Synthesis and characterization of self-assembled inorganic–organic hybrid arsenotungstates

A series of 12 inorganic–organic hybrid 4f-substituted arsenotungstates de­corated with 3d-based complexes along with acetate bridging, viz. {[Cu₂(H₂O)(1,10-phen)₂(μ-CH₃COO)₂]₄[Ln₂(H₂O)₂(μ-CH₃COO)₂(α-AsW₁₁O₃₉)₂]}²⁻ (Ln^III = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu), have been synthesized. These compounds were isolated using a one-pot synthetic strategy with copper, lanthanoid, trilacunary arsenotungstate and 1,10-phenanthroline as precursors. They were characterized using various analytical techniques, such as single-crystal X-ray diffraction (SC-XRD), powder XRD (PXRD), Fourier transform IR (FT–IR) spectroscopy, UV–Vis spectroscopy and thermogravimetric analysis (TGA). In all these compounds, a dinuclear Ln₂(ac)₂ moiety is sandwiched between two monolacunary [AsW₁₁O₃₉]⁷⁻ polyoxometalates (POMs), where the Ln₂(ac)₂ moiety is comprised of two acetate ligands in a μ-κO,O′:κO fashion. Moreover, the anion is decorated by a copper–phenanthroline–acetate complex through a terminal O atom of the polyanion.

Computing details

For all structures, data collection: CrysAlis PRO (Agilent, 2013); cell refinement: CrysAlis PRO (Agilent, 2013); data reduction: CrysAlis PRO (Agilent, 2013). Program(s) used to solve structure: SHELXT2014 (Sheldrick, 2015a) for fhsp17b; SHELXS (Sheldrick, 2008) for fhsp24d; SIR2004 (Burla et al., 2005) for fhsp25c. Program(s) used to refine structure: SHELXL (Sheldrick, 2015b) for fhsp17b; SHELXL2017 (Sheldrick, 2015) for fhsp21c, fhsp22a, fhsp23d, fhsp24d, fhsp25c. For all structures, molecular graphics: OLEX2 (Dolomanov et al., 2009); software used to prepare material for publication: OLEX2 (Dolomanov et al., 2009).

(fhsp17b)

Crystal data

C116H90.67As2Cu8Eu2K2N16O110W22·7.5(O)	F(000) = 15715
Mr = 8673.69	Dx = 2.860 Mg m^−3
Monoclinic, I2/a	Mo Kα radiation, λ = 0.71073 Å
a = 30.5449 (13) Å	Cell parameters from 11692 reflections
b = 14.2507 (5) Å	θ = 3.2–28.2°
c = 48.6187 (17) Å	µ = 14.43 mm^−1
β = 107.836 (4)°	T = 293 K
V = 20145.9 (14) Å^3	Block, blue
Z = 4	0.09 × 0.07 × 0.01 mm

Data collection

Agilent Xcalibur Sapphire3 diffractometer	18907 independent reflections
Radiation source: fine-focus sealed X-ray tube, Enhance (Mo) X-ray Source	12701 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.109
Detector resolution: 15.9853 pixels mm^-1	θmax = 25.7°, θmin = 2.8°
ω scans	h = −29→37
Absorption correction: multi-scan (CrysAlis PRO; Agilent, 2013)	k = −17→17
Tmin = 0.079, Tmax = 1.000	l = −59→59
83314 measured reflections

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.064	H-atom parameters constrained
wR(F^2) = 0.174	w = 1/[σ^2(Fo^2) + (0.0554P)^2 + 694.6223P] where P = (Fo^2 + 2Fc^2)/3
S = 1.06	(Δ/σ)max = 0.001
18907 reflections	Δρmax = 2.78 e Å^−3
995 parameters	Δρmin = −1.56 e Å^−3

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
C1	0.2125 (7)	−0.1049 (15)	0.3911 (5)	0.043 (6)
H1	0.234323	−0.095446	0.381601	0.052*
C2	0.2264 (10)	−0.119 (2)	0.4206 (6)	0.069 (8)*
H2	0.257613	−0.120681	0.430782	0.083*
C3	0.1951 (9)	−0.129 (2)	0.4347 (5)	0.070 (9)
H3	0.205141	−0.138746	0.454616	0.084*
C4	0.1494 (8)	−0.1257 (16)	0.4208 (5)	0.045 (6)
C5	0.1125 (10)	−0.1405 (18)	0.4327 (6)	0.062 (8)
H5	0.119890	−0.151202	0.452470	0.074*
C6	0.0684 (8)	−0.1399 (18)	0.4173 (6)	0.055 (7)
H6	0.045659	−0.146081	0.426308	0.066*
C7	0.0565 (7)	−0.1298 (14)	0.3869 (5)	0.040 (6)
C8	0.0110 (8)	−0.1338 (19)	0.3683 (6)	0.059 (7)
H8	−0.012914	−0.145483	0.375867	0.071*
C9	0.0017 (8)	−0.1211 (16)	0.3397 (6)	0.060 (8)
H9	−0.028394	−0.125271	0.327489	0.072*
C10	0.0394 (9)	−0.1008 (16)	0.3281 (6)	0.057 (7)
H10	0.033265	−0.088820	0.308482	0.068*
C11	0.0892 (7)	−0.1145 (17)	0.3733 (5)	0.047 (6)
C12	0.1363 (6)	−0.1135 (13)	0.3918 (4)	0.025 (4)*
C13	0.1658 (8)	−0.3367 (16)	0.3754 (5)	0.046 (6)
H13	0.193983	−0.324612	0.372520	0.055*
C14	0.1667 (10)	−0.362 (2)	0.4017 (6)	0.075 (9)
H14	0.194602	−0.366780	0.416390	0.090*
C15	0.1255 (12)	−0.3813 (17)	0.4074 (7)	0.071 (9)
H15	0.125064	−0.396228	0.425903	0.085*
C16	0.0845 (10)	−0.377 (2)	0.3840 (6)	0.063 (8)
C17	0.0385 (14)	−0.395 (2)	0.3863 (8)	0.095 (12)
H17	0.036031	−0.412597	0.404266	0.113*
C18	0.0010 (12)	−0.389 (3)	0.3648 (8)	0.096 (12)
H18	−0.027611	−0.399758	0.367133	0.116*
C19	0.0051 (10)	−0.3646 (19)	0.3383 (9)	0.078 (10)
C20	−0.0342 (12)	−0.356 (3)	0.3148 (9)	0.117 (16)
H20	−0.063196	−0.369755	0.316396	0.141*
C21	−0.0287 (10)	−0.329 (2)	0.2898 (10)	0.102 (14)
H21	−0.054254	−0.325080	0.273433	0.122*
C22	0.0159 (8)	−0.304 (2)	0.2874 (6)	0.071 (9)
H22	0.018147	−0.281483	0.269939	0.085*
C23	0.0483 (8)	−0.3394 (16)	0.3350 (6)	0.050 (7)
C24	0.0888 (9)	−0.3474 (15)	0.3584 (6)	0.053 (7)
C25	0.3997 (7)	0.6976 (14)	0.3724 (4)	0.031 (5)
H25	0.377103	0.705022	0.381448	0.038*
C26	0.3864 (7)	0.7052 (16)	0.3418 (4)	0.040 (6)
H26	0.356473	0.721443	0.331216	0.048*
C27	0.4194 (8)	0.6878 (17)	0.3282 (5)	0.050 (6)
H27	0.412408	0.688466	0.308191	0.060*
C28	0.4634 (8)	0.6691 (19)	0.3462 (4)	0.051 (7)
C29	0.5007 (9)	0.653 (2)	0.3333 (5)	0.074 (9)
H29	0.495093	0.651525	0.313379	0.089*
C30	0.5448 (11)	0.639 (2)	0.3524 (6)	0.074 (9)
H30	0.568764	0.630534	0.344617	0.089*
C31	0.5556 (8)	0.6379 (17)	0.3832 (6)	0.053 (7)
C32	0.5992 (8)	0.6215 (19)	0.4016 (5)	0.057 (7)
H32	0.623593	0.609662	0.394436	0.068*
C33	0.6056 (8)	0.6231 (19)	0.4308 (6)	0.064 (8)
H33	0.634932	0.617726	0.443915	0.077*
C34	0.5667 (7)	0.6331 (19)	0.4406 (5)	0.058 (7)
H34	0.570965	0.629098	0.460313	0.070*
C35	0.5187 (7)	0.6463 (16)	0.3944 (4)	0.037 (5)
C36	0.4729 (7)	0.6670 (14)	0.3752 (4)	0.031 (5)
C37	0.5840 (7)	0.8617 (17)	0.4749 (5)	0.049 (6)
H37	0.578454	0.860310	0.492655	0.059*
C38	0.6305 (8)	0.8531 (16)	0.4738 (5)	0.048 (6)
H38	0.654529	0.842619	0.490656	0.058*
C39	0.6387 (8)	0.860 (2)	0.4486 (6)	0.068 (9)
H39	0.668918	0.861931	0.448197	0.082*
C40	0.6013 (8)	0.8654 (16)	0.4219 (5)	0.048 (6)
C41	0.6059 (8)	0.8694 (19)	0.3944 (5)	0.058 (7)
H41	0.635032	0.865988	0.392273	0.069*
C42	0.5700 (10)	0.8779 (18)	0.3715 (5)	0.059 (7)
H42	0.573463	0.875317	0.353179	0.070*
C43	0.5242 (10)	0.8916 (14)	0.3747 (5)	0.050 (6)
C44	0.4849 (10)	0.9050 (18)	0.3514 (5)	0.062 (8)
H44	0.487106	0.905185	0.332792	0.074*
C45	0.4431 (9)	0.9178 (18)	0.3554 (6)	0.058 (7)
H45	0.416770	0.926455	0.339790	0.069*
C46	0.4410 (8)	0.9176 (18)	0.3841 (6)	0.057 (7)
H46	0.413334	0.930705	0.387646	0.068*
C47	0.5209 (8)	0.8869 (16)	0.4019 (4)	0.040 (6)
C48	0.5586 (8)	0.8764 (15)	0.4264 (4)	0.041 (6)
C49	0.0955 (10)	−0.125 (2)	0.2740 (6)	0.070 (8)
C50	0.0798 (16)	−0.087 (3)	0.2440 (8)	0.16 (2)
H50A	0.049302	−0.062286	0.239951	0.234*
H50B	0.079675	−0.136756	0.230522	0.234*
H50C	0.100339	−0.038484	0.242066	0.234*
C51	0.2098 (7)	−0.1935 (15)	0.3226 (4)	0.037 (5)
C52	0.2579 (6)	−0.2076 (13)	0.3208 (4)	0.029 (5)
H52A	0.281797	−0.207358	0.339348	0.035*
H52B	0.265797	−0.166954	0.307017	0.035*
C53	0.3935 (7)	0.7887 (17)	0.4365 (4)	0.041 (6)
C54	0.3427 (7)	0.8017 (16)	0.4336 (5)	0.047 (6)
H54A	0.324285	0.774972	0.415674	0.070*
H54B	0.336024	0.867455	0.433920	0.070*
H54C	0.335904	0.770951	0.449375	0.070*	0.3336
C55	0.4977 (6)	0.7223 (15)	0.4919 (4)	0.033 (5)
C56	0.5078 (9)	0.6911 (18)	0.5211 (5)	0.057 (7)
H56A	0.540306	0.680885	0.529146	0.085*
H56B	0.491728	0.633559	0.521590	0.085*
H56C	0.498186	0.737956	0.532235	0.085*
C57	0.2568 (7)	0.0861 (13)	0.2587 (4)	0.033 (5)
C58	0.2480 (8)	0.0170 (17)	0.2806 (5)	0.052 (6)*
H58A	0.215660	0.003671	0.275499	0.078*
H58B	0.258199	0.044095	0.299562	0.078*
H58C	0.264537	−0.040131	0.280389	0.078*
As1	0.29577 (6)	0.29836 (12)	0.37464 (3)	0.0139 (4)
Cu1	0.13921 (9)	−0.08465 (19)	0.33397 (6)	0.0385 (6)
Cu2	0.11937 (9)	−0.2862 (2)	0.31282 (6)	0.0430 (7)
Cu3	0.46600 (8)	0.66677 (18)	0.43171 (5)	0.0330 (6)
Cu4	0.48330 (9)	0.87012 (18)	0.44770 (6)	0.0367 (6)
Eu1	0.23033 (3)	0.29253 (7)	0.28554 (2)	0.0253 (2)
K1	0.22056 (19)	0.5687 (4)	0.29438 (11)	0.0190 (12)	0.6664
K2	0.3488 (4)	0.5658 (8)	0.4602 (3)	0.022 (3)	0.3336
N1	0.1690 (6)	−0.1051 (12)	0.3764 (4)	0.039 (4)
N2	0.0813 (5)	−0.0993 (15)	0.3450 (4)	0.048 (5)
N3	0.1281 (6)	−0.3269 (14)	0.3525 (4)	0.049 (5)
N4	0.0530 (6)	−0.3125 (13)	0.3092 (5)	0.052 (6)
N5	0.4411 (5)	0.6811 (11)	0.3883 (3)	0.033 (4)
N6	0.5254 (5)	0.6477 (12)	0.4234 (3)	0.033 (4)
N7	0.5496 (5)	0.8715 (12)	0.4512 (3)	0.035 (4)
N8	0.4785 (6)	0.8985 (13)	0.4061 (4)	0.042 (5)
O1	0.4448 (4)	0.5088 (9)	0.4237 (3)	0.033 (3)*
O2	0.4630 (4)	0.1563 (10)	0.4232 (3)	0.036 (3)*
O3	0.3876 (4)	0.3093 (10)	0.4869 (3)	0.036 (3)*
O4	0.4157 (4)	0.3261 (9)	0.4013 (3)	0.030 (3)*
O5	0.3825 (4)	0.2225 (9)	0.4342 (3)	0.027 (3)*
O6	0.3724 (4)	0.4012 (9)	0.4343 (3)	0.027 (3)*
O7	0.3935 (4)	0.4761 (9)	0.3667 (3)	0.026 (3)*
O8	0.3515 (4)	0.5521 (9)	0.4016 (3)	0.030 (3)*
O9	0.3012 (4)	0.3842 (9)	0.4554 (3)	0.032 (3)*
O10	0.3140 (4)	0.1972 (9)	0.4547 (3)	0.026 (3)*
O11	0.3779 (4)	0.0728 (9)	0.4000 (3)	0.030 (3)*
O12	0.4104 (4)	0.1820 (8)	0.3664 (2)	0.022 (3)*
O13	0.2124 (4)	0.4595 (10)	0.4419 (3)	0.036 (3)*
O14	0.2309 (4)	0.2741 (9)	0.4342 (3)	0.027 (3)*
O15	0.2368 (4)	0.0778 (9)	0.4415 (3)	0.033 (3)*
O16	0.2978 (4)	0.0899 (9)	0.4079 (3)	0.027 (3)*
O17	0.3129 (5)	−0.0656 (10)	0.3751 (3)	0.041 (4)*
O18	0.3397 (4)	0.0716 (9)	0.3429 (3)	0.032 (3)*
O19	0.3822 (4)	0.1587 (10)	0.3049 (3)	0.038 (3)*
O20	0.3673 (4)	0.3263 (9)	0.3332 (3)	0.027 (3)*
O21	0.3610 (4)	0.5022 (9)	0.3055 (3)	0.035 (3)*
O22	0.3101 (4)	0.5515 (9)	0.3437 (3)	0.027 (3)*
O23	0.2725 (4)	0.6612 (9)	0.3785 (3)	0.035 (3)*
O24	0.2736 (4)	0.4931 (9)	0.4089 (3)	0.028 (3)*
O25	0.3318 (4)	0.2140 (8)	0.3718 (3)	0.025 (3)*
O26	0.2902 (4)	0.2927 (8)	0.4080 (2)	0.021 (3)*
O27	0.3216 (4)	0.4001 (8)	0.3726 (2)	0.020 (3)*
O28	0.2456 (4)	0.2879 (8)	0.3490 (3)	0.024 (3)*
O29	0.2037 (4)	0.3829 (9)	0.3880 (3)	0.027 (3)*
O30	0.2167 (4)	0.1644 (9)	0.3872 (3)	0.028 (3)*
O31	0.2551 (4)	0.0894 (9)	0.3526 (3)	0.032 (3)*
O32	0.2978 (4)	0.2146 (9)	0.3089 (3)	0.030 (3)*
O33	0.2851 (4)	0.4033 (9)	0.3094 (3)	0.030 (3)*
O34	0.2331 (4)	0.4886 (9)	0.3533 (3)	0.028 (3)*
O35	0.1362 (4)	0.4591 (9)	0.3397 (3)	0.027 (3)*
O36	0.1569 (4)	0.0693 (9)	0.3398 (3)	0.028 (3)*
O37	0.1617 (4)	0.2665 (8)	0.3442 (3)	0.024 (3)*
O38	0.1963 (4)	0.1766 (8)	0.3070 (2)	0.024 (3)*
O39	0.1864 (4)	0.3862 (9)	0.3074 (3)	0.028 (3)*
O40	0.2366 (4)	0.1616 (9)	0.2540 (3)	0.026 (3)*
O41	0.2867 (4)	0.0660 (9)	0.2465 (3)	0.031 (3)*
O42	0.1524 (5)	0.2743 (11)	0.2517 (3)	0.052 (4)*
O43	0.1958 (5)	−0.1145 (11)	0.3253 (3)	0.048 (4)*
O44	0.1852 (5)	−0.2694 (11)	0.3184 (3)	0.048 (4)*
O45	0.1056 (5)	−0.0686 (12)	0.2939 (3)	0.051 (4)*
O46	0.1022 (6)	−0.2137 (14)	0.2771 (4)	0.071 (5)*
O47	0.1224 (5)	−0.4204 (12)	0.2904 (4)	0.060 (5)*
O48	0.4931 (5)	0.8045 (11)	0.4847 (3)	0.042 (4)*
O49	0.4948 (5)	0.6565 (10)	0.4725 (3)	0.042 (4)*
O50	0.4170 (5)	0.8597 (10)	0.4387 (3)	0.038 (3)*
O51	0.4086 (5)	0.7060 (10)	0.4373 (3)	0.037 (3)*
O52	0.4837 (6)	1.0087 (12)	0.4675 (4)	0.066 (5)*
O53	0.3073 (14)	0.492 (3)	0.5044 (9)	0.089 (13)*	0.5
O54	0.250000	0.236 (5)	0.500000	0.10 (2)*	0.5
O55	0.250000	0.019 (2)	0.500000	0.094 (9)*
O56	0.0435 (10)	0.104 (2)	0.2907 (7)	0.166 (12)*
O57	0.3316 (8)	0.7903 (18)	0.2540 (6)	0.118 (8)*
O58	0.3745 (10)	0.951 (2)	0.2843 (7)	0.164 (12)*
O59	0.3776 (6)	0.0267 (13)	0.4619 (4)	0.069 (5)*
O60	0.2937 (7)	0.6423 (16)	0.2754 (5)	0.099 (7)*
O61	0.4369 (11)	0.512 (2)	0.4934 (7)	0.062 (9)*	0.5
W1	0.39564 (3)	0.45092 (6)	0.40415 (2)	0.02495 (19)
W2	0.40896 (3)	0.19175 (6)	0.40397 (2)	0.02400 (18)
W3	0.35069 (3)	0.30329 (6)	0.45261 (2)	0.02581 (19)
W4	0.24296 (3)	0.39665 (6)	0.42407 (2)	0.02463 (19)
W5	0.25797 (3)	0.16039 (6)	0.42352 (2)	0.02455 (19)
W6	0.31528 (3)	0.05367 (6)	0.37443 (2)	0.02456 (18)
W7	0.35590 (3)	0.19237 (6)	0.32997 (2)	0.02419 (19)
W8	0.34025 (3)	0.44673 (6)	0.33029 (2)	0.02453 (19)
W9	0.28828 (3)	0.54609 (6)	0.37677 (2)	0.02444 (18)
W10	0.18479 (2)	0.39378 (5)	0.34380 (2)	0.02241 (18)
W11	0.19731 (3)	0.15703 (5)	0.34336 (2)	0.02307 (18)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
C1	0.030 (13)	0.043 (14)	0.058 (15)	−0.008 (10)	0.016 (11)	−0.012 (12)
C3	0.051 (17)	0.13 (3)	0.024 (12)	0.010 (17)	0.008 (12)	−0.003 (15)
C4	0.049 (15)	0.039 (14)	0.048 (14)	0.016 (11)	0.019 (12)	0.005 (11)
C5	0.08 (2)	0.063 (18)	0.067 (18)	0.009 (15)	0.061 (17)	0.018 (14)
C6	0.037 (15)	0.068 (18)	0.073 (19)	−0.017 (13)	0.038 (14)	−0.001 (14)
C7	0.035 (13)	0.028 (12)	0.075 (17)	0.008 (9)	0.042 (13)	0.007 (11)
C8	0.022 (13)	0.08 (2)	0.08 (2)	−0.005 (12)	0.013 (13)	−0.013 (16)
C9	0.042 (15)	0.032 (14)	0.09 (2)	0.022 (11)	−0.009 (14)	0.015 (14)
C10	0.058 (17)	0.033 (14)	0.077 (19)	−0.016 (12)	0.016 (15)	−0.003 (13)
C11	0.033 (13)	0.059 (17)	0.050 (15)	0.009 (11)	0.017 (11)	0.020 (12)
C13	0.049 (15)	0.045 (15)	0.053 (15)	0.018 (11)	0.028 (13)	0.018 (12)
C14	0.08 (2)	0.09 (2)	0.051 (18)	0.009 (17)	0.002 (16)	0.018 (16)
C15	0.12 (3)	0.030 (15)	0.08 (2)	−0.009 (15)	0.05 (2)	0.016 (14)
C16	0.060 (19)	0.07 (2)	0.069 (19)	0.008 (15)	0.035 (17)	0.006 (16)
C17	0.14 (3)	0.06 (2)	0.11 (3)	0.01 (2)	0.08 (3)	0.03 (2)
C18	0.07 (2)	0.14 (4)	0.09 (3)	0.01 (2)	0.05 (2)	0.02 (3)
C19	0.06 (2)	0.034 (16)	0.14 (3)	−0.002 (14)	0.04 (2)	−0.015 (18)
C20	0.05 (2)	0.19 (5)	0.12 (3)	−0.02 (2)	0.03 (2)	−0.04 (3)
C21	0.04 (2)	0.05 (2)	0.17 (4)	0.005 (15)	−0.02 (2)	−0.04 (2)
C22	0.025 (14)	0.10 (2)	0.063 (18)	0.007 (14)	−0.017 (12)	−0.028 (17)
C23	0.041 (15)	0.038 (14)	0.09 (2)	−0.014 (11)	0.050 (15)	−0.023 (13)
C24	0.057 (17)	0.018 (12)	0.09 (2)	−0.017 (11)	0.028 (16)	−0.010 (12)
C25	0.033 (12)	0.029 (12)	0.033 (11)	0.004 (9)	0.012 (10)	0.000 (9)
C26	0.026 (12)	0.065 (16)	0.020 (10)	−0.024 (11)	−0.008 (9)	0.001 (10)
C27	0.044 (15)	0.066 (18)	0.044 (14)	0.001 (12)	0.020 (12)	−0.006 (12)
C28	0.039 (14)	0.09 (2)	0.023 (11)	−0.011 (13)	0.007 (10)	−0.020 (12)
C29	0.053 (17)	0.13 (3)	0.031 (14)	−0.003 (17)	0.000 (13)	−0.003 (16)
C30	0.09 (2)	0.09 (2)	0.060 (19)	0.001 (18)	0.049 (18)	−0.021 (17)
C31	0.037 (14)	0.050 (16)	0.078 (19)	−0.015 (11)	0.027 (14)	−0.025 (14)
C32	0.030 (13)	0.09 (2)	0.051 (16)	0.008 (13)	0.013 (12)	−0.012 (14)
C33	0.037 (15)	0.08 (2)	0.066 (18)	0.021 (13)	−0.001 (13)	−0.010 (15)
C34	0.026 (13)	0.09 (2)	0.048 (15)	0.005 (13)	−0.002 (11)	−0.009 (14)
C35	0.034 (12)	0.058 (15)	0.016 (10)	−0.001 (10)	0.007 (9)	−0.004 (10)
C36	0.028 (11)	0.038 (13)	0.024 (10)	0.001 (9)	0.005 (9)	0.001 (9)
C37	0.039 (14)	0.065 (18)	0.037 (13)	−0.006 (12)	0.003 (11)	−0.019 (12)
C38	0.035 (14)	0.049 (15)	0.061 (16)	−0.006 (11)	0.014 (12)	0.005 (13)
C39	0.022 (13)	0.12 (3)	0.076 (19)	0.011 (14)	0.032 (13)	0.041 (18)
C40	0.047 (15)	0.045 (15)	0.053 (15)	−0.003 (11)	0.019 (12)	0.025 (12)
C41	0.045 (15)	0.09 (2)	0.060 (17)	0.002 (14)	0.045 (14)	0.011 (15)
C42	0.08 (2)	0.068 (19)	0.026 (13)	−0.008 (15)	0.019 (13)	0.010 (12)
C43	0.09 (2)	0.010 (11)	0.048 (15)	−0.013 (12)	0.026 (15)	−0.009 (10)
C44	0.09 (2)	0.064 (19)	0.038 (14)	−0.030 (16)	0.023 (15)	0.008 (13)
C45	0.054 (17)	0.055 (17)	0.053 (17)	−0.004 (13)	0.000 (13)	0.019 (13)
C46	0.032 (14)	0.052 (17)	0.08 (2)	−0.008 (12)	0.015 (14)	−0.012 (15)
C47	0.054 (15)	0.052 (15)	0.028 (11)	0.002 (11)	0.035 (11)	−0.004 (10)
C48	0.060 (16)	0.040 (14)	0.022 (11)	0.006 (11)	0.009 (11)	0.002 (10)
C49	0.09 (2)	0.08 (2)	0.052 (17)	0.014 (17)	0.045 (17)	0.006 (16)
C50	0.28 (6)	0.08 (3)	0.08 (3)	0.05 (3)	0.02 (3)	−0.02 (2)
C51	0.048 (14)	0.033 (12)	0.037 (12)	0.007 (10)	0.022 (11)	0.022 (10)
C52	0.029 (11)	0.034 (12)	0.024 (10)	0.001 (9)	0.010 (9)	0.009 (9)
C53	0.034 (13)	0.062 (17)	0.030 (12)	−0.002 (11)	0.015 (10)	−0.007 (11)
C54	0.025 (12)	0.047 (15)	0.061 (16)	0.006 (10)	0.003 (11)	0.001 (12)
C55	0.019 (11)	0.046 (14)	0.040 (12)	0.007 (9)	0.019 (9)	0.006 (10)
C56	0.070 (18)	0.074 (19)	0.031 (13)	−0.021 (14)	0.021 (13)	−0.008 (12)
C57	0.050 (13)	0.017 (10)	0.036 (11)	−0.016 (9)	0.018 (10)	−0.013 (9)
As1	0.0167 (9)	0.0147 (9)	0.0102 (8)	0.0009 (7)	0.0042 (7)	0.0010 (7)
Cu1	0.0394 (16)	0.0404 (16)	0.0384 (15)	−0.0018 (12)	0.0157 (13)	−0.0024 (12)
Cu2	0.0353 (15)	0.0445 (18)	0.0515 (17)	−0.0022 (13)	0.0168 (13)	−0.0061 (14)
Cu3	0.0329 (14)	0.0396 (16)	0.0259 (13)	−0.0019 (11)	0.0080 (11)	−0.0044 (11)
Cu4	0.0348 (15)	0.0373 (16)	0.0385 (15)	−0.0028 (12)	0.0121 (12)	−0.0031 (12)
Eu1	0.0279 (5)	0.0287 (6)	0.0200 (5)	−0.0006 (4)	0.0081 (4)	−0.0004 (4)
K1	0.020 (3)	0.024 (3)	0.018 (3)	−0.008 (2)	0.014 (2)	−0.011 (2)
K2	0.031 (7)	0.015 (6)	0.032 (7)	0.011 (5)	0.026 (6)	0.015 (5)
N1	0.036 (11)	0.033 (11)	0.046 (11)	−0.002 (8)	0.008 (9)	0.007 (9)
N2	0.015 (9)	0.083 (16)	0.040 (11)	−0.010 (9)	−0.004 (8)	−0.010 (10)
N3	0.019 (10)	0.059 (14)	0.072 (14)	−0.004 (9)	0.019 (10)	−0.003 (11)
N4	0.035 (11)	0.036 (12)	0.094 (17)	−0.008 (9)	0.035 (12)	−0.035 (11)
N5	0.027 (10)	0.033 (10)	0.035 (10)	0.009 (8)	0.004 (8)	0.015 (8)
N6	0.020 (9)	0.049 (11)	0.027 (9)	−0.002 (8)	0.003 (7)	−0.007 (8)
N7	0.032 (10)	0.049 (12)	0.023 (9)	−0.010 (8)	0.006 (8)	0.001 (8)
N8	0.027 (10)	0.043 (12)	0.053 (12)	0.009 (8)	0.008 (9)	0.015 (9)
W1	0.0241 (4)	0.0295 (4)	0.0204 (4)	−0.0042 (3)	0.0055 (3)	−0.0028 (3)
W2	0.0216 (4)	0.0297 (4)	0.0201 (4)	0.0023 (3)	0.0055 (3)	−0.0003 (3)
W3	0.0284 (4)	0.0323 (5)	0.0167 (4)	0.0007 (3)	0.0069 (3)	−0.0008 (3)
W4	0.0271 (4)	0.0298 (5)	0.0187 (4)	0.0026 (3)	0.0095 (3)	−0.0019 (3)
W5	0.0268 (4)	0.0295 (5)	0.0189 (4)	0.0000 (3)	0.0092 (3)	0.0030 (3)
W6	0.0246 (4)	0.0259 (4)	0.0230 (4)	0.0017 (3)	0.0070 (3)	−0.0008 (3)
W7	0.0232 (4)	0.0322 (5)	0.0172 (4)	0.0019 (3)	0.0063 (3)	−0.0025 (3)
W8	0.0257 (4)	0.0289 (4)	0.0191 (4)	−0.0040 (3)	0.0071 (3)	0.0002 (3)
W9	0.0253 (4)	0.0254 (4)	0.0221 (4)	−0.0012 (3)	0.0065 (3)	−0.0018 (3)
W10	0.0224 (4)	0.0261 (4)	0.0196 (4)	0.0011 (3)	0.0078 (3)	−0.0004 (3)
W11	0.0238 (4)	0.0259 (4)	0.0203 (4)	−0.0029 (3)	0.0079 (3)	−0.0005 (3)

