Bis[1,2-bis(diphenylphosphino)ethane-P,P']chloroosmium(II) Hexafluorophosphate Dichloromethane Solvate

Lough, A.J.; Morris, R.H.; Schlaf, M.

doi:10.1107/S0108270196006208

Bis[1,2-bis(diphenylphosphino)ethane-P,P']chloroosmium(II) Hexafluorophosphate Dichloromethane Solvate

The cation molecule of the title compound, [OsCl(C₂₆H₂₄P₂)₂]PF₆.1.5CH₂Cl₂, has a distorted trigonalbipyramidal structure. Despite strong steric repulsion between the PPh₂ groups, the Os-P bonds in the equatorial plane are short [2.2416 (12) and 2.2587 (13) Å] and the P-Os-P angle is only 94.24 (5)°.

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Bis[1,2-bis(diphenylphosphino)ethane-P,P']chloroosmium(II) Hexafluorophosphate Dichloromethane Solvate

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	Crystallographic Information File (CIF) Contains datablocks s9418, fg1187
	Structure factor file (CIF format) Contains datablock s9418