Macrocyclic Thioether Complexes of Palladium with Dibromoiodide Anions

Blake, A.J.; Gilby, L.M.; Gould, R.O.; Lippolis, V.; Parsons, S.; Schröder, M.

doi:10.1107/S0108270197014212

Macrocyclic Thioether Complexes of Palladium with Dibromoiodide Anions

A. J. Blake, L. M. Gilby, R. O. Gould, V. Lippolis, S. Parsons and M. Schröder

The structure of bis(1,4,7-trithiacyclononane)palladium(II) bis(dibromoiodide), [Pd(C₆H₁₂S₃)₂](IBr₂)₂ comprises ribbons in which neighbouring cations are linked by pairs of anions through S

Br contacts of 3.767 (5)–3.877 (5) Å. In (1,4,8,11-tetrathiacyclotetradecane)palladium(II) bis(dibromoiodide), [Pd(C₁₀H₂₀S₄)₂](IBr₂)₂, Pd

I, S

Br and S

I contacts link cations and anions into an infinite three-dimensional network.

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Macrocyclic Thioether Complexes of Palladium with Dibromoiodide Anions

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	Crystallographic Information File (CIF) Contains datablocks 1, 2, global
	Structure factor file (CIF format) Contains datablock 1
	Structure factor file (CIF format) Contains datablock 2