Geometric parameters (Å, º)

C1—C2	1.38 (3)	Cu4—N8	2.022 (18)
C1—N1	1.30 (2)	Cu4—O48	1.966 (15)
C2—C3	1.35 (3)	Cu4—O50	1.941 (14)
C3—C4	1.35 (3)	Cu4—O52	2.195 (18)
C4—C5	1.43 (3)	Eu1—O28	2.977 (12)
C4—C12	1.35 (3)	Eu1—O32	2.312 (13)
C5—C6	1.33 (3)	Eu1—O33	2.334 (13)
C6—C7	1.42 (3)	Eu1—O38	2.360 (11)
C7—C8	1.41 (3)	Eu1—O39	2.362 (12)
C7—C11	1.37 (3)	Eu1—O40	2.458 (12)
C8—C9	1.34 (3)	Eu1—O40^ii	2.518 (12)
C9—C10	1.46 (3)	Eu1—O41^ii	2.503 (13)
C10—N2	1.29 (3)	Eu1—O42	2.458 (16)
C11—C12	1.44 (3)	Eu1—W10	3.8020 (11)
C11—N2	1.34 (3)	Eu1—W11	3.7928 (12)
C12—N1	1.43 (2)	K1—O22	3.044 (13)
C13—C14	1.32 (3)	K1—O33	3.015 (14)
C13—N3	1.34 (3)	K1—O34	2.998 (13)
C14—C15	1.40 (4)	K1—O39	2.941 (14)
C15—C16	1.41 (4)	K1—O41^ii	2.723 (14)
C16—C17	1.47 (4)	K1—O44^iii	2.938 (16)
C16—C24	1.36 (3)	K1—O47^iii	2.949 (17)
C17—C18	1.30 (4)	K1—O57^iv	3.13 (3)
C18—C19	1.37 (4)	K1—O60	2.87 (2)
C19—C20	1.39 (5)	K1—W9	3.918 (6)
C19—C23	1.42 (3)	K1—W10	3.845 (5)
C20—C21	1.34 (5)	K2—O6	2.857 (16)
C21—C22	1.44 (4)	K2—O8	2.885 (16)
C22—N4	1.30 (3)	K2—O9	2.942 (17)
C23—C24	1.41 (3)	K2—O24	3.011 (18)
C23—N4	1.36 (3)	K2—O51	3.135 (17)
C24—N3	1.35 (3)	K2—O53	3.00 (4)
C25—C26	1.42 (3)	K2—O61	2.79 (4)
C25—N5	1.29 (2)	K2—W1	3.814 (11)
C26—C27	1.39 (3)	K2—W3	3.761 (11)
C27—C28	1.39 (3)	K2—W4	3.983 (12)
C28—C29	1.48 (3)	K2—W9	3.919 (12)
C28—C36	1.35 (3)	O1—W1	1.723 (13)
C29—C30	1.39 (4)	O2—W2	1.706 (13)
C30—C31	1.43 (3)	O3—W3	1.706 (13)
C31—C32	1.38 (3)	O4—W1	1.900 (13)
C31—C35	1.40 (3)	O4—W2	1.934 (13)
C32—C33	1.37 (3)	O5—W2	1.932 (12)
C33—C34	1.41 (3)	O5—W3	1.898 (12)
C34—N6	1.30 (2)	O6—W1	1.947 (12)
C35—C36	1.45 (3)	O6—W3	1.882 (12)
C35—N6	1.36 (2)	O7—W1	1.838 (12)
C36—N5	1.33 (2)	O7—W8	2.046 (12)
C37—C38	1.44 (3)	O8—W1	1.951 (12)
C37—N7	1.31 (2)	O8—W9	1.941 (12)
C38—C39	1.33 (3)	O9—W3	1.938 (12)
C39—C40	1.45 (3)	O9—W4	1.963 (13)
C40—C41	1.38 (3)	O10—W3	1.902 (12)
C40—C48	1.40 (3)	O10—W5	1.979 (12)
C41—C42	1.31 (3)	O11—W2	1.924 (13)
C42—C43	1.47 (3)	O11—W6	1.954 (12)
C43—C44	1.39 (3)	O12—W2	1.846 (11)
C43—C47	1.36 (3)	O12—W7	2.031 (11)
C44—C45	1.36 (3)	O13—W4	1.710 (13)
C45—C46	1.42 (3)	O14—W4	1.880 (12)
C46—N8	1.34 (3)	O14—W5	1.960 (12)
C47—C48	1.39 (3)	O15—W5	1.707 (13)
C47—N8	1.38 (2)	O16—W5	1.907 (12)
C48—N7	1.32 (2)	O16—W6	1.931 (12)
C49—C50	1.49 (4)	O17—W6	1.702 (15)
C49—O45	1.22 (3)	O18—W6	1.916 (12)
C49—O46	1.28 (3)	O18—W7	1.947 (13)
C51—C52	1.51 (3)	O19—W7	1.720 (13)
C51—O43	1.22 (2)	O20—W7	1.938 (12)
C51—O44	1.30 (2)	O20—W8	1.890 (12)
C52—K1^i	3.50 (2)	O21—W8	1.716 (13)
C53—C54	1.53 (3)	O22—W8	1.966 (12)
C53—O50	1.23 (2)	O22—W9	1.923 (11)
C53—O51	1.26 (3)	O23—W9	1.719 (13)
C55—C56	1.43 (3)	O24—W4	1.933 (12)
C55—O48	1.22 (2)	O24—W9	1.906 (12)
C55—O49	1.31 (2)	O25—W2	2.418 (12)
C57—C58	1.53 (3)	O25—W6	2.351 (12)
C57—Eu1^ii	2.88 (2)	O25—W7	2.386 (11)
C57—O40	1.23 (2)	O26—W3	2.384 (11)
C57—O41	1.27 (2)	O26—W4	2.362 (11)
As1—O25	1.664 (12)	O26—W5	2.356 (11)
As1—O26	1.684 (11)	O27—W1	2.421 (11)
As1—O27	1.669 (11)	O27—W8	2.389 (11)
As1—O28	1.659 (12)	O27—W9	2.352 (11)
Cu1—Cu2	3.049 (4)	O28—W10	2.346 (12)
Cu1—N1	2.006 (18)	O28—W11	2.341 (12)
Cu1—N2	2.012 (17)	O29—W4	1.807 (12)
Cu1—O36	2.257 (13)	O29—W10	2.054 (12)
Cu1—O43	1.947 (15)	O30—W5	1.828 (12)
Cu1—O45	1.919 (16)	O30—W11	2.035 (12)
Cu2—K1^i	4.041 (6)	O31—W6	1.890 (13)
Cu2—N3	1.95 (2)	O31—W11	1.938 (12)
Cu2—N4	2.017 (17)	O32—W7	1.783 (12)
Cu2—O44	1.960 (15)	O33—W8	1.790 (12)
Cu2—O46	1.948 (19)	O34—W9	1.906 (12)
Cu2—O47	2.217 (17)	O34—W10	1.950 (12)
Cu3—Cu4	3.005 (4)	O35—W10	1.710 (12)
Cu3—N5	2.024 (16)	O36—W11	1.728 (12)
Cu3—N6	1.996 (15)	O37—W10	1.949 (12)
Cu3—O1	2.341 (14)	O37—W11	1.909 (12)
Cu3—O49	1.914 (15)	O38—W11	1.778 (11)
Cu3—O51	1.936 (14)	O39—W10	1.791 (12)
Cu4—N7	1.978 (16)
N1—C1—C2	121 (2)	O61—K2—O9	99.9 (8)
C3—C2—C1	120 (3)	O61—K2—O24	137.9 (9)
C2—C3—C4	122 (2)	O61—K2—O51	79.4 (8)
C3—C4—C5	128 (2)	O61—K2—O53	92.0 (11)
C3—C4—C12	117 (2)	O61—K2—W1	77.8 (7)
C12—C4—C5	115 (2)	O61—K2—W3	75.1 (8)
C6—C5—C4	124 (2)	O61—K2—W4	126.8 (8)
C5—C6—C7	119 (2)	O61—K2—W9	130.2 (8)
C8—C7—C6	124 (2)	W1—K2—W4	81.8 (2)
C11—C7—C6	122 (2)	W1—K2—W9	52.46 (15)
C11—C7—C8	115 (2)	W3—K2—W1	58.84 (17)
C9—C8—C7	121 (2)	W3—K2—W4	52.39 (16)
C8—C9—C10	119 (2)	W3—K2—W9	81.0 (2)
N2—C10—C9	120 (2)	W9—K2—W4	55.84 (17)
C7—C11—C12	116 (2)	C1—N1—C12	118.4 (18)
N2—C11—C7	126 (2)	C1—N1—Cu1	129.0 (15)
N2—C11—C12	118.0 (18)	C12—N1—Cu1	112.4 (12)
C4—C12—C11	124.7 (18)	C10—N2—C11	119 (2)
C4—C12—N1	121.6 (18)	C10—N2—Cu1	127.7 (18)
N1—C12—C11	113.6 (16)	C11—N2—Cu1	113.3 (14)
C14—C13—N3	126 (2)	C13—N3—C24	113 (2)
C13—C14—C15	119 (3)	C13—N3—Cu2	132.4 (15)
C14—C15—C16	118 (3)	C24—N3—Cu2	114.2 (17)
C15—C16—C17	124 (3)	C22—N4—C23	118 (2)
C24—C16—C15	116 (3)	C22—N4—Cu2	131 (2)
C24—C16—C17	119 (3)	C23—N4—Cu2	111.1 (17)
C18—C17—C16	124 (3)	C25—N5—C36	118.0 (17)
C17—C18—C19	118 (3)	C25—N5—Cu3	129.2 (14)
C18—C19—C20	119 (3)	C36—N5—Cu3	112.8 (12)
C18—C19—C23	121 (3)	C34—N6—C35	118.3 (18)
C20—C19—C23	119 (4)	C34—N6—Cu3	130.9 (15)
C21—C20—C19	117 (4)	C35—N6—Cu3	110.8 (13)
C20—C21—C22	122 (3)	C37—N7—C48	118.3 (19)
N4—C22—C21	121 (3)	C37—N7—Cu4	126.9 (15)
C24—C23—C19	120 (3)	C48—N7—Cu4	114.6 (15)
N4—C23—C19	123 (3)	C46—N8—C47	121 (2)
N4—C23—C24	117 (2)	C46—N8—Cu4	128.5 (16)
C16—C24—C23	117 (2)	C47—N8—Cu4	109.9 (13)
N3—C24—C16	127 (3)	W1—O1—Cu3	134.6 (7)
N3—C24—C23	116 (2)	W1—O4—W2	151.4 (7)
N5—C25—C26	123.7 (19)	W3—O5—W2	152.9 (7)
C27—C26—C25	118.0 (19)	W1—O6—K2	103.5 (5)
C26—C27—C28	116 (2)	W3—O6—K2	103.1 (5)
C27—C28—C29	119 (2)	W3—O6—W1	152.7 (7)
C36—C28—C27	121 (2)	W1—O7—W8	126.5 (6)
C36—C28—C29	120 (2)	W1—O8—K2	102.4 (5)
C30—C29—C28	117 (2)	W9—O8—K2	107.0 (5)
C29—C30—C31	124 (2)	W9—O8—W1	123.0 (7)
C32—C31—C30	123 (2)	W3—O9—K2	98.7 (5)
C32—C31—C35	120 (2)	W3—O9—W4	122.8 (6)
C35—C31—C30	117 (2)	W4—O9—K2	106.9 (6)
C33—C32—C31	118 (2)	W3—O10—W5	123.7 (6)
C32—C33—C34	119 (2)	W2—O11—W6	122.9 (7)
N6—C34—C33	123 (2)	W2—O12—W7	126.5 (6)
C31—C35—C36	119.9 (19)	W4—O14—W5	124.5 (6)
N6—C35—C31	121 (2)	W5—O16—W6	148.3 (7)
N6—C35—C36	118.2 (17)	W6—O18—W7	125.1 (7)
C28—C36—C35	122.1 (18)	W8—O20—W7	145.6 (7)
N5—C36—C28	122.8 (19)	W8—O22—K1	101.5 (5)
N5—C36—C35	115.1 (16)	W9—O22—K1	101.8 (5)
N7—C37—C38	121 (2)	W9—O22—W8	124.3 (6)
C39—C38—C37	120 (2)	W4—O24—K2	105.2 (5)
C38—C39—C40	121 (2)	W9—O24—K2	103.4 (5)
C41—C40—C39	126 (2)	W9—O24—W4	149.1 (7)
C41—C40—C48	121 (2)	As1—O25—W2	125.4 (6)
C48—C40—C39	112 (2)	As1—O25—W6	122.7 (6)
C42—C41—C40	121 (2)	As1—O25—W7	123.3 (6)
C41—C42—C43	120 (2)	W6—O25—W2	91.2 (4)
C44—C43—C42	123 (2)	W6—O25—W7	92.8 (4)
C47—C43—C42	117 (2)	W7—O25—W2	92.3 (4)
C47—C43—C44	120 (2)	As1—O26—W3	126.5 (6)
C45—C44—C43	121 (2)	As1—O26—W4	122.8 (6)
C44—C45—C46	118 (2)	As1—O26—W5	121.4 (6)
N8—C46—C45	120 (2)	W4—O26—W3	92.4 (4)
C43—C47—C48	124 (2)	W5—O26—W3	92.4 (4)
C43—C47—N8	119 (2)	W5—O26—W4	92.2 (4)
N8—C47—C48	117.0 (18)	As1—O27—W1	126.1 (6)
C47—C48—C40	116.5 (19)	As1—O27—W8	122.3 (6)
N7—C48—C40	127 (2)	As1—O27—W9	122.5 (6)
N7—C48—C47	116 (2)	W8—O27—W1	92.3 (4)
O45—C49—C50	117 (3)	W9—O27—W1	91.5 (4)
O45—C49—O46	124 (3)	W9—O27—W8	93.0 (4)
O46—C49—C50	118 (3)	As1—O28—Eu1	126.3 (5)
O43—C51—C52	120.4 (19)	As1—O28—W10	122.8 (6)
O43—C51—O44	125 (2)	As1—O28—W11	124.3 (6)
O44—C51—C52	114.0 (18)	W10—O28—Eu1	90.3 (4)
C51—C52—K1^i	85.9 (12)	W11—O28—Eu1	90.2 (4)
O50—C53—C54	117 (2)	W11—O28—W10	92.9 (4)
O50—C53—O51	125 (2)	W4—O29—W10	153.8 (7)
O51—C53—C54	118 (2)	W5—O30—W11	154.5 (7)
O48—C55—C56	124 (2)	W6—O31—W11	157.5 (7)
O48—C55—O49	120.2 (19)	W7—O32—Eu1	161.4 (7)
O49—C55—C56	116 (2)	Eu1—O33—K1	95.3 (4)
C58—C57—Eu1^ii	176.0 (14)	W8—O33—Eu1	157.3 (7)
O40—C57—C58	120.6 (18)	W8—O33—K1	107.4 (5)
O40—C57—Eu1^ii	60.7 (10)	W9—O34—K1	103.8 (5)
O40—C57—O41	120.3 (18)	W9—O34—W10	155.0 (7)
O41—C57—C58	119.0 (18)	W10—O34—K1	99.8 (5)
O41—C57—Eu1^ii	60.1 (10)	W11—O36—Cu1	148.4 (7)
O25—As1—O26	108.0 (6)	W11—O37—W10	123.3 (6)
O25—As1—O27	106.6 (6)	W11—O38—Eu1	132.3 (6)
O27—As1—O26	106.8 (5)	Eu1—O39—K1	96.6 (4)
O28—As1—O25	110.8 (6)	W10—O39—Eu1	132.1 (6)
O28—As1—O26	112.1 (6)	W10—O39—K1	106.2 (5)
O28—As1—O27	112.2 (6)	C57—O40—Eu1^ii	94.2 (11)
N1—Cu1—Cu2	101.0 (5)	C57—O40—Eu1	132.9 (12)
N1—Cu1—N2	82.5 (7)	Eu1—O40—Eu1^ii	113.9 (5)
N1—Cu1—O36	89.8 (6)	C57—O41—Eu1^ii	93.9 (11)
N2—Cu1—Cu2	83.8 (6)	C57—O41—K1^ii	126.4 (11)
N2—Cu1—O36	105.3 (7)	Eu1^ii—O41—K1^ii	99.1 (4)
O36—Cu1—Cu2	166.8 (3)	C51—O43—Cu1	125.9 (14)
O43—Cu1—Cu2	79.6 (5)	C51—O44—Cu2	130.1 (14)
O43—Cu1—N1	92.2 (7)	C51—O44—K1^i	116.9 (13)
O43—Cu1—N2	161.2 (8)	Cu2—O44—K1^i	109.6 (6)
O43—Cu1—O36	92.6 (6)	C49—O45—Cu1	130.5 (19)
O45—Cu1—Cu2	77.3 (5)	C49—O46—Cu2	128.1 (18)
O45—Cu1—N1	174.8 (7)	Cu2—O47—K1^i	102.0 (6)
O45—Cu1—N2	92.5 (7)	C55—O48—Cu4	133.8 (14)
O45—Cu1—O36	92.5 (6)	C55—O49—Cu3	126.7 (14)
O45—Cu1—O43	92.3 (6)	C53—O50—Cu4	128.6 (15)
Cu1—Cu2—K1^i	118.07 (12)	C53—O51—Cu3	127.2 (14)
N3—Cu2—Cu1	89.6 (6)	C53—O51—K2	111.0 (12)
N3—Cu2—K1^i	100.6 (5)	Cu3—O51—K2	121.1 (6)
N3—Cu2—N4	82.0 (8)	O1—W1—K2	81.7 (5)
N3—Cu2—O44	94.3 (7)	O1—W1—O4	104.1 (6)
N3—Cu2—O47	102.5 (7)	O1—W1—O6	102.5 (5)
N4—Cu2—Cu1	107.2 (5)	O1—W1—O7	102.4 (6)
N4—Cu2—K1^i	134.7 (5)	O1—W1—O8	98.6 (6)
N4—Cu2—O47	89.4 (6)	O1—W1—O27	168.5 (5)
O44—Cu2—Cu1	75.4 (5)	O4—W1—K2	130.9 (4)
O44—Cu2—K1^i	43.2 (5)	O4—W1—O6	85.1 (5)
O44—Cu2—N4	175.3 (8)	O4—W1—O8	156.7 (5)
O44—Cu2—O47	88.8 (6)	O4—W1—O27	86.1 (5)
O46—Cu2—Cu1	76.8 (6)	O6—W1—K2	46.8 (4)
O46—Cu2—K1^i	95.1 (5)	O6—W1—O8	85.1 (5)
O46—Cu2—N3	162.8 (8)	O6—W1—O27	83.3 (4)
O46—Cu2—N4	91.9 (9)	O7—W1—K2	135.8 (4)
O46—Cu2—O44	92.5 (7)	O7—W1—O4	91.4 (5)
O46—Cu2—O47	93.4 (7)	O7—W1—O6	155.0 (5)
O47—Cu2—Cu1	160.8 (4)	O7—W1—O8	88.7 (5)
O47—Cu2—K1^i	45.5 (4)	O7—W1—O27	71.7 (4)
N5—Cu3—Cu4	98.8 (5)	O8—W1—K2	47.6 (4)
N5—Cu3—O1	85.8 (6)	O8—W1—O27	71.8 (5)
N6—Cu3—Cu4	94.9 (5)	O27—W1—K2	95.7 (3)
N6—Cu3—N5	82.9 (6)	O2—W2—O4	103.0 (6)
N6—Cu3—O1	93.3 (6)	O2—W2—O5	102.2 (6)
O1—Cu3—Cu4	171.1 (3)	O2—W2—O11	99.2 (6)
O49—Cu3—Cu4	79.5 (5)	O2—W2—O12	101.9 (6)
O49—Cu3—N5	174.9 (6)	O2—W2—O25	169.0 (5)
O49—Cu3—N6	92.5 (6)	O4—W2—O25	85.9 (5)
O49—Cu3—O1	96.6 (6)	O5—W2—O4	84.6 (5)
O49—Cu3—O51	91.5 (6)	O5—W2—O25	84.8 (5)
O51—Cu3—Cu4	77.3 (4)	O11—W2—O4	157.6 (5)
O51—Cu3—N5	92.8 (6)	O11—W2—O5	88.1 (5)
O51—Cu3—N6	170.5 (7)	O11—W2—O25	72.3 (5)
O51—Cu3—O1	94.9 (5)	O12—W2—O4	88.4 (5)
N7—Cu4—Cu3	97.2 (5)	O12—W2—O5	155.8 (5)
N7—Cu4—N8	80.9 (7)	O12—W2—O11	89.7 (5)
N7—Cu4—O52	94.8 (7)	O12—W2—O25	71.6 (4)
N8—Cu4—Cu3	88.9 (5)	O3—W3—K2	83.1 (5)
N8—Cu4—O52	104.3 (7)	O3—W3—O5	102.3 (6)
O48—Cu4—Cu3	75.1 (4)	O3—W3—O6	101.7 (6)
O48—Cu4—N7	93.5 (6)	O3—W3—O9	101.4 (6)
O48—Cu4—N8	162.4 (7)	O3—W3—O10	102.1 (6)
O48—Cu4—O52	92.8 (6)	O3—W3—O26	171.3 (5)
O50—Cu4—Cu3	77.3 (4)	O5—W3—K2	132.5 (4)
O50—Cu4—N7	171.4 (6)	O5—W3—O9	156.3 (5)
O50—Cu4—N8	92.2 (6)	O5—W3—O10	86.4 (5)
O50—Cu4—O48	91.5 (6)	O5—W3—O26	84.2 (5)
O50—Cu4—O52	91.9 (6)	O6—W3—K2	47.7 (4)
O52—Cu4—Cu3	163.3 (4)	O6—W3—O5	85.5 (5)
C57^ii—Eu1—O28	140.7 (4)	O6—W3—O9	89.3 (5)
C57^ii—Eu1—W10	119.6 (4)	O6—W3—O10	155.9 (5)
C57^ii—Eu1—W11	171.0 (4)	O6—W3—O26	84.5 (5)
O28—Eu1—W10	38.1 (2)	O9—W3—K2	50.6 (4)
O28—Eu1—W11	38.1 (2)	O9—W3—O26	72.3 (5)
O32—Eu1—C57^ii	110.5 (5)	O10—W3—K2	139.3 (4)
O32—Eu1—O28	69.3 (4)	O10—W3—O9	89.1 (5)
O32—Eu1—O33	71.6 (4)	O10—W3—O26	72.2 (5)
O32—Eu1—O38	83.9 (4)	O26—W3—K2	97.0 (3)
O32—Eu1—O39	126.5 (4)	O9—W4—K2	45.0 (4)
O32—Eu1—O40	73.4 (4)	O9—W4—O26	72.5 (5)
O32—Eu1—O40^ii	89.7 (4)	O13—W4—K2	87.4 (5)
O32—Eu1—O41^ii	132.6 (4)	O13—W4—O9	99.3 (6)
O32—Eu1—O42	144.4 (5)	O13—W4—O14	100.0 (6)
O32—Eu1—W10	106.9 (3)	O13—W4—O24	103.0 (6)
O32—Eu1—W11	77.9 (3)	O13—W4—O26	168.7 (5)
O33—Eu1—C57^ii	74.0 (5)	O13—W4—O29	104.1 (6)
O33—Eu1—O28	68.8 (4)	O14—W4—K2	130.1 (4)
O33—Eu1—O38	126.8 (4)	O14—W4—O9	85.3 (5)
O33—Eu1—O39	79.3 (4)	O14—W4—O24	156.4 (5)
O33—Eu1—O40	130.0 (4)	O14—W4—O26	72.1 (4)
O33—Eu1—O40^ii	79.0 (4)	O24—W4—K2	46.8 (4)
O33—Eu1—O41^ii	75.2 (4)	O24—W4—O9	86.0 (5)
O33—Eu1—O42	143.5 (5)	O24—W4—O26	84.4 (5)
O33—Eu1—W10	75.1 (3)	O26—W4—K2	91.7 (3)
O33—Eu1—W11	106.8 (3)	O29—W4—K2	134.6 (4)
O38—Eu1—C57^ii	158.6 (5)	O29—W4—O9	156.6 (5)
O38—Eu1—O28	58.4 (4)	O29—W4—O14	91.6 (5)
O38—Eu1—O39	79.0 (4)	O29—W4—O24	87.8 (5)
O38—Eu1—O40^ii	148.7 (4)	O29—W4—O26	84.4 (5)
O38—Eu1—O40	82.7 (4)	O10—W5—O26	71.6 (4)
O38—Eu1—O41^ii	143.5 (4)	O14—W5—O10	85.1 (5)
O38—Eu1—O42	75.9 (5)	O14—W5—O26	71.0 (4)
O38—Eu1—W10	67.9 (3)	O15—W5—O10	99.5 (6)
O38—Eu1—W11	20.3 (3)	O15—W5—O14	100.3 (6)
O39—Eu1—C57^ii	102.9 (5)	O15—W5—O16	103.2 (6)
O39—Eu1—O28	58.5 (4)	O15—W5—O26	167.6 (5)
O39—Eu1—O40^ii	127.8 (4)	O15—W5—O30	105.0 (6)
O39—Eu1—O40	150.7 (4)	O16—W5—O10	86.4 (5)
O39—Eu1—O41^ii	77.7 (4)	O16—W5—O14	156.0 (5)
O39—Eu1—O42	78.1 (5)	O16—W5—O26	85.0 (5)
O39—Eu1—W10	20.5 (3)	O30—W5—O10	155.5 (5)
O39—Eu1—W11	68.8 (3)	O30—W5—O14	90.4 (5)
O40—Eu1—C57^ii	86.3 (5)	O30—W5—O16	88.2 (5)
O40^ii—Eu1—C57^ii	25.1 (5)	O30—W5—O26	84.2 (5)
O40—Eu1—O28	127.7 (4)	O11—W6—O25	73.4 (5)
O40^ii—Eu1—O28	145.6 (4)	O16—W6—O11	84.0 (5)
O40—Eu1—O40^ii	66.1 (5)	O16—W6—O25	84.5 (5)
O40—Eu1—O41^ii	105.3 (4)	O17—W6—O11	99.5 (6)
O40^ii—Eu1—W10	142.6 (3)	O17—W6—O16	103.0 (6)
O40—Eu1—W10	150.3 (3)	O17—W6—O18	100.3 (6)
O40—Eu1—W11	99.5 (3)	O17—W6—O25	169.3 (5)
O40^ii—Eu1—W11	163.4 (3)	O17—W6—O31	103.9 (6)
O41^ii—Eu1—C57^ii	26.0 (5)	O18—W6—O11	86.9 (5)
O41^ii—Eu1—O28	126.9 (4)	O18—W6—O16	156.0 (5)
O41^ii—Eu1—O40^ii	51.0 (4)	O18—W6—O25	71.6 (5)
O41^ii—Eu1—W10	96.0 (3)	O31—W6—O11	156.0 (6)
O41^ii—Eu1—W11	145.1 (3)	O31—W6—O16	85.9 (5)
O42—Eu1—C57^ii	83.6 (5)	O31—W6—O18	93.7 (5)
O42—Eu1—O28	120.3 (4)	O31—W6—O25	84.0 (5)
O42—Eu1—O40^ii	92.8 (4)	O12—W7—O25	69.6 (4)
O42—Eu1—O40	75.3 (5)	O18—W7—O12	82.9 (5)
O42—Eu1—O41^ii	72.2 (5)	O18—W7—O25	70.3 (5)
O42—Eu1—W10	92.3 (3)	O19—W7—O12	99.3 (5)
O42—Eu1—W11	91.2 (4)	O19—W7—O18	101.6 (6)
W11—Eu1—W10	53.13 (2)	O19—W7—O20	102.8 (6)
C52^iii—K1—W9	71.8 (3)	O19—W7—O25	166.6 (5)
C52^iii—K1—W10	119.0 (3)	O19—W7—O32	103.9 (6)
O22—K1—C52^iii	70.7 (4)	O20—W7—O12	85.6 (5)
O22—K1—O57^iv	140.4 (5)	O20—W7—O18	154.4 (5)
O22—K1—W9	28.7 (2)	O20—W7—O25	84.2 (5)
O22—K1—W10	79.3 (3)	O32—W7—O12	156.8 (5)
O33—K1—C52^iii	120.5 (4)	O32—W7—O18	92.0 (6)
O33—K1—O22	51.9 (3)	O32—W7—O20	89.6 (5)
O33—K1—O57^iv	145.9 (5)	O32—W7—O25	87.3 (5)
O33—K1—W9	65.6 (3)	O7—W8—K1	132.6 (3)
O33—K1—W10	68.4 (3)	O7—W8—O27	69.4 (4)
O34—K1—C52^iii	93.7 (4)	O20—W8—K1	139.3 (4)
O34—K1—O22	52.8 (3)	O20—W8—O7	84.7 (5)
O34—K1—O33	65.7 (3)	O20—W8—O22	154.5 (5)
O34—K1—O57^iv	148.0 (5)	O20—W8—O27	84.1 (4)
O34—K1—W9	28.2 (2)	O21—W8—K1	88.8 (4)
O34—K1—W10	30.0 (2)	O21—W8—O7	98.4 (5)
O39—K1—C52^iii	145.6 (4)	O21—W8—O20	102.9 (6)
O39—K1—O22	93.0 (4)	O21—W8—O22	101.2 (6)
O39—K1—O33	60.4 (3)	O21—W8—O27	165.6 (5)
O39—K1—O34	53.7 (3)	O21—W8—O33	104.3 (6)
O39—K1—O47^iii	68.9 (4)	O22—W8—K1	49.2 (4)
O39—K1—O57^iv	126.6 (5)	O22—W8—O7	83.5 (5)
O39—K1—W9	79.6 (3)	O22—W8—O27	70.6 (4)
O39—K1—W10	26.6 (2)	O27—W8—K1	94.1 (3)
O41^ii—K1—C52^iii	148.8 (4)	O33—W8—K1	46.9 (4)
O41^ii—K1—O22	111.7 (4)	O33—W8—O7	157.2 (5)
O41^ii—K1—O33	61.8 (4)	O33—W8—O20	92.4 (6)
O41^ii—K1—O34	112.8 (4)	O33—W8—O22	89.7 (5)
O41^ii—K1—O39	65.1 (4)	O33—W8—O27	87.8 (5)
O41^ii—K1—O44^iii	152.5 (5)	K1—W9—K2	170.51 (18)
O41^ii—K1—O47^iii	97.8 (5)	O8—W9—K1	138.1 (4)
O41^ii—K1—O57^iv	89.7 (6)	O8—W9—K2	44.8 (4)
O41^ii—K1—O60	85.4 (5)	O8—W9—O27	73.6 (5)
O41^ii—K1—W9	126.0 (3)	O22—W9—K1	49.5 (4)
O41^ii—K1—W10	91.4 (3)	O22—W9—K2	133.6 (4)
O44^iii—K1—C52^iii	41.9 (4)	O22—W9—O8	89.1 (5)
O44^iii—K1—O22	95.8 (4)	O22—W9—O27	72.1 (4)
O44^iii—K1—O33	144.1 (4)	O23—W9—K1	84.5 (4)
O44^iii—K1—O34	82.7 (4)	O23—W9—K2	86.0 (5)
O44^iii—K1—O39	114.3 (4)	O23—W9—O8	99.7 (6)
O44^iii—K1—O47^iii	59.6 (5)	O23—W9—O22	100.2 (6)
O44^iii—K1—O57^iv	68.3 (6)	O23—W9—O24	101.4 (6)
O44^iii—K1—W9	78.5 (3)	O23—W9—O27	169.6 (5)
O44^iii—K1—W10	92.9 (3)	O23—W9—O34	103.3 (6)
O47^iii—K1—C52^iii	100.8 (5)	O24—W9—K1	133.4 (4)
O47^iii—K1—O22	134.9 (4)	O24—W9—K2	48.4 (4)
O47^iii—K1—O33	129.3 (4)	O24—W9—O8	87.0 (5)
O47^iii—K1—O34	85.0 (4)	O24—W9—O22	158.4 (5)
O47^iii—K1—O57^iv	69.1 (6)	O24—W9—O27	86.4 (5)
O47^iii—K1—W9	106.2 (3)	O24—W9—O34	86.2 (5)
O47^iii—K1—W10	66.3 (3)	O27—W9—K1	95.2 (3)
O57^iv—K1—C52^iii	74.0 (6)	O27—W9—K2	94.2 (3)
O57^iv—K1—W9	143.9 (5)	O34—W9—K1	48.0 (4)
O57^iv—K1—W10	135.1 (5)	O34—W9—K2	134.4 (4)
O60—K1—C52^iii	65.5 (5)	O34—W9—O8	156.9 (5)
O60—K1—O22	71.4 (5)	O34—W9—O22	89.2 (5)
O60—K1—O33	81.2 (5)	O34—W9—O27	84.0 (5)
O60—K1—O34	124.3 (5)	Eu1—W10—K1	62.71 (8)
O60—K1—O39	139.1 (5)	O28—W10—Eu1	51.5 (3)
O60—K1—O44^iii	105.0 (6)	O28—W10—K1	96.7 (3)
O60—K1—O47^iii	146.8 (6)	O29—W10—Eu1	134.6 (3)
O60—K1—O57^iv	77.9 (6)	O29—W10—K1	131.3 (3)
O60—K1—W9	98.0 (5)	O29—W10—O28	83.1 (4)
O60—K1—W10	146.9 (5)	O34—W10—Eu1	91.0 (3)
W10—K1—W9	57.99 (8)	O34—W10—K1	50.2 (4)
O6—K2—O8	54.6 (4)	O34—W10—O28	84.5 (5)
O6—K2—O9	55.1 (4)	O34—W10—O29	81.6 (5)
O6—K2—O24	65.4 (4)	O35—W10—Eu1	128.4 (4)
O6—K2—O51	96.5 (5)	O35—W10—K1	88.6 (4)
O6—K2—O53	104.3 (9)	O35—W10—O28	172.9 (5)
O6—K2—W1	29.8 (3)	O35—W10—O29	96.9 (5)
O6—K2—W3	29.2 (3)	O35—W10—O34	102.5 (5)
O6—K2—W4	65.8 (3)	O35—W10—O37	101.8 (5)
O6—K2—W9	65.6 (3)	O35—W10—O39	101.6 (6)
O8—K2—O9	91.4 (5)	O37—W10—Eu1	82.6 (3)
O8—K2—O24	53.3 (4)	O37—W10—K1	141.5 (3)
O8—K2—O51	59.6 (4)	O37—W10—O28	71.2 (4)
O8—K2—O53	146.2 (10)	O37—W10—O29	84.6 (5)
O8—K2—W1	30.0 (3)	O37—W10—O34	153.3 (5)
O8—K2—W3	80.2 (4)	O39—W10—Eu1	27.5 (4)
O8—K2—W4	77.8 (4)	O39—W10—K1	47.3 (4)
O8—K2—W9	28.3 (3)	O39—W10—O28	78.9 (5)
O9—K2—O24	53.0 (4)	O39—W10—O29	161.3 (5)
O9—K2—O51	149.3 (5)	O39—W10—O34	91.6 (5)
O9—K2—O53	56.1 (9)	O39—W10—O37	94.2 (5)
O9—K2—W1	81.4 (4)	O28—W11—Eu1	51.7 (3)
O9—K2—W3	30.6 (3)	O30—W11—Eu1	133.9 (3)
O9—K2—W4	28.1 (3)	O30—W11—O28	82.3 (5)
O9—K2—W9	77.8 (4)	O31—W11—Eu1	89.7 (4)
O24—K2—O51	107.7 (5)	O31—W11—O28	82.7 (5)
O24—K2—W1	67.5 (3)	O31—W11—O30	80.3 (5)
O24—K2—W3	66.9 (3)	O36—W11—Eu1	129.6 (4)
O24—K2—W4	27.9 (3)	O36—W11—O28	173.3 (5)
O24—K2—W9	28.2 (2)	O36—W11—O30	96.5 (5)
O51—K2—W1	68.4 (3)	O36—W11—O31	103.6 (6)
O51—K2—W3	124.8 (4)	O36—W11—O37	101.4 (5)
O51—K2—W4	135.4 (4)	O36—W11—O38	102.6 (6)
O51—K2—W9	79.6 (3)	O37—W11—Eu1	83.3 (3)
O53—K2—O24	95.3 (9)	O37—W11—O28	71.9 (4)
O53—K2—O51	154.0 (10)	O37—W11—O30	85.4 (5)
O53—K2—W1	134.0 (9)	O37—W11—O31	152.3 (5)
O53—K2—W3	75.2 (8)	O38—W11—Eu1	27.4 (4)
O53—K2—W4	68.9 (8)	O38—W11—O28	79.1 (5)
O53—K2—W9	123.2 (9)	O38—W11—O30	160.7 (5)
O61—K2—O6	72.6 (8)	O38—W11—O31	92.6 (5)
O61—K2—O8	103.8 (8)	O38—W11—O37	93.3 (5)

