Bis(μ-{N-[(methylthio)phenylmethylene]methanamine N-oxide}-O:O)bis[bis(1,1,1,5,5,5,-hexafluoropentane-2,4-dionato-O, 4-dionato-O,O')nickel(II)]

Dickman, M.H.; Ward, J.P.; Villamena, F.A.; Crist, D.R.

doi:10.1107/S0108270198000730

Bis(μ-{N-[(methylthio)phenylmethylene]methanamine N-oxide}-O:O)bis[bis(1,1,1,5,5,5,-hexafluoropentane-2,4-dionato-O, 4-dionato-O,O')nickel(II)]

M. H. Dickman, J. P. Ward, F. A. Villamena and D. R. Crist

The title compound, [Ni₂(C₅HF₆O₂)₄(C₉H₁₁NOS)₂], crystallizes as a centrosymmetric dimer containing two Ni(hfac)₂ moieties bridged by two nitrone ligands (hfac is the 1,1,1,5,5,5-hexafluoropentane-2,4-dionate anion). The Ni

Ni distance is 3.2904 (5) Å, with Ni—O_nitrone distances of 2.0776 (12) and 2.0974 (12) Å. The average Ni—O_hfac distance is 2.022 (16) Å.

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Bis(μ-{N-[(methylthio)phenylmethylene]methanamine N-oxide}-O:O)bis[bis(1,1,1,5,5,5,-hexafluoropentane-2,4-dionato-O, 4-dionato-O,O')nickel(II)]

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	Crystallographic Information File (CIF) Contains datablocks fr1094, global
	Structure factor file (CIF format) Contains datablocks fr1094, vcif WARNING: Line 140: length exceeds internal buffer size (4096) - rest discarded