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The Fe–C system, which is widely used to grow commercial high-pressure–high-temperature diamond monocrystals, is rather complicated due to the formation of carbides. The carbide Fe3C is a normal run product, but the pressure at which Fe7C3 carbide becomes stable is a subject of discussion. This paper demonstrates the synthesis of Fe7C3 carbide and its detailed study using single-crystal and powder X-ray diffraction, as well as electron probe micro-analysis and scanning electron microscopy. The experiments were performed using a multiple-anvil high-pressure apparatus of `split-sphere' (BARS) type at a pressure of 5.5 GPa and a temperature of 1623 K. Our results show that in the Fe–C system, in addition to diamond, a phase that corresponds to the Fe7C3 carbide was synthesized. This means that both carbides (Fe7C3 and Fe3C) are stable at 5.5 GPa. Two crystal phases are described, Fe14C6 and Fe28C12−x. Fe14C6 is based on the well known rhombic structure of Fe7C3, while Fe28C12−x has a different packing order of Fe6C polyhedrons. The results obtained in this study should be taken into account when synthesizing and growing diamond at high pressures and temperatures in metal–carbon systems with a high iron content, as well as when conducting experimental studies on the synthesis of diamond directly from carbide.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600576719013347/gj5230sup1.cif
Contains datablocks global, II, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600576719013347/gj5230Isup2.hkl
Contains datablock I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600576719013347/gj5230IIsup3.hkl
Contains datablock II

CCDC references: 1950083; 1956500

Computing details top

For both structures, data collection: Bruker APEX2 V2013.6-2; cell refinement: Bruker SAINT V8.32B; data reduction: Bruker SAINT V8.32B; program(s) used to solve structure: SHELXT 2014/5. Program(s) used to refine structure: SHELXL 2018/3 for (I); olex2.refine (Bourhis et al., 2015) for (II). For both structures, molecular graphics: Olex2 (Dolomanov et al., 2009); software used to prepare material for publication: Olex2 (Dolomanov et al., 2009).

iron carbide (I) top
Crystal data top
C6Fe14Dx = 7.609 Mg m3
Mr = 853.96Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, PbcaCell parameters from 4135 reflections
a = 11.9698 (6) Åθ = 3.4–33.2°
b = 4.5240 (2) ŵ = 26.26 mm1
c = 13.7658 (6) ÅT = 298 K
V = 745.44 (6) Å3Block, metallic light gray
Z = 40.12 × 0.08 × 0.04 mm
F(000) = 1600
Data collection top
Bruker APEX-II CCD
diffractometer
1268 reflections with I > 2σ(I)
Detector resolution: 25 pixels mm-1Rint = 0.029
φ and ω scansθmax = 33.2°, θmin = 3.0°
Absorption correction: multi-scan
SADABS-2012/1 (Bruker,2012) was used for absorption correction. wR2(int) was 0.1120 before and 0.0329 after correction. The Ratio of minimum to maximum transmission is 0.5837. The λ/2 correction factor is 0.0015.
h = 1618
Tmin = 0.436, Tmax = 0.747k = 66
6522 measured reflectionsl = 2110
1428 independent reflections
Refinement top
Refinement on F2Primary atom site location: dual
Least-squares matrix: full w = 1/[σ2(Fo2) + (0.036P)2 + 1.365P]
where P = (Fo2 + 2Fc2)/3
R[F2 > 2σ(F2)] = 0.025(Δ/σ)max = 0.001
wR(F2) = 0.066Δρmax = 1.83 e Å3
S = 1.09Δρmin = 0.84 e Å3
1428 reflectionsExtinction correction: SHELXL-2018/3 (Sheldrick 2018), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
92 parametersExtinction coefficient: 0.0031 (2)
0 restraints
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Fe10.58215 (3)0.24110 (7)0.37329 (2)0.00332 (10)
Fe20.31084 (3)0.57276 (7)0.46759 (2)0.00412 (10)
Fe30.31312 (3)0.56322 (7)0.28399 (2)0.00430 (9)
Fe40.12724 (3)0.56340 (8)0.37470 (2)0.00425 (10)
Fe50.47545 (3)0.25065 (7)0.53109 (2)0.00425 (10)
Fe60.29253 (3)0.25177 (7)0.62536 (2)0.00410 (10)
Fe70.47666 (3)0.22765 (7)0.21469 (2)0.00433 (10)
C30.3411 (2)0.9648 (5)0.23224 (17)0.0093 (4)
C10.4392 (2)0.4646 (6)0.38006 (16)0.0084 (4)
C20.3435 (2)0.9697 (5)0.51866 (17)0.0083 (4)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Fe10.00189 (17)0.00476 (18)0.00332 (17)0.00025 (9)0.00002 (9)0.00030 (9)
Fe20.00240 (16)0.00623 (16)0.00373 (15)0.00019 (10)0.00014 (10)0.00011 (10)
Fe30.00255 (15)0.00655 (16)0.00381 (15)0.00010 (10)0.00005 (10)0.00006 (10)
Fe40.00259 (16)0.00629 (17)0.00389 (16)0.00011 (11)0.00026 (9)0.00001 (9)
Fe50.00433 (17)0.00416 (16)0.00428 (16)0.00033 (10)0.00074 (11)0.00050 (9)
Fe60.00269 (17)0.00385 (17)0.00577 (18)0.00001 (9)0.00005 (9)0.00047 (9)
Fe70.00374 (16)0.00477 (16)0.00448 (16)0.00040 (10)0.00079 (11)0.00063 (9)
C30.0096 (10)0.0095 (9)0.0089 (10)0.0013 (8)0.0022 (8)0.0003 (7)
C10.0040 (10)0.0095 (10)0.0118 (10)0.0005 (8)0.0009 (7)0.0003 (7)
C20.0089 (10)0.0089 (9)0.0071 (9)0.0001 (8)0.0037 (8)0.0009 (7)
Geometric parameters (Å, º) top
Fe1—Fe2i2.6735 (4)Fe3—C31.980 (2)
Fe1—Fe3ii2.6281 (4)Fe3—C3iii2.029 (3)
Fe1—Fe4iii2.6323 (5)Fe3—C12.056 (2)
Fe1—Fe52.5203 (5)Fe4—Fe5x2.6461 (5)
Fe1—Fe5iv2.6753 (4)Fe4—Fe5vii2.6198 (4)
Fe1—Fe6iv2.6874 (5)Fe4—Fe7vii2.6363 (5)
Fe1—Fe6v2.5184 (6)Fe4—Fe7xi2.6590 (5)
Fe1—Fe72.5229 (5)Fe4—C3iii2.047 (2)
Fe1—Fe7vi2.6091 (4)Fe4—C1vii1.983 (3)
Fe1—C3ii1.994 (2)Fe4—C2iii2.057 (2)
Fe1—C11.990 (3)Fe5—Fe5iv2.4943 (6)
Fe1—C2i1.978 (2)Fe5—Fe5i2.4836 (6)
Fe2—Fe2iii2.6903 (4)Fe5—Fe62.5451 (5)
Fe2—Fe32.5279 (5)Fe5—Fe7xii2.5294 (6)
Fe2—Fe4vii2.6667 (5)Fe5—C12.334 (2)
Fe2—Fe42.5429 (5)Fe5—C1i2.049 (2)
Fe2—Fe5i2.6801 (5)Fe5—C2xiii2.035 (2)
Fe2—Fe52.6019 (5)Fe5—C2i2.482 (3)
Fe2—Fe62.6218 (4)Fe6—Fe6vii2.4806 (3)
Fe2—Fe6vii2.6275 (4)Fe6—Fe6iii2.4806 (3)
Fe2—C12.013 (2)Fe6—Fe7xii2.5255 (5)
Fe2—C21.968 (2)Fe6—C3xiv2.037 (2)
Fe2—C2iii2.031 (2)Fe6—C3xv2.384 (3)
Fe3—Fe42.5513 (5)Fe6—C2xiii2.039 (2)
Fe3—Fe4vii2.6813 (4)Fe6—C2iii2.404 (3)
Fe3—Fe4iii2.6799 (4)Fe7—Fe7vi2.5246 (3)
Fe3—Fe6viii2.6585 (4)Fe7—Fe7ii2.5246 (3)
Fe3—Fe6ix2.6191 (4)Fe7—C3xiii2.026 (3)
Fe3—Fe7vi2.6241 (5)Fe7—C1ii2.033 (2)
Fe3—Fe72.6546 (5)
Fe2i—Fe1—Fe5iv88.986 (13)Fe1—Fe5—Fe4iii61.573 (14)
Fe2i—Fe1—Fe6iv89.327 (14)Fe1—Fe5—Fe6151.100 (19)
Fe3ii—Fe1—Fe2i122.879 (17)Fe1—Fe5—Fe7xii149.203 (18)
Fe3ii—Fe1—Fe4iii111.515 (15)Fe2—Fe5—Fe4v170.185 (18)
Fe3ii—Fe1—Fe5iv105.880 (15)Fe2—Fe5—Fe4iii63.237 (13)
Fe3ii—Fe1—Fe6iv59.027 (12)Fe4iii—Fe5—Fe4v123.457 (14)
Fe4iii—Fe1—Fe2i123.118 (15)Fe5iv—Fe5—Fe164.481 (16)
Fe4iii—Fe1—Fe5iv59.802 (13)Fe5i—Fe5—Fe166.332 (16)
Fe4iii—Fe1—Fe6iv106.142 (16)Fe5i—Fe5—Fe263.555 (16)
Fe5—Fe1—Fe2i62.048 (13)Fe5iv—Fe5—Fe2124.92 (2)
Fe5—Fe1—Fe3ii163.147 (17)Fe5i—Fe5—Fe4iii96.98 (2)
Fe5—Fe1—Fe4iii61.074 (13)Fe5iv—Fe5—Fe4v61.196 (15)
Fe5—Fe1—Fe5iv57.288 (14)Fe5i—Fe5—Fe4v119.61 (2)
Fe5—Fe1—Fe6iv106.927 (14)Fe5iv—Fe5—Fe4iii62.260 (16)
Fe5iv—Fe1—Fe6iv56.667 (12)Fe5i—Fe5—Fe5iv130.68 (3)
Fe5—Fe1—Fe7119.51 (2)Fe5iv—Fe5—Fe6112.30 (2)
Fe5—Fe1—Fe7vi104.413 (15)Fe5i—Fe5—Fe6112.18 (2)