Symmetry codes: (i) x, y−1, z; (ii) −x+1/2, −y+1/2, −z+1/2; (iii) x, y+1, z; (iv) −x+1/2, −y+3/2, −z+1/2.

(fhsp21c)

Crystal data

K2{[Cu2(H2O)(C12H8N2)2(C2H3O2)2]4[Gd2(H2O)2(C2H3O2)2 (AsW11O39)2]}·22H2O	F(000) = 16000
Mr = 8821.61	Dx = 2.965 Mg m^−3
Monoclinic, I2/a	Mo Kα radiation, λ = 0.71073 Å
a = 30.5038 (7) Å	Cell parameters from 19211 reflections
b = 14.1439 (4) Å	θ = 3.2–28.4°
c = 48.2029 (12) Å	µ = 14.73 mm^−1
β = 108.131 (3)°	T = 190 K
V = 19764.2 (9) Å^3	Block, blue
Z = 4	0.08 × 0.07 × 0.02 mm

Data collection

Agulent Xcalibur Sapphire3 diffractometer	18730 independent reflections
Radiation source: Enhance (Mo) X-ray Source	15124 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.078
Detector resolution: 15.9853 pixels mm^-1	θmax = 25.7°, θmin = 3.1°
ω scans	h = −37→37
Absorption correction: multi-scan (CrysAlis PRO; Agilent, 2013)	k = −17→17
Tmin = 0.313, Tmax = 1.000	l = −58→58
123422 measured reflections

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.045	H-atom parameters constrained
wR(F^2) = 0.100	w = 1/[σ^2(Fo^2) + (0.0228P)^2 + 986.8466P] where P = (Fo^2 + 2Fc^2)/3
S = 1.08	(Δ/σ)max = 0.001
18730 reflections	Δρmax = 2.98 e Å^−3
677 parameters	Δρmin = −1.85 e Å^−3

