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The cation of the title compound, [Au(C18H15PS)2](PO2F2), lies with the Au atom on a 2-fold axis, with Au—S 2.277 (2) Å and S—Au—S 172.40 (12)°. The deviation from linearity is not caused by Au
Au interactions. It may be caused by intramolecular π–π interactions between phenyl rings. Bond lengths and angles are normal.
Au interactions. It may be caused by intramolecular π–π interactions between phenyl rings. Bond lengths and angles are normal.
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