Fe6v—Fe1—Fe2i60.717 (12)Fe5i—Fe5—Fe7xii107.93 (2)
Fe6v—Fe1—Fe3ii62.162 (12)Fe5iv—Fe5—Fe7xii112.14 (2)
Fe6v—Fe1—Fe4iii162.929 (17)Fe6—Fe5—Fe261.233 (13)
Fe6v—Fe1—Fe5120.011 (16)Fe6—Fe5—Fe4iii90.918 (15)
Fe6v—Fe1—Fe5iv105.350 (15)Fe6—Fe5—Fe4v109.992 (16)
Fe6v—Fe1—Fe6iv56.802 (11)Fe7xii—Fe5—Fe2108.561 (16)
Fe6v—Fe1—Fe7vi105.213 (15)Fe7xii—Fe5—Fe4v61.782 (13)
Fe6v—Fe1—Fe7120.475 (16)Fe7xii—Fe5—Fe4iii146.759 (17)
Fe7—Fe1—Fe2i163.021 (16)Fe7xii—Fe5—Fe659.694 (13)
Fe7vi—Fe1—Fe2i104.116 (14)C1—Fe5—Fe148.21 (6)
Fe7—Fe1—Fe3ii61.213 (13)C1i—Fe5—Fe1105.82 (7)
Fe7vi—Fe1—Fe3ii90.264 (13)C1—Fe5—Fe247.76 (6)
Fe7—Fe1—Fe4iii61.471 (13)C1i—Fe5—Fe2103.06 (7)
Fe7vi—Fe1—Fe4iii90.238 (15)C1i—Fe5—Fe4v72.70 (7)
Fe7vi—Fe1—Fe5iv149.361 (19)C1—Fe5—Fe4iii46.76 (6)
Fe7—Fe1—Fe5iv106.064 (15)C1i—Fe5—Fe4iii158.08 (7)
Fe7—Fe1—Fe6iv105.386 (14)C1—Fe5—Fe4v141.89 (6)
Fe7vi—Fe1—Fe6iv148.624 (16)C1i—Fe5—Fe5iv131.22 (7)
Fe7—Fe1—Fe7vi58.908 (9)C1i—Fe5—Fe5i61.10 (7)
C3ii—Fe1—Fe2i102.50 (7)C1—Fe5—Fe5i50.22 (6)
C3ii—Fe1—Fe3ii48.37 (7)C1—Fe5—Fe5iv96.62 (6)
C3ii—Fe1—Fe4iii126.78 (7)C1—Fe5—Fe6107.07 (6)
C3ii—Fe1—Fe5iv154.02 (7)C1i—Fe5—Fe697.08 (7)
C3ii—Fe1—Fe5148.48 (7)C1i—Fe5—Fe7xii51.41 (7)
C3ii—Fe1—Fe6v62.52 (7)C1—Fe5—Fe7xii151.05 (6)
C3ii—Fe1—Fe6iv99.73 (7)C1i—Fe5—C1111.32 (7)
C3ii—Fe1—Fe767.19 (7)C1i—Fe5—C2i88.96 (9)
C3ii—Fe1—Fe7vi50.06 (7)C1—Fe5—C2i94.76 (8)
C1—Fe1—Fe2i102.33 (7)C2i—Fe5—Fe146.58 (5)
C1—Fe1—Fe3ii127.19 (6)C2xiii—Fe5—Fe1108.07 (7)
C1—Fe1—Fe4iii48.40 (7)C2i—Fe5—Fe2142.51 (6)
C1—Fe1—Fe561.00 (7)C2xiii—Fe5—Fe274.57 (7)
C1—Fe1—Fe5iv100.25 (7)C2i—Fe5—Fe4v47.16 (5)
C1—Fe1—Fe6v148.54 (8)C2i—Fe5—Fe4iii93.04 (5)
C1—Fe1—Fe6iv154.34 (8)C2xiii—Fe5—Fe4iii50.55 (7)
C1—Fe1—Fe767.81 (7)C2xiii—Fe5—Fe4v103.81 (7)
C1—Fe1—Fe7vi50.28 (7)C2xiii—Fe5—Fe5iv65.54 (7)
C1—Fe1—C3ii99.91 (10)C2xiii—Fe5—Fe5i136.25 (7)
C2i—Fe1—Fe2i47.18 (7)C2i—Fe5—Fe5i93.61 (6)
C2i—Fe1—Fe3ii104.91 (7)C2i—Fe5—Fe5iv48.27 (6)
C2i—Fe1—Fe4iii106.00 (7)C2xiii—Fe5—Fe651.42 (7)
C2i—Fe1—Fe565.68 (7)C2i—Fe5—Fe6153.22 (6)
C2i—Fe1—Fe5iv49.09 (7)C2i—Fe5—Fe7xii106.64 (5)
C2i—Fe1—Fe6iv48.99 (7)C2xiii—Fe5—Fe7xii96.47 (7)
C2i—Fe1—Fe6v63.31 (7)C2xiii—Fe5—C1i146.09 (10)
C2i—Fe1—Fe7149.79 (7)C2xiii—Fe5—C192.29 (9)
C2i—Fe1—Fe7vi151.29 (7)C2xiii—Fe5—C2i113.81 (7)
C2i—Fe1—C3ii125.81 (11)Fe1x—Fe6—Fe2iii62.560 (13)
C2i—Fe1—C1126.63 (10)Fe1x—Fe6—Fe294.736 (15)
Fe1i—Fe2—Fe2iii121.614 (9)Fe1x—Fe6—Fe3xii95.445 (15)
Fe1i—Fe2—Fe5i56.169 (12)Fe1x—Fe6—Fe5149.760 (16)
Fe3—Fe2—Fe1i145.019 (16)Fe1x—Fe6—Fe7xii150.288 (16)
Fe3—Fe2—Fe2iii89.512 (9)Fe2—Fe6—Fe2iii61.662 (12)
Fe3—Fe2—Fe460.415 (12)Fe3xii—Fe6—Fe2iii124.454 (16)
Fe3—Fe2—Fe4vii62.083 (12)Fe3xii—Fe6—Fe2169.79 (2)
Fe3—Fe2—Fe5i90.090 (13)Fe5—Fe6—Fe260.451 (13)
Fe3—Fe2—Fe5108.552 (15)Fe5—Fe6—Fe2iii89.027 (14)
Fe3—Fe2—Fe6vii146.800 (16)Fe5—Fe6—Fe3xii110.065 (18)
Fe3—Fe2—Fe6145.052 (16)Fe6iii—Fe6—Fe1x66.50 (2)
Fe4vii—Fe2—Fe1i89.858 (13)Fe6vii—Fe6—Fe1x65.03 (2)
Fe4—Fe2—Fe1i146.230 (17)Fe6iii—Fe6—Fe2iii61.683 (12)
Fe4vii—Fe2—Fe2iii148.245 (12)Fe6vii—Fe6—Fe261.915 (9)
Fe4—Fe2—Fe2iii61.194 (15)Fe6vii—Fe6—Fe2iii95.036 (16)
Fe4—Fe2—Fe4vii90.741 (16)Fe6iii—Fe6—Fe2122.640 (12)
Fe4vii—Fe2—Fe5i59.325 (12)Fe6vii—Fe6—Fe3xii122.328 (11)
Fe4—Fe2—Fe5144.494 (17)Fe6iii—Fe6—Fe3xii62.772 (9)
Fe4—Fe2—Fe5i146.437 (16)Fe6iii—Fe6—Fe5110.565 (16)
Fe4—Fe2—Fe6109.579 (17)Fe6vii—Fe6—Fe5110.788 (16)
Fe4—Fe2—Fe6vii90.793 (14)Fe6iii—Fe6—Fe6vii131.53 (3)
Fe5—Fe2—Fe1i62.506 (13)Fe6vii—Fe6—Fe7xii108.940 (17)
Fe5i—Fe2—Fe2iii140.117 (16)Fe6iii—Fe6—Fe7xii113.067 (17)
Fe5—Fe2—Fe2iii86.505 (12)Fe7xii—Fe6—Fe2iii145.566 (18)
Fe5—Fe2—Fe4vii114.633 (16)Fe7xii—Fe6—Fe2108.060 (18)
Fe5—Fe2—Fe5i56.072 (14)Fe7xii—Fe6—Fe3xii62.096 (13)
Fe5—Fe2—Fe658.316 (14)Fe7xii—Fe6—Fe559.843 (16)
Fe5—Fe2—Fe6vii104.567 (16)C3xv—Fe6—Fe1x47.91 (6)
Fe6—Fe2—Fe1i62.341 (12)C3xiv—Fe6—Fe1x105.80 (7)
Fe6vii—Fe2—Fe1i56.721 (14)C3xiv—Fe6—Fe2iii157.78 (7)
Fe6vii—Fe2—Fe2iii90.243 (14)C3xiv—Fe6—Fe2103.05 (7)
Fe6—Fe2—Fe2iii59.273 (9)C3xv—Fe6—Fe2iii93.87 (6)
Fe6vii—Fe2—Fe4vii105.705 (14)C3xv—Fe6—Fe2142.64 (6)
Fe6—Fe2—Fe4vii151.821 (16)C3xiv—Fe6—Fe3xii73.35 (7)
Fe6—Fe2—Fe5i103.843 (16)C3xv—Fe6—Fe3xii47.55 (6)
Fe6vii—Fe2—Fe5i110.609 (15)C3xiv—Fe6—Fe597.11 (7)
Fe6—Fe2—Fe6vii56.401 (11)C3xv—Fe6—Fe5153.02 (6)
C1—Fe2—Fe1i101.61 (7)C3xiv—Fe6—Fe6vii62.81 (7)
C1—Fe2—Fe2iii102.06 (7)C3xv—Fe6—Fe6vii95.69 (6)
C1—Fe2—Fe352.35 (7)C3xv—Fe6—Fe6iii49.45 (6)
C1—Fe2—Fe4vii72.73 (7)C3xiv—Fe6—Fe6iii133.75 (7)
C1—Fe2—Fe4110.77 (7)C3xv—Fe6—Fe7xii107.48 (6)
C1—Fe2—Fe5i49.30 (7)C3xiv—Fe6—Fe7xii51.37 (7)
C1—Fe2—Fe559.13 (7)C3xiv—Fe6—C3xv90.27 (11)
C1—Fe2—Fe6115.15 (7)C3xv—Fe6—C2iii95.21 (9)
C1—Fe2—Fe6vii158.29 (7)C3xiv—Fe6—C2iii112.13 (9)
C1—Fe2—C2iii147.75 (10)C3xiv—Fe6—C2xiii145.99 (11)
C2iii—Fe2—Fe1i102.97 (7)C2iii—Fe6—Fe1x47.31 (6)
C2—Fe2—Fe1i47.51 (7)C2xiii—Fe6—Fe1x108.21 (7)
C2—Fe2—Fe2iii151.03 (7)C2xiii—Fe6—Fe2iii49.66 (7)
C2iii—Fe2—Fe2iii46.72 (7)C2xiii—Fe6—Fe274.04 (7)
C2—Fe2—Fe3111.76 (7)C2iii—Fe6—Fe2iii45.77 (6)
C2iii—Fe2—Fe3110.61 (7)C2iii—Fe6—Fe247.43 (6)
C2—Fe2—Fe4111.51 (7)C2iii—Fe6—Fe3xii142.76 (6)
C2—Fe2—Fe4vii49.95 (7)C2xiii—Fe6—Fe3xii103.40 (7)
C2iii—Fe2—Fe451.99 (7)C2xiii—Fe6—Fe551.25 (7)
C2iii—Fe2—Fe4vii127.59 (7)C2iii—Fe6—Fe5105.78 (6)
C2iii—Fe2—Fe5116.35 (7)C2xiii—Fe6—Fe6iii63.39 (7)
C2iii—Fe2—Fe5i159.13 (7)C2iii—Fe6—Fe6iii95.50 (6)
C2—Fe2—Fe5i62.34 (7)C2xiii—Fe6—Fe6vii133.91 (7)
C2—Fe2—Fe5103.92 (7)C2iii—Fe6—Fe6vii49.32 (6)
C2iii—Fe2—Fe660.66 (7)C2iii—Fe6—Fe7xii150.86 (6)
C2—Fe2—Fe6103.06 (7)C2xiii—Fe6—Fe7xii96.47 (7)
C2iii—Fe2—Fe6vii49.93 (7)C2xiii—Fe6—C3xv112.84 (9)
C2—Fe2—Fe6vii61.11 (7)C2xiii—Fe6—C2iii91.10 (10)
C2—Fe2—C1106.49 (10)Fe1—Fe7—Fe1ii123.858 (17)
C2—Fe2—C2iii105.47 (11)Fe1—Fe7—Fe3ii61.371 (13)
Fe1vi—Fe3—Fe4iii121.009 (15)Fe1ii—Fe7—Fe3116.763 (17)
Fe1vi—Fe3—Fe4vii89.901 (13)Fe1ii—Fe7—Fe3ii91.308 (15)
Fe1vi—Fe3—Fe6viii56.894 (14)Fe1—Fe7—Fe392.541 (15)
Fe1vi—Fe3—Fe761.792 (12)Fe1—Fe7—Fe4iii61.309 (13)
Fe2—Fe3—Fe1vi145.446 (16)Fe1ii—Fe7—Fe4xvi116.743 (16)
Fe2—Fe3—Fe4vii61.500 (12)Fe1—Fe7—Fe4xvi92.718 (15)
Fe2—Fe3—Fe460.083 (12)Fe1ii—Fe7—Fe4iii91.305 (14)
Fe2—Fe3—Fe4iii63.347 (12)Fe1—Fe7—Fe5ix150.072 (18)
Fe2—Fe3—Fe6viii144.164 (16)Fe1—Fe7—Fe6ix149.012 (19)
Fe2—Fe3—Fe6ix147.334 (16)Fe1—Fe7—Fe7ii65.016 (17)
Fe2—Fe3—Fe7vi89.919 (14)Fe1—Fe7—Fe7vi62.251 (17)
Fe2—Fe3—Fe7112.147 (15)Fe3ii—Fe7—Fe3150.088 (16)
Fe4—Fe3—Fe1vi144.992 (16)Fe3ii—Fe7—Fe4xvi60.994 (13)
Fe4—Fe3—Fe4vii90.228 (16)Fe3—Fe7—Fe4xvi109.846 (16)
Fe4—Fe3—Fe4iii90.258 (16)Fe3ii—Fe7—Fe4iii111.512 (15)
Fe4iii—Fe3—Fe4vii115.096 (16)Fe4iii—Fe7—Fe360.862 (13)
Fe4—Fe3—Fe6viii89.261 (14)Fe4iii—Fe7—Fe4xvi150.162 (17)
Fe4—Fe3—Fe6ix109.037 (17)Fe5ix—Fe7—Fe1ii64.364 (12)
Fe4—Fe3—Fe7144.997 (17)Fe5ix—Fe7—Fe3109.428 (15)
Fe4—Fe3—Fe7vi146.385 (16)Fe5ix—Fe7—Fe3ii91.343 (14)
Fe6ix—Fe3—Fe1vi61.616 (13)Fe5ix—Fe7—Fe4iii147.466 (17)
Fe6viii—Fe3—Fe4iii140.810 (16)Fe5ix—Fe7—Fe4xvi61.268 (12)
Fe6ix—Fe3—Fe4vii150.752 (16)Fe6ix—Fe7—Fe1ii64.507 (13)
Fe6viii—Fe3—Fe4vii104.092 (14)Fe6ix—Fe7—Fe3ii148.285 (17)