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
C1	0.2858 (4)	0.3884 (10)	0.1072 (3)	0.023 (3)*
H1	0.264117	0.395093	0.116998	0.028*
C2	0.2710 (5)	0.3752 (11)	0.0773 (3)	0.029 (3)*
H2	0.239600	0.373320	0.067221	0.035*
C3	0.3021 (5)	0.3648 (11)	0.0624 (3)	0.033 (3)*
H3	0.291659	0.355373	0.042326	0.039*
C4	0.3496 (5)	0.3681 (11)	0.0771 (3)	0.027 (3)*
C5	0.3848 (5)	0.3583 (12)	0.0640 (3)	0.040 (4)*
H5	0.377094	0.353217	0.043833	0.048*
C6	0.4295 (5)	0.3561 (12)	0.0805 (3)	0.039 (4)*
H6	0.452146	0.346746	0.071506	0.047*
C7	0.4427 (4)	0.3677 (11)	0.1111 (3)	0.026 (3)*
C8	0.4892 (5)	0.3639 (11)	0.1299 (3)	0.031 (3)*
H8	0.512882	0.351858	0.122110	0.037*
C9	0.4991 (5)	0.3773 (12)	0.1587 (3)	0.038 (4)*
H9	0.529422	0.375050	0.170888	0.045*
C10	0.4621 (5)	0.3951 (11)	0.1702 (3)	0.030 (3)*
H10	0.468907	0.406531	0.190047	0.036*
C11	0.4094 (4)	0.3824 (11)	0.1248 (3)	0.027 (3)*
C12	0.3617 (4)	0.3820 (9)	0.1072 (2)	0.017 (3)*
C13	0.3330 (5)	0.1618 (11)	0.1239 (3)	0.033 (3)*
H13	0.304991	0.173831	0.127098	0.040*
C14	0.3326 (5)	0.1355 (12)	0.0967 (3)	0.039 (4)*
H14	0.304864	0.130808	0.081609	0.047*
C15	0.3736 (6)	0.1160 (13)	0.0916 (4)	0.048 (4)*
H15	0.373801	0.099153	0.072942	0.058*
C16	0.4145 (5)	0.1214 (12)	0.1142 (3)	0.039 (4)*
C17	0.4605 (6)	0.1049 (14)	0.1119 (4)	0.056 (5)*
H17	0.463660	0.090424	0.093760	0.067*
C18	0.4986 (7)	0.1102 (15)	0.1355 (4)	0.061 (5)*
H18	0.527042	0.095958	0.133270	0.073*
C19	0.4972 (5)	0.1365 (13)	0.1636 (3)	0.041 (4)*
C20	0.5350 (6)	0.1441 (14)	0.1885 (4)	0.053 (5)*
H20	0.564408	0.129555	0.187818	0.064*
C21	0.5288 (6)	0.1729 (14)	0.2139 (4)	0.050 (5)*
H21	0.553978	0.178314	0.230685	0.060*
C22	0.4848 (5)	0.1944 (13)	0.2148 (4)	0.042 (4)*
H22	0.481206	0.214064	0.232425	0.051*
C23	0.4529 (5)	0.1573 (12)	0.1659 (3)	0.035 (4)*
C24	0.4122 (5)	0.1491 (11)	0.1413 (3)	0.030 (3)*
C25	0.1019 (4)	1.1980 (10)	0.1276 (3)	0.020 (3)*
H25	0.124680	1.205602	0.118693	0.025*
C26	0.1140 (5)	1.2046 (10)	0.1580 (3)	0.026 (3)*
H26	0.144277	1.218279	0.169002	0.032*
C27	0.0813 (4)	1.1908 (11)	0.1715 (3)	0.028 (3)*
H27	0.088939	1.194672	0.191658	0.033*
C28	0.0357 (4)	1.1706 (11)	0.1542 (3)	0.027 (3)*
C29	−0.0018 (5)	1.1577 (12)	0.1665 (3)	0.038 (4)*
H29	0.004148	1.159768	0.186635	0.046*
C30	−0.0451 (5)	1.1426 (12)	0.1488 (3)	0.039 (4)*
H30	−0.068627	1.134862	0.157104	0.047*
C31	−0.0561 (5)	1.1382 (11)	0.1175 (3)	0.028 (3)*
C32	−0.1007 (5)	1.1262 (11)	0.0977 (3)	0.035 (4)*
H32	−0.126080	1.120717	0.104409	0.042*
C33	−0.1059 (5)	1.1229 (12)	0.0686 (3)	0.036 (4)*
H33	−0.135097	1.113574	0.055317	0.043*
C34	−0.0686 (4)	1.1330 (10)	0.0584 (3)	0.028 (3)*
H34	−0.073342	1.129195	0.038467	0.033*
C35	−0.0202 (4)	1.1504 (10)	0.1059 (3)	0.024 (3)*
C36	0.0262 (4)	1.1690 (10)	0.1247 (3)	0.019 (3)*
C37	0.0602 (5)	1.4131 (10)	0.1160 (3)	0.027 (3)*
H37	0.088491	1.419883	0.112734	0.033*
C38	0.0585 (5)	1.4200 (11)	0.1451 (3)	0.031 (3)*
H38	0.085083	1.433372	0.160360	0.038*
C39	0.0183 (5)	1.4073 (11)	0.1503 (3)	0.034 (4)*
H39	0.017253	1.408210	0.169388	0.041*
C40	−0.0231 (4)	1.3923 (11)	0.1266 (3)	0.027 (3)*
C41	−0.0684 (5)	1.3815 (11)	0.1294 (3)	0.034 (3)*
H41	−0.071971	1.379822	0.147837	0.041*
C42	−0.1051 (5)	1.3739 (11)	0.1061 (3)	0.032 (3)*
H42	−0.134074	1.369524	0.108520	0.039*
C43	−0.1013 (5)	1.3723 (11)	0.0770 (3)	0.029 (3)*
C44	−0.1381 (5)	1.3607 (11)	0.0513 (3)	0.030 (3)*
H44	−0.167863	1.351838	0.052160	0.036*
C45	−0.1304 (5)	1.3622 (11)	0.0248 (3)	0.034 (3)*
H45	−0.154876	1.361026	0.007537	0.040*
C46	−0.0853 (4)	1.3657 (10)	0.0243 (3)	0.026 (3)*
H46	−0.080068	1.362155	0.006326	0.031*
C47	−0.0575 (4)	1.3777 (10)	0.0737 (3)	0.022 (3)*
C48	−0.0181 (4)	1.3892 (10)	0.0989 (3)	0.019 (3)*
C49	0.1060 (4)	1.2822 (11)	0.0626 (3)	0.025 (3)*
C50	0.1569 (5)	1.2932 (13)	0.0661 (3)	0.042 (4)*
H50A	0.171712	1.232562	0.069801	0.062*
H50B	0.170855	1.334916	0.082100	0.062*
H50C	0.160428	1.319214	0.048469	0.062*
C51	0.0016 (4)	1.2173 (9)	0.0073 (2)	0.015 (3)*
C52	−0.0068 (5)	1.1911 (12)	−0.0232 (3)	0.038 (4)*
H52A	−0.003116	1.124066	−0.024584	0.058*
H52B	0.014756	1.223380	−0.030707	0.058*
H52C	−0.037680	1.208712	−0.034347	0.058*
C53	0.2907 (4)	0.3022 (10)	0.1780 (3)	0.024 (3)*
C54	0.2431 (5)	0.2936 (11)	0.1808 (3)	0.030 (3)*
H54A	0.218212	0.294682	0.162445	0.036*
H54B	0.237002	0.335337	0.195143	0.036*
C55	0.4032 (5)	0.3738 (13)	0.2260 (3)	0.040 (4)*
C56	0.4195 (10)	0.414 (2)	0.2561 (6)	0.129 (11)*
H56A	0.425382	0.480251	0.255113	0.194*
H56B	0.447293	0.382425	0.267182	0.194*
H56C	0.396140	0.404710	0.265390	0.194*
C57	0.2416 (4)	0.5854 (10)	0.2410 (3)	0.020 (3)*
C58	0.2510 (5)	0.5131 (12)	0.2198 (3)	0.039 (4)*
H58A	0.263820	0.456714	0.230343	0.059*
H58B	0.272454	0.539227	0.210958	0.059*
H58C	0.222663	0.497965	0.204960	0.059*
As1	0.20447 (3)	0.79665 (8)	0.12498 (2)	0.0069 (2)*
Cu1	0.36109 (5)	0.41223 (12)	0.16475 (3)	0.0223 (4)
Cu2	0.38088 (5)	0.21146 (13)	0.18734 (4)	0.0265 (4)
Cu3	0.03308 (5)	1.16401 (12)	0.06775 (3)	0.0187 (3)
Cu4	0.01738 (5)	1.36939 (12)	0.05206 (3)	0.0194 (3)
Gd1	0.27088 (2)	0.79110 (4)	0.21485 (2)	0.01296 (13)
K1	0.21958 (12)	0.4292 (3)	0.29370 (8)	0.0131 (8)*	0.6667
K2	0.1494 (2)	1.0655 (5)	0.03776 (14)	0.0082 (14)*	0.3333
N1	0.3307 (3)	0.3918 (8)	0.1223 (2)	0.023 (2)*
N2	0.4188 (4)	0.3961 (8)	0.1537 (2)	0.024 (3)*
N3	0.4475 (4)	0.1877 (10)	0.1914 (3)	0.036 (3)*
N4	0.3720 (4)	0.1712 (9)	0.1464 (2)	0.026 (3)*
N5	0.0589 (3)	1.1812 (8)	0.1111 (2)	0.019 (2)*
N6	−0.0256 (3)	1.1482 (8)	0.0764 (2)	0.023 (2)*
N7	0.0233 (3)	1.3974 (8)	0.0937 (2)	0.020 (2)*
N8	−0.0489 (3)	1.3738 (8)	0.0483 (2)	0.020 (2)*
O1	0.2640 (3)	0.5750 (6)	0.05761 (17)	0.0203 (19)*
O2	0.1118 (3)	0.8081 (7)	0.01183 (18)	0.023 (2)*
O3	0.2865 (3)	0.9605 (6)	0.05721 (17)	0.0195 (19)*
O4	0.1975 (3)	0.8818 (6)	0.04340 (17)	0.0184 (19)*
O5	0.1860 (2)	0.6950 (6)	0.04424 (16)	0.0128 (17)*
O6	0.2695 (3)	0.7712 (6)	0.06476 (17)	0.0176 (18)*
O7	0.2841 (3)	0.6632 (6)	0.11240 (16)	0.0151 (18)*
O8	0.2033 (3)	0.5868 (6)	0.09148 (16)	0.0151 (18)*
O9	0.1174 (3)	0.7202 (6)	0.06561 (16)	0.0139 (17)*
O10	0.1278 (3)	0.9004 (6)	0.06551 (17)	0.0170 (18)*
O11	0.2260 (3)	0.9919 (6)	0.09033 (16)	0.0148 (17)*
O12	0.2965 (3)	0.8819 (6)	0.11194 (16)	0.0152 (18)*
O13	0.2099 (2)	0.7919 (6)	0.09140 (15)	0.0102 (16)*
O14	0.3440 (3)	0.5668 (6)	0.16013 (17)	0.0190 (19)*
O15	0.1883 (3)	0.4298 (6)	0.12443 (17)	0.0181 (19)*
O16	0.0364 (3)	0.6530 (6)	0.07587 (17)	0.0175 (18)*
O17	0.0544 (3)	1.0059 (6)	0.07538 (17)	0.0183 (19)*
O18	0.2273 (3)	1.1619 (6)	0.12113 (17)	0.0181 (18)*
O19	0.3645 (3)	0.9588 (6)	0.16001 (17)	0.0188 (19)*
O20	0.2458 (3)	0.5857 (6)	0.14771 (17)	0.0166 (18)*
O21	0.1227 (2)	0.5702 (6)	0.09960 (16)	0.0117 (17)*
O22	0.0847 (2)	0.8231 (6)	0.09796 (16)	0.0119 (17)*
O23	0.1485 (3)	1.0504 (6)	0.09834 (16)	0.0151 (17)*
O24	0.2679 (3)	0.9893 (6)	0.14624 (16)	0.0164 (18)*
O25	0.3400 (2)	0.7679 (6)	0.15592 (16)	0.0119 (17)*
O26	0.2553 (2)	0.7872 (6)	0.15077 (15)	0.0111 (16)*
O27	0.1686 (3)	0.7104 (6)	0.12766 (16)	0.0143 (17)*
O28	0.1786 (2)	0.9000 (6)	0.12721 (16)	0.0117 (17)*
O29	0.3053 (3)	0.6738 (6)	0.19342 (17)	0.0163 (18)*
O30	0.1618 (3)	0.5680 (6)	0.15700 (17)	0.0170 (18)*
O31	0.0903 (3)	0.6779 (6)	0.13383 (16)	0.0146 (18)*
O32	0.1068 (3)	0.9749 (6)	0.13336 (16)	0.0139 (17)*
O33	0.1894 (3)	1.0527 (6)	0.15590 (16)	0.0163 (18)*
O34	0.3148 (3)	0.8855 (6)	0.19282 (16)	0.0161 (18)*
O35	0.1327 (2)	0.8241 (6)	0.16664 (16)	0.0126 (17)*
O36	0.2155 (3)	0.9029 (6)	0.19043 (16)	0.0152 (18)*
O37	0.2030 (3)	0.7106 (6)	0.19110 (16)	0.0152 (18)*
O38	0.1398 (3)	0.9998 (7)	0.19513 (18)	0.022 (2)*
O39	0.1188 (3)	0.6549 (7)	0.19540 (17)	0.0209 (19)*
O40	0.3486 (3)	0.7711 (7)	0.24835 (19)	0.028 (2)*
O41	0.3048 (3)	0.3838 (7)	0.1743 (2)	0.030 (2)*
O42	0.3147 (3)	0.2275 (7)	0.18089 (19)	0.027 (2)*
O43	0.3962 (3)	0.4326 (8)	0.2054 (2)	0.033 (2)*
O44	0.3962 (3)	0.2859 (8)	0.2237 (2)	0.036 (2)*
O45	0.3775 (3)	0.0761 (8)	0.2099 (2)	0.034 (2)*
O46	0.0034 (3)	1.1531 (7)	0.0263 (2)	0.030 (2)*
O47	0.0069 (3)	1.3037 (7)	0.01430 (18)	0.024 (2)*
O48	0.0901 (3)	1.2007 (7)	0.06119 (18)	0.023 (2)*
O49	0.0838 (3)	1.3577 (7)	0.06145 (19)	0.029 (2)*
O50	0.0202 (3)	1.5065 (8)	0.0309 (2)	0.043 (3)*
O51	0.2118 (3)	0.5673 (6)	0.25312 (17)	0.0175 (18)*
O60	0.2940 (4)	0.3566 (9)	0.2755 (2)	0.051 (3)*
O53	0.250000	0.5089 (12)	0.000000	0.042 (4)*
O54	0.1774 (4)	0.4092 (10)	0.0086 (3)	0.066 (4)*
O55	0.4560 (4)	0.5971 (11)	0.2101 (3)	0.066 (4)*
O56	0.0608 (7)	1.0106 (17)	0.0056 (5)	0.142 (8)*
O57	0.3334 (4)	0.2031 (10)	0.2535 (3)	0.064 (4)*
O58	0.1230 (3)	0.5164 (8)	0.0371 (2)	0.041 (3)*
O59	0.4138 (5)	0.7653 (12)	0.2125 (3)	0.080 (4)*
O52	0.2647 (3)	0.6607 (6)	0.24620 (16)	0.0147 (17)*
W1	0.24198 (2)	0.65823 (4)	0.07560 (2)	0.01242 (11)
W2	0.14882 (2)	0.80162 (4)	0.04626 (2)	0.01327 (11)
W3	0.25671 (2)	0.89631 (4)	0.07489 (2)	0.01261 (11)
W4	0.30355 (2)	0.65509 (4)	0.15660 (2)	0.01154 (10)
W5	0.18532 (2)	0.54976 (4)	0.12534 (2)	0.01255 (11)
W6	0.09119 (2)	0.68787 (4)	0.09543 (2)	0.01235 (11)
W7	0.10402 (2)	0.94962 (4)	0.09536 (2)	0.01290 (11)
W8	0.21144 (2)	1.04653 (4)	0.12272 (2)	0.01250 (10)
W9	0.31549 (2)	0.89373 (4)	0.15608 (2)	0.01125 (10)
W10	0.16043 (2)	0.94565 (4)	0.16979 (2)	0.01275 (11)
W11	0.14485 (2)	0.68943 (4)	0.17006 (2)	0.01261 (11)
O0AA	0.250000	0.7198 (18)	0.000000	0.092 (7)*
O1AA	0.1211 (5)	1.4495 (13)	0.2163 (4)	0.095 (5)*
O2AA	0.5456 (6)	0.5373 (14)	0.2382 (4)	0.104 (6)*
O3AA	0.3654 (7)	0.5843 (18)	0.2504 (5)	0.145 (8)*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Cu1	0.0237 (8)	0.0190 (9)	0.0270 (8)	0.0019 (7)	0.0118 (7)	0.0015 (7)
Cu2	0.0203 (8)	0.0232 (10)	0.0360 (9)	0.0014 (7)	0.0091 (7)	0.0044 (8)
Cu3	0.0220 (8)	0.0175 (9)	0.0156 (7)	0.0002 (7)	0.0042 (6)	0.0024 (6)
Cu4	0.0212 (8)	0.0164 (9)	0.0208 (8)	0.0010 (7)	0.0067 (6)	0.0017 (7)
Gd1	0.0156 (3)	0.0130 (3)	0.0106 (3)	0.0005 (2)	0.0047 (2)	0.0004 (2)
W1	0.0140 (2)	0.0131 (3)	0.0110 (2)	0.0001 (2)	0.00519 (18)	−0.00210 (19)
W2	0.0153 (2)	0.0155 (3)	0.0088 (2)	−0.0002 (2)	0.00331 (18)	0.00040 (19)
W3	0.0148 (2)	0.0132 (3)	0.0109 (2)	−0.0019 (2)	0.00554 (18)	0.00075 (19)
W4	0.0123 (2)	0.0105 (3)	0.0121 (2)	0.00198 (19)	0.00421 (18)	0.00046 (19)
W5	0.0127 (2)	0.0105 (3)	0.0140 (2)	−0.00076 (19)	0.00355 (18)	0.0004 (2)
W6	0.0112 (2)	0.0137 (3)	0.0122 (2)	−0.00127 (19)	0.00376 (18)	−0.00023 (19)
W7	0.0131 (2)	0.0124 (3)	0.0124 (2)	0.0029 (2)	0.00274 (18)	0.0017 (2)
W8	0.0139 (2)	0.0106 (3)	0.0126 (2)	0.00076 (19)	0.00352 (18)	0.00059 (19)
W9	0.0118 (2)	0.0107 (3)	0.0116 (2)	−0.00072 (19)	0.00413 (17)	0.00041 (19)
W10	0.0137 (2)	0.0137 (3)	0.0111 (2)	0.0030 (2)	0.00416 (18)	−0.00048 (19)
W11	0.0130 (2)	0.0146 (3)	0.0102 (2)	−0.00172 (19)	0.00373 (18)	0.00095 (19)

Geometric parameters (Å, º)

