1—C39—C40—C41	−100.4 (3)
C12—C11—C16—C15	−1.0 (4)	C38—C39—C40—Rh1	105.0 (2)
P1—C11—C16—C15	172.7 (2)	C39—C40—C41—C42	40.5 (4)
C1—P1—C17—C22	133.5 (2)	Rh1—C40—C41—C42	−42.2 (3)
C11—P1—C17—C22	−118.5 (2)	C36—C35—C42—C41	−91.3 (3)
Rh1—P1—C17—C22	4.1 (2)	Rh1—C35—C42—C41	−10.7 (3)
C1—P1—C17—C18	−52.0 (2)	C40—C41—C42—C35	35.9 (3)