Fe6ix—Fe3—Fe4iii87.390 (13)Fe6ix—Fe7—Fe360.682 (13)
Fe6ix—Fe3—Fe6viii56.064 (11)Fe6ix—Fe7—Fe4xvi110.192 (16)
Fe6ix—Fe3—Fe7vi104.491 (16)Fe6ix—Fe7—Fe4iii90.316 (15)
Fe6ix—Fe3—Fe757.223 (14)Fe6ix—Fe7—Fe5ix60.464 (13)
Fe7vi—Fe3—Fe1vi57.417 (12)Fe7vi—Fe7—Fe1ii173.89 (2)
Fe7—Fe3—Fe4vii116.978 (16)Fe7ii—Fe7—Fe1ii58.842 (11)
Fe7—Fe3—Fe4iii59.233 (12)Fe7vi—Fe7—Fe3ii92.24 (2)
Fe7vi—Fe3—Fe4iii88.884 (14)Fe7ii—Fe7—Fe3ii62.037 (16)
Fe7vi—Fe3—Fe4vii60.147 (13)Fe7vi—Fe7—Fe360.821 (14)
Fe7vi—Fe3—Fe6viii111.874 (16)Fe7ii—Fe7—Fe3122.50 (2)
Fe7—Fe3—Fe6viii103.630 (16)Fe7ii—Fe7—Fe4xvi122.68 (2)
Fe7vi—Fe3—Fe757.142 (9)Fe7vi—Fe7—Fe4iii92.02 (2)
C3—Fe3—Fe1vi48.84 (7)Fe7vi—Fe7—Fe4xvi61.075 (14)
C3iii—Fe3—Fe1vi102.24 (7)Fe7ii—Fe7—Fe4iii61.979 (16)
C3—Fe3—Fe2110.24 (7)Fe7ii—Fe7—Fe5ix114.884 (18)
C3iii—Fe3—Fe2110.19 (7)Fe7vi—Fe7—Fe5ix110.562 (17)
C3iii—Fe3—Fe451.55 (7)Fe7ii—Fe7—Fe6ix114.435 (18)
C3iii—Fe3—Fe4vii126.24 (7)Fe7vi—Fe7—Fe6ix110.340 (17)
C3—Fe3—Fe4vii49.32 (7)Fe7ii—Fe7—Fe7vi127.27 (3)
C3—Fe3—Fe4108.88 (7)C3xiii—Fe7—Fe1108.17 (7)
C3—Fe3—Fe4iii153.73 (8)C3xiii—Fe7—Fe1ii49.01 (7)
C3iii—Fe3—Fe4iii102.76 (7)C3xiii—Fe7—Fe3ii126.91 (7)
C3iii—Fe3—Fe6viii49.29 (7)C3xiii—Fe7—Fe372.69 (7)
C3—Fe3—Fe6ix102.42 (7)C3xiii—Fe7—Fe4iii50.00 (7)
C3iii—Fe3—Fe6ix60.14 (7)C3xiii—Fe7—Fe4xvi158.96 (7)
C3—Fe3—Fe6viii59.75 (7)C3xiii—Fe7—Fe5ix97.89 (7)
C3iii—Fe3—Fe7114.80 (7)C3xiii—Fe7—Fe6ix51.75 (7)
C3iii—Fe3—Fe7vi159.64 (7)C3xiii—Fe7—Fe7vi131.10 (7)
C3—Fe3—Fe7105.69 (7)C3xiii—Fe7—Fe7ii66.76 (7)
C3—Fe3—Fe7vi65.16 (8)C3xiii—Fe7—C1ii97.44 (10)
C3—Fe3—C3iii103.26 (11)C1ii—Fe7—Fe1108.75 (7)
C3—Fe3—C1107.83 (10)C1ii—Fe7—Fe1ii48.85 (7)
C3iii—Fe3—C1147.84 (10)C1ii—Fe7—Fe3ii50.46 (7)
C1—Fe3—Fe1vi104.25 (7)C1ii—Fe7—Fe3158.55 (7)
C1—Fe3—Fe250.83 (7)C1ii—Fe7—Fe4iii127.22 (7)
C1—Fe3—Fe4iii47.28 (7)C1ii—Fe7—Fe4xvi72.64 (7)
C1—Fe3—Fe4vii71.82 (7)C1ii—Fe7—Fe5ix52.00 (7)
C1—Fe3—Fe4108.99 (7)C1ii—Fe7—Fe6ix98.13 (7)
C1—Fe3—Fe6ix119.17 (7)C1ii—Fe7—Fe7vi131.45 (7)
C1—Fe3—Fe6viii161.07 (7)C1ii—Fe7—Fe7ii67.23 (7)
C1—Fe3—Fe7vi49.68 (7)Fe1vi—C3—Fe3vii141.84 (14)
C1—Fe3—Fe764.26 (7)Fe1vi—C3—Fe4vii136.34 (13)
Fe1vii—Fe4—Fe2iii121.493 (16)Fe1vi—C3—Fe6viii69.57 (8)
Fe1vii—Fe4—Fe3vii89.574 (14)Fe1vi—C3—Fe6xvii85.69 (9)
Fe1vii—Fe4—Fe5x60.905 (13)Fe1vi—C3—Fe7xviii80.93 (9)
Fe1vii—Fe4—Fe7vii57.221 (12)Fe3—C3—Fe1vi82.80 (9)
Fe1vii—Fe4—Fe7xi61.680 (13)Fe3—C3—Fe3vii85.46 (10)
Fe2—Fe4—Fe1vii145.235 (16)Fe3vii—C3—Fe4vii77.52 (8)
Fe2—Fe4—Fe2iii62.129 (11)Fe3—C3—Fe4vii83.49 (9)
Fe2—Fe4—Fe3vii89.428 (15)Fe3—C3—Fe6xvii142.12 (14)
Fe2iii—Fe4—Fe3vii148.395 (18)Fe3vii—C3—Fe6viii72.31 (8)
Fe2—Fe4—Fe359.502 (14)Fe3vii—C3—Fe6xvii81.69 (9)
Fe2—Fe4—Fe5vii89.246 (14)Fe3—C3—Fe6viii74.42 (8)
Fe2—Fe4—Fe5x110.849 (15)Fe3—C3—Fe7xviii135.82 (13)
Fe2—Fe4—Fe7xi145.899 (18)Fe4vii—C3—Fe6viii143.61 (12)
Fe2—Fe4—Fe7vii145.397 (17)Fe6xvii—C3—Fe4vii127.43 (12)
Fe3—Fe4—Fe1vii145.777 (16)Fe6xvii—C3—Fe6viii67.74 (7)
Fe3—Fe4—Fe2iii89.544 (15)Fe7xviii—C3—Fe3vii129.92 (12)
Fe3—Fe4—Fe3vii62.606 (11)Fe7xviii—C3—Fe4vii80.68 (9)
Fe3—Fe4—Fe5x146.983 (18)Fe7xviii—C3—Fe6xvii76.88 (9)
Fe3—Fe4—Fe5vii144.237 (17)Fe7xviii—C3—Fe6viii134.83 (12)
Fe3—Fe4—Fe7xi111.374 (15)Fe1—C1—Fe2143.90 (12)
Fe3—Fe4—Fe7vii90.147 (13)Fe1—C1—Fe3135.36 (12)
Fe5vii—Fe4—Fe1vii57.353 (12)Fe1—C1—Fe570.80 (8)
Fe5vii—Fe4—Fe2iii90.315 (13)Fe1—C1—Fe5i85.34 (10)
Fe5x—Fe4—Fe2iii60.590 (12)Fe1—C1—Fe7vi80.88 (9)
Fe5x—Fe4—Fe3vii149.806 (18)Fe2—C1—Fe376.81 (9)
Fe5vii—Fe4—Fe3vii103.596 (15)Fe2—C1—Fe573.11 (7)
Fe5vii—Fe4—Fe5x56.543 (14)Fe2—C1—Fe5i82.56 (9)
Fe5x—Fe4—Fe7xi56.951 (14)Fe2—C1—Fe7vi128.32 (13)
Fe5vii—Fe4—Fe7vii111.969 (17)Fe3—C1—Fe5143.08 (12)
Fe5vii—Fe4—Fe7xi104.299 (16)Fe4iii—C1—Fe182.99 (10)
Fe7xi—Fe4—Fe2iii86.265 (15)Fe4iii—C1—Fe286.47 (10)
Fe7vii—Fe4—Fe2iii140.027 (17)Fe4iii—C1—Fe383.11 (9)
Fe7vii—Fe4—Fe3vii59.905 (12)Fe4iii—C1—Fe5i142.90 (12)
Fe7xi—Fe4—Fe3vii116.547 (15)Fe4iii—C1—Fe574.22 (8)
Fe7vii—Fe4—Fe5x103.703 (16)Fe4iii—C1—Fe7vi135.29 (12)
Fe7vii—Fe4—Fe7xi56.947 (9)Fe5i—C1—Fe3127.86 (13)
C3iii—Fe4—Fe1vii103.63 (7)Fe5i—C1—Fe568.68 (7)
C3iii—Fe4—Fe2109.01 (7)Fe7vi—C1—Fe379.86 (8)
C3iii—Fe4—Fe2iii103.10 (7)Fe7vi—C1—Fe5136.25 (12)
C3iii—Fe4—Fe350.92 (7)Fe7vi—C1—Fe5i76.59 (9)
C3iii—Fe4—Fe3vii71.83 (7)Fe1i—C2—Fe2vii141.27 (13)
C3iii—Fe4—Fe5vii160.87 (7)Fe1i—C2—Fe4vii138.36 (13)
C3iii—Fe4—Fe5x118.66 (7)Fe1i—C2—Fe5xviii83.61 (9)
C3iii—Fe4—Fe7vii49.32 (7)Fe1i—C2—Fe5i67.74 (7)
C3iii—Fe4—Fe7xi63.73 (7)Fe1i—C2—Fe6vii69.37 (7)
C3iii—Fe4—C2iii147.88 (10)Fe1i—C2—Fe6xviii83.96 (9)
C1vii—Fe4—Fe1vii48.61 (7)Fe2—C2—Fe1i85.31 (10)
C1vii—Fe4—Fe2108.22 (7)Fe2—C2—Fe2vii84.55 (9)
C1vii—Fe4—Fe2iii148.81 (7)Fe2—C2—Fe4vii82.97 (9)
C1vii—Fe4—Fe3vii49.60 (7)Fe2vii—C2—Fe4vii76.93 (8)
C1vii—Fe4—Fe3111.61 (7)Fe2vii—C2—Fe5i142.28 (11)
C1vii—Fe4—Fe5x101.41 (7)Fe2—C2—Fe5i73.05 (8)
C1vii—Fe4—Fe5vii59.02 (7)Fe2—C2—Fe5xviii138.98 (13)
C1vii—Fe4—Fe7xi105.56 (7)Fe2vii—C2—Fe5xviii126.28 (12)
C1vii—Fe4—Fe7vii65.41 (7)Fe2vii—C2—Fe6vii71.91 (8)
C1vii—Fe4—C3iii108.02 (10)Fe2—C2—Fe6vii73.11 (8)
C1vii—Fe4—C2iii102.78 (9)Fe2—C2—Fe6xviii140.27 (13)
C2iii—Fe4—Fe1vii103.42 (7)Fe2vii—C2—Fe6xviii80.41 (9)
C2iii—Fe4—Fe251.08 (7)Fe4vii—C2—Fe5i70.62 (7)
C2iii—Fe4—Fe2iii47.08 (7)Fe4vii—C2—Fe6vii142.05 (12)
C2iii—Fe4—Fe3108.85 (7)Fe5xviii—C2—Fe4vii79.63 (9)
C2iii—Fe4—Fe3vii125.28 (7)Fe5xviii—C2—Fe5i66.19 (7)
C2iii—Fe4—Fe5x62.22 (7)Fe5xviii—C2—Fe6xviii77.33 (8)
C2iii—Fe4—Fe5vii49.81 (7)Fe5xviii—C2—Fe6vii136.93 (11)
C2iii—Fe4—Fe7xi116.33 (7)Fe6xviii—C2—Fe4vii128.02 (12)
C2iii—Fe4—Fe7vii160.64 (7)Fe6xviii—C2—Fe5i135.35 (11)
Fe1—Fe5—Fe295.958 (16)Fe6vii—C2—Fe5i126.54 (10)
Fe1—Fe5—Fe4v93.739 (16)Fe6xviii—C2—Fe6vii67.29 (7)
Symmetry codes: (i) x+1, y+1, z+1; (ii) x+1, y1/2, z+1/2; (iii) x+1/2, y1/2, z; (iv) x+1, y, z+1; (v) x+1/2, y+1/2, z+1; (vi) x+1, y+1/2, z+1/2; (vii) x+1/2, y+1/2, z; (viii) x+1/2, y+1, z1/2; (ix) x, y+1/2, z1/2; (x) x1/2, y+1/2, z+1; (xi) x1/2, y, z+1/2; (xii) x, y+1/2, z+1/2; (xiii) x, y1, z; (xiv) x, y+3/2, z+1/2; (xv) x+1/2, y+1, z+1/2; (xvi) x+1/2, y, z+1/2; (xvii) x, y+3/2, z1/2; (xviii) x, y+1, z.
Iron carbide (II) top
Crystal data top
C6Fe14Dx = 7.622 Mg m3
Mr = 853.90Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, PbcaCell parameters from 2015 reflections
a = 4.5251 (4) Åθ = 6.8–30.3°
b = 13.7555 (10) ŵ = 26.30 mm1
c = 23.9096 (16) ÅT = 298 K
V = 1488.3 (2) Å3Block, metallic light gray
Z = 80.08 × 0.04 × 0.04 mm
F(000) = 3240.5764
Data collection top
Bruker DUO CCD area-detector
diffractometer
2275 independent reflections
Radiation source: fine-focus sealed tube1095 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.060
Detector resolution: 25 pixels mm-1θmax = 30.5°, θmin = 1.7°
φ and ω scansh = 66
Absorption correction: multi-scan
SADABS-2008/1 (Bruker,2008) was used for absorption correction. wR2(int) was 0.0871 before and 0.0484 after correction. The Ratio of minimum to maximum transmission is 0.7968. The λ/2 correction factor is 0.0015.