C1—C2	1.383 (18)	Cu3—O48	1.932 (9)
C1—N1	1.338 (16)	Cu4—N7	1.998 (10)
C2—C3	1.361 (19)	Cu4—N8	1.973 (10)
C3—C4	1.403 (19)	Cu4—O47	1.979 (9)
C4—C5	1.414 (19)	Cu4—O49	1.940 (9)
C4—C12	1.392 (17)	Cu4—O50	2.207 (12)
C5—C6	1.35 (2)	Gd1—K1^ii	3.997 (4)
C6—C7	1.415 (19)	Gd1—O29	2.366 (8)
C7—C8	1.425 (18)	Gd1—O34	2.365 (8)
C7—C11	1.390 (18)	Gd1—O36	2.345 (8)
C8—C9	1.335 (19)	Gd1—O37	2.328 (8)
C9—C10	1.425 (19)	Gd1—O40	2.435 (9)
C10—N2	1.313 (16)	Gd1—O51^ii	2.483 (8)
C11—C12	1.438 (17)	Gd1—O52	2.429 (8)
C11—N2	1.343 (16)	Gd1—O52^ii	2.537 (8)
C12—N1	1.366 (15)	K1—O24^ii	3.027 (9)
C13—C14	1.36 (2)	K1—O33^ii	3.079 (8)
C13—N4	1.344 (17)	K1—O34^ii	2.969 (9)
C14—C15	1.38 (2)	K1—O36^ii	3.033 (9)
C15—C16	1.38 (2)	K1—O42^i	2.880 (10)
C16—C17	1.46 (2)	K1—O45^i	2.914 (10)
C16—C24	1.38 (2)	K1—O51	2.722 (9)
C17—C18	1.35 (2)	K1—O60	2.866 (12)
C18—C19	1.42 (2)	K1—O57^i	3.000 (14)
C19—C20	1.38 (2)	K1—W8^ii	3.937 (4)
C19—C23	1.42 (2)	K1—W9^ii	3.858 (4)
C20—C21	1.36 (2)	K2—O4	2.954 (11)
C21—C22	1.39 (2)	K2—O10	2.868 (11)
C22—N3	1.332 (19)	K2—O11	3.045 (10)
C23—C24	1.431 (19)	K2—O23	2.937 (10)
C23—N3	1.360 (18)	K2—O48	3.079 (11)
C24—N4	1.362 (17)	K2—O56	2.78 (2)
C25—C26	1.399 (17)	K2—W2	3.755 (7)
C25—N5	1.328 (15)	K2—W3	3.999 (7)
C26—C27	1.362 (18)	K2—W7	3.834 (7)
C27—C28	1.409 (18)	K2—W8	3.950 (6)
C28—C29	1.454 (19)	O1—W1	1.719 (9)
C28—C36	1.360 (17)	O2—W2	1.695 (8)
C29—C30	1.35 (2)	O3—W3	1.690 (8)
C30—C31	1.445 (19)	O4—W2	1.906 (8)
C31—C32	1.406 (19)	O4—W3	1.976 (8)
C31—C35	1.387 (18)	O5—W1	1.965 (7)
C32—C33	1.37 (2)	O5—W2	1.909 (8)
C33—C34	1.377 (19)	O6—W1	1.951 (9)
C34—N6	1.346 (16)	O6—W3	1.908 (9)
C35—C36	1.448 (17)	O7—W1	1.839 (7)
C35—N6	1.377 (16)	O7—W4	2.029 (7)
C36—N5	1.365 (15)	O8—W1	1.888 (8)
C37—C38	1.421 (18)	O8—W5	1.948 (8)
C37—N7	1.311 (16)	O9—W2	1.916 (8)
C38—C39	1.338 (19)	O9—W6	1.906 (7)
C39—C40	1.430 (19)	O10—W2	1.895 (8)
C40—C41	1.440 (19)	O10—W7	1.932 (8)
C40—C48	1.390 (17)	O11—W3	1.922 (8)
C41—C42	1.318 (19)	O11—W8	1.914 (8)
C42—C43	1.443 (19)	O12—W3	1.831 (7)
C43—C44	1.399 (18)	O12—W9	2.031 (7)
C43—C47	1.397 (18)	O13—W1	2.360 (8)
C44—C45	1.367 (19)	O13—W2	2.388 (7)
C45—C46	1.384 (18)	O13—W3	2.358 (7)
C46—N8	1.335 (16)	O14—W4	1.726 (8)
C47—C48	1.426 (17)	O15—W5	1.700 (9)
C47—N8	1.334 (15)	O16—W6	1.717 (8)
C48—N7	1.368 (15)	O17—W7	1.716 (8)
C49—C50	1.519 (19)	O18—W8	1.711 (9)
C49—O48	1.244 (16)	O19—W9	1.714 (8)
C49—O49	1.257 (16)	O20—W4	1.944 (8)
C50—K2	3.478 (19)	O20—W5	1.894 (8)
C51—C52	1.459 (18)	O21—W5	1.949 (7)
C51—O46	1.280 (15)	O21—W6	1.901 (8)
C51—O47	1.264 (15)	O22—W6	1.931 (8)
C53—C54	1.506 (18)	O22—W7	1.900 (8)
C53—O41	1.264 (16)	O23—W7	1.942 (8)
C53—O42	1.269 (16)	O23—W8	1.915 (7)
C54—K1^i	3.445 (15)	O24—W8	1.921 (8)
C55—C56	1.49 (3)	O24—W9	1.932 (8)
C55—O43	1.261 (18)	O25—W4	1.952 (8)
C55—O44	1.261 (19)	O25—W9	1.932 (8)
C57—C58	1.533 (19)	O26—W4	2.340 (8)
C57—Gd1^ii	2.870 (13)	O26—W9	2.327 (8)
C57—O51	1.251 (14)	O27—W5	2.339 (8)
C57—O52	1.258 (15)	O27—W6	2.409 (7)
As1—O13	1.679 (7)	O27—W11	2.390 (7)
As1—O26	1.664 (7)	O28—W7	2.420 (7)
As1—O27	1.671 (8)	O28—W8	2.341 (8)
As1—O28	1.679 (8)	O28—W10	2.377 (7)
Cu1—Cu2	3.034 (2)	O29—W4	1.779 (8)
Cu1—N1	1.989 (10)	O30—W5	1.895 (8)
Cu1—N2	2.005 (11)	O30—W11	1.954 (9)
Cu1—O14	2.243 (9)	O31—W6	1.866 (7)
Cu1—O41	1.951 (9)	O31—W11	2.010 (7)
Cu1—O43	1.939 (9)	O32—W7	1.842 (7)
Cu2—K1^i	3.991 (4)	O32—W10	2.036 (7)
Cu2—N3	2.009 (12)	O33—W8	1.921 (8)
Cu2—N4	1.988 (11)	O33—W10	1.972 (8)
Cu2—O42	1.959 (9)	O34—W9	1.781 (8)
Cu2—O44	1.970 (10)	O35—W10	1.901 (8)
Cu2—O45	2.220 (11)	O35—W11	1.938 (8)
Cu3—Cu4	3.002 (2)	O36—W10	1.772 (8)
Cu3—N5	2.004 (10)	O37—W11	1.773 (7)
Cu3—N6	1.975 (10)	O38—W10	1.719 (8)
Cu3—O17	2.326 (9)	O39—W11	1.722 (8)
Cu3—O46	1.924 (9)
N1—C1—C2	121.2 (12)	O56—K2—O23	103.1 (5)
C3—C2—C1	120.6 (13)	O56—K2—O48	78.3 (5)
C2—C3—C4	120.6 (13)	O56—K2—W2	75.3 (5)
C3—C4—C5	125.5 (13)	O56—K2—W3	127.0 (6)
C12—C4—C3	115.4 (12)	O56—K2—W7	77.1 (5)
C12—C4—C5	119.1 (12)	O56—K2—W8	129.0 (5)
C6—C5—C4	120.7 (15)	W2—K2—W3	52.24 (9)
C5—C6—C7	121.2 (15)	W2—K2—W7	58.75 (11)
C6—C7—C8	124.3 (13)	W2—K2—W8	80.59 (13)
C11—C7—C6	120.0 (12)	W7—K2—W3	81.37 (13)
C11—C7—C8	115.7 (12)	W7—K2—W8	52.03 (9)
C9—C8—C7	120.9 (14)	W8—K2—W3	55.54 (9)
C8—C9—C10	118.5 (14)	C1—N1—C12	118.0 (11)
N2—C10—C9	122.4 (13)	C1—N1—Cu1	129.4 (9)
C7—C11—C12	118.3 (12)	C12—N1—Cu1	112.7 (8)
N2—C11—C7	124.1 (12)	C10—N2—C11	118.4 (12)
N2—C11—C12	117.6 (11)	C10—N2—Cu1	129.9 (9)
C4—C12—C11	120.5 (11)	C11—N2—Cu1	111.7 (8)
N1—C12—C4	124.3 (11)	C22—N3—C23	118.5 (13)
N1—C12—C11	115.1 (11)	C22—N3—Cu2	129.9 (11)
N4—C13—C14	123.1 (14)	C23—N3—Cu2	111.6 (9)
C13—C14—C15	119.4 (15)	C13—N4—C24	116.8 (12)
C14—C15—C16	119.7 (16)	C13—N4—Cu2	130.0 (10)
C15—C16—C17	125.6 (16)	C24—N4—Cu2	113.2 (9)
C15—C16—C24	117.7 (15)	C25—N5—C36	117.8 (10)
C24—C16—C17	116.7 (14)	C25—N5—Cu3	129.9 (8)
C18—C17—C16	121.2 (18)	C36—N5—Cu3	112.3 (8)
C17—C18—C19	123.2 (18)	C34—N6—C35	116.7 (11)
C18—C19—C23	116.2 (15)	C34—N6—Cu3	130.4 (9)
C20—C19—C18	125.7 (16)	C35—N6—Cu3	112.9 (8)
C20—C19—C23	118.1 (15)	C37—N7—C48	118.0 (11)
C21—C20—C19	119.4 (17)	C37—N7—Cu4	130.1 (9)
C20—C21—C22	120.2 (17)	C48—N7—Cu4	111.5 (8)
N3—C22—C21	122.3 (16)	C46—N8—Cu4	129.1 (9)
C19—C23—C24	121.2 (14)	C47—N8—C46	116.8 (11)
N3—C23—C19	121.5 (13)	C47—N8—Cu4	113.9 (8)
N3—C23—C24	117.2 (13)	W2—O4—K2	98.9 (3)
C16—C24—C23	121.4 (13)	W2—O4—W3	123.5 (4)
N4—C24—C16	123.2 (13)	W3—O4—K2	106.8 (4)
N4—C24—C23	115.4 (12)	W2—O5—W1	123.9 (4)
N5—C25—C26	122.0 (12)	W3—O6—W1	123.5 (4)
C27—C26—C25	119.6 (13)	W1—O7—W4	154.0 (4)
C26—C27—C28	118.9 (13)	W1—O8—W5	149.1 (4)
C27—C28—C29	122.9 (13)	W6—O9—W2	154.5 (5)
C36—C28—C27	118.0 (12)	W2—O10—K2	102.1 (3)
C36—C28—C29	119.0 (12)	W2—O10—W7	153.2 (5)
C30—C29—C28	120.2 (14)	W7—O10—K2	104.3 (4)
C29—C30—C31	122.1 (14)	W3—O11—K2	105.0 (3)
C32—C31—C30	125.1 (13)	W8—O11—K2	103.2 (3)
C35—C31—C30	117.4 (12)	W8—O11—W3	149.8 (5)
C35—C31—C32	117.5 (13)	W3—O12—W9	154.1 (4)
C33—C32—C31	118.6 (14)	As1—O13—W1	121.2 (4)
C32—C33—C34	121.1 (14)	As1—O13—W2	126.3 (4)
N6—C34—C33	122.3 (13)	As1—O13—W3	123.5 (4)
C31—C35—C36	120.7 (12)	W1—O13—W2	92.1 (3)
N6—C35—C31	123.7 (12)	W3—O13—W1	92.2 (2)
N6—C35—C36	115.6 (11)	W3—O13—W2	92.2 (3)
C28—C36—C35	120.5 (11)	W4—O14—Cu1	148.4 (5)
C28—C36—N5	123.5 (11)	W7—O17—Cu3	133.6 (4)
N5—C36—C35	115.9 (11)	W5—O20—W4	156.4 (5)
N7—C37—C38	122.4 (13)	W6—O21—W5	124.1 (4)
C39—C38—C37	119.6 (13)	W7—O22—W6	152.8 (4)
C38—C39—C40	120.1 (14)	W7—O23—K2	101.7 (3)
C39—C40—C41	125.2 (13)	W8—O23—K2	107.1 (3)
C48—C40—C39	116.1 (12)	W8—O23—W7	124.6 (4)
C48—C40—C41	118.7 (12)	W8—O24—K1^ii	103.1 (3)
C42—C41—C40	121.0 (14)	W8—O24—W9	155.1 (5)
C41—C42—C43	121.8 (14)	W9—O24—K1^ii	99.8 (3)
C44—C43—C42	125.4 (13)	W9—O25—W4	122.0 (4)
C47—C43—C42	118.5 (12)	As1—O26—W4	124.0 (4)
C47—C43—C44	116.0 (12)	As1—O26—W9	123.4 (4)
C45—C44—C43	120.1 (13)	W9—O26—W4	93.4 (3)
C44—C45—C46	118.5 (13)	As1—O27—W5	123.2 (4)
N8—C46—C45	123.5 (13)	As1—O27—W6	125.5 (4)
C43—C47—C48	119.5 (12)	As1—O27—W11	122.5 (4)
N8—C47—C43	124.8 (11)	W5—O27—W6	91.5 (3)
N8—C47—C48	115.6 (11)	W5—O27—W11	92.8 (3)
C40—C48—C47	120.4 (11)	W11—O27—W6	92.2 (3)
N7—C48—C40	123.7 (11)	As1—O28—W7	125.4 (4)
N7—C48—C47	115.8 (11)	As1—O28—W8	122.8 (4)
O48—C49—C50	118.0 (13)	As1—O28—W10	122.2 (4)
O48—C49—O49	126.1 (12)	W8—O28—W7	91.7 (3)
O49—C49—C50	115.8 (13)	W8—O28—W10	93.5 (3)
C49—C50—K2	85.5 (9)	W10—O28—W7	92.4 (3)
O46—C51—C52	119.8 (13)	W4—O29—Gd1	131.3 (4)
O47—C51—C52	118.8 (12)	W5—O30—W11	125.7 (4)
O47—C51—O46	121.4 (11)	W6—O31—W11	126.3 (4)
O41—C53—C54	118.0 (12)	W7—O32—W10	126.4 (4)
O41—C53—O42	124.5 (12)	W8—O33—K1^ii	101.3 (3)
O42—C53—C54	117.4 (13)	W8—O33—W10	123.9 (4)
C53—C54—K1^i	83.4 (8)	W10—O33—K1^ii	100.7 (3)
O43—C55—C56	116.1 (19)	Gd1—O34—K1^ii	96.4 (3)
O43—C55—O44	126.8 (15)	W9—O34—Gd1	131.8 (4)
O44—C55—C56	117.1 (18)	W9—O34—K1^ii	105.9 (4)
C58—C57—Gd1^ii	174.3 (10)	W10—O35—W11	144.4 (4)
O51—C57—C58	119.2 (12)	Gd1—O36—K1^ii	95.2 (2)
O51—C57—Gd1^ii	59.6 (6)	W10—O36—Gd1	157.1 (5)
O51—C57—O52	121.5 (12)	W10—O36—K1^ii	107.7 (4)
O52—C57—C58	119.3 (11)	W11—O37—Gd1	160.5 (5)
O52—C57—Gd1^ii	62.1 (6)	C53—O41—Cu1	125.8 (9)
O26—As1—O13	111.6 (3)	C53—O42—Cu2	130.1 (9)
O26—As1—O27	111.4 (4)	C53—O42—K1^i	114.6 (8)
O26—As1—O28	111.7 (4)	Cu2—O42—K1^i	109.6 (4)
O27—As1—O13	108.0 (4)	C55—O43—Cu1	127.0 (11)
O27—As1—O28	107.4 (4)	C55—O44—Cu2	126.3 (10)
O28—As1—O13	106.6 (4)	Cu2—O45—K1^i	101.2 (4)
N1—Cu1—Cu2	102.2 (3)	C51—O46—Cu3	126.0 (9)
N1—Cu1—N2	82.8 (4)	C51—O47—Cu4	132.0 (8)
N1—Cu1—O14	91.2 (4)	C49—O48—Cu3	126.5 (9)
N2—Cu1—Cu2	84.0 (3)	C49—O48—K2	109.3 (8)
N2—Cu1—O14	106.3 (4)	Cu3—O48—K2	123.7 (4)
O14—Cu1—Cu2	164.2 (2)	C49—O49—Cu4	126.2 (9)
O41—Cu1—Cu2	79.3 (3)	C57—O51—Gd1^ii	94.7 (8)
O41—Cu1—N1	92.9 (4)	C57—O51—K1	124.8 (8)
O41—Cu1—N2	161.5 (5)	Gd1^ii—O51—K1	100.3 (3)
O41—Cu1—O14	91.7 (4)	C57—O52—Gd1^ii	92.0 (7)
O43—Cu1—Cu2	77.9 (3)	C57—O52—Gd1	131.7 (7)
O43—Cu1—N1	174.5 (4)	Gd1—O52—Gd1^ii	113.0 (3)
O43—Cu1—N2	91.7 (4)	O1—W1—O5	100.1 (3)
O43—Cu1—O14	89.6 (4)	O1—W1—O6	99.1 (4)
O43—Cu1—O41	92.5 (4)	O1—W1—O7	104.3 (4)
Cu1—Cu2—K1^i	117.88 (8)	O1—W1—O8	103.3 (4)
N3—Cu2—Cu1	105.9 (4)	O1—W1—O13	167.9 (3)
N3—Cu2—K1^i	136.0 (4)	O5—W1—O13	71.9 (3)
N3—Cu2—O45	90.4 (5)	O6—W1—O5	85.4 (3)
N4—Cu2—Cu1	87.8 (4)	O6—W1—O13	71.7 (3)
N4—Cu2—K1^i	101.9 (3)	O7—W1—O5	155.5 (3)
N4—Cu2—N3	82.6 (5)	O7—W1—O6	89.8 (3)
N4—Cu2—O45	103.1 (4)	O7—W1—O8	88.1 (3)
O42—Cu2—Cu1	75.8 (3)	O7—W1—O13	83.8 (3)
O42—Cu2—K1^i	42.8 (3)	O8—W1—O5	87.2 (3)
O42—Cu2—N3	175.6 (5)	O8—W1—O6	157.4 (3)
O42—Cu2—N4	93.5 (4)	O8—W1—O13	85.6 (3)
O42—Cu2—O44	91.5 (4)	O2—W2—K2	82.2 (3)
O42—Cu2—O45	88.6 (4)	O2—W2—O4	101.2 (4)
O44—Cu2—Cu1	77.6 (3)	O2—W2—O5	102.6 (4)
O44—Cu2—K1^i	92.8 (3)	O2—W2—O9	103.1 (4)
O44—Cu2—N3	92.8 (5)	O2—W2—O10	102.5 (4)
O44—Cu2—N4	162.9 (5)	O2—W2—O13	171.4 (3)
O44—Cu2—O45	93.4 (4)	O4—W2—K2	51.0 (3)
O45—Cu2—Cu1	161.6 (3)	O4—W2—O5	88.7 (3)
O45—Cu2—K1^i	45.8 (2)	O4—W2—O9	155.7 (3)
N5—Cu3—Cu4	97.2 (3)	O4—W2—O13	72.3 (3)
N5—Cu3—O17	87.2 (4)	O5—W2—K2	139.2 (3)
N6—Cu3—Cu4	94.5 (3)	O5—W2—O9	86.8 (3)
N6—Cu3—N5	83.1 (4)	O5—W2—O13	72.1 (3)
N6—Cu3—O17	94.9 (4)	O9—W2—K2	132.1 (3)
O17—Cu3—Cu4	170.0 (2)	O9—W2—O13	83.6 (3)
O46—Cu3—Cu4	80.2 (3)	O10—W2—K2	48.3 (3)
O46—Cu3—N5	174.8 (4)	O10—W2—O4	89.2 (4)
O46—Cu3—N6	92.6 (4)	O10—W2—O5	154.7 (3)
O46—Cu3—O17	96.0 (4)	O10—W2—O9	84.8 (3)
O46—Cu3—O48	90.5 (4)	O10—W2—O13	83.3 (3)
O48—Cu3—Cu4	77.3 (3)	O13—W2—K2	97.4 (2)
O48—Cu3—N5	93.3 (4)	O3—W3—K2	86.9 (3)
O48—Cu3—N6	170.6 (4)	O3—W3—O4	100.1 (4)
O48—Cu3—O17	93.6 (3)	O3—W3—O6	100.6 (4)
N7—Cu4—Cu3	88.9 (3)	O3—W3—O11	102.8 (4)
N7—Cu4—O50	106.6 (4)	O3—W3—O12	104.8 (4)
N8—Cu4—Cu3	97.6 (3)	O3—W3—O13	169.5 (3)
N8—Cu4—N7	81.8 (4)	O4—W3—K2	45.0 (3)
N8—Cu4—O47	93.5 (4)	O4—W3—O13	71.9 (3)
N8—Cu4—O50	96.6 (4)	O6—W3—K2	130.1 (3)
O47—Cu4—Cu3	75.2 (3)	O6—W3—O4	85.3 (3)
O47—Cu4—N7	162.8 (4)	O6—W3—O11	156.2 (3)
O47—Cu4—O50	90.3 (4)	O6—W3—O13	72.5 (3)
O49—Cu4—Cu3	77.6 (3)	O11—W3—K2	47.4 (2)
O49—Cu4—N7	91.2 (4)	O11—W3—O4	86.0 (3)
O49—Cu4—N8	171.6 (4)	O11—W3—O13	83.7 (3)
O49—Cu4—O47	91.9 (4)	O12—W3—K2	134.8 (3)
O49—Cu4—O50	89.7 (4)	O12—W3—O4	155.1 (3)
O50—Cu4—Cu3	160.2 (3)	O12—W3—O6	91.1 (4)
C57^ii—Gd1—K1^ii	60.3 (3)	O12—W3—O11	87.5 (3)
O29—Gd1—C57^ii	158.5 (3)	O12—W3—O13	83.5 (3)
O29—Gd1—K1^ii	126.3 (2)	O13—W3—K2	91.7 (2)
O29—Gd1—O40	74.6 (3)	O7—W4—O26	82.0 (3)
O29—Gd1—O51^ii	143.1 (3)	O14—W4—O7	96.4 (3)
O29—Gd1—O52^ii	149.5 (3)	O14—W4—O20	103.2 (4)
O29—Gd1—O52	82.5 (3)	O14—W4—O25	101.5 (4)
O34—Gd1—C57^ii	102.4 (3)	O14—W4—O26	173.0 (3)
O34—Gd1—K1^ii	47.6 (2)	O14—W4—O29	102.1 (4)
O34—Gd1—O29	79.0 (3)	O20—W4—O7	81.2 (3)
O34—Gd1—O40	78.0 (3)	O20—W4—O25	153.1 (3)
O34—Gd1—O51^ii	77.5 (3)	O20—W4—O26	83.3 (3)
O34—Gd1—O52	150.8 (3)	O25—W4—O7	85.3 (3)
O34—Gd1—O52^ii	127.8 (3)	O25—W4—O26	71.7 (3)
O36—Gd1—C57^ii	73.8 (3)	O29—W4—O7	161.3 (3)
O36—Gd1—K1^ii	49.1 (2)	O29—W4—O20	92.2 (3)
O36—Gd1—O29	127.0 (3)	O29—W4—O25	93.2 (3)
O36—Gd1—O34	79.3 (3)	O29—W4—O26	79.9 (3)
O36—Gd1—O40	144.3 (3)	O8—W5—O21	84.4 (3)
O36—Gd1—O51^ii	75.5 (3)	O8—W5—O27	84.4 (3)
O36—Gd1—O52	129.9 (3)	O15—W5—O8	102.5 (4)
O36—Gd1—O52^ii	77.5 (3)	O15—W5—O20	103.4 (4)
O37—Gd1—C57^ii	111.0 (3)	O15—W5—O21	100.4 (4)
O37—Gd1—K1^ii	121.0 (2)	O15—W5—O27	169.9 (3)
O37—Gd1—O29	83.7 (3)	O15—W5—O30	101.1 (4)
O37—Gd1—O34	126.7 (3)	O20—W5—O8	85.8 (3)
O37—Gd1—O36	72.0 (3)	O20—W5—O21	155.7 (4)
O37—Gd1—O40	143.5 (3)	O20—W5—O27	84.3 (3)
O37—Gd1—O51^ii	133.2 (3)	O20—W5—O30	92.9 (3)
O37—Gd1—O52^ii	88.6 (3)	O21—W5—O27	72.6 (3)
O37—Gd1—O52	72.9 (3)	O30—W5—O8	156.0 (4)
O40—Gd1—C57^ii	84.6 (3)	O30—W5—O21	87.2 (3)
O40—Gd1—K1^ii	95.5 (2)	O30—W5—O27	71.7 (3)
O40—Gd1—O51^ii	72.9 (3)	O9—W6—O22	83.4 (3)
O40—Gd1—O52^ii	95.4 (3)	O9—W6—O27	84.1 (3)
O51^ii—Gd1—C57^ii	25.8 (3)	O16—W6—O9	102.8 (3)
O51^ii—Gd1—K1^ii	42.07 (19)	O16—W6—O21	100.4 (4)
O51^ii—Gd1—O52^ii	51.7 (3)	O16—W6—O22	102.6 (4)
O52^ii—Gd1—C57^ii	26.0 (3)	O16—W6—O27	169.6 (4)
O52—Gd1—C57^ii	86.9 (3)	O16—W6—O31	102.1 (3)
O52—Gd1—K1^ii	146.9 (2)	O21—W6—O9	88.4 (3)
O52^ii—Gd1—K1^ii	82.6 (2)	O21—W6—O22	156.8 (3)
O52—Gd1—O40	75.4 (3)	O21—W6—O27	71.7 (3)
O52—Gd1—O51^ii	105.6 (3)	O22—W6—O27	85.8 (3)
O52—Gd1—O52^ii	67.0 (3)	O31—W6—O9	155.0 (3)
C54^i—K1—W8^ii	72.7 (2)	O31—W6—O21	89.6 (3)
C54^i—K1—W9^ii	119.7 (3)	O31—W6—O22	88.8 (3)
O24^ii—K1—C54^i	94.5 (3)	O31—W6—O27	71.6 (3)
O24^ii—K1—O33^ii	53.1 (2)	O10—W7—K2	46.4 (3)
O24^ii—K1—O36^ii	65.3 (2)	O10—W7—O23	84.5 (3)
O24^ii—K1—W8^ii	28.38 (15)	O10—W7—O28	82.6 (3)
O24^ii—K1—W9^ii	29.56 (16)	O17—W7—K2	81.3 (3)
O33^ii—K1—C54^i	71.2 (3)	O17—W7—O10	102.7 (4)
O33^ii—K1—W8^ii	28.58 (15)	O17—W7—O22	103.7 (4)
O33^ii—K1—W9^ii	79.01 (17)	O17—W7—O23	100.1 (4)
O34^ii—K1—C54^i	146.0 (3)	O17—W7—O28	169.1 (4)
O34^ii—K1—O24^ii	53.3 (2)	O17—W7—O32	103.2 (4)
O34^ii—K1—O33^ii	92.7 (2)	O22—W7—K2	129.7 (2)
O34^ii—K1—O36^ii	60.1 (2)	O22—W7—O10	84.6 (3)
O34^ii—K1—O57^i	125.0 (3)	O22—W7—O23	155.5 (3)
O34^ii—K1—W8^ii	79.16 (17)	O22—W7—O28	86.2 (3)
O34^ii—K1—W9^ii	26.35 (15)	O23—W7—K2	48.6 (2)
O36^ii—K1—C54^i	120.6 (3)	O23—W7—O28	70.6 (3)
O36^ii—K1—O33^ii	51.6 (2)	O28—W7—K2	95.9 (2)
O36^ii—K1—W8^ii	64.83 (16)	O32—W7—K2	136.2 (3)
O36^ii—K1—W9^ii	67.68 (16)	O32—W7—O10	154.0 (3)
O42^i—K1—C54^i	42.9 (3)	O32—W7—O22	92.1 (3)
O42^i—K1—O24^ii	80.8 (3)	O32—W7—O23	88.2 (3)
O42^i—K1—O33^ii	94.9 (3)	O32—W7—O28	71.5 (3)
O42^i—K1—O34^ii	112.7 (3)	K1^ii—W8—K2	170.45 (12)
O42^i—K1—O36^ii	142.1 (3)	O11—W8—K1^ii	133.2 (2)
O42^i—K1—O45^i	60.6 (3)	O11—W8—K2	48.6 (2)
O42^i—K1—O57^i	70.2 (3)	O11—W8—O23	87.3 (3)
O42^i—K1—W8^ii	77.35 (19)	O11—W8—O24	85.3 (3)
O42^i—K1—W9^ii	91.4 (2)	O11—W8—O28	86.1 (3)
O45^i—K1—C54^i	102.4 (3)	O11—W8—O33	158.1 (4)
O45^i—K1—O24^ii	83.7 (3)	O18—W8—K1^ii	83.9 (3)
O45^i—K1—O33^ii	134.4 (3)	O18—W8—K2	86.5 (3)
O45^i—K1—O34^ii	67.3 (3)	O18—W8—O11	102.0 (4)
O45^i—K1—O36^ii	127.4 (3)	O18—W8—O23	100.9 (4)
O45^i—K1—O57^i	69.0 (3)	O18—W8—O24	102.4 (4)
O45^i—K1—W8^ii	105.9 (2)	O18—W8—O28	169.7 (3)
O45^i—K1—W9^ii	65.1 (2)	O18—W8—O33	99.9 (4)
O51—K1—C54^i	149.1 (3)	O23—W8—K1^ii	137.7 (2)
O51—K1—O24^ii	111.8 (3)	O23—W8—K2	45.3 (2)
O51—K1—O33^ii	111.3 (3)	O23—W8—O24	156.6 (4)
O51—K1—O34^ii	64.3 (2)	O23—W8—O28	72.9 (3)
O51—K1—O36^ii	61.5 (2)	O23—W8—O33	88.0 (3)
O51—K1—O42^i	153.6 (3)	O24—W8—K1^ii	48.5 (2)
O51—K1—O45^i	96.7 (3)	O24—W8—K2	133.8 (3)
O51—K1—O60	86.4 (3)	O24—W8—O28	84.4 (3)
O51—K1—O57^i	89.8 (3)	O28—W8—K1^ii	95.17 (18)
O51—K1—W8^ii	124.9 (2)	O28—W8—K2	94.3 (2)
O51—K1—W9^ii	90.3 (2)	O33—W8—K1^ii	50.1 (2)
O60—K1—C54^i	64.9 (3)	O33—W8—K2	132.9 (2)
O60—K1—O24^ii	123.5 (3)	O33—W8—O24	90.6 (3)
O60—K1—O33^ii	70.4 (3)	O33—W8—O28	72.1 (3)
O60—K1—O34^ii	138.7 (3)	O12—W9—K1^ii	131.8 (2)
O60—K1—O36^ii	80.8 (3)	O12—W9—O26	82.7 (3)
O60—K1—O42^i	106.3 (3)	O19—W9—K1^ii	89.1 (3)
O60—K1—O45^i	149.3 (3)	O19—W9—O12	96.6 (3)
O60—K1—O57^i	80.5 (4)	O19—W9—O24	102.3 (4)
O60—K1—W8^ii	97.0 (2)	O19—W9—O25	99.8 (4)
O60—K1—W9^ii	145.6 (3)	O19—W9—O26	172.1 (4)
O57^i—K1—C54^i	74.9 (4)	O19—W9—O34	101.8 (4)
O57^i—K1—O24^ii	147.2 (3)	O24—W9—K1^ii	50.6 (2)
O57^i—K1—O33^ii	142.2 (3)	O24—W9—O12	81.5 (3)
O57^i—K1—O36^ii	146.6 (3)	O24—W9—O25	155.0 (3)
O57^i—K1—W8^ii	145.1 (3)	O24—W9—O26	85.4 (3)
O57^i—K1—W9^ii	133.8 (3)	O25—W9—K1^ii	141.6 (2)
W9^ii—K1—W8^ii	57.70 (5)	O25—W9—O12	84.5 (3)
C50—K2—W2	151.6 (3)	O25—W9—O26	72.3 (3)
C50—K2—W3	115.7 (3)	O26—W9—K1^ii	97.25 (19)
C50—K2—W7	96.1 (3)	O34—W9—K1^ii	47.7 (3)
C50—K2—W8	72.8 (3)	O34—W9—O12	161.5 (3)
O4—K2—C50	143.9 (4)	O34—W9—O24	92.8 (3)
O4—K2—O11	52.6 (2)	O34—W9—O25	93.9 (3)
O4—K2—O48	147.6 (3)	O34—W9—O26	79.3 (3)
O4—K2—W2	30.10 (17)	O28—W10—K1^ii	94.20 (18)
O4—K2—W3	28.24 (17)	O32—W10—K1^ii	132.7 (2)
O4—K2—W7	80.7 (2)	O32—W10—O28	69.6 (3)
O4—K2—W8	77.4 (2)	O33—W10—K1^ii	50.0 (2)
O10—K2—C50	124.6 (4)	O33—W10—O28	70.5 (3)
O10—K2—O4	54.6 (3)	O33—W10—O32	82.9 (3)
O10—K2—O11	64.0 (3)	O35—W10—K1^ii	140.2 (2)
O10—K2—O23	53.3 (3)	O35—W10—O28	84.4 (3)
O10—K2—O48	95.1 (3)	O35—W10—O32	84.0 (3)
O10—K2—W2	29.57 (18)	O35—W10—O33	154.5 (3)
O10—K2—W3	65.1 (2)	O36—W10—K1^ii	47.0 (3)
O10—K2—W7	29.22 (18)	O36—W10—O28	87.5 (3)
O10—K2—W8	64.3 (2)	O36—W10—O32	157.1 (3)
O11—K2—C50	92.9 (3)	O36—W10—O33	90.4 (3)
O11—K2—O48	107.1 (3)	O36—W10—O35	93.3 (4)
O11—K2—W2	66.3 (2)	O38—W10—K1^ii	88.7 (3)
O11—K2—W3	27.66 (16)	O38—W10—O28	166.1 (3)
O11—K2—W7	66.90 (19)	O38—W10—O32	98.5 (3)
O11—K2—W8	28.15 (16)	O38—W10—O33	101.6 (4)
O23—K2—C50	72.4 (3)	O38—W10—O35	101.9 (4)
O23—K2—O4	90.1 (3)	O38—W10—O36	104.3 (4)
O23—K2—O11	52.4 (2)	O30—W11—O27	69.7 (3)
O23—K2—O48	59.5 (3)	O30—W11—O31	83.1 (3)
O23—K2—W2	79.5 (2)	O31—W11—O27	69.9 (3)
O23—K2—W3	76.8 (2)	O35—W11—O27	84.6 (3)
O23—K2—W7	29.74 (17)	O35—W11—O30	154.1 (3)
O23—K2—W8	27.60 (16)	O35—W11—O31	85.4 (3)
O48—K2—C50	41.9 (3)	O37—W11—O27	87.3 (3)
O48—K2—W2	123.6 (3)	O37—W11—O30	90.9 (4)
O48—K2—W3	134.4 (3)	O37—W11—O31	157.1 (3)
O48—K2—W7	67.3 (2)	O37—W11—O35	90.8 (4)
O48—K2—W8	79.0 (2)	O39—W11—O27	166.2 (3)
O56—K2—C50	114.3 (6)	O39—W11—O30	101.9 (4)
O56—K2—O4	100.0 (6)	O39—W11—O31	98.8 (3)
O56—K2—O10	73.0 (5)	O39—W11—O35	102.8 (4)
O56—K2—O11	136.9 (6)	O39—W11—O37	104.0 (4)

Symmetry codes: (i) −x+1/2, −y+1/2, −z+1/2; (ii) −x+1/2, −y+3/2, −z+1/2.

