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The cation of the title compound, [Au(C
18H
15PS)
2](PO
2F
2), lies with the Au atom on a 2-fold axis, with Au—S 2.277 (2) Å and S—Au—S 172.40 (12)°. The deviation from linearity is not caused by Au
![...](/logos/entities/ctdot_rmgif.gif)
Au interactions. It may be caused by intramolecular
π–
π interactions between phenyl rings. Bond lengths and angles are normal.
Supporting information
![cif](https://journals.iucr.org//../logos/filetypeicons/bw/b1/ciflogo.png) | Crystallographic Information File (CIF) Contains datablocks global, ausp |
![fcf](https://journals.iucr.org//../logos/filetypeicons/bw/b1/fcflogo.png) | Structure factor file (CIF format) Contains datablock ausp |
CCDC reference: 129026
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