k = 1619
Tmin = 0.595, Tmax = 0.746l = 3420
12211 measured reflections
Refinement top
Refinement on F20 restraints
Least-squares matrix: full0 constraints
R[F2 > 2σ(F2)] = 0.059Primary atom site location: dual
wR(F2) = 0.226 w = 1/[σ2(Fo2) + (0.1074P)2 + 12.8085P]
where P = (Fo2 + 2Fc2)/3
S = 1.10(Δ/σ)max = 0.001
2275 reflectionsΔρmax = 4.19 e Å3
208 parametersΔρmin = 3.66 e Å3
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Fe10.5723 (5)0.84167 (13)0.53065 (8)0.0007 (4)
Fe20.5649 (4)0.65837 (13)0.53111 (8)0.0004 (4)
Fe30.5640 (4)0.75145 (13)0.43871 (8)0.0004 (4)
Fe40.2416 (4)0.99970 (15)0.41610 (11)0.0001 (5)
Fe50.7398 (4)0.75294 (16)0.33380 (12)0.0045 (6)
Fe60.7268 (4)0.91103 (18)0.38672 (12)0.0048 (5)
Fe70.2508 (4)0.99774 (16)0.52140 (11)0.0019 (5)
Fe80.2291 (4)0.84099 (17)0.36319 (10)0.0008 (5)
Fe91.2476 (4)0.65815 (17)0.36272 (11)0.0022 (5)
Fe100.7481 (4)0.75144 (16)0.22873 (11)0.0035 (5)
Fe110.7483 (4)0.59542 (17)0.38669 (12)0.0037 (5)
Fe120.9272 (6)0.59407 (16)0.28047 (9)0.0095 (5)
Fe130.9366 (6)0.50077 (15)0.18834 (9)0.0094 (5)
Fe140.9379 (6)0.41051 (16)0.28174 (10)0.0096 (5)
C10.464 (3)0.8960 (9)0.4544 (6)0.004 (2)
C20.971 (3)0.8921 (10)0.5472 (6)0.004 (2)
C30.965 (3)0.7466 (9)0.4050 (5)0.002 (2)
C40.529 (3)0.6457 (16)0.2971 (8)0.001 (4)0.666700
C50.540 (4)0.3586 (15)0.2964 (8)0.002 (3)0.666700
C61.058 (5)0.5023 (13)0.3139 (11)0.025 (3)0.333330
C70.538 (4)0.5095 (15)0.1548 (9)0.001 (4)0.666700
C81.077 (6)0.4066 (19)0.2180 (13)0.017 (5)0.333330
C91.060 (6)0.5929 (18)0.2180 (9)0.023 (4)0.333330
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Fe10.0008 (9)0.0005 (8)0.0008 (8)0.0003 (7)0.0005 (8)0.0002 (6)
Fe20.0004 (8)0.0004 (8)0.0010 (8)0.0011 (7)0.0003 (7)0.0004 (6)
Fe30.0002 (8)0.0006 (8)0.0003 (8)0.0000 (7)0.0009 (7)0.0004 (6)
Fe40.0009 (12)0.0016 (10)0.0003 (11)0.0009 (5)0.0000 (6)0.0005 (8)
Fe50.0034 (13)0.0063 (11)0.0038 (12)0.0004 (7)0.0000 (6)0.0003 (9)
Fe60.0034 (11)0.0053 (11)0.0055 (12)0.0023 (7)0.0002 (7)0.0011 (9)
Fe70.0007 (13)0.0028 (10)0.0022 (12)0.0008 (6)0.0001 (6)0.0001 (8)
Fe80.0003 (10)0.0017 (10)0.0011 (11)0.0003 (6)0.0005 (6)0.0019 (8)
Fe90.0023 (13)0.0002 (10)0.0046 (13)0.0006 (6)0.0000 (6)0.0010 (8)
Fe100.0031 (13)0.0060 (11)0.0014 (11)0.0009 (6)0.0001 (6)0.0006 (9)
Fe110.0015 (12)0.0059 (12)0.0038 (12)0.0019 (6)0.0000 (6)0.0007 (9)
Fe120.0122 (12)0.0107 (11)0.0057 (10)0.0002 (9)0.0003 (10)0.0004 (8)
Fe130.0114 (11)0.0095 (10)0.0073 (10)0.0010 (9)0.0000 (9)0.0001 (9)
Fe140.0109 (11)0.0087 (10)0.0091 (11)0.0013 (9)0.0027 (10)0.0004 (8)
C10.005 (6)0.001 (5)0.008 (6)0.009 (5)0.003 (5)0.000 (4)
C20.001 (6)0.001 (5)0.013 (6)0.004 (5)0.001 (5)0.008 (5)
C30.004 (6)0.009 (6)0.007 (5)0.000 (5)0.001 (4)0.003 (4)
C40.018 (6)0.017 (11)0.000 (8)0.007 (6)0.008 (6)0.011 (8)
C50.004 (8)0.003 (9)0.006 (7)0.012 (7)0.009 (6)0.001 (7)
C60.025 (9)0.034 (7)0.017 (11)0.007 (6)0.001 (8)0.005 (7)
C70.003 (8)0.011 (10)0.004 (9)0.003 (7)0.006 (7)0.012 (7)
C80.027 (9)0.023 (10)0.001 (14)0.003 (8)0.000 (9)0.010 (10)
C90.016 (11)0.019 (10)0.033 (7)0.005 (8)0.002 (8)0.000 (7)
Geometric parameters (Å, º) top
Fe1—Fe22.522 (3)Fe7—Fe7vi2.490 (4)
Fe1—Fe2i2.730 (3)Fe7—Fe11i2.544 (4)
Fe1—Fe2ii2.674 (3)Fe7—C1iii2.033 (13)
Fe1—Fe3ii2.670 (3)Fe7—C12.336 (13)
Fe1—Fe32.525 (3)Fe7—C2iii2.447 (14)
Fe1—Fe3i2.733 (3)Fe7—C2v2.024 (14)
Fe1—Fe4iii2.663 (3)Fe8—Fe9v2.516 (4)
Fe1—Fe7iii2.659 (3)Fe8—Fe10xi2.521 (4)
Fe1—Fe72.603 (3)Fe8—Fe13ix2.629 (3)
Fe1—Fe9i2.670 (3)Fe8—Fe14vii2.641 (3)
Fe1—Fe11i2.609 (3)Fe8—C12.542 (14)
Fe1—C12.029 (14)Fe8—C3v2.028 (13)
Fe1—C21.973 (13)Fe8—C5viii2.02 (2)
Fe1—C3i2.019 (13)Fe8—C7ix2.583 (19)
Fe2—Fe3i2.683 (3)Fe8—C8ix2.55 (3)
Fe2—Fe3ii2.676 (3)Fe9—Fe10xii2.535 (4)
Fe2—Fe32.553 (3)Fe9—Fe112.486 (3)
Fe2—Fe4ii2.638 (3)Fe9—Fe11x2.491 (2)
Fe2—Fe6i2.667 (3)Fe9—Fe122.597 (3)
Fe2—Fe7iv2.641 (3)Fe9—Fe13xii2.628 (3)
Fe2—Fe7ii2.626 (3)Fe9—C2ii2.478 (15)
Fe2—Fe8ii2.634 (3)Fe9—C32.034 (13)
Fe2—C1ii1.986 (13)Fe9—C4x2.03 (2)
Fe2—C2i2.042 (14)Fe9—C62.59 (2)
Fe2—C3i2.060 (12)Fe9—C7xii2.29 (2)
Fe3—Fe52.631 (3)Fe9—C9xii2.56 (3)
Fe3—Fe62.628 (3)Fe10—Fe10xii2.481 (2)
Fe3—Fe82.660 (3)Fe10—Fe10xi2.481 (2)
Fe3—Fe9v2.645 (3)Fe10—Fe122.622 (3)
Fe3—Fe112.617 (3)Fe10—Fe12xi2.616 (3)
Fe3—C12.073 (13)Fe10—Fe14vii2.665 (3)
Fe3—C2i2.048 (14)Fe10—Fe14xiii2.621 (3)
Fe3—C31.987 (13)Fe10—C4xii2.030 (19)
Fe4—Fe6v2.722 (3)Fe10—C42.401 (18)
Fe4—Fe62.608 (3)Fe10—C5ix2.06 (2)
Fe4—Fe7vi2.683 (3)Fe10—C5vii2.390 (17)
Fe4—Fe7iii2.740 (3)Fe11—Fe122.666 (4)
Fe4—Fe72.518 (4)Fe11—Fe13xi2.627 (3)
Fe4—Fe82.524 (3)Fe11—C2i2.026 (14)
Fe4—Fe9vii2.526 (3)Fe11—C32.341 (13)
Fe4—Fe11vii2.749 (3)Fe11—C42.459 (17)
Fe4—Fe11viii2.673 (3)Fe11—C62.58 (3)
Fe4—Fe13ix2.624 (3)Fe11—C7xii2.02 (2)
Fe4—C11.973 (14)Fe12—Fe12xi2.691 (2)
Fe4—C2iii1.977 (13)Fe12—Fe12xii2.691 (2)
Fe4—C7ix1.972 (19)Fe12—Fe132.550 (3)
Fe5—Fe62.517 (4)Fe12—Fe13xi2.670 (4)
Fe5—Fe8x2.620 (3)Fe12—Fe13xii2.742 (4)
Fe5—Fe82.702 (3)Fe12—Fe142.526 (3)
Fe5—Fe92.731 (3)Fe12—C4xii2.04 (2)
Fe5—Fe9v2.672 (3)Fe12—C41.975 (19)
Fe5—Fe10xi2.680 (3)Fe12—C61.61 (2)
Fe5—Fe102.512 (4)Fe12—C7xii2.000 (18)
Fe5—Fe10xii2.744 (3)Fe12—C9xi1.66 (3)
Fe5—Fe112.509 (4)Fe12—C91.61 (2)
Fe5—Fe122.668 (3)Fe13—Fe14xi2.673 (4)
Fe5—Fe14vii2.626 (3)Fe13—Fe142.555 (3)
Fe5—C31.986 (12)Fe13—Fe14xii2.683 (4)
Fe5—C41.96 (2)Fe13—C4xii2.07 (2)
Fe5—C5vii1.976 (18)Fe13—C5xii2.044 (19)
Fe5—C8xiii2.59 (3)Fe13—C6xi1.71 (2)
Fe6—Fe7iii2.532 (4)Fe13—C71.98 (2)
Fe6—Fe8x2.532 (3)Fe13—C81.61 (3)
Fe6—Fe82.513 (3)Fe13—C91.56 (2)
Fe6—Fe11vii2.539 (4)Fe14—Fe14xii2.724 (3)
Fe6—Fe13xiii2.658 (4)Fe14—Fe14xi2.724 (3)
Fe6—Fe14vii2.618 (4)Fe14—C5xii2.054 (18)
Fe6—C12.019 (13)Fe14—C51.97 (2)
Fe6—C32.543 (13)Fe14—C61.58 (2)
Fe6—C5vii2.509 (17)Fe14—C7xii2.09 (2)
Fe6—C6vii2.50 (2)Fe14—C81.65 (3)
Fe6—C7ix2.062 (19)Fe14—C8xi1.63 (3)
Fe7—Fe7iii2.478 (4)
Fe4iii—Fe1—Fe3ii89.91 (8)Fe5—Fe9—Fe1ii89.50 (10)
Fe4iii—Fe1—Fe3145.46 (10)Fe5—Fe9—Fe3x113.44 (11)
Fe4iii—Fe1—Fe3i121.47 (9)Fe5x—Fe9—Fe3x59.33 (8)
Fe7—Fe1—Fe3108.85 (10)Fe5x—Fe9—Fe4xiv122.40 (10)
Fe7iii—Fe1—Fe3i140.21 (10)Fe5—Fe9—Fe4xiv123.78 (9)
Fe7iii—Fe1—Fe390.30 (9)Fe8x—Fe9—Fe1ii89.14 (10)
Fe7—Fe1—Fe3i86.50 (8)Fe8x—Fe9—Fe3x61.97 (8)
Fe7iii—Fe1—Fe3ii106.02 (9)Fe8x—Fe9—Fe4xiv149.39 (14)
Fe7—Fe1—Fe3ii152.23 (10)Fe8x—Fe9—Fe5x62.69 (8)
Fe7—Fe1—Fe4iii62.71 (8)Fe8x—Fe9—Fe559.74 (8)
Fe7iii—Fe1—Fe4iii56.48 (8)Fe10xii—Fe9—Fe1ii145.42 (11)
Fe9i—Fe1—Fe3i89.69 (8)Fe10xii—Fe9—Fe3x110.26 (10)
Fe9i—Fe1—Fe3ii59.39 (7)Fe10xii—Fe9—Fe4xiv150.74 (13)