(fhsp22a)

Crystal data

K2{[Cu2(H2O)(C12H8N2)2(C2H3O2)2]4[Tb2(H2O)2(C2H3O2)2 (AsW11O39)2]}·22H2O	F(000) = 16008
Mr = 8824.95	Dx = 2.996 Mg m^−3
Monoclinic, I2/a	Mo Kα radiation, λ = 0.71073 Å
a = 30.4415 (7) Å	Cell parameters from 27392 reflections
b = 14.0792 (3) Å	θ = 3.1–28.5°
c = 48.0609 (14) Å	µ = 14.92 mm^−1
β = 108.235 (3)°	T = 133 K
V = 19564.1 (9) Å^3	Block, blue
Z = 4	0.09 × 0.07 × 0.01 mm

Data collection

Agulent Xcalibur Sapphire3 diffractometer	18532 independent reflections
Radiation source: Enhance (Mo) X-ray Source	14576 reflections with I > 2σ(I)
Detector resolution: 15.9853 pixels mm^-1	Rint = 0.097
ω scans	θmax = 25.7°, θmin = 2.8°
Absorption correction: multi-scan (CrysAlis PRO; Agilent, 2013)	h = −37→37
Tmin = 0.336, Tmax = 1.000	k = −17→17
130000 measured reflections	l = −58→58

Refinement

Refinement on F^2	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.046	w = 1/[σ^2(Fo^2) + (0.0224P)^2 + 707.2657P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.098	(Δ/σ)max = 0.001
S = 1.06	Δρmax = 3.37 e Å^−3
18532 reflections	Δρmin = −1.28 e Å^−3
683 parameters	Extinction correction: SHELXL2017 (Sheldrick, 2015), Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
0 restraints	Extinction coefficient: 0.0000070 (6)

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
C1	0.1011 (4)	1.1969 (9)	0.1273 (3)	0.016 (3)*
H1	0.123951	1.205143	0.118429	0.020*
C2	0.1133 (5)	1.2033 (9)	0.1579 (3)	0.022 (3)*
H2	0.143624	1.216781	0.168936	0.027*
C3	0.0812 (5)	1.1898 (9)	0.1710 (3)	0.026 (3)*
H3	0.088952	1.193487	0.191317	0.031*
C4	0.0356 (5)	1.1702 (10)	0.1539 (3)	0.026 (3)*
C5	−0.0027 (5)	1.1580 (10)	0.1665 (4)	0.034 (4)*
H5	0.003133	1.161554	0.186687	0.041*
C6	−0.0458 (5)	1.1418 (11)	0.1487 (3)	0.035 (4)*
H6	−0.069527	1.132540	0.156714	0.042*
C7	−0.0561 (5)	1.1384 (10)	0.1172 (3)	0.027 (3)*
C8	−0.1010 (5)	1.1261 (11)	0.0974 (4)	0.036 (4)*
H8	−0.126450	1.120704	0.104086	0.043*
C9	−0.1063 (5)	1.1221 (10)	0.0682 (3)	0.032 (4)*
H9	−0.135361	1.111325	0.054734	0.039*
C10	−0.0685 (4)	1.1342 (9)	0.0587 (3)	0.022 (3)*
H10	−0.073087	1.132742	0.038692	0.026*
C11	−0.0199 (4)	1.1506 (9)	0.1057 (3)	0.021 (3)*
C12	0.0261 (4)	1.1663 (9)	0.1240 (3)	0.019 (3)*
C13	−0.0859 (4)	1.3656 (9)	0.0243 (3)	0.023 (3)*
H13	−0.080573	1.362686	0.006249	0.027*
C14	−0.1315 (5)	1.3613 (10)	0.0245 (3)	0.027 (3)*
H14	−0.155988	1.357901	0.007116	0.033*
C15	−0.1392 (5)	1.3623 (10)	0.0506 (3)	0.030 (3)*
H15	−0.169372	1.357651	0.051198	0.035*
C16	−0.1027 (4)	1.3702 (9)	0.0767 (3)	0.021 (3)*
C17	−0.1063 (5)	1.3735 (10)	0.1061 (3)	0.029 (3)*
H17	−0.135093	1.368466	0.108808	0.035*
C18	−0.0690 (5)	1.3837 (10)	0.1288 (3)	0.032 (4)*
H18	−0.072371	1.384015	0.147376	0.038*
C19	−0.0236 (5)	1.3943 (9)	0.1265 (3)	0.023 (3)*
C20	0.0170 (5)	1.4065 (10)	0.1501 (3)	0.032 (4)*
H20	0.016257	1.406266	0.169256	0.038*
C21	0.0575 (5)	1.4186 (10)	0.1442 (3)	0.029 (3)*
H21	0.084380	1.431051	0.159560	0.035*
C22	0.0596 (5)	1.4129 (9)	0.1166 (3)	0.022 (3)*
H22	0.088072	1.419891	0.113474	0.026*
C23	−0.0189 (4)	1.3891 (9)	0.0989 (3)	0.018 (3)*
C24	−0.0587 (4)	1.3758 (9)	0.0736 (3)	0.019 (3)*
C25	0.0015 (4)	1.2183 (9)	0.0075 (3)	0.018 (3)*
C26	−0.0068 (5)	1.1917 (10)	−0.0232 (3)	0.030 (3)*
H26A	−0.038978	1.199902	−0.033858	0.045*
H26B	0.001660	1.126388	−0.024214	0.045*
H26C	0.011465	1.231238	−0.031530	0.045*
C27	0.1061 (5)	1.2814 (10)	0.0623 (3)	0.024 (3)*
C28	0.1575 (5)	1.2936 (11)	0.0664 (4)	0.040 (4)*
H28A	0.172193	1.232467	0.068892	0.060*
H28B	0.171387	1.331715	0.083512	0.060*
H28C	0.161395	1.324420	0.049543	0.060*
C29	0.2868 (4)	0.3872 (9)	0.1078 (3)	0.021 (3)*
H29	0.265346	0.393249	0.117875	0.026*
C30	0.2708 (5)	0.3752 (10)	0.0780 (3)	0.029 (3)*
H30	0.239232	0.373300	0.068143	0.035*
C31	0.3018 (5)	0.3662 (10)	0.0632 (4)	0.032 (4)*
H31	0.291292	0.358510	0.042919	0.039*
C32	0.3492 (5)	0.3682 (10)	0.0777 (3)	0.030 (3)*
C33	0.3844 (5)	0.3579 (11)	0.0644 (4)	0.040 (4)*
H33	0.376593	0.349668	0.044283	0.048*
C34	0.4300 (5)	0.3599 (11)	0.0813 (3)	0.034 (4)*
H34	0.452636	0.355212	0.072128	0.041*
C35	0.4437 (5)	0.3687 (10)	0.1122 (3)	0.024 (3)*
C36	0.4887 (5)	0.3640 (10)	0.1304 (3)	0.030 (4)*
H36	0.512401	0.351978	0.122505	0.036*
C37	0.4988 (5)	0.3765 (10)	0.1592 (3)	0.031 (4)*
H37	0.529298	0.374163	0.171341	0.037*
C38	0.4628 (5)	0.3933 (10)	0.1712 (3)	0.026 (3)*
H38	0.469772	0.403588	0.191203	0.031*
C39	0.4093 (5)	0.3805 (9)	0.1250 (3)	0.023 (3)*
C40	0.3618 (5)	0.3818 (9)	0.1078 (3)	0.023 (3)*
C41	0.3328 (5)	0.1610 (10)	0.1239 (3)	0.028 (3)*
H41	0.304637	0.172689	0.127054	0.033*
C42	0.3323 (6)	0.1362 (11)	0.0972 (4)	0.042 (4)*
H42	0.304376	0.131680	0.082142	0.051*
C43	0.3736 (5)	0.1171 (11)	0.0915 (4)	0.038 (4)*
H43	0.373428	0.101008	0.072695	0.045*
C44	0.4141 (5)	0.1221 (10)	0.1138 (3)	0.032 (4)*
C45	0.4594 (6)	0.1060 (12)	0.1110 (4)	0.047 (5)*
H45	0.462600	0.093563	0.092703	0.057*
C46	0.4981 (6)	0.1091 (12)	0.1358 (4)	0.048 (5)*
H46	0.526582	0.092441	0.133955	0.058*
C47	0.4962 (5)	0.1355 (11)	0.1626 (4)	0.037 (4)*
C48	0.5340 (6)	0.1428 (12)	0.1882 (4)	0.048 (5)*
H48	0.563406	0.128045	0.187515	0.058*
C49	0.5288 (6)	0.1703 (12)	0.2136 (4)	0.046 (4)*
H49	0.554431	0.174426	0.230327	0.055*
C50	0.4848 (5)	0.1928 (11)	0.2151 (4)	0.040 (4)*
H50	0.481328	0.212933	0.232683	0.048*
C51	0.4520 (5)	0.1552 (11)	0.1654 (3)	0.032 (4)*
C52	0.4122 (5)	0.1483 (11)	0.1414 (3)	0.032 (4)*
C53	0.4045 (6)	0.3735 (13)	0.2273 (4)	0.046 (4)*
C54	0.4264 (9)	0.4090 (19)	0.2574 (6)	0.110 (9)*
H54A	0.403441	0.415633	0.267159	0.165*
H54B	0.440480	0.469606	0.256682	0.165*
H54C	0.449689	0.364830	0.268056	0.165*
C55	0.2918 (5)	0.3000 (10)	0.1789 (3)	0.023 (3)*
C56	0.2436 (5)	0.2912 (10)	0.1819 (3)	0.031 (4)*
H56A	0.218549	0.292442	0.163505	0.037*
H56B	0.237636	0.332906	0.196366	0.037*
C57	0.2404 (4)	0.5859 (9)	0.2405 (3)	0.016 (3)*
C58	0.2491 (5)	0.5124 (10)	0.2199 (3)	0.026 (3)*
H58A	0.246727	0.541692	0.201427	0.039*
H58B	0.226492	0.462607	0.216886	0.039*
H58C	0.279472	0.486133	0.228191	0.039*
As1	0.20425 (4)	0.79604 (8)	0.12521 (3)	0.0094 (3)
Cu1	0.03261 (5)	1.16373 (11)	0.06744 (3)	0.0175 (3)
Cu2	0.01663 (5)	1.36935 (11)	0.05201 (4)	0.0183 (4)
Cu3	0.36120 (5)	0.41092 (11)	0.16541 (4)	0.0216 (4)
Cu4	0.38077 (6)	0.20964 (12)	0.18759 (4)	0.0260 (4)
K1	0.1483 (2)	1.0669 (5)	0.03779 (15)	0.0132 (14)*	0.4
K2	0.28090 (14)	1.0708 (3)	0.20675 (9)	0.0104 (9)*	0.6
N1	0.0585 (4)	1.1798 (7)	0.1108 (2)	0.019 (2)*
N2	−0.0265 (4)	1.1475 (7)	0.0764 (2)	0.020 (2)*
N3	−0.0502 (3)	1.3733 (7)	0.0478 (2)	0.016 (2)*
N4	0.0228 (4)	1.3978 (7)	0.0939 (2)	0.019 (2)*
N5	0.3306 (4)	0.3905 (8)	0.1228 (2)	0.023 (3)*
N6	0.4183 (4)	0.3948 (8)	0.1540 (3)	0.024 (3)*
N7	0.3715 (4)	0.1699 (8)	0.1465 (3)	0.023 (3)*
N8	0.4476 (4)	0.1856 (8)	0.1911 (3)	0.027 (3)*
O1	0.0541 (3)	1.0062 (6)	0.07555 (18)	0.0144 (19)*
O2	0.2263 (3)	1.1622 (6)	0.1213 (2)	0.021 (2)*
O3	0.1405 (3)	1.0007 (6)	0.19563 (19)	0.021 (2)*
O4	0.1062 (3)	0.9745 (6)	0.13333 (18)	0.0157 (19)*
O5	0.1892 (3)	1.0517 (6)	0.15583 (18)	0.0148 (19)*
O6	0.1482 (3)	1.0499 (6)	0.09849 (19)	0.0171 (19)*
O7	0.1328 (3)	0.8233 (6)	0.16639 (18)	0.0157 (19)*
O8	0.0850 (3)	0.8234 (6)	0.09823 (18)	0.0144 (19)*
O9	0.1272 (3)	0.8993 (6)	0.06549 (19)	0.0163 (19)*
O10	0.2255 (3)	0.9908 (6)	0.09053 (19)	0.0166 (19)*
O11	0.2672 (3)	0.9893 (6)	0.14617 (18)	0.0138 (18)*
O12	0.2152 (3)	0.9022 (6)	0.19071 (19)	0.020 (2)*
O13	0.1785 (3)	0.8999 (5)	0.12760 (18)	0.0125 (18)*
O14	0.3645 (3)	0.9585 (6)	0.16059 (19)	0.020 (2)*
O15	0.2862 (3)	0.9604 (6)	0.05745 (19)	0.020 (2)*
O16	0.1112 (3)	0.8076 (6)	0.0120 (2)	0.022 (2)*
O17	0.0363 (3)	0.6518 (6)	0.07640 (18)	0.0160 (19)*
O18	0.1190 (3)	0.6537 (6)	0.19604 (19)	0.018 (2)*
O19	0.2966 (3)	0.8820 (6)	0.11212 (18)	0.0137 (18)*
O20	0.1974 (3)	0.8814 (6)	0.04414 (19)	0.0169 (19)*
O21	0.1173 (3)	0.7193 (6)	0.06560 (18)	0.0130 (18)*
O22	0.0907 (3)	0.6777 (6)	0.13416 (18)	0.0141 (19)*
O23	0.2034 (3)	0.7111 (6)	0.19116 (19)	0.0169 (19)*
O24	0.3140 (3)	0.8842 (6)	0.19282 (18)	0.0143 (18)*
O25	0.2550 (3)	0.7866 (5)	0.15098 (18)	0.0124 (18)*
O26	0.1683 (3)	0.7098 (5)	0.12809 (18)	0.0122 (18)*
O27	0.2099 (3)	0.7907 (6)	0.09179 (18)	0.0161 (19)*
O28	0.1875 (3)	0.4286 (6)	0.12476 (19)	0.019 (2)*
O29	0.2630 (3)	0.5746 (6)	0.05772 (19)	0.019 (2)*
O30	0.3443 (3)	0.5668 (6)	0.16076 (19)	0.0168 (19)*
O31	0.1617 (3)	0.5666 (6)	0.15712 (18)	0.0154 (19)*
O32	0.1221 (3)	0.5704 (6)	0.09993 (19)	0.019 (2)*
O33	0.1857 (3)	0.6943 (6)	0.04444 (18)	0.0144 (18)*
O34	0.2689 (3)	0.7701 (6)	0.06446 (19)	0.0168 (19)*
O35	0.3396 (3)	0.7663 (6)	0.15614 (19)	0.0165 (19)*
O36	0.3047 (3)	0.6734 (6)	0.19341 (18)	0.0136 (18)*
O37	0.2456 (3)	0.5840 (6)	0.14774 (19)	0.0161 (19)*
O38	0.2033 (3)	0.5837 (6)	0.09203 (19)	0.0157 (19)*
O39	0.2837 (3)	0.6631 (6)	0.11250 (18)	0.0133 (18)*
O40	0.3488 (3)	0.7699 (6)	0.2483 (2)	0.026 (2)*
O41	0.2646 (3)	0.6610 (6)	0.24600 (18)	0.0148 (19)*
O42	0.2119 (3)	0.5697 (6)	0.25360 (19)	0.020 (2)*
O43	0.0029 (3)	1.1521 (6)	0.0258 (2)	0.026 (2)*
O44	0.0061 (3)	1.3043 (6)	0.0144 (2)	0.023 (2)*
O45	0.0899 (3)	1.2006 (6)	0.0610 (2)	0.022 (2)*
O46	0.0835 (3)	1.3573 (6)	0.0618 (2)	0.024 (2)*
O47	0.0194 (3)	1.5071 (7)	0.0307 (2)	0.039 (3)*
O48	0.3970 (3)	0.4315 (7)	0.2062 (2)	0.033 (2)*
O49	0.3969 (3)	0.2835 (7)	0.2237 (2)	0.037 (3)*
O50	0.3052 (3)	0.3823 (7)	0.1747 (2)	0.028 (2)*
O51	0.3146 (3)	0.2259 (7)	0.1811 (2)	0.027 (2)*
O52	0.3778 (3)	0.0748 (7)	0.2106 (2)	0.034 (3)*
O53	0.2037 (4)	1.1463 (8)	0.2248 (3)	0.054 (3)*
O54	0.4133 (5)	0.7668 (10)	0.2126 (3)	0.073 (4)*
O55	0.4564 (4)	0.5975 (8)	0.2100 (3)	0.055 (3)*
O56	0.1765 (5)	0.4084 (9)	0.0084 (3)	0.069 (4)*
O57	−0.1216 (3)	1.4834 (7)	−0.0373 (2)	0.037 (3)*
O58	0.250000	0.5067 (11)	0.000000	0.041 (4)*
O59	−0.250000	1.2846 (13)	0.000000	0.068 (5)*
Tb1	0.27073 (2)	0.79058 (4)	0.21489 (2)	0.01308 (13)
W1	0.10373 (2)	0.94926 (4)	0.09563 (2)	0.01344 (12)
W2	0.21120 (2)	1.04637 (4)	0.12292 (2)	0.01265 (11)
W3	0.16052 (2)	0.94518 (4)	0.17008 (2)	0.01318 (12)
W4	0.31518 (2)	0.89325 (3)	0.15631 (2)	0.01164 (11)
W5	0.25636 (2)	0.89585 (4)	0.07507 (2)	0.01283 (12)
W6	0.14835 (2)	0.80083 (4)	0.04650 (2)	0.01304 (12)
W7	0.09091 (2)	0.68701 (4)	0.09572 (2)	0.01274 (12)
W8	0.14503 (2)	0.68856 (4)	0.17040 (2)	0.01271 (12)
W9	0.18512 (2)	0.54845 (4)	0.12555 (2)	0.01248 (11)
W10	0.24163 (2)	0.65719 (4)	0.07579 (2)	0.01307 (12)
W11	0.30329 (2)	0.65419 (4)	0.15689 (2)	0.01199 (11)
O1AA	0.1654 (5)	1.3000 (9)	0.2458 (3)	0.067 (4)*
O0AA	0.3655 (6)	0.5829 (11)	0.2506 (4)	0.096 (5)*
O2AA	0.0602 (8)	1.0126 (16)	0.0061 (5)	0.159 (9)*
O3AA	0.5447 (6)	0.5367 (12)	0.2380 (4)	0.101 (5)*
O4AA	0.1169 (5)	1.4507 (11)	0.2154 (4)	0.088 (5)*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
As1	0.0084 (6)	0.0111 (6)	0.0093 (6)	0.0008 (5)	0.0038 (5)	0.0006 (5)
Cu1	0.0200 (8)	0.0168 (9)	0.0136 (9)	0.0014 (7)	0.0020 (7)	0.0030 (7)
Cu2	0.0189 (8)	0.0182 (9)	0.0170 (9)	0.0007 (7)	0.0046 (7)	0.0031 (7)
Cu3	0.0207 (9)	0.0214 (9)	0.0251 (10)	0.0030 (7)	0.0105 (8)	0.0016 (7)
Cu4	0.0192 (9)	0.0243 (10)	0.0333 (11)	0.0026 (7)	0.0066 (8)	0.0029 (8)
Tb1	0.0145 (3)	0.0145 (3)	0.0100 (3)	0.0011 (2)	0.0035 (2)	−0.0003 (2)
W1	0.0119 (2)	0.0154 (3)	0.0122 (3)	0.0028 (2)	0.0026 (2)	0.0026 (2)
W2	0.0132 (2)	0.0125 (3)	0.0114 (3)	0.0006 (2)	0.0025 (2)	0.0006 (2)
W3	0.0123 (2)	0.0171 (3)	0.0097 (3)	0.0033 (2)	0.0028 (2)	−0.0003 (2)
W4	0.0111 (2)	0.0126 (3)	0.0111 (3)	−0.0009 (2)	0.0034 (2)	0.0000 (2)
W5	0.0138 (3)	0.0151 (3)	0.0105 (3)	−0.0023 (2)	0.0051 (2)	−0.0001 (2)
W6	0.0139 (2)	0.0169 (3)	0.0079 (3)	−0.0004 (2)	0.0029 (2)	0.0006 (2)
W7	0.0098 (2)	0.0157 (3)	0.0125 (3)	−0.0016 (2)	0.0032 (2)	0.0002 (2)
W8	0.0119 (2)	0.0170 (3)	0.0091 (3)	−0.0007 (2)	0.0031 (2)	0.0008 (2)
W9	0.0117 (2)	0.0128 (3)	0.0126 (3)	−0.0007 (2)	0.0032 (2)	0.0008 (2)
W10	0.0132 (2)	0.0164 (3)	0.0105 (3)	−0.0006 (2)	0.0049 (2)	−0.0026 (2)
W11	0.0114 (2)	0.0137 (3)	0.0112 (3)	0.0024 (2)	0.0039 (2)	0.0001 (2)

Geometric parameters (Å, º)