Fe9i—Fe1—Fe3146.75 (10)Fe10xii—Fe9—Fe5x61.90 (9)
Fe9i—Fe1—Fe4iii56.55 (8)Fe10xii—Fe9—Fe562.67 (9)
Fe9i—Fe1—Fe7iii110.90 (10)Fe10xii—Fe9—Fe8x59.87 (9)
Fe9i—Fe1—Fe7104.27 (10)Fe11—Fe9—Fe1ii60.66 (8)
Fe11i—Fe1—Fe3ii114.82 (9)Fe11x—Fe9—Fe1ii92.91 (10)
Fe11i—Fe1—Fe3144.53 (11)Fe11x—Fe9—Fe3x61.17 (8)
Fe11i—Fe1—Fe3i58.62 (7)Fe11—Fe9—Fe3x120.13 (11)
Fe11i—Fe1—Fe4iii62.85 (8)Fe11—Fe9—Fe4xiv66.51 (8)
Fe11i—Fe1—Fe758.44 (9)Fe11x—Fe9—Fe4xiv64.37 (8)
Fe11i—Fe1—Fe7iii104.37 (10)Fe11—Fe9—Fe5x170.69 (11)
Fe11i—Fe1—Fe9i56.17 (8)Fe11—Fe9—Fe557.26 (8)
C1—Fe1—Fe3i102.2 (4)Fe11x—Fe9—Fe5x58.03 (8)
C1—Fe1—Fe3ii128.6 (4)Fe11x—Fe9—Fe5171.43 (11)
C1—Fe1—Fe352.8 (4)Fe11x—Fe9—Fe8x112.05 (9)
C1—Fe1—Fe4iii101.8 (4)Fe11—Fe9—Fe8x108.40 (9)
C1—Fe1—Fe759.0 (4)Fe11x—Fe9—Fe10xii111.90 (9)
C1—Fe1—Fe7iii49.2 (4)Fe11—Fe9—Fe10xii112.05 (9)
C1—Fe1—Fe9i158.2 (4)Fe12—Fe9—Fe1ii123.88 (10)
C1—Fe1—Fe11i115.0 (4)Fe12—Fe9—Fe3x170.67 (12)
C2—Fe1—Fe3i151.7 (4)Fe12—Fe9—Fe4xiv95.77 (10)
C2—Fe1—Fe3111.2 (4)Fe12—Fe9—Fe560.04 (9)
C2—Fe1—Fe3ii49.6 (4)Fe12—Fe9—Fe5x115.78 (13)
C2—Fe1—Fe4iii47.7 (4)Fe12—Fe9—Fe8x108.90 (11)
C2—Fe1—Fe7103.8 (4)Fe12—Fe9—Fe10xii61.27 (9)
C2—Fe1—Fe7iii61.7 (4)Fe12—Fe9—Fe1163.22 (9)
C2—Fe1—Fe9i62.4 (4)Fe12—Fe9—Fe11x124.35 (11)
C2—Fe1—Fe11i104.2 (4)Fe13xii—Fe9—Fe1ii122.75 (11)
C2—Fe1—C1105.7 (6)Fe13xii—Fe9—Fe3x122.85 (11)
C3i—Fe1—Fe3111.4 (4)Fe13xii—Fe9—Fe4xiv61.17 (9)
C3i—Fe1—Fe3i46.5 (4)Fe13xii—Fe9—Fe5x90.60 (10)
C3i—Fe1—Fe3ii72.7 (4)Fe13xii—Fe9—Fe5123.33 (12)
C3i—Fe1—Fe4iii101.8 (4)Fe13xii—Fe9—Fe8x146.73 (12)
C3i—Fe1—Fe7iii158.2 (4)Fe13xii—Fe9—Fe10xii90.92 (10)
C3i—Fe1—Fe7115.3 (4)Fe13xii—Fe9—Fe1196.72 (10)
C3i—Fe1—Fe9i49.0 (4)Fe13xii—Fe9—Fe11x61.68 (9)
C3i—Fe1—Fe11i59.2 (4)Fe13xii—Fe9—Fe1263.29 (9)
C3i—Fe1—C1148.0 (5)C2ii—Fe9—Fe1ii44.9 (3)
C3i—Fe1—C2106.2 (6)C2ii—Fe9—Fe3x47.0 (3)
Fe3i—Fe2—Fe1ii148.89 (9)C2ii—Fe9—Fe4xiv46.5 (3)
Fe3—Fe2—Fe1ii62.19 (7)C2ii—Fe9—Fe5x91.2 (3)
Fe3ii—Fe2—Fe1i148.51 (9)C2ii—Fe9—Fe5134.1 (3)
Fe3—Fe2—Fe159.66 (7)C2ii—Fe9—Fe8x106.8 (3)
Fe3ii—Fe2—Fe161.74 (7)C2ii—Fe9—Fe10xii153.0 (3)
Fe3i—Fe2—Fe163.26 (8)C2ii—Fe9—Fe11x48.1 (3)
Fe3ii—Fe2—Fe1ii55.68 (7)C2ii—Fe9—Fe1194.2 (3)
Fe3—Fe2—Fe1i61.38 (7)C2ii—Fe9—Fe12142.3 (3)
Fe3i—Fe2—Fe1i56.24 (7)C2ii—Fe9—Fe13xii92.4 (3)
Fe4ii—Fe2—Fe1i121.11 (9)C3—Fe9—Fe1ii48.6 (4)
Fe4ii—Fe2—Fe1145.30 (10)C3—Fe9—Fe3x73.1 (4)
Fe4ii—Fe2—Fe1ii90.21 (8)C3—Fe9—Fe4xiv106.1 (4)
Fe4ii—Fe2—Fe3ii89.84 (8)C3—Fe9—Fe5x111.1 (4)
Fe4ii—Fe2—Fe3145.86 (10)C3—Fe9—Fe546.5 (4)
Fe4ii—Fe2—Fe3i120.56 (9)C3—Fe9—Fe8x51.6 (4)
Fe6i—Fe2—Fe1i85.90 (9)C3—Fe9—Fe10xii97.3 (4)
Fe6i—Fe2—Fe1111.63 (10)C3—Fe9—Fe11x131.6 (4)
Fe6i—Fe2—Fe1ii151.76 (10)C3—Fe9—Fe1161.4 (4)
Fe6i—Fe2—Fe3ii116.84 (9)C3—Fe9—Fe12103.2 (4)
Fe6i—Fe2—Fe3144.68 (11)C3—Fe9—Fe13xii158.1 (4)
Fe6i—Fe2—Fe3i58.84 (7)C3—Fe9—C2ii89.5 (5)
Fe6i—Fe2—Fe4ii61.73 (8)C6—Fe9—C4x77.8 (8)
Fe7iv—Fe2—Fe1147.48 (10)C9xii—Fe9—C7xii77.2 (8)
Fe7ii—Fe2—Fe1ii58.12 (7)Fe8xii—Fe10—Fe5xii62.50 (9)
Fe7ii—Fe2—Fe1i90.16 (8)Fe8xii—Fe10—Fe5150.13 (13)
Fe7iv—Fe2—Fe1ii114.03 (9)Fe8xii—Fe10—Fe5xi59.51 (8)
Fe7ii—Fe2—Fe1144.24 (10)Fe9xi—Fe10—Fe5xi62.16 (8)
Fe7iv—Fe2—Fe1i60.03 (7)Fe9xi—Fe10—Fe5150.05 (13)
Fe7ii—Fe2—Fe3ii103.75 (9)Fe9xi—Fe10—Fe5xii61.55 (8)
Fe7iv—Fe2—Fe3i87.33 (8)Fe9xi—Fe10—Fe8xii59.69 (10)
Fe7iv—Fe2—Fe3110.03 (10)Fe10xi—Fe10—Fe5xii170.29 (17)
Fe7ii—Fe2—Fe389.82 (9)Fe10xi—Fe10—Fe564.93 (12)
Fe7ii—Fe2—Fe3i141.02 (10)Fe10xi—Fe10—Fe5xi57.22 (9)
Fe7iv—Fe2—Fe3ii150.22 (9)Fe10xii—Fe10—Fe5xi171.17 (17)
Fe7ii—Fe2—Fe4ii57.16 (9)Fe10xii—Fe10—Fe5xii58.11 (9)
Fe7iv—Fe2—Fe4ii61.09 (7)Fe10xii—Fe10—Fe566.66 (13)
Fe7ii—Fe2—Fe6i104.08 (10)Fe10xii—Fe10—Fe8xii112.86 (11)
Fe7iv—Fe2—Fe6i56.97 (9)Fe10xi—Fe10—Fe8xii109.04 (10)
Fe8ii—Fe2—Fe1i139.90 (10)Fe10xii—Fe10—Fe9xi110.76 (10)
Fe8ii—Fe2—Fe189.83 (9)Fe10xi—Fe10—Fe9xi110.65 (10)
Fe8ii—Fe2—Fe1ii106.37 (9)Fe12—Fe10—Fe5xi121.50 (11)
Fe8ii—Fe2—Fe3ii60.11 (7)Fe12xi—Fe10—Fe5xii114.84 (11)
Fe8ii—Fe2—Fe3i88.78 (8)Fe12xi—Fe10—Fe5xi59.66 (8)
Fe8ii—Fe2—Fe3145.98 (10)Fe12—Fe10—Fe5xii90.74 (9)
Fe8ii—Fe2—Fe4ii57.20 (8)Fe12—Fe10—Fe562.59 (9)
Fe8ii—Fe2—Fe6i57.06 (8)Fe12xi—Fe10—Fe594.73 (10)
Fe8ii—Fe2—Fe7ii111.78 (10)Fe12—Fe10—Fe8xii145.63 (12)
Fe8ii—Fe2—Fe7iv103.86 (10)Fe12xi—Fe10—Fe8xii108.18 (11)
C1ii—Fe2—Fe1i148.7 (4)Fe12xi—Fe10—Fe9xi60.53 (9)
C1ii—Fe2—Fe1111.4 (4)Fe12—Fe10—Fe9xi89.38 (10)
C1ii—Fe2—Fe1ii47.8 (4)Fe12xi—Fe10—Fe10xi61.84 (7)
C1ii—Fe2—Fe3109.9 (4)Fe12—Fe10—Fe10xi95.08 (11)
C1ii—Fe2—Fe3i153.6 (4)Fe14xiii—Fe10—Fe5xii59.36 (8)
C1ii—Fe2—Fe3ii50.2 (4)Fe14xiii—Fe10—Fe595.56 (11)
C1ii—Fe2—Fe4ii48.0 (4)Fe14vii—Fe10—Fe560.86 (9)
C1ii—Fe2—Fe6i105.0 (4)Fe14xiii—Fe10—Fe5xi113.34 (11)
C1ii—Fe2—Fe7ii58.9 (4)Fe14vii—Fe10—Fe5xi89.32 (9)
C1ii—Fe2—Fe7iv101.1 (4)Fe14vii—Fe10—Fe5xii121.41 (11)
C1ii—Fe2—Fe8ii65.0 (4)Fe14vii—Fe10—Fe8xii90.15 (10)
C2i—Fe2—Fe1109.8 (4)Fe14xiii—Fe10—Fe8xii61.79 (9)
C2i—Fe2—Fe1ii71.3 (4)Fe14vii—Fe10—Fe9xi145.63 (12)
C2i—Fe2—Fe1i47.1 (4)Fe14xiii—Fe10—Fe9xi109.92 (12)
C2i—Fe2—Fe3ii125.5 (4)Fe14vii—Fe10—Fe10xi61.11 (8)
C2i—Fe2—Fe3i103.2 (4)Fe14xiii—Fe10—Fe10xi122.25 (8)
C2i—Fe2—Fe351.5 (4)Fe14vii—Fe10—Fe12123.45 (12)
C2i—Fe2—Fe4ii102.8 (4)Fe14vii—Fe10—Fe12xi122.96 (10)
C2i—Fe2—Fe6i115.7 (4)Fe14xiii—Fe10—Fe12xi169.66 (14)
C2i—Fe2—Fe7ii49.5 (4)Fe14xiii—Fe10—Fe12124.54 (10)
C2i—Fe2—Fe7iv61.4 (4)C5vii—Fe10—C4xii113.3 (7)
C2i—Fe2—Fe8ii160.0 (4)C5vii—Fe10—C494.5 (7)
C2i—Fe2—C1ii102.8 (5)C5ix—Fe10—C4111.8 (7)
C3i—Fe2—Fe1i103.1 (4)C5ix—Fe10—C4xii145.3 (8)
C3i—Fe2—Fe1ii125.9 (4)Fe3—Fe11—Fe1ii63.06 (9)
C3i—Fe2—Fe151.1 (4)Fe4iv—Fe11—Fe1ii115.49 (12)
C3i—Fe2—Fe3ii72.0 (4)Fe4xiv—Fe11—Fe1ii59.54 (8)
C3i—Fe2—Fe3108.9 (4)Fe4iv—Fe11—Fe390.85 (9)
C3i—Fe2—Fe3i47.3 (4)Fe4xiv—Fe11—Fe3122.60 (11)
C3i—Fe2—Fe4ii103.6 (4)Fe5—Fe11—Fe1ii95.97 (11)
C3i—Fe2—Fe6i63.6 (4)Fe5—Fe11—Fe361.73 (9)
C3i—Fe2—Fe7ii160.6 (4)Fe5—Fe11—Fe4iv123.05 (9)
C3i—Fe2—Fe7iv118.5 (4)Fe5—Fe11—Fe4xiv123.74 (9)
C3i—Fe2—Fe8ii49.3 (4)Fe6xiv—Fe11—Fe1ii107.84 (11)
C3i—Fe2—C1ii108.0 (5)Fe6xiv—Fe11—Fe3146.45 (13)
C3i—Fe2—C2i148.2 (5)Fe6xiv—Fe11—Fe4xiv58.94 (8)
Fe5—Fe3—Fe1145.26 (10)Fe6xiv—Fe11—Fe4iv62.91 (8)
Fe5—Fe3—Fe1ii90.28 (8)Fe6xiv—Fe11—Fe5149.71 (15)
Fe5—Fe3—Fe1i121.14 (9)Fe7ii—Fe11—Fe1ii60.67 (8)
Fe6—Fe3—Fe1i139.82 (10)Fe7ii—Fe11—Fe390.23 (11)
Fe6—Fe3—Fe189.84 (9)Fe7ii—Fe11—Fe4iv61.85 (9)
Fe6—Fe3—Fe1ii106.41 (9)Fe7ii—Fe11—Fe4xiv62.22 (8)
Fe6—Fe3—Fe557.18 (9)Fe7ii—Fe11—Fe5150.52 (14)
Fe8—Fe3—Fe1111.84 (10)Fe7ii—Fe11—Fe6xiv59.76 (10)
Fe8—Fe3—Fe1i86.19 (9)Fe9v—Fe11—Fe1ii124.79 (11)
Fe8—Fe3—Fe1ii151.48 (10)Fe9—Fe11—Fe1ii63.17 (8)
Fe8—Fe3—Fe561.41 (8)Fe9—Fe11—Fe396.57 (9)
Fe8—Fe3—Fe656.75 (8)Fe9v—Fe11—Fe362.32 (8)
Fe9v—Fe3—Fe1147.62 (11)Fe9—Fe11—Fe4xiv57.45 (8)
Fe9v—Fe3—Fe1ii114.35 (9)Fe9—Fe11—Fe4iv170.31 (11)
Fe9v—Fe3—Fe1i60.31 (8)Fe9v—Fe11—Fe4xiv171.28 (11)
Fe9v—Fe3—Fe560.83 (8)Fe9v—Fe11—Fe4iv58.46 (8)
Fe9v—Fe3—Fe6103.42 (11)Fe9—Fe11—Fe566.29 (8)
Fe9v—Fe3—Fe856.63 (9)Fe9v—Fe11—Fe564.59 (8)
Fe11—Fe3—Fe1i90.14 (8)Fe9—Fe11—Fe6xiv107.84 (9)
Fe11—Fe3—Fe1ii58.32 (7)Fe9v—Fe11—Fe6xiv112.74 (10)
Fe11—Fe3—Fe1144.31 (11)Fe9—Fe11—Fe7ii111.72 (10)
Fe11—Fe3—Fe557.12 (9)Fe9v—Fe11—Fe7ii112.17 (10)
Fe11—Fe3—Fe6111.78 (10)Fe12—Fe11—Fe1ii123.60 (10)
Fe11—Fe3—Fe8103.81 (10)Fe12—Fe11—Fe3123.73 (11)
Fe11—Fe3—Fe9v56.51 (7)Fe12—Fe11—Fe4xiv89.16 (10)
C1—Fe3—Fe151.2 (4)Fe12—Fe11—Fe4iv119.95 (12)
C1—Fe3—Fe1ii125.7 (4)Fe12—Fe11—Fe561.99 (10)
C1—Fe3—Fe1i103.2 (4)Fe12—Fe11—Fe6xiv88.84 (11)
C1—Fe3—Fe5103.4 (4)Fe12—Fe11—Fe7ii144.90 (12)
C1—Fe3—Fe649.1 (4)Fe12—Fe11—Fe9v93.41 (10)
C1—Fe3—Fe863.6 (4)Fe12—Fe11—Fe960.44 (9)
C1—Fe3—Fe9v118.2 (4)Fe13xi—Fe11—Fe1ii169.57 (12)
C1—Fe3—Fe11160.4 (4)Fe13xi—Fe11—Fe3124.05 (10)
C2i—Fe3—Fe1109.5 (4)Fe13xi—Fe11—Fe4xiv112.83 (11)
C2i—Fe3—Fe1ii71.2 (4)Fe13xi—Fe11—Fe4iv59.35 (9)
C2i—Fe3—Fe1i47.2 (4)Fe13xi—Fe11—Fe594.33 (11)
C2i—Fe3—Fe5103.1 (4)Fe13xi—Fe11—Fe6xiv61.90 (10)
C2i—Fe3—Fe6160.3 (4)Fe13xi—Fe11—Fe7ii110.04 (11)
C2i—Fe3—Fe8116.2 (4)Fe13xi—Fe11—Fe9v61.73 (9)
C2i—Fe3—Fe9v62.2 (4)Fe13xi—Fe11—Fe9120.17 (12)
C2i—Fe3—Fe1149.7 (4)Fe13xi—Fe11—Fe1260.59 (10)
C2i—Fe3—C1148.2 (5)C2i—Fe11—Fe1ii74.3 (4)
C3—Fe3—Fe1i148.9 (4)C2i—Fe11—Fe350.4 (4)
C3—Fe3—Fe1ii47.5 (4)C2i—Fe11—Fe4iv47.3 (4)
C3—Fe3—Fe1110.9 (4)C2i—Fe11—Fe4xiv111.2 (4)
C3—Fe3—Fe548.5 (4)C2i—Fe11—Fe5108.1 (4)
C3—Fe3—Fe665.2 (4)C2i—Fe11—Fe6xiv96.4 (4)
C3—Fe3—Fe8105.1 (4)C2i—Fe11—Fe7ii51.0 (4)
C3—Fe3—Fe9v101.5 (4)C2i—Fe11—Fe9v65.6 (4)
C3—Fe3—Fe1159.3 (4)C2i—Fe11—Fe9135.6 (4)
C3—Fe3—C1107.7 (5)C2i—Fe11—Fe12158.8 (4)
C3—Fe3—C2i102.9 (5)C2i—Fe11—Fe13xi104.0 (4)
Fe6—Fe4—Fe1iii104.23 (9)C3—Fe11—Fe1ii47.8 (3)
Fe6v—Fe4—Fe1iii139.57 (10)C3—Fe11—Fe346.8 (3)
Fe7iii—Fe4—Fe1iii57.57 (8)C3—Fe11—Fe4iv137.4 (3)
Fe7vi—Fe4—Fe1iii89.17 (9)C3—Fe11—Fe4xiv91.5 (3)
Fe7—Fe4—Fe1iii61.68 (8)C3—Fe11—Fe548.2 (3)
Fe7vi—Fe4—Fe6148.79 (12)C3—Fe11—Fe6xiv150.3 (3)
Fe7iii—Fe4—Fe6v149.76 (11)C3—Fe11—Fe7ii106.5 (3)
Fe7iii—Fe4—Fe656.45 (8)C3—Fe11—Fe9v96.7 (3)
Fe7—Fe4—Fe6104.51 (10)C3—Fe11—Fe949.7 (3)
Fe7—Fe4—Fe6v105.51 (10)C3—Fe11—Fe1293.3 (3)
Fe7vi—Fe4—Fe6v55.86 (8)C3—Fe11—Fe13xi142.5 (3)
Fe8—Fe4—Fe1iii162.85 (9)C3—Fe11—C2i92.2 (5)
Fe8—Fe4—Fe658.62 (8)C6—Fe11—C476.7 (8)
Fe8—Fe4—Fe6v57.58 (8)Fe9—Fe12—Fe562.47 (8)
Fe8—Fe4—Fe7iii107.65 (9)Fe10xii—Fe12—Fe562.55 (8)
Fe8—Fe4—Fe7119.49 (11)Fe10—Fe12—Fe556.70 (9)
Fe8—Fe4—Fe7vi105.78 (9)Fe10xii—Fe12—Fe958.20 (9)
Fe9vii—Fe4—Fe1iii61.87 (8)Fe10—Fe12—Fe9104.45 (11)
Fe9vii—Fe4—Fe6104.55 (11)Fe11—Fe12—Fe556.12 (9)
Fe9vii—Fe4—Fe6v105.82 (10)Fe11—Fe12—Fe956.35 (8)
Fe9vii—Fe4—Fe7iii104.38 (9)Fe11—Fe12—Fe10xii104.06 (11)
Fe9vii—Fe4—Fe7120.93 (12)Fe11—Fe12—Fe10110.48 (11)
Fe9vii—Fe4—Fe7vi106.62 (9)Fe12xii—Fe12—Fe5121.73 (7)
Fe9vii—Fe4—Fe8119.57 (13)Fe12xi—Fe12—Fe589.51 (7)
Fe11viii—Fe4—Fe1iii89.10 (9)Fe12xii—Fe12—Fe986.59 (8)
Fe11vii—Fe4—Fe1iii57.61 (8)Fe12xi—Fe12—Fe9151.55 (10)
Fe11vii—Fe4—Fe6v150.15 (14)Fe12xii—Fe12—Fe1090.25 (10)
Fe11viii—Fe4—Fe6v56.14 (8)Fe12xii—Fe12—Fe10xii59.18 (7)
Fe11vii—Fe4—Fe656.51 (8)Fe12xi—Fe12—Fe1058.98 (8)
Fe11viii—Fe4—Fe6149.07 (14)Fe12xi—Fe12—Fe10xii114.91 (9)
Fe11viii—Fe4—Fe7106.38 (10)Fe12xi—Fe12—Fe11105.10 (9)
Fe11viii—Fe4—Fe7iii146.34 (11)Fe12xii—Fe12—Fe11140.46 (12)
Fe11vii—Fe4—Fe7104.30 (10)Fe13xi—Fe12—Fe589.76 (10)
Fe11viii—Fe4—Fe7vi56.72 (8)Fe13xii—Fe12—Fe5121.37 (11)
Fe11vii—Fe4—Fe7vi146.46 (11)Fe13—Fe12—Fe5146.13 (12)
Fe11vii—Fe4—Fe7iii55.22 (8)Fe13xi—Fe12—Fe9114.56 (11)
Fe11vii—Fe4—Fe8107.75 (11)Fe13xii—Fe12—Fe958.91 (9)
Fe11viii—Fe4—Fe8106.00 (11)Fe13—Fe12—Fe9144.65 (13)
Fe11viii—Fe4—Fe9vii57.18 (7)Fe13xii—Fe12—Fe10xii86.76 (10)
Fe11vii—Fe4—Fe9vii56.04 (7)Fe13xii—Fe12—Fe10140.78 (12)
Fe13ix—Fe4—Fe1iii123.20 (11)Fe13xi—Fe12—Fe10105.76 (11)
Fe13ix—Fe4—Fe690.29 (11)Fe13—Fe12—Fe1090.76 (10)
Fe13ix—Fe4—Fe6v59.59 (10)Fe13—Fe12—Fe10xii109.55 (12)
Fe13ix—Fe4—Fe7163.04 (10)Fe13xi—Fe12—Fe10xii151.96 (12)
Fe13ix—Fe4—Fe7vi105.94 (10)Fe13—Fe12—Fe11146.27 (12)
Fe13ix—Fe4—Fe7iii140.94 (11)Fe13xi—Fe12—Fe1158.99 (9)
Fe13ix—Fe4—Fe861.38 (9)Fe13xii—Fe12—Fe1189.97 (10)
Fe13ix—Fe4—Fe9vii61.33 (9)Fe13xii—Fe12—Fe12xi148.67 (9)
Fe13ix—Fe4—Fe11vii90.69 (11)Fe13xi—Fe12—Fe12xi56.79 (6)
Fe13ix—Fe4—Fe11viii59.46 (10)Fe13—Fe12—Fe12xi63.02 (11)
C1—Fe4—Fe1iii102.1 (4)Fe14—Fe12—Fe5144.99 (12)
C1—Fe4—Fe650.0 (4)Fe14—Fe12—Fe9108.63 (11)
C1—Fe4—Fe6v103.5 (4)Fe14—Fe12—Fe10146.84 (12)
C1—Fe4—Fe761.3 (4)Fe14—Fe12—Fe10xii144.85 (13)
C1—Fe4—Fe7vi100.1 (4)Fe14—Fe12—Fe1190.07 (10)
C1—Fe4—Fe7iii47.8 (4)Fe14—Fe12—Fe12xi91.30 (8)
C1—Fe4—Fe867.6 (4)Fe14—Fe12—Fe1360.45 (9)
C1—Fe4—Fe9vii148.1 (4)Fe14—Fe12—Fe13xii60.83 (9)
C1—Fe4—Fe11viii154.5 (4)Fe14—Fe12—Fe13xi62.10 (9)
C1—Fe4—Fe11vii92.1 (4)C6—Fe12—C4121.2 (11)
C1—Fe4—Fe13ix127.1 (4)C6—Fe12—C4xii129.9 (11)
C2iii—Fe4—Fe1iii47.5 (4)C9—Fe12—C7xii128.2 (12)
C2iii—Fe4—Fe6151.8 (4)C9xi—Fe12—C7xii103.1 (9)
C2iii—Fe4—Fe6v92.0 (4)Fe6xv—Fe13—Fe4xvi62.03 (8)
C2iii—Fe4—Fe7iii99.0 (4)Fe8xvi—Fe13—Fe4xvi57.43 (8)
C2iii—Fe4—Fe7vi48.6 (4)Fe8xvi—Fe13—Fe6xv57.23 (8)
C2iii—Fe4—Fe764.7 (4)Fe9xi—Fe13—Fe4xvi57.50 (8)
C2iii—Fe4—Fe8149.6 (4)Fe9xi—Fe13—Fe6xv104.80 (11)
C2iii—Fe4—Fe9vii65.4 (4)Fe9xi—Fe13—Fe8xvi112.22 (11)
C2iii—Fe4—Fe11viii48.9 (4)Fe11xii—Fe13—Fe4xvi61.18 (8)
C2iii—Fe4—Fe11vii99.3 (4)Fe11xii—Fe13—Fe6xv57.42 (10)
C2iii—Fe4—Fe13ix105.6 (4)Fe11xii—Fe13—Fe8xvi104.33 (11)
C2iii—Fe4—C1125.9 (6)Fe11xii—Fe13—Fe9xi56.59 (8)
Fe6—Fe5—Fe361.34 (10)Fe12—Fe13—Fe4xvi145.06 (12)
Fe8x—Fe5—Fe390.19 (11)Fe12xii—Fe13—Fe4xvi121.60 (11)
Fe8—Fe5—Fe359.81 (9)Fe12xi—Fe13—Fe4xvi90.17 (10)
Fe8x—Fe5—Fe659.03 (8)Fe12xi—Fe13—Fe6xv151.99 (13)
Fe8—Fe5—Fe657.44 (8)Fe12xii—Fe13—Fe6xv86.29 (11)
Fe9—Fe5—Fe390.53 (11)Fe12—Fe13—Fe6xv145.76 (14)
Fe9v—Fe5—Fe359.84 (9)Fe12xi—Fe13—Fe8xvi106.20 (11)
Fe9—Fe5—Fe6107.75 (11)Fe12xii—Fe13—Fe8xvi140.34 (12)
Fe9v—Fe5—Fe6105.79 (11)Fe12—Fe13—Fe8xvi145.18 (12)
Fe9v—Fe5—Fe855.85 (8)Fe12xi—Fe13—Fe9xi57.81 (8)
Fe9—Fe5—Fe8x56.06 (8)Fe12xii—Fe13—Fe9xi90.25 (10)
Fe9—Fe5—Fe8150.20 (14)Fe12—Fe13—Fe9xi88.93 (10)
Fe9v—Fe5—Fe8x149.40 (15)Fe12xii—Fe13—Fe11xii60.42 (9)
Fe10—Fe5—Fe3163.25 (10)Fe12—Fe13—Fe11xii110.46 (11)