C1—C2	1.400 (18)	Cu3—O50	1.935 (9)
C1—N1	1.313 (15)	Cu4—K2^i	3.958 (4)
C2—C3	1.333 (17)	Cu4—N7	1.983 (11)
C3—C4	1.403 (19)	Cu4—N8	2.017 (11)
C4—C5	1.482 (19)	Cu4—O49	1.951 (11)
C4—C12	1.376 (18)	Cu4—O51	1.954 (9)
C5—C6	1.34 (2)	Cu4—O52	2.214 (10)
C6—C7	1.44 (2)	K1—O6	2.928 (11)
C7—C8	1.41 (2)	K1—O9	2.879 (10)
C7—C11	1.390 (18)	K1—O10	3.061 (11)
C8—C9	1.36 (2)	K1—O20	2.977 (10)
C9—C10	1.372 (18)	K1—O45	3.030 (11)
C10—N2	1.309 (16)	K1—W1	3.830 (6)
C11—C12	1.417 (18)	K1—W2	3.948 (7)
C11—N2	1.362 (17)	K1—W5	4.018 (6)
C12—N1	1.342 (15)	K1—W6	3.769 (6)
C13—C14	1.394 (18)	K1—O2AA	2.74 (2)
C13—N3	1.307 (16)	K2—O5	3.094 (9)
C14—C15	1.344 (19)	K2—O11	3.034 (9)
C15—C16	1.398 (19)	K2—O12	3.044 (9)
C16—C17	1.448 (19)	K2—O24	2.964 (9)
C16—C24	1.396 (17)	K2—O42^ii	2.708 (10)
C17—C18	1.31 (2)	K2—O51^iii	2.851 (10)
C18—C19	1.428 (18)	K2—O52^iii	2.897 (10)
C19—C20	1.402 (19)	K2—O53	2.948 (12)
C19—C23	1.382 (18)	K2—W2	3.937 (4)
C20—C21	1.358 (18)	K2—W4	3.846 (4)
C21—C22	1.353 (19)	K2—O1AA^iv	2.975 (14)
C22—N4	1.312 (16)	O1—W1	1.716 (8)
C23—C24	1.433 (18)	O2—W2	1.702 (8)
C23—N4	1.367 (15)	O3—W3	1.721 (8)
C24—N3	1.343 (16)	O4—W1	1.825 (8)
C25—C26	1.465 (18)	O4—W3	2.049 (8)
C25—O43	1.272 (15)	O5—W2	1.901 (8)
C25—O44	1.252 (14)	O5—W3	1.964 (8)
C27—C28	1.526 (19)	O6—W1	1.935 (8)
C27—O45	1.232 (15)	O6—W2	1.910 (8)
C27—O46	1.267 (15)	O7—W3	1.895 (8)
C28—K1	3.453 (17)	O7—W8	1.932 (8)
C29—C30	1.373 (19)	O8—W1	1.878 (8)
C29—N5	1.301 (16)	O8—W7	1.936 (8)
C30—C31	1.356 (19)	O9—W1	1.936 (8)
C31—C32	1.393 (19)	O9—W6	1.881 (8)
C32—C33	1.414 (19)	O10—W2	1.910 (8)
C32—C40	1.391 (19)	O10—W5	1.913 (8)
C33—C34	1.37 (2)	O11—W2	1.900 (8)
C34—C35	1.41 (2)	O11—W4	1.937 (8)
C35—C36	1.377 (19)	O12—Tb1	2.334 (9)
C35—C39	1.383 (17)	O12—W3	1.757 (9)
C36—C37	1.33 (2)	O13—W1	2.417 (8)
C37—C38	1.407 (18)	O13—W2	2.331 (8)
C38—N6	1.346 (17)	O13—W3	2.362 (8)
C39—C40	1.425 (18)	O14—W4	1.717 (8)
C39—N6	1.349 (17)	O15—W5	1.688 (8)
C40—N5	1.364 (16)	O16—W6	1.693 (9)
C41—C42	1.33 (2)	O17—W7	1.706 (8)
C41—N7	1.337 (17)	O18—W8	1.732 (8)
C42—C43	1.39 (2)	O19—W4	2.026 (8)
C43—C44	1.36 (2)	O19—W5	1.828 (8)
C44—C45	1.44 (2)	O20—W5	1.950 (8)
C44—C52	1.40 (2)	O20—W6	1.907 (8)
C45—C46	1.39 (2)	O21—W6	1.897 (8)
C46—C47	1.36 (2)	O21—W7	1.917 (8)
C47—C48	1.40 (2)	O22—W7	1.854 (8)
C47—C51	1.42 (2)	O22—W8	1.997 (8)
C48—C49	1.34 (2)	O23—Tb1	2.299 (8)
C49—C50	1.40 (2)	O23—W8	1.774 (8)
C50—N8	1.342 (19)	O24—Tb1	2.339 (8)
C51—C52	1.39 (2)	O24—W4	1.771 (8)
C51—N8	1.354 (18)	O25—W4	2.319 (8)
C52—N7	1.373 (17)	O25—W11	2.335 (8)
C53—C54	1.48 (3)	O26—W7	2.403 (8)
C53—O48	1.266 (19)	O26—W8	2.372 (8)
C53—O49	1.289 (19)	O26—W9	2.341 (8)
C55—C56	1.522 (18)	O27—W5	2.355 (8)
C55—O50	1.266 (15)	O27—W6	2.391 (8)
C55—O51	1.239 (15)	O27—W10	2.349 (8)
C56—K2^i	3.391 (15)	O28—W9	1.689 (8)
C57—C58	1.513 (17)	O29—W10	1.698 (8)
C57—O41	1.269 (14)	O30—W11	1.721 (8)
C57—O42	1.241 (14)	O31—W8	1.953 (8)
C57—Tb1^ii	2.861 (12)	O31—W9	1.885 (8)
As1—O13	1.679 (8)	O32—W7	1.876 (8)
As1—O25	1.657 (8)	O32—W9	1.952 (9)
As1—O26	1.669 (8)	O33—W6	1.904 (8)
As1—O27	1.670 (8)	O33—W10	1.958 (8)
Cu1—Cu2	2.990 (2)	O34—W5	1.914 (8)
Cu1—N1	1.998 (11)	O34—W10	1.948 (8)
Cu1—N2	1.989 (10)	O35—W4	1.938 (8)
Cu1—O1	2.311 (8)	O35—W11	1.934 (8)
Cu1—O43	1.928 (10)	O36—Tb1	2.350 (8)
Cu1—O45	1.936 (9)	O36—W11	1.763 (8)
Cu2—N3	1.981 (10)	O37—W9	1.884 (8)
Cu2—N4	2.004 (11)	O37—W11	1.942 (8)
Cu2—O44	1.960 (9)	O38—W9	1.925 (8)
Cu2—O46	1.947 (9)	O38—W10	1.901 (8)
Cu2—O47	2.207 (10)	O39—W10	1.829 (8)
Cu3—Cu4	3.021 (2)	O39—W11	2.031 (8)
Cu3—N5	1.989 (12)	O40—Tb1	2.433 (9)
Cu3—N6	1.992 (11)	O41—Tb1	2.403 (8)
Cu3—O30	2.250 (8)	O41—Tb1^ii	2.534 (8)
Cu3—O48	1.945 (11)	O42—Tb1^ii	2.437 (9)
N1—C1—C2	122.1 (12)	W1—O8—W7	153.6 (4)
C3—C2—C1	119.7 (13)	W1—O9—K1	103.6 (3)
C2—C3—C4	119.1 (14)	W6—O9—K1	102.7 (3)
C3—C4—C5	122.8 (13)	W6—O9—W1	153.3 (5)
C12—C4—C3	117.9 (12)	W2—O10—K1	102.7 (3)
C12—C4—C5	119.2 (13)	W2—O10—W5	150.2 (5)
C6—C5—C4	119.5 (15)	W5—O10—K1	105.4 (4)
C5—C6—C7	121.6 (14)	W2—O11—K2	103.5 (3)
C8—C7—C6	124.0 (13)	W2—O11—W4	155.6 (5)
C11—C7—C6	118.2 (13)	W4—O11—K2	99.0 (3)
C11—C7—C8	117.9 (14)	Tb1—O12—K2	94.7 (3)
C9—C8—C7	118.6 (14)	W3—O12—K2	107.8 (4)
C8—C9—C10	119.6 (15)	W3—O12—Tb1	157.5 (5)
N2—C10—C9	123.7 (14)	As1—O13—W1	125.0 (4)
C7—C11—C12	121.7 (13)	As1—O13—W2	122.8 (4)
N2—C11—C7	122.0 (12)	As1—O13—W3	122.3 (4)
N2—C11—C12	116.3 (11)	W2—O13—W1	91.7 (3)
C4—C12—C11	119.8 (12)	W2—O13—W3	93.8 (3)
N1—C12—C4	122.7 (12)	W3—O13—W1	92.5 (3)
N1—C12—C11	117.4 (12)	W5—O19—W4	153.5 (4)
N3—C13—C14	123.9 (13)	W5—O20—K1	107.4 (4)
C15—C14—C13	118.1 (14)	W6—O20—K1	98.6 (3)
C14—C15—C16	121.2 (14)	W6—O20—W5	124.6 (4)
C15—C16—C17	126.7 (12)	W6—O21—W7	154.0 (5)
C24—C16—C15	115.4 (12)	W7—O22—W8	127.1 (4)
C24—C16—C17	118.0 (13)	W8—O23—Tb1	161.2 (5)
C18—C17—C16	120.3 (14)	Tb1—O24—K2	96.7 (3)
C17—C18—C19	123.5 (15)	W4—O24—K2	105.9 (3)
C20—C19—C18	125.5 (13)	W4—O24—Tb1	132.7 (4)
C23—C19—C18	117.6 (13)	As1—O25—W4	123.4 (4)
C23—C19—C20	116.9 (12)	As1—O25—W11	124.0 (4)
C21—C20—C19	118.5 (14)	W4—O25—W11	93.4 (3)
C22—C21—C20	121.3 (15)	As1—O26—W7	125.4 (4)
N4—C22—C21	122.3 (13)	As1—O26—W8	122.8 (4)
C19—C23—C24	120.4 (11)	As1—O26—W9	122.8 (4)
N4—C23—C19	122.9 (12)	W8—O26—W7	92.5 (3)
N4—C23—C24	116.7 (11)	W9—O26—W7	91.3 (3)
C16—C24—C23	120.2 (12)	W9—O26—W8	92.9 (3)
N3—C24—C16	124.4 (12)	As1—O27—W5	123.6 (4)
N3—C24—C23	115.3 (11)	As1—O27—W6	125.8 (4)
O43—C25—C26	117.7 (12)	As1—O27—W10	121.8 (4)
O44—C25—C26	119.0 (12)	W5—O27—W6	92.0 (3)
O44—C25—O43	123.3 (12)	W10—O27—W5	92.3 (3)
O45—C27—C28	119.2 (12)	W10—O27—W6	92.0 (3)
O45—C27—O46	124.9 (12)	W11—O30—Cu3	147.5 (4)
O46—C27—C28	115.8 (12)	W9—O31—W8	125.8 (4)
C27—C28—K1	83.7 (8)	W7—O32—W9	124.8 (5)
N5—C29—C30	123.2 (13)	W6—O33—W10	124.0 (4)
C31—C30—C29	118.9 (14)	W5—O34—W10	122.8 (4)
C30—C31—C32	121.1 (15)	W11—O35—W4	122.0 (4)
C31—C32—C33	125.7 (15)	W11—O36—Tb1	131.9 (4)
C40—C32—C31	115.4 (13)	W9—O37—W11	156.6 (5)
C40—C32—C33	118.9 (14)	W10—O38—W9	149.1 (5)
C34—C33—C32	120.1 (16)	W10—O39—W11	153.8 (4)
C33—C34—C35	122.3 (14)	C57—O41—Tb1	131.0 (8)
C36—C35—C34	124.9 (13)	C57—O41—Tb1^ii	91.4 (7)
C36—C35—C39	117.5 (13)	Tb1—O41—Tb1^ii	113.0 (3)
C39—C35—C34	117.5 (13)	C57—O42—K2^ii	125.1 (8)
C37—C36—C35	121.0 (14)	C57—O42—Tb1^ii	96.7 (7)
C36—C37—C38	119.4 (14)	Tb1^ii—O42—K2^ii	101.4 (3)
N6—C38—C37	121.0 (14)	C25—O43—Cu1	123.9 (9)
C35—C39—C40	121.1 (13)	C25—O44—Cu2	132.0 (9)
N6—C39—C35	122.9 (13)	C27—O45—Cu1	127.2 (9)
N6—C39—C40	116.0 (12)	C27—O45—K1	108.8 (8)
C32—C40—C39	120.0 (12)	Cu1—O45—K1	123.6 (4)
N5—C40—C32	123.5 (12)	C27—O46—Cu2	126.7 (9)
N5—C40—C39	116.4 (12)	C53—O48—Cu3	127.9 (11)
C42—C41—N7	123.5 (14)	C53—O49—Cu4	128.9 (11)
C41—C42—C43	120.2 (16)	C55—O50—Cu3	125.5 (9)
C44—C43—C42	119.3 (16)	C55—O51—Cu4	129.4 (9)
C43—C44—C45	125.2 (15)	C55—O51—K2^i	114.5 (8)
C43—C44—C52	117.7 (14)	Cu4—O51—K2^i	109.5 (4)
C52—C44—C45	117.1 (15)	Cu4—O52—K2^i	100.7 (4)
C46—C45—C44	119.5 (17)	C57^ii—Tb1—K2	60.2 (3)
C47—C46—C45	123.1 (17)	O12—Tb1—C57^ii	74.1 (3)
C46—C47—C48	125.8 (16)	O12—Tb1—K2	49.6 (2)
C46—C47—C51	117.6 (16)	O12—Tb1—O24	79.5 (3)
C48—C47—C51	116.5 (15)	O12—Tb1—O36	127.1 (3)
C49—C48—C47	121.6 (17)	O12—Tb1—O40	144.6 (3)
C48—C49—C50	120.0 (18)	O12—Tb1—O41	129.5 (3)
N8—C50—C49	120.3 (16)	O12—Tb1—O41^ii	77.2 (3)
C52—C51—C47	120.9 (14)	O12—Tb1—O42^ii	75.4 (3)
N8—C51—C47	120.9 (14)	O23—Tb1—C57^ii	111.8 (3)
N8—C51—C52	118.2 (13)	O23—Tb1—K2	121.2 (2)
C51—C52—C44	121.6 (14)	O23—Tb1—O12	71.7 (3)
N7—C52—C44	122.7 (14)	O23—Tb1—O24	126.2 (3)
N7—C52—C51	115.7 (14)	O23—Tb1—O36	83.5 (3)
O48—C53—C54	118.6 (18)	O23—Tb1—O40	143.5 (3)
O48—C53—O49	123.1 (17)	O23—Tb1—O41^ii	88.8 (3)
O49—C53—C54	118.1 (18)	O23—Tb1—O41	73.1 (3)
O50—C55—C56	117.3 (12)	O23—Tb1—O42^ii	133.4 (3)
O51—C55—C56	117.0 (12)	O24—Tb1—C57^ii	102.3 (3)
O51—C55—O50	125.7 (12)	O24—Tb1—K2	47.6 (2)
C55—C56—K2^i	83.2 (8)	O24—Tb1—O36	79.0 (3)
C58—C57—Tb1^ii	173.1 (9)	O24—Tb1—O40	78.1 (3)
O41—C57—C58	119.8 (11)	O24—Tb1—O41	151.0 (3)
O41—C57—Tb1^ii	62.3 (6)	O24—Tb1—O41^ii	127.9 (3)
O42—C57—C58	120.0 (11)	O24—Tb1—O42^ii	77.5 (3)
O42—C57—O41	120.0 (11)	O36—Tb1—C57^ii	158.0 (3)
O42—C57—Tb1^ii	57.8 (6)	O36—Tb1—K2	126.4 (2)
O25—As1—O13	111.4 (4)	O36—Tb1—O40	74.5 (3)
O25—As1—O26	111.3 (4)	O36—Tb1—O41^ii	149.5 (3)
O25—As1—O27	111.2 (4)	O36—Tb1—O41	82.6 (3)
O26—As1—O13	107.2 (4)	O36—Tb1—O42^ii	143.1 (3)
O26—As1—O27	108.3 (4)	O40—Tb1—C57^ii	84.2 (3)
O27—As1—O13	107.2 (4)	O40—Tb1—K2	95.4 (2)
N1—Cu1—Cu2	97.4 (3)	O40—Tb1—O41^ii	95.6 (3)
N1—Cu1—O1	86.2 (4)	O40—Tb1—O42^ii	73.1 (3)
N2—Cu1—Cu2	94.4 (3)	O41^ii—Tb1—C57^ii	26.3 (3)
N2—Cu1—N1	82.9 (4)	O41—Tb1—C57^ii	86.9 (3)
N2—Cu1—O1	94.6 (4)	O41—Tb1—K2	146.7 (2)
O1—Cu1—Cu2	170.6 (2)	O41^ii—Tb1—K2	82.55 (19)
O43—Cu1—Cu2	80.7 (3)	O41—Tb1—O40	75.4 (3)
O43—Cu1—N1	175.3 (4)	O41—Tb1—O41^ii	67.0 (3)
O43—Cu1—N2	93.0 (4)	O41—Tb1—O42^ii	105.7 (3)
O43—Cu1—O1	96.3 (3)	O42^ii—Tb1—C57^ii	25.5 (3)
O43—Cu1—O45	90.6 (4)	O42^ii—Tb1—K2	41.7 (2)
O45—Cu1—Cu2	77.6 (3)	O42^ii—Tb1—O41^ii	51.8 (3)
O45—Cu1—N1	93.2 (4)	O1—W1—K1	80.7 (3)
O45—Cu1—N2	170.6 (4)	O1—W1—O4	102.9 (4)
O45—Cu1—O1	93.6 (3)	O1—W1—O6	99.9 (4)
N3—Cu2—Cu1	97.7 (3)	O1—W1—O8	104.2 (4)
N3—Cu2—N4	82.3 (4)	O1—W1—O9	102.4 (4)
N3—Cu2—O47	96.6 (4)	O1—W1—O13	168.7 (3)
N4—Cu2—Cu1	89.3 (3)	O4—W1—K1	136.3 (3)
N4—Cu2—O47	106.6 (4)	O4—W1—O6	88.7 (4)
O44—Cu2—Cu1	75.1 (3)	O4—W1—O8	92.1 (4)
O44—Cu2—N3	93.0 (4)	O4—W1—O9	154.6 (4)
O44—Cu2—N4	163.0 (4)	O4—W1—O13	71.8 (3)
O44—Cu2—O47	90.2 (4)	O6—W1—K1	48.4 (3)
O46—Cu2—Cu1	77.2 (3)	O6—W1—O9	84.6 (3)
O46—Cu2—N3	171.6 (4)	O6—W1—O13	70.5 (3)
O46—Cu2—N4	90.8 (4)	O8—W1—K1	129.8 (3)
O46—Cu2—O44	92.2 (4)	O8—W1—O6	155.1 (3)
O46—Cu2—O47	90.0 (4)	O8—W1—O9	84.1 (3)
O47—Cu2—Cu1	159.9 (3)	O8—W1—O13	86.1 (3)
N5—Cu3—Cu4	101.8 (3)	O9—W1—K1	46.9 (3)
N5—Cu3—N6	82.5 (5)	O9—W1—O13	82.9 (3)
N5—Cu3—O30	91.1 (4)	O13—W1—K1	96.2 (2)
N6—Cu3—Cu4	84.1 (3)	K2—W2—K1	170.20 (11)
N6—Cu3—O30	106.0 (4)	O2—W2—K1	86.1 (3)
O30—Cu3—Cu4	164.6 (2)	O2—W2—K2	84.1 (3)
O48—Cu3—Cu4	78.3 (3)	O2—W2—O5	99.9 (4)
O48—Cu3—N5	174.2 (4)	O2—W2—O6	100.4 (4)
O48—Cu3—N6	91.8 (4)	O2—W2—O10	102.7 (4)
O48—Cu3—O30	89.6 (4)	O2—W2—O11	103.1 (4)
O50—Cu3—Cu4	79.3 (3)	O2—W2—O13	168.9 (3)
O50—Cu3—N5	92.5 (4)	O5—W2—K1	132.6 (3)
O50—Cu3—N6	161.3 (4)	O5—W2—K2	50.4 (2)
O50—Cu3—O30	92.0 (3)	O5—W2—O6	87.9 (3)
O50—Cu3—O48	93.2 (4)	O5—W2—O10	157.4 (3)
Cu3—Cu4—K2^i	117.68 (8)	O5—W2—O13	71.5 (3)
N7—Cu4—Cu3	87.9 (3)	O6—W2—K1	45.0 (3)
N7—Cu4—K2^i	102.2 (3)	O6—W2—K2	137.9 (3)
N7—Cu4—N8	82.1 (5)	O6—W2—O10	87.2 (3)
N7—Cu4—O52	103.9 (4)	O6—W2—O13	72.9 (3)
N8—Cu4—Cu3	105.7 (3)	O10—W2—K1	49.2 (3)
N8—Cu4—K2^i	136.5 (3)	O10—W2—K2	133.0 (3)
N8—Cu4—O52	90.7 (4)	O10—W2—O13	85.9 (3)
O49—Cu4—Cu3	77.3 (3)	O11—W2—K1	134.1 (3)
O49—Cu4—K2^i	93.1 (3)	O11—W2—K2	48.6 (2)
O49—Cu4—N7	162.4 (4)	O11—W2—O5	90.7 (3)
O49—Cu4—N8	92.7 (5)	O11—W2—O6	156.4 (3)
O49—Cu4—O51	92.2 (4)	O11—W2—O10	85.1 (3)
O49—Cu4—O52	92.9 (4)	O11—W2—O13	84.3 (3)
O51—Cu4—Cu3	75.8 (3)	O13—W2—K1	94.7 (2)
O51—Cu4—K2^i	42.8 (3)	O13—W2—K2	95.1 (2)
O51—Cu4—N7	93.3 (4)	O3—W3—K2	88.0 (3)
O51—Cu4—N8	175.0 (5)	O3—W3—O4	98.8 (4)
O51—Cu4—O52	88.7 (4)	O3—W3—O5	101.4 (4)
O52—Cu4—Cu3	161.2 (3)	O3—W3—O7	103.4 (4)
O52—Cu4—K2^i	46.0 (3)	O3—W3—O12	103.8 (4)
C28—K1—W1	96.5 (3)	O3—W3—O13	165.9 (3)
C28—K1—W2	72.6 (3)	O4—W3—K2	132.9 (2)
C28—K1—W5	115.0 (3)	O4—W3—O13	69.7 (3)
C28—K1—W6	151.3 (3)	O5—W3—K2	50.4 (2)
O6—K1—C28	72.8 (3)	O5—W3—O4	82.7 (3)
O6—K1—O10	52.1 (2)	O5—W3—O13	69.9 (3)
O6—K1—O20	89.0 (3)	O7—W3—K2	140.4 (3)
O6—K1—O45	60.0 (3)	O7—W3—O4	83.4 (3)
O6—K1—W1	29.61 (17)	O7—W3—O5	153.2 (3)
O6—K1—W2	27.48 (17)	O7—W3—O13	83.8 (3)
O6—K1—W5	76.3 (2)	O12—W3—K2	47.2 (3)
O6—K1—W6	79.0 (2)	O12—W3—O4	157.3 (4)
O9—K1—C28	125.1 (4)	O12—W3—O5	90.8 (4)
O9—K1—O6	53.3 (3)	O12—W3—O7	93.2 (4)
O9—K1—O10	63.6 (3)	O12—W3—O13	87.7 (3)
O9—K1—O20	54.0 (2)	O13—W3—K2	94.2 (2)
O9—K1—O45	95.6 (3)	O11—W4—K2	51.2 (3)
O9—K1—W1	29.43 (17)	O11—W4—O19	81.3 (3)
O9—K1—W2	64.3 (2)	O11—W4—O25	85.3 (3)
O9—K1—W5	64.7 (2)	O11—W4—O35	154.6 (3)
O9—K1—W6	29.14 (17)	O14—W4—K2	88.7 (3)
O10—K1—C28	92.7 (4)	O14—W4—O11	102.7 (4)
O10—K1—W1	66.57 (19)	O14—W4—O19	96.6 (4)
O10—K1—W2	28.17 (16)	O14—W4—O24	102.0 (4)
O10—K1—W5	27.31 (16)	O14—W4—O25	172.0 (3)
O10—K1—W6	65.59 (19)	O14—W4—O35	99.8 (4)
O20—K1—C28	142.6 (4)	O19—W4—K2	132.0 (2)
O20—K1—O10	51.5 (2)	O19—W4—O25	83.2 (3)
O20—K1—O45	147.2 (3)	O24—W4—K2	47.8 (3)
O20—K1—W1	80.0 (2)	O24—W4—O11	93.0 (3)
O20—K1—W2	76.4 (2)	O24—W4—O19	161.4 (3)
O20—K1—W5	27.57 (17)	O24—W4—O25	78.6 (3)
O20—K1—W6	30.02 (16)	O24—W4—O35	93.7 (4)
O45—K1—C28	42.5 (3)	O25—W4—K2	97.5 (2)
O45—K1—O10	107.4 (3)	O35—W4—K2	141.5 (3)
O45—K1—W1	67.7 (2)	O35—W4—O19	84.6 (3)
O45—K1—W2	79.3 (2)	O35—W4—O25	72.1 (3)
O45—K1—W5	134.5 (3)	O10—W5—K1	47.3 (3)
O45—K1—W6	123.8 (2)	O10—W5—O20	85.6 (3)
W1—K1—W2	51.93 (9)	O10—W5—O27	83.5 (3)
W1—K1—W5	81.01 (13)	O10—W5—O34	156.0 (3)
W2—K1—W5	55.25 (9)	O15—W5—K1	87.0 (3)
W6—K1—W1	58.52 (9)	O15—W5—O10	103.0 (4)
W6—K1—W2	80.16 (13)	O15—W5—O19	104.1 (4)
W6—K1—W5	51.90 (8)	O15—W5—O20	100.7 (4)
O2AA—K1—C28	115.0 (6)	O15—W5—O27	169.8 (4)
O2AA—K1—O6	103.0 (5)	O15—W5—O34	100.4 (4)
O2AA—K1—O9	73.0 (5)	O19—W5—K1	134.7 (3)
O2AA—K1—O10	136.5 (6)	O19—W5—O10	87.5 (4)
O2AA—K1—O20	100.6 (5)	O19—W5—O20	155.2 (3)
O2AA—K1—O45	78.1 (5)	O19—W5—O27	83.8 (3)
O2AA—K1—W1	77.1 (5)	O19—W5—O34	91.9 (4)
O2AA—K1—W2	128.9 (5)	O20—W5—K1	45.0 (3)
O2AA—K1—W5	127.0 (5)	O20—W5—O27	71.8 (3)
O2AA—K1—W6	75.6 (5)	O27—W5—K1	91.9 (2)
C56^iii—K2—W2	72.9 (3)	O34—W5—K1	129.8 (3)
C56^iii—K2—W4	120.0 (3)	O34—W5—O20	85.0 (3)
O5—K2—C56^iii	71.4 (3)	O34—W5—O27	72.6 (3)
O5—K2—W2	28.26 (15)	O9—W6—K1	48.2 (3)
O5—K2—W4	78.50 (17)	O9—W6—O20	89.1 (3)
O11—K2—C56^iii	94.5 (3)	O9—W6—O21	85.0 (3)
O11—K2—O5	52.4 (2)	O9—W6—O27	83.8 (3)
O11—K2—O12	65.2 (2)	O9—W6—O33	155.1 (4)
O11—K2—W2	27.99 (15)	O16—W6—K1	81.8 (3)
O11—K2—W4	29.83 (15)	O16—W6—O9	102.0 (4)
O12—K2—C56^iii	120.2 (3)	O16—W6—O20	101.7 (4)
O12—K2—O5	51.2 (2)	O16—W6—O21	103.1 (4)
O12—K2—W2	64.64 (18)	O16—W6—O27	171.2 (3)
O12—K2—W4	67.68 (17)	O16—W6—O33	102.7 (4)
O24—K2—C56^iii	146.3 (3)	O20—W6—K1	51.4 (3)
O24—K2—O5	91.8 (2)	O20—W6—O27	71.6 (3)
O24—K2—O11	53.3 (2)	O21—W6—K1	132.2 (3)
O24—K2—O12	59.7 (2)	O21—W6—O20	155.1 (4)
O24—K2—W2	78.71 (19)	O21—W6—O27	83.7 (3)
O24—K2—W4	26.29 (16)	O21—W6—O33	86.8 (3)
O24—K2—O1AA^iv	124.8 (3)	O27—W6—K1	97.7 (2)
O42^ii—K2—C56^iii	149.4 (3)	O33—W6—K1	139.2 (3)
O42^ii—K2—O5	110.3 (3)	O33—W6—O20	88.5 (3)
O42^ii—K2—O11	110.8 (3)	O33—W6—O27	71.9 (3)
O42^ii—K2—O12	60.7 (3)	O8—W7—O26	85.3 (3)
O42^ii—K2—O24	63.5 (3)	O17—W7—O8	103.2 (4)
O42^ii—K2—O51^iii	154.5 (3)	O17—W7—O21	103.0 (4)
O42^ii—K2—O52^iii	96.5 (3)	O17—W7—O22	102.4 (4)
O42^ii—K2—O53	87.3 (3)	O17—W7—O26	169.3 (3)
O42^ii—K2—W2	123.7 (2)	O17—W7—O32	100.3 (4)
O42^ii—K2—W4	89.5 (2)	O21—W7—O8	83.2 (3)
O42^ii—K2—O1AA^iv	90.2 (3)	O21—W7—O26	84.3 (3)
O51^iii—K2—C56^iii	43.3 (3)	O22—W7—O8	88.8 (3)
O51^iii—K2—O5	94.7 (3)	O22—W7—O21	154.4 (3)
O51^iii—K2—O11	80.5 (3)	O22—W7—O26	70.9 (3)
O51^iii—K2—O12	141.7 (3)	O22—W7—O32	89.4 (4)
O51^iii—K2—O24	112.8 (3)	O32—W7—O8	156.3 (3)
O51^iii—K2—O52^iii	61.1 (3)	O32—W7—O21	88.4 (3)
O51^iii—K2—O53	106.1 (3)	O32—W7—O26	71.7 (3)
O51^iii—K2—W2	77.1 (2)	O7—W8—O22	84.7 (3)
O51^iii—K2—W4	91.2 (2)	O7—W8—O26	83.7 (3)
O51^iii—K2—O1AA^iv	71.1 (3)	O7—W8—O31	153.2 (3)
O52^iii—K2—C56^iii	103.1 (3)	O18—W8—O7	103.5 (4)
O52^iii—K2—O5	134.5 (3)	O18—W8—O22	99.2 (4)
O52^iii—K2—O11	84.3 (3)	O18—W8—O23	104.6 (4)
O52^iii—K2—O12	127.4 (3)	O18—W8—O26	166.3 (3)
O52^iii—K2—O24	67.7 (3)	O18—W8—O31	101.9 (4)
O52^iii—K2—O53	149.7 (4)	O22—W8—O26	69.5 (3)
O52^iii—K2—W2	106.2 (2)	O23—W8—O7	90.5 (4)
O52^iii—K2—W4	65.3 (2)	O23—W8—O22	156.2 (3)
O52^iii—K2—O1AA^iv	68.6 (3)	O23—W8—O26	86.8 (3)
O53—K2—C56^iii	64.1 (3)	O23—W8—O31	91.4 (4)
O53—K2—O5	70.1 (3)	O31—W8—O22	82.9 (3)
O53—K2—O11	122.4 (3)	O31—W8—O26	69.7 (3)
O53—K2—O12	80.5 (3)	O28—W9—O26	169.1 (3)
O53—K2—O24	138.2 (3)	O28—W9—O31	100.6 (4)
O53—K2—W2	96.2 (3)	O28—W9—O32	100.6 (4)
O53—K2—W4	145.0 (3)	O28—W9—O37	103.7 (4)
O53—K2—O1AA^iv	81.4 (4)	O28—W9—O38	102.3 (4)
W4—K2—W2	57.59 (6)	O31—W9—O26	71.5 (3)
O1AA^iv—K2—C56^iii	75.7 (4)	O31—W9—O32	86.6 (4)
O1AA^iv—K2—O5	143.4 (3)	O31—W9—O38	156.8 (3)
O1AA^iv—K2—O11	147.6 (3)	O32—W9—O26	72.0 (3)
O1AA^iv—K2—O12	146.2 (3)	O37—W9—O26	84.5 (3)
O1AA^iv—K2—W2	146.0 (3)	O37—W9—O31	93.3 (4)
O1AA^iv—K2—W4	133.5 (3)	O37—W9—O32	155.3 (3)
C1—N1—C12	118.4 (11)	O37—W9—O38	85.4 (3)
C1—N1—Cu1	130.1 (9)	O38—W9—O26	85.3 (3)
C12—N1—Cu1	111.5 (9)	O38—W9—O32	85.1 (3)
C10—N2—C11	118.2 (11)	O29—W10—O27	167.9 (4)
C10—N2—Cu1	130.1 (9)	O29—W10—O33	99.7 (4)
C11—N2—Cu1	111.7 (8)	O29—W10—O34	98.7 (4)
C13—N3—C24	117.0 (11)	O29—W10—O38	102.7 (4)
C13—N3—Cu2	129.4 (9)	O29—W10—O39	105.1 (4)
C24—N3—Cu2	113.3 (9)	O33—W10—O27	72.0 (3)
C22—N4—C23	117.9 (11)	O34—W10—O27	72.2 (3)
C22—N4—Cu2	130.7 (9)	O34—W10—O33	84.9 (3)
C23—N4—Cu2	110.9 (8)	O38—W10—O27	86.2 (3)
C29—N5—C40	117.9 (12)	O38—W10—O33	87.9 (3)
C29—N5—Cu3	130.0 (9)	O38—W10—O34	158.3 (3)
C40—N5—Cu3	112.1 (9)	O39—W10—O27	83.3 (3)
C38—N6—C39	118.0 (12)	O39—W10—O33	155.2 (3)
C38—N6—Cu3	129.1 (10)	O39—W10—O34	90.1 (3)
C39—N6—Cu3	112.9 (9)	O39—W10—O38	87.9 (4)
C41—N7—C52	116.6 (12)	O30—W11—O25	172.4 (3)
C41—N7—Cu4	130.6 (9)	O30—W11—O35	100.7 (4)
C52—N7—Cu4	112.8 (9)	O30—W11—O36	102.2 (4)
C50—N8—C51	120.7 (13)	O30—W11—O37	103.6 (4)
C50—N8—Cu4	128.2 (10)	O30—W11—O39	97.0 (4)
C51—N8—Cu4	111.1 (10)	O35—W11—O25	71.8 (3)
W1—O1—Cu1	134.1 (4)	O35—W11—O37	153.3 (3)
W1—O4—W3	126.0 (4)	O35—W11—O39	84.9 (3)
W2—O5—K2	101.3 (3)	O36—W11—O25	79.4 (3)
W2—O5—W3	124.8 (4)	O36—W11—O35	93.3 (4)
W3—O5—K2	100.4 (3)	O36—W11—O37	92.4 (4)
W1—O6—K1	102.0 (4)	O36—W11—O39	160.7 (3)
W2—O6—K1	107.5 (3)	O37—W11—O25	83.6 (3)
W2—O6—W1	124.8 (4)	O37—W11—O39	81.2 (3)
W3—O7—W8	144.4 (4)	O39—W11—O25	81.7 (3)