Fe10xi—Fe5—Fe3106.31 (10)Fe12xi—Fe13—Fe11xii113.90 (10)
Fe10xii—Fe5—Fe3140.60 (11)Fe14—Fe13—Fe4xvi146.06 (12)
Fe10xi—Fe5—Fe6105.52 (10)Fe14xi—Fe13—Fe4xvi89.57 (10)
Fe10xii—Fe5—Fe6107.46 (10)Fe14xii—Fe13—Fe4xvi120.73 (11)
Fe10—Fe5—Fe6120.67 (13)Fe14—Fe13—Fe6xv111.29 (11)
Fe10xii—Fe5—Fe8149.56 (12)Fe14xi—Fe13—Fe6xv116.67 (11)
Fe10—Fe5—Fe8x105.02 (10)Fe14xii—Fe13—Fe6xv58.71 (9)
Fe10xi—Fe5—Fe8x148.72 (12)Fe14xii—Fe13—Fe8xvi88.81 (9)
Fe10—Fe5—Fe8106.06 (10)Fe14xi—Fe13—Fe8xvi59.75 (9)
Fe10xi—Fe5—Fe855.85 (8)Fe14—Fe13—Fe8xvi90.23 (10)
Fe10xii—Fe5—Fe8x56.01 (8)Fe14—Fe13—Fe9xi143.79 (12)
Fe10—Fe5—Fe9v105.51 (11)Fe14xi—Fe13—Fe9xi103.42 (11)
Fe10xi—Fe5—Fe9v56.55 (8)Fe14xii—Fe13—Fe9xi141.27 (12)
Fe10xi—Fe5—Fe9146.71 (12)Fe14xii—Fe13—Fe11xii87.57 (10)
Fe10—Fe5—Fe9103.68 (10)Fe14—Fe13—Fe11xii146.76 (13)
Fe10xii—Fe5—Fe9v146.75 (12)Fe14xi—Fe13—Fe11xii150.00 (13)
Fe10xii—Fe5—Fe955.17 (8)Fe14—Fe13—Fe1259.31 (9)
Fe11—Fe5—Fe361.15 (9)Fe14xi—Fe13—Fe12xii148.24 (12)
Fe11—Fe5—Fe6119.55 (14)Fe14xi—Fe13—Fe12xi55.58 (9)
Fe11—Fe5—Fe8105.61 (11)Fe14xii—Fe13—Fe12xi148.75 (12)
Fe11—Fe5—Fe8x104.54 (11)Fe14—Fe13—Fe12xii89.29 (10)
Fe11—Fe5—Fe9v57.38 (8)Fe14xi—Fe13—Fe1289.34 (11)
Fe11—Fe5—Fe956.44 (8)Fe14xii—Fe13—Fe1290.96 (11)
Fe11—Fe5—Fe10xii104.79 (10)Fe14—Fe13—Fe12xi89.52 (10)
Fe11—Fe5—Fe10xi106.69 (10)Fe14xii—Fe13—Fe12xii56.30 (9)
Fe11—Fe5—Fe10119.78 (13)C5xii—Fe13—C4xii147.8 (8)
Fe12—Fe5—Fe3123.04 (11)C6xi—Fe13—C4xii101.3 (7)
Fe12—Fe5—Fe6162.81 (11)C6xi—Fe13—C5xii104.2 (8)
Fe12—Fe5—Fe8x103.77 (10)C8—Fe13—C7126.1 (12)
Fe12—Fe5—Fe8139.75 (11)C9—Fe13—C7117.6 (12)
Fe12—Fe5—Fe957.49 (9)C9—Fe13—C8108.3 (14)
Fe12—Fe5—Fe9v89.37 (10)Fe6xiv—Fe14—Fe5xiv57.36 (9)
Fe12—Fe5—Fe1060.71 (9)Fe8xiv—Fe14—Fe5xiv61.72 (8)
Fe12—Fe5—Fe10xi89.49 (10)Fe8xiv—Fe14—Fe6xiv57.08 (9)
Fe12—Fe5—Fe10xii57.79 (8)Fe10xv—Fe14—Fe5xiv61.45 (8)
Fe12—Fe5—Fe1161.89 (9)Fe10xiv—Fe14—Fe5xiv56.70 (9)
Fe14vii—Fe5—Fe3111.45 (11)Fe10xv—Fe14—Fe6xiv104.37 (11)
Fe14vii—Fe5—Fe661.17 (10)Fe10xiv—Fe14—Fe6xiv111.61 (12)
Fe14vii—Fe5—Fe8x90.24 (10)Fe10xiv—Fe14—Fe8xiv103.50 (10)
Fe14vii—Fe5—Fe859.43 (9)Fe10xv—Fe14—Fe8xiv57.25 (9)
Fe14vii—Fe5—Fe9v105.68 (10)Fe12—Fe14—Fe5xiv145.61 (13)
Fe14vii—Fe5—Fe9140.51 (11)Fe12—Fe14—Fe6xiv90.19 (11)
Fe14vii—Fe5—Fe1062.44 (9)Fe12—Fe14—Fe8xiv112.44 (11)
Fe14vii—Fe5—Fe10xii90.26 (10)Fe12—Fe14—Fe10xv147.55 (13)
Fe14vii—Fe5—Fe10xi59.19 (9)Fe12—Fe14—Fe10xiv144.00 (12)
Fe14vii—Fe5—Fe11163.04 (10)Fe13xi—Fe14—Fe5xiv89.82 (10)
Fe14vii—Fe5—Fe12123.15 (13)Fe13xii—Fe14—Fe5xiv121.00 (11)
C3—Fe5—Fe348.5 (4)Fe13—Fe14—Fe5xiv144.56 (12)
C3—Fe5—Fe667.6 (4)Fe13xi—Fe14—Fe6xiv60.17 (9)
C3—Fe5—Fe8x49.9 (4)Fe13xii—Fe14—Fe6xiv88.99 (10)
C3—Fe5—Fe8103.6 (4)Fe13—Fe14—Fe6xiv146.71 (12)
C3—Fe5—Fe948.0 (4)Fe13xi—Fe14—Fe8xiv116.95 (11)
C3—Fe5—Fe9v100.6 (4)Fe13xii—Fe14—Fe8xiv59.29 (9)
C3—Fe5—Fe10148.1 (4)Fe13—Fe14—Fe8xiv145.24 (13)
C3—Fe5—Fe10xi154.7 (4)Fe13—Fe14—Fe10xv108.87 (12)
C3—Fe5—Fe10xii92.1 (4)Fe13xii—Fe14—Fe10xv87.46 (10)
C3—Fe5—Fe1161.5 (4)Fe13xi—Fe14—Fe10xiv103.87 (10)
C3—Fe5—Fe12102.2 (4)Fe13xii—Fe14—Fe10xiv140.83 (12)
C3—Fe5—Fe14vii126.8 (4)Fe13xi—Fe14—Fe10xv150.47 (12)
C5vii—Fe5—C4126.5 (7)Fe13—Fe14—Fe10xiv89.00 (10)
Fe4—Fe6—Fe391.57 (10)Fe13—Fe14—Fe1260.24 (9)
Fe4x—Fe6—Fe3119.47 (11)Fe13xii—Fe14—Fe1263.58 (9)
Fe5—Fe6—Fe361.48 (9)Fe13xi—Fe14—Fe1261.60 (9)
Fe5—Fe6—Fe4124.01 (10)Fe14xii—Fe14—Fe5xiv121.22 (7)
Fe5—Fe6—Fe4x119.80 (10)Fe14xi—Fe14—Fe5xiv90.56 (7)
Fe7iii—Fe6—Fe390.85 (11)Fe14xi—Fe14—Fe6xiv107.32 (10)
Fe7iii—Fe6—Fe4x61.29 (8)Fe14xii—Fe14—Fe6xiv140.39 (12)
Fe7iii—Fe6—Fe464.42 (9)Fe14xi—Fe14—Fe8xiv152.18 (10)
Fe7iii—Fe6—Fe5149.71 (14)Fe14xii—Fe14—Fe8xiv86.39 (8)
Fe8x—Fe6—Fe392.22 (9)Fe14xi—Fe14—Fe10xiv58.18 (8)
Fe8—Fe6—Fe362.26 (8)Fe14xi—Fe14—Fe10xv113.39 (9)
Fe8—Fe6—Fe459.02 (8)Fe14xii—Fe14—Fe10xv59.77 (7)
Fe8—Fe6—Fe4x175.22 (12)Fe14xii—Fe14—Fe10xiv89.85 (10)
Fe8x—Fe6—Fe4173.47 (11)Fe14xi—Fe14—Fe1288.70 (8)
Fe8x—Fe6—Fe4x57.28 (8)Fe14xii—Fe14—Fe1290.53 (8)
Fe8—Fe6—Fe564.98 (8)Fe14xi—Fe14—Fe13xi56.39 (6)
Fe8x—Fe6—Fe562.52 (8)Fe14xi—Fe14—Fe1360.74 (11)
Fe8x—Fe6—Fe7iii110.20 (10)Fe14xi—Fe14—Fe13xii148.23 (9)
Fe8—Fe6—Fe7iii114.85 (10)Fe14xii—Fe14—Fe13xii56.50 (6)
Fe11vii—Fe6—Fe3147.89 (14)Fe14xii—Fe14—Fe1360.98 (11)
Fe11vii—Fe6—Fe464.55 (8)Fe14xii—Fe14—Fe13xi148.28 (9)
Fe11vii—Fe6—Fe4x60.95 (7)C6—Fe14—C5xii130.2 (11)
Fe11vii—Fe6—Fe5149.55 (15)C6—Fe14—C5121.3 (11)
Fe11vii—Fe6—Fe7iii60.22 (10)C8xi—Fe14—C7xii103.5 (11)
Fe11vii—Fe6—Fe8x109.88 (9)C8—Fe14—C7xii127.6 (11)
Fe11vii—Fe6—Fe8115.01 (10)Fe3—C1—Fe176.0 (5)
Fe13xiii—Fe6—Fe3150.22 (12)Fe4—C1—Fe1143.8 (7)
Fe13xiii—Fe6—Fe4x58.38 (9)Fe4—C1—Fe3136.1 (7)
Fe13xiii—Fe6—Fe4116.56 (12)Fe6—C1—Fe1128.1 (7)
Fe13xiii—Fe6—Fe592.78 (11)Fe6—C1—Fe379.9 (5)
Fe13xiii—Fe6—Fe7iii109.43 (11)Fe6—C1—Fe481.6 (5)
Fe13xiii—Fe6—Fe8122.71 (12)Fe7—C1—Fe172.8 (4)
Fe13xiii—Fe6—Fe8x60.81 (9)Fe7iii—C1—Fe181.8 (5)
Fe13xiii—Fe6—Fe11vii60.68 (9)Fe7—C1—Fe3142.1 (6)
Fe14vii—Fe6—Fe3111.80 (11)Fe7iii—C1—Fe3127.1 (7)
Fe14vii—Fe6—Fe4x119.49 (12)Fe7—C1—Fe471.0 (4)
Fe14vii—Fe6—Fe491.15 (11)Fe7iii—C1—Fe486.3 (5)
Fe14vii—Fe6—Fe561.47 (10)Fe7—C1—Fe6137.0 (6)
Fe14vii—Fe6—Fe7iii147.62 (13)Fe7iii—C1—Fe677.3 (5)
Fe14vii—Fe6—Fe861.92 (9)Fe8—C1—Fe1139.6 (6)
Fe14vii—Fe6—Fe8x92.38 (11)Fe8—C1—Fe369.5 (4)
Fe14vii—Fe6—Fe11vii90.87 (12)Fe8—C1—Fe466.6 (4)
Fe14vii—Fe6—Fe13xiii61.12 (10)Fe8—C1—Fe665.7 (4)
C1—Fe6—Fe350.9 (4)Fe8—C1—Fe7iii136.3 (6)
C1—Fe6—Fe448.4 (4)Fe8—C1—Fe7126.4 (6)
C1—Fe6—Fe4x110.0 (4)Fe3ii—C2—Fe183.2 (5)
C1—Fe6—Fe5109.2 (4)Fe4iii—C2—Fe184.8 (5)
C1—Fe6—Fe7iii51.6 (4)Fe4iii—C2—Fe3ii138.9 (8)
C1—Fe6—Fe8x131.9 (4)Fe7iii—C2—Fe173.1 (4)
C1—Fe6—Fe867.2 (4)Fe7x—C2—Fe1139.8 (8)
C1—Fe6—Fe11vii97.4 (4)Fe7x—C2—Fe3ii127.9 (7)
C1—Fe6—Fe13xiii157.9 (4)Fe7iii—C2—Fe3ii142.3 (6)
C1—Fe6—Fe14vii127.0 (4)Fe7iii—C2—Fe4iii68.4 (4)
C3—Fe6—Fe345.1 (3)Fe7x—C2—Fe4iii84.2 (5)
C3—Fe6—Fe4136.6 (3)Fe9i—C2—Fe172.7 (4)
C3—Fe6—Fe4x89.5 (3)Fe9i—C2—Fe3ii70.8 (4)
C3—Fe6—Fe546.2 (3)Fe9i—C2—Fe4iii68.0 (4)
C3—Fe6—Fe7iii105.9 (3)Fe9i—C2—Fe7x136.1 (6)
C3—Fe6—Fe8x47.1 (3)Fe9i—C2—Fe7iii126.0 (5)
C3—Fe6—Fe894.4 (3)Fe11ii—C2—Fe1138.8 (8)
C3—Fe6—Fe11vii150.4 (3)Fe11ii—C2—Fe3ii79.9 (5)
C3—Fe6—Fe13xiii106.6 (3)Fe11ii—C2—Fe4iii83.8 (5)
C3—Fe6—Fe14vii106.4 (3)Fe11ii—C2—Fe7iii136.4 (6)
C3—Fe6—C191.2 (5)Fe11ii—C2—Fe7x77.8 (5)
C6vii—Fe6—C5vii76.3 (8)Fe11ii—C2—Fe9i66.3 (4)
Fe4—Fe7—Fe1iii61.84 (8)Fe3—C3—Fe1ii86.0 (5)
Fe4vi—Fe7—Fe1iii119.99 (10)Fe5—C3—Fe1ii143.4 (7)
Fe4—Fe7—Fe195.91 (10)Fe5—C3—Fe383.0 (5)
Fe4iii—Fe7—Fe1iii89.55 (8)Fe6—C3—Fe1ii140.2 (6)
Fe4iii—Fe7—Fe159.72 (8)Fe6—C3—Fe369.7 (4)
Fe4vi—Fe7—Fe1115.32 (10)Fe6—C3—Fe566.2 (4)
Fe6iii—Fe7—Fe1iii88.99 (10)Fe8x—C3—Fe1ii128.2 (7)
Fe6iii—Fe7—Fe1108.22 (11)Fe8x—C3—Fe3135.8 (7)
Fe6iii—Fe7—Fe4iii59.13 (8)Fe8x—C3—Fe581.5 (5)
Fe6iii—Fe7—Fe4vi62.85 (9)Fe8x—C3—Fe666.2 (4)
Fe6iii—Fe7—Fe4149.64 (13)Fe9—C3—Fe1ii82.4 (5)
Fe7iii—Fe7—Fe1iii60.77 (10)Fe9—C3—Fe3142.7 (7)
Fe7vi—Fe7—Fe1124.39 (14)Fe9—C3—Fe585.6 (5)
Fe7iii—Fe7—Fe163.06 (10)Fe9—C3—Fe6135.5 (6)
Fe7vi—Fe7—Fe1iii93.52 (13)Fe9—C3—Fe8x76.6 (4)
Fe7iii—Fe7—Fe4vi170.31 (18)Fe11—C3—Fe1ii73.1 (4)
Fe7iii—Fe7—Fe466.53 (12)Fe11—C3—Fe373.9 (4)
Fe7vi—Fe7—Fe464.78 (12)Fe11—C3—Fe570.3 (4)
Fe7iii—Fe7—Fe4iii57.44 (10)Fe11—C3—Fe6125.5 (6)
Fe7vi—Fe7—Fe4iii170.96 (17)Fe11—C3—Fe8x136.3 (6)
Fe7vi—Fe7—Fe4vi58.11 (10)Fe11—C3—Fe968.8 (4)
Fe7vi—Fe7—Fe6iii112.38 (14)Fe9v—C4—Fe584.0 (9)
Fe7iii—Fe7—Fe6iii108.02 (13)Fe10—C4—Fe569.5 (6)
Fe11i—Fe7—Fe1iii145.51 (12)Fe10xi—C4—Fe584.3 (9)
Fe11i—Fe7—Fe160.89 (8)Fe10xi—C4—Fe9v77.3 (7)
Fe11i—Fe7—Fe4vi61.43 (8)Fe10—C4—Fe9v137.2 (11)
Fe11i—Fe7—Fe4iii62.56 (8)Fe11—C4—Fe568.1 (5)
Fe11i—Fe7—Fe4150.34 (13)Fe11—C4—Fe9v66.6 (5)
Fe11i—Fe7—Fe6iii60.02 (10)Fe11—C4—Fe10xi136.0 (11)
C1—Fe7—Fe148.1 (3)Fe11—C4—Fe10126.7 (6)
C1iii—Fe7—Fe1iii49.0 (4)Fe12—C4—Fe585.3 (6)
C1—Fe7—Fe1iii93.0 (3)Fe12xi—C4—Fe5141.1 (10)
C1iii—Fe7—Fe1102.4 (4)Fe12—C4—Fe9v139.4 (9)
C1—Fe7—Fe447.8 (3)Fe12xi—C4—Fe9v126.2 (7)
C1iii—Fe7—Fe4iii45.9 (4)Fe12xi—C4—Fe10xi80.2 (6)
C1iii—Fe7—Fe4vi111.0 (4)Fe12—C4—Fe1072.9 (5)
C1iii—Fe7—Fe4106.7 (4)Fe12—C4—Fe10xi140.2 (10)
C1—Fe7—Fe4vi137.1 (3)Fe12xi—C4—Fe1071.7 (6)
C1—Fe7—Fe4iii92.0 (4)Fe12—C4—Fe1173.0 (5)
C1—Fe7—Fe6iii151.1 (4)Fe12xi—C4—Fe11141.8 (11)
C1iii—Fe7—Fe6iii51.1 (4)Fe13xi—C4—Fe5138.4 (9)
C1—Fe7—Fe11i107.0 (3)Fe13xi—C4—Fe9v79.8 (6)
C1iii—Fe7—Fe11i96.9 (4)Fe13xi—C4—Fe10141.5 (11)
C2iii—Fe7—Fe1142.8 (3)Fe13xi—C4—Fe10xi128.0 (7)
C2v—Fe7—Fe1iii158.1 (4)Fe13xi—C4—Fe1170.4 (5)
C2iii—Fe7—Fe1iii45.2 (3)Fe13xi—C4—Fe12xi76.8 (8)
C2v—Fe7—Fe174.4 (4)Fe13xi—C4—Fe1282.7 (8)
C2iii—Fe7—Fe4iii134.5 (3)Fe6xiv—C5—Fe5xiv67.1 (5)
C2v—Fe7—Fe4vi47.1 (4)Fe8iv—C5—Fe5xiv81.9 (8)
C2v—Fe7—Fe4107.6 (4)Fe8iv—C5—Fe6xiv67.0 (5)
C2iii—Fe7—Fe446.9 (3)Fe10xiv—C5—Fe5xiv69.5 (5)
C2v—Fe7—Fe4iii111.6 (4)Fe10xvi—C5—Fe5xiv85.7 (9)
C2iii—Fe7—Fe4vi91.4 (3)Fe10xiv—C5—Fe6xiv126.2 (7)
C2iii—Fe7—Fe6iii106.9 (3)Fe10xvi—C5—Fe6xiv136.4 (10)
C2v—Fe7—Fe6iii96.7 (4)Fe10xvi—C5—Fe8iv76.3 (8)
C2v—Fe7—Fe11i51.1 (4)Fe10xiv—C5—Fe8iv134.6 (11)
C2iii—Fe7—Fe11i152.7 (3)Fe13xi—C5—Fe5xiv137.6 (9)
C2v—Fe7—C1iii145.8 (6)Fe13xi—C5—Fe6xiv70.6 (5)
C2v—Fe7—C192.1 (5)Fe13xi—C5—Fe8iv80.6 (6)
C2iii—Fe7—C194.7 (5)Fe13xi—C5—Fe10xvi126.4 (8)
C2iii—Fe7—C1iii90.3 (5)Fe13xi—C5—Fe10xiv143.4 (11)
Fe4—Fe8—Fe392.72 (10)Fe14—C5—Fe5xiv83.5 (6)
Fe5—Fe8—Fe358.78 (8)Fe14xi—C5—Fe5xiv141.3 (9)
Fe5v—Fe8—Fe3116.72 (11)Fe14xi—C5—Fe6xiv141.0 (11)
Fe5—Fe8—Fe4119.93 (10)Fe14—C5—Fe6xiv70.4 (6)
Fe5v—Fe8—Fe4123.59 (10)Fe14—C5—Fe8iv137.3 (9)
Fe6v—Fe8—Fe3122.47 (11)Fe14xi—C5—Fe8iv128.7 (8)
Fe6—Fe8—Fe360.99 (8)Fe14—C5—Fe10xvi141.9 (9)
Fe6v—Fe8—Fe465.14 (8)Fe14xi—C5—Fe10xvi80.8 (6)
Fe6—Fe8—Fe462.36 (8)Fe14—C5—Fe10xiv74.7 (6)
Fe6—Fe8—Fe5v174.05 (11)Fe14xi—C5—Fe10xiv71.8 (5)
Fe6v—Fe8—Fe5v58.45 (8)Fe14xi—C5—Fe13xi77.2 (7)
Fe6v—Fe8—Fe5174.93 (11)Fe14—C5—Fe13xi83.9 (9)
Fe6—Fe8—Fe557.57 (9)Fe9—C6—Fe6xiv105.8 (10)
Fe9v—Fe8—Fe361.40 (8)Fe11—C6—Fe6xiv59.9 (6)
Fe9v—Fe8—Fe4150.00 (13)Fe11—C6—Fe957.5 (5)
Fe9v—Fe8—Fe5v64.21 (8)Fe12—C6—Fe6xiv123.3 (13)
Fe9v—Fe8—Fe561.47 (8)Fe12—C6—Fe972.3 (7)
Fe9v—Fe8—Fe6v114.27 (9)Fe12—C6—Fe1175.2 (9)
Fe9v—Fe8—Fe6110.75 (10)Fe13xii—C6—Fe6xiv122.0 (11)
Fe10xi—Fe8—Fe3110.25 (10)Fe13xii—C6—Fe972.1 (7)
Fe10xi—Fe8—Fe4149.20 (13)Fe13xii—C6—Fe11124.8 (12)
Fe10xi—Fe8—Fe5v64.48 (9)Fe13xii—C6—Fe12111.3 (11)
Fe10xi—Fe8—Fe561.64 (8)Fe14—C6—Fe6xiv76.1 (7)
Fe10xi—Fe8—Fe6v114.22 (10)Fe14—C6—Fe9177.3 (14)
Fe10xi—Fe8—Fe6110.60 (10)Fe14—C6—Fe11122.7 (12)
Fe10xi—Fe8—Fe9v60.44 (10)Fe14—C6—Fe12105.1 (15)
Fe13ix—Fe8—Fe3150.21 (11)Fe14—C6—Fe13xii108.7 (14)
Fe13ix—Fe8—Fe461.19 (9)Fe6xvi—C7—Fe4xvi80.5 (7)
Fe13ix—Fe8—Fe5119.80 (11)Fe8xvi—C7—Fe4xvi65.7 (5)
Fe13ix—Fe8—Fe5v91.13 (10)Fe8xvi—C7—Fe6xvi64.4 (5)
Fe13ix—Fe8—Fe6v61.96 (9)Fe9xi—C7—Fe4xvi72.2 (7)
Fe13ix—Fe8—Fe692.29 (10)Fe9xi—C7—Fe6xvi137.6 (11)
Fe13ix—Fe8—Fe9v147.46 (12)Fe9xi—C7—Fe8xvi126.9 (8)
Fe13ix—Fe8—Fe10xi90.55 (10)Fe11xi—C7—Fe4xvi86.9 (9)
Fe14vii—Fe8—Fe3110.07 (10)Fe11xi—C7—Fe6xvi76.8 (7)
Fe14vii—Fe8—Fe492.50 (10)Fe11xi—C7—Fe8xvi135.0 (9)
Fe14vii—Fe8—Fe558.85 (9)Fe11xi—C7—Fe9xi70.0 (7)
Fe14vii—Fe8—Fe5v116.86 (12)Fe12xi—C7—Fe4xvi146.3 (11)
Fe14vii—Fe8—Fe6v122.56 (11)Fe12xi—C7—Fe6xvi127.5 (9)
Fe14vii—Fe8—Fe660.99 (9)Fe12xi—C7—Fe8xvi138.8 (11)
Fe14vii—Fe8—Fe9v109.85 (11)Fe12xi—C7—Fe9xi74.1 (6)
Fe14vii—Fe8—Fe10xi60.97 (9)Fe12xi—C7—Fe11xi83.0 (7)
Fe14vii—Fe8—Fe13ix60.96 (9)Fe13—C7—Fe4xvi83.2 (7)
C1—Fe8—Fe346.9 (3)Fe13—C7—Fe6xvi133.2 (10)
C1—Fe8—Fe445.8 (3)Fe13—C7—Fe8xvi68.9 (6)
C1—Fe8—Fe589.9 (3)Fe13—C7—Fe9xi75.5 (6)
C1—Fe8—Fe5v136.2 (3)Fe13—C7—Fe11xi145.5 (11)
C1—Fe8—Fe6v94.1 (3)Fe13—C7—Fe12xi87.1 (8)
C1—Fe8—Fe647.1 (3)Fe14xi—C7—Fe4xvi133.6 (10)
C1—Fe8—Fe9v106.7 (3)Fe14xi—C7—Fe6xvi78.2 (7)
C1—Fe8—Fe10xi151.5 (3)Fe14xi—C7—Fe8xvi67.9 (6)
C1—Fe8—Fe13ix105.8 (3)Fe14xi—C7—Fe9xi143.5 (10)
C1—Fe8—Fe14vii106.6 (3)Fe14xi—C7—Fe11xi126.6 (9)
C3v—Fe8—Fe372.8 (4)Fe14xi—C7—Fe12xi76.3 (7)
C3v—Fe8—Fe4108.6 (4)Fe14xi—C7—Fe1382.1 (9)
C3v—Fe8—Fe5110.2 (4)Fe8xvi—C8—Fe5xv61.3 (7)
C3v—Fe8—Fe5v48.6 (4)Fe13—C8—Fe5xv125.1 (16)
C3v—Fe8—Fe6131.5 (4)Fe13—C8—Fe8xvi74.6 (11)
C3v—Fe8—Fe6v66.7 (4)Fe14xii—C8—Fe5xv73.1 (9)
C3v—Fe8—Fe9v51.8 (4)Fe14—C8—Fe5xv126.2 (14)
C3v—Fe8—Fe10xi97.9 (4)Fe14xii—C8—Fe8xvi123.9 (15)
C3v—Fe8—Fe13ix126.7 (4)Fe14—C8—Fe8xvi120.4 (13)
C3v—Fe8—Fe14vii158.7 (4)Fe14xii—C8—Fe13111.8 (16)
C3v—Fe8—C190.8 (5)Fe14—C8—Fe13103.3 (15)
C8ix—Fe8—C7ix77.2 (7)Fe12—C9—Fe9xi119.4 (14)
Fe3x—Fe9—Fe1ii60.30 (8)Fe12xii—C9—Fe9xi124.5 (12)
Fe4xiv—Fe9—Fe1ii61.58 (9)Fe13—C9—Fe9xi75.1 (9)
Fe4xiv—Fe9—Fe3x93.51 (10)Fe13—C9—Fe12107.3 (15)
Fe5x—Fe9—Fe1ii119.63 (12)Fe13—C9—Fe12xii112.1 (15)
Symmetry codes: (i) x1/2, y+3/2, z+1; (ii) x+1/2, y+3/2, z+1; (iii) x+1, y+2, z+1; (iv) x+1/2, y1/2, z; (v) x1, y, z; (vi) x, y+2, z+1; (vii) x+3/2, y+1/2, z; (viii) x+1/2, y+1/2, z; (ix) x+1, y+1/2, z+1/2; (x) x+1, y, z; (xi) x1/2, y, z+1/2; (xii) x+1/2, y, z+1/2; (xiii) x+2, y+1/2, z+1/2; (xiv) x+3/2, y1/2, z; (xv) x+2, y1/2, z+1/2; (xvi) x+1, y1/2, z+1/2.
 

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