Symmetry codes: (i) x, y−1, z; (ii) −x+1/2, −y+3/2, −z+1/2; (iii) x, y+1, z; (iv) −x+1/2, −y+5/2, −z+1/2.

(fhsp23d)

Crystal data

K2{[Cu2(H2O)(C12H8N2)2(C2H3O2)2]4[Dy2(H2O)2(C2H3O2)2 (AsW11O39)2]}·24H2O	F(000) = 16064
Mr = 8860.08	Dx = 2.992 Mg m^−3
Monoclinic, I2/a	Mo Kα radiation, λ = 0.71073 Å
a = 30.4810 (6) Å	Cell parameters from 28283 reflections
b = 14.1040 (3) Å	θ = 2.9–28.9°
c = 48.1783 (8) Å	µ = 14.88 mm^−1
β = 108.247 (2)°	T = 134 K
V = 19670.5 (7) Å^3	Block, blue
Z = 4	0.09 × 0.07 × 0.01 mm

Data collection

Agulent Xcalibur Sapphire3 diffractometer	19347 independent reflections
Radiation source: Enhance (Mo) X-ray Source	15998 reflections with I > 2σ(I)
Detector resolution: 15.9853 pixels mm^-1	Rint = 0.078
ω scans	θmax = 26.0°, θmin = 2.9°
Absorption correction: multi-scan (CrysAlis PRO; Agilent, 2013)	h = −37→37
Tmin = 0.510, Tmax = 1.000	k = −17→17
130351 measured reflections	l = −59→59

Refinement

Refinement on F^2	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.046	w = 1/[σ^2(Fo^2) + (0.0216P)^2 + 930.7491P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.096	(Δ/σ)max = 0.001
S = 1.07	Δρmax = 2.59 e Å^−3
19347 reflections	Δρmin = −1.52 e Å^−3
687 parameters	Extinction correction: SHELXL2017 (Sheldrick, 2015), Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
0 restraints	Extinction coefficient: 0.0000065 (6)

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
C1	0.2861 (4)	0.6133 (9)	0.1081 (3)	0.021 (3)*
H1	0.264444	0.608536	0.117970	0.026*
C2	0.2707 (5)	0.6252 (10)	0.0781 (3)	0.024 (3)*
H2	0.239180	0.626838	0.068305	0.029*
C3	0.3006 (5)	0.6345 (10)	0.0630 (3)	0.030 (3)*
H3	0.290155	0.643652	0.042866	0.036*
C4	0.3488 (5)	0.6299 (10)	0.0784 (3)	0.027 (3)*
C5	0.3843 (5)	0.6405 (11)	0.0653 (3)	0.032 (3)*
H5	0.376130	0.646590	0.045085	0.039*
C6	0.4294 (5)	0.6420 (11)	0.0811 (3)	0.035 (4)*
H6	0.451688	0.651014	0.071873	0.042*
C7	0.4430 (4)	0.6297 (10)	0.1121 (3)	0.025 (3)*
C8	0.4891 (5)	0.6346 (10)	0.1307 (3)	0.027 (3)*
H8	0.512890	0.645728	0.122801	0.032*
C9	0.4987 (5)	0.6231 (11)	0.1598 (3)	0.032 (3)*
H9	0.529045	0.627052	0.172092	0.039*
C10	0.4624 (4)	0.6052 (10)	0.1713 (3)	0.024 (3)*
H10	0.469263	0.593888	0.191240	0.029*
C11	0.4089 (4)	0.6182 (9)	0.1251 (3)	0.019 (3)*
C12	0.3615 (4)	0.6168 (9)	0.1086 (3)	0.020 (3)*
C13	0.3323 (5)	0.8397 (10)	0.1248 (3)	0.030 (3)*
H13	0.304631	0.828925	0.128579	0.036*
C14	0.3312 (5)	0.8653 (11)	0.0973 (3)	0.038 (4)*
H14	0.303228	0.870862	0.082452	0.046*
C15	0.3734 (5)	0.8831 (12)	0.0919 (4)	0.042 (4)*
H15	0.373261	0.899269	0.073163	0.051*
C16	0.4145 (5)	0.8768 (11)	0.1141 (3)	0.037 (4)*
C17	0.4598 (6)	0.8955 (13)	0.1113 (4)	0.052 (5)*
H17	0.462941	0.910191	0.093145	0.062*
C18	0.4971 (7)	0.8914 (14)	0.1352 (4)	0.058 (5)*
H18	0.525806	0.905853	0.133289	0.069*
C19	0.4952 (5)	0.8668 (12)	0.1625 (3)	0.041 (4)*
C20	0.5336 (6)	0.8569 (13)	0.1880 (4)	0.048 (4)*
H20	0.563094	0.869691	0.187075	0.058*
C21	0.5285 (6)	0.8297 (13)	0.2132 (4)	0.048 (4)*
H21	0.554154	0.824936	0.229846	0.058*
C22	0.4846 (5)	0.8084 (12)	0.2149 (4)	0.041 (4)*
H22	0.481289	0.789590	0.232620	0.050*
C23	0.4527 (5)	0.8439 (10)	0.1653 (3)	0.029 (3)*
C24	0.4119 (5)	0.8510 (11)	0.1414 (3)	0.030 (3)*
C25	0.1014 (4)	−0.1986 (8)	0.1276 (2)	0.013 (2)*
H25	0.124303	−0.207546	0.118877	0.016*
C26	0.1133 (4)	−0.2041 (9)	0.1579 (3)	0.019 (3)*
H26	0.143657	−0.217538	0.168964	0.023*
C27	0.0813 (4)	−0.1903 (9)	0.1713 (3)	0.022 (3)*
H27	0.089053	−0.194198	0.191570	0.026*
C28	0.0355 (4)	−0.1696 (9)	0.1541 (3)	0.021 (3)*
C29	−0.0023 (5)	−0.1559 (11)	0.1664 (3)	0.033 (3)*
H29	0.003702	−0.157832	0.186536	0.039*
C30	−0.0458 (5)	−0.1406 (11)	0.1487 (3)	0.036 (4)*
H30	−0.069382	−0.131632	0.156870	0.044*
C31	−0.0561 (5)	−0.1378 (10)	0.1173 (3)	0.027 (3)*
C32	−0.1009 (5)	−0.1241 (12)	0.0973 (3)	0.040 (4)*
H32	−0.126209	−0.116444	0.103972	0.048*
C33	−0.1067 (5)	−0.1221 (10)	0.0680 (3)	0.030 (3)*
H33	−0.135918	−0.113403	0.054602	0.037*
C34	−0.0692 (4)	−0.1330 (9)	0.0584 (3)	0.022 (3)*
H34	−0.073919	−0.131352	0.038324	0.026*
C35	−0.0207 (4)	−0.1498 (9)	0.1057 (3)	0.019 (3)*
C36	0.0251 (4)	−0.1674 (9)	0.1241 (3)	0.019 (3)*
C37	0.0591 (5)	−0.4130 (10)	0.1163 (3)	0.024 (3)*
H37	0.087412	−0.420951	0.113106	0.029*
C38	0.0578 (5)	−0.4181 (10)	0.1451 (3)	0.025 (3)*
H38	0.084624	−0.430131	0.160451	0.030*
C39	0.0176 (5)	−0.4056 (10)	0.1504 (3)	0.031 (3)*
H39	0.016736	−0.405687	0.169562	0.038*
C40	−0.0239 (4)	−0.3922 (9)	0.1266 (3)	0.021 (3)*
C41	−0.0694 (5)	−0.3826 (10)	0.1291 (3)	0.027 (3)*
H41	−0.072766	−0.383052	0.147648	0.033*
C42	−0.1071 (5)	−0.3729 (10)	0.1058 (3)	0.025 (3)*
H42	−0.136009	−0.367377	0.108336	0.030*
C43	−0.1033 (4)	−0.3709 (9)	0.0766 (3)	0.019 (3)*
C44	−0.1402 (5)	−0.3621 (10)	0.0503 (3)	0.029 (3)*
H44	−0.170416	−0.356892	0.050657	0.035*
C45	−0.1308 (5)	−0.3612 (10)	0.0245 (3)	0.029 (3)*
H45	−0.154921	−0.358619	0.007024	0.035*
C46	−0.0862 (4)	−0.3640 (9)	0.0243 (3)	0.019 (3)*
H46	−0.080695	−0.359367	0.006375	0.023*
C47	−0.0590 (4)	−0.3760 (9)	0.0739 (3)	0.020 (3)*
C48	−0.0190 (4)	−0.3889 (9)	0.0990 (3)	0.018 (3)*
C49	0.2913 (4)	0.6975 (10)	0.1791 (3)	0.022 (3)*
C50	0.2441 (4)	0.7087 (10)	0.1817 (3)	0.025 (3)*
H50A	0.246420	0.716965	0.201904	0.038*
H50B	0.226146	0.653161	0.174192	0.038*
H50C	0.229473	0.763222	0.170767	0.038*
C51	0.4053 (5)	0.6283 (11)	0.2279 (3)	0.034 (3)*
C52	0.4276 (8)	0.5929 (19)	0.2578 (5)	0.095 (8)*
H52A	0.410649	0.539462	0.261434	0.143*
H52B	0.428002	0.642181	0.271641	0.143*
H52C	0.458726	0.573901	0.259883	0.143*
C53	0.1056 (4)	−0.2823 (9)	0.0624 (3)	0.019 (3)*
C54	0.1562 (5)	−0.2940 (12)	0.0658 (3)	0.038 (4)*
H54A	0.159760	−0.310650	0.047318	0.058*
H54B	0.169048	−0.343325	0.079755	0.058*
H54C	0.172141	−0.235586	0.072587	0.058*
C55	0.0011 (4)	−0.2179 (9)	0.0078 (2)	0.014 (2)*
C56	−0.0073 (5)	−0.1908 (11)	−0.0234 (3)	0.031 (3)*
H56A	−0.036857	−0.214606	−0.035019	0.046*
H56B	0.016432	−0.217422	−0.030196	0.046*
H56C	−0.006962	−0.123001	−0.024974	0.046*
C100	0.2489 (5)	0.4865 (11)	0.2196 (3)	0.031 (3)*
C101	0.2412 (4)	0.4144 (8)	0.2408 (2)	0.013 (2)*
As1	0.20409 (4)	0.20373 (8)	0.12530 (2)	0.0075 (2)
Cu1	0.36140 (5)	0.58863 (11)	0.16585 (3)	0.0206 (3)
Cu2	0.38088 (5)	0.79021 (12)	0.18770 (4)	0.0247 (4)
Cu3	0.03251 (5)	−0.16388 (11)	0.06751 (3)	0.0169 (3)
Cu4	0.01625 (5)	−0.36940 (11)	0.05198 (3)	0.0169 (3)
Dy1	0.27051 (2)	0.20937 (4)	0.21491 (2)	0.01169 (12)
N1	0.3308 (3)	0.6085 (7)	0.1233 (2)	0.018 (2)*
N2	0.4191 (4)	0.6040 (8)	0.1546 (2)	0.023 (2)*
N3	0.3718 (4)	0.8295 (8)	0.1464 (2)	0.024 (2)*
N4	0.4477 (4)	0.8146 (9)	0.1915 (2)	0.031 (3)*
N5	0.0583 (3)	−0.1809 (7)	0.1107 (2)	0.015 (2)*
N6	−0.0261 (3)	−0.1459 (7)	0.0761 (2)	0.018 (2)*
N7	0.0224 (3)	−0.3974 (8)	0.0937 (2)	0.019 (2)*
N8	−0.0506 (3)	−0.3729 (7)	0.0480 (2)	0.014 (2)*
O1	0.0538 (3)	−0.0064 (6)	0.07571 (16)	0.0143 (17)*
O2	0.1114 (3)	0.1915 (6)	0.01235 (18)	0.0206 (19)*
O3	0.0364 (3)	0.3473 (6)	0.07654 (16)	0.0139 (17)*
O4	0.1171 (3)	0.2807 (6)	0.06578 (17)	0.0157 (18)*
O5	0.1273 (3)	0.0992 (6)	0.06587 (17)	0.0181 (18)*
O6	0.0847 (3)	0.1770 (6)	0.09836 (16)	0.0144 (17)*
O7	0.0900 (3)	0.3221 (6)	0.13440 (16)	0.0153 (18)*
O8	0.1223 (3)	0.4297 (6)	0.10022 (16)	0.0127 (17)*
O9	0.1859 (3)	0.3052 (6)	0.04467 (16)	0.0136 (17)*
O10	0.1969 (3)	0.1176 (6)	0.04388 (17)	0.0156 (18)*
O11	0.1480 (3)	−0.0499 (6)	0.09868 (16)	0.0149 (17)*
O12	0.1066 (3)	0.0241 (6)	0.13418 (17)	0.0153 (18)*
O13	0.1193 (3)	0.3449 (6)	0.19623 (18)	0.0202 (19)*
O14	0.1620 (3)	0.4345 (6)	0.15760 (16)	0.0141 (17)*
O15	0.1878 (3)	0.5710 (6)	0.12469 (17)	0.0177 (18)*
O16	0.2027 (3)	0.4149 (6)	0.09209 (17)	0.0159 (18)*
O17	0.2628 (3)	0.4254 (6)	0.05791 (17)	0.0178 (18)*
O18	0.2689 (3)	0.2294 (6)	0.06484 (17)	0.0167 (18)*
O19	0.2861 (3)	0.0394 (6)	0.05724 (17)	0.0198 (19)*
O20	0.2258 (3)	0.0082 (6)	0.09065 (17)	0.0161 (18)*
O21	0.2263 (3)	−0.1621 (6)	0.12146 (17)	0.0186 (18)*
O23	0.1895 (3)	−0.0528 (6)	0.15637 (16)	0.0151 (17)*
O24	0.1407 (3)	0.0002 (6)	0.19573 (17)	0.0198 (19)*
O25	0.1329 (3)	0.1775 (6)	0.16695 (16)	0.0144 (17)*
O26	0.1784 (2)	0.1009 (5)	0.12771 (16)	0.0109 (16)*
O27	0.1682 (2)	0.2900 (5)	0.12849 (15)	0.0084 (16)*
O28	0.2093 (2)	0.2093 (6)	0.09166 (16)	0.0116 (16)*
O29	0.2551 (2)	0.2123 (5)	0.15115 (15)	0.0106 (16)*
O30	0.2455 (3)	0.4154 (6)	0.14769 (16)	0.0141 (17)*
O31	0.2831 (3)	0.3375 (6)	0.11286 (16)	0.0139 (17)*
O32	0.2960 (3)	0.1177 (6)	0.11251 (16)	0.0141 (17)*
O33	0.2672 (3)	0.0099 (6)	0.14677 (16)	0.0141 (17)*
O34	0.2155 (3)	0.0993 (6)	0.19070 (17)	0.0162 (18)*
O35	0.2032 (3)	0.2883 (6)	0.19130 (16)	0.0149 (17)*
O36	0.3643 (3)	0.0417 (6)	0.16085 (17)	0.0169 (18)*
O37	0.3142 (3)	0.1154 (6)	0.19315 (16)	0.0142 (17)*
O38	0.3043 (3)	0.3260 (6)	0.19358 (16)	0.0125 (17)*
O39	0.3438 (3)	0.4338 (6)	0.16085 (16)	0.0144 (17)*
O40	0.3399 (3)	0.2334 (6)	0.15648 (16)	0.0137 (17)*
O41	0.3474 (3)	0.2298 (6)	0.24808 (18)	0.024 (2)*
O42	0.2647 (3)	0.3386 (6)	0.24641 (16)	0.0139 (17)*
O43	0.3970 (3)	0.5680 (7)	0.2063 (2)	0.030 (2)*
O44	0.3968 (3)	0.7162 (7)	0.2240 (2)	0.033 (2)*
O45	0.3147 (3)	0.7743 (7)	0.18144 (19)	0.027 (2)*
O46	0.3060 (3)	0.6162 (7)	0.17543 (19)	0.027 (2)*
O47	0.3779 (3)	0.9240 (7)	0.2106 (2)	0.035 (2)*
O48	0.0896 (3)	−0.2004 (7)	0.06091 (19)	0.025 (2)*
O49	0.0833 (3)	−0.3576 (7)	0.06140 (19)	0.026 (2)*
O50	0.0030 (3)	−0.1518 (7)	0.02596 (19)	0.027 (2)*
O51	0.0056 (3)	−0.3040 (6)	0.01412 (17)	0.0186 (18)*
O52	0.0181 (4)	−0.5074 (8)	0.0309 (2)	0.045 (3)*
O53	0.4130 (5)	0.2325 (11)	0.2125 (3)	0.074 (4)*
O54	0.4540 (5)	0.9633 (12)	0.2615 (3)	0.094 (5)*
O55	0.250000	0.2835 (14)	0.000000	0.066 (5)*
O57	0.1768 (5)	0.5881 (11)	0.0094 (3)	0.074 (4)*
O58	0.1652 (5)	0.6986 (10)	0.2457 (3)	0.068 (4)*
O59	0.2119 (3)	0.4299 (6)	0.25372 (17)	0.0159 (18)*
O60	0.0596 (7)	−0.0091 (15)	0.0053 (4)	0.123 (7)*
O61	0.250000	0.4928 (11)	0.000000	0.043 (4)*
O62	0.2042 (4)	0.8556 (9)	0.2249 (3)	0.053 (3)*
O63	0.4564 (4)	0.4024 (9)	0.2098 (3)	0.054 (3)*
O65	0.3664 (5)	0.4159 (11)	0.2510 (3)	0.080 (4)*
O66	0.1161 (5)	−0.4511 (12)	0.2147 (3)	0.088 (5)*
O67	−0.1208 (3)	−0.4830 (8)	−0.0375 (2)	0.041 (3)*
W1	0.10368 (2)	0.05051 (4)	0.09590 (2)	0.01226 (10)
W2	0.14823 (2)	0.19886 (4)	0.04672 (2)	0.01217 (10)
W3	0.09080 (2)	0.31268 (3)	0.09597 (2)	0.01154 (10)
W4	0.14515 (2)	0.31124 (4)	0.17055 (2)	0.01164 (10)
W5	0.18496 (2)	0.45132 (3)	0.12565 (2)	0.01133 (10)
W6	0.24148 (2)	0.34254 (3)	0.07595 (2)	0.01194 (10)
W7	0.25625 (2)	0.10397 (3)	0.07528 (2)	0.01220 (11)
W8	0.21113 (2)	−0.04658 (3)	0.12312 (2)	0.01134 (10)
W9	0.16062 (2)	0.05476 (4)	0.17027 (2)	0.01167 (10)
W10	0.31503 (2)	0.10672 (3)	0.15657 (2)	0.01048 (10)
W11	0.30314 (2)	0.34551 (3)	0.15710 (2)	0.01080 (10)
K1	0.21877 (13)	0.5703 (3)	0.29304 (8)	0.0111 (8)*	0.6
K2	0.1482 (2)	−0.0676 (5)	0.03808 (13)	0.0142 (13)*	0.4
O0AA	−0.1857 (9)	−0.009 (2)	0.0061 (6)	0.181 (10)*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
As1	0.0067 (5)	0.0082 (6)	0.0079 (5)	0.0002 (4)	0.0027 (4)	0.0004 (4)
Cu1	0.0197 (8)	0.0186 (8)	0.0263 (9)	−0.0025 (7)	0.0114 (7)	−0.0013 (7)
Cu2	0.0168 (8)	0.0222 (9)	0.0339 (9)	−0.0015 (7)	0.0062 (7)	−0.0023 (7)
Cu3	0.0188 (8)	0.0172 (8)	0.0123 (7)	−0.0010 (6)	0.0013 (6)	−0.0029 (6)
Cu4	0.0168 (7)	0.0169 (8)	0.0167 (8)	0.0003 (6)	0.0051 (6)	−0.0023 (6)
Dy1	0.0122 (3)	0.0134 (3)	0.0090 (3)	−0.0008 (2)	0.0026 (2)	0.0000 (2)
W1	0.0101 (2)	0.0145 (2)	0.0107 (2)	−0.0023 (2)	0.00120 (18)	−0.00254 (19)
W2	0.0122 (2)	0.0160 (3)	0.0076 (2)	0.0007 (2)	0.00215 (18)	−0.00047 (19)
W3	0.0084 (2)	0.0142 (2)	0.0112 (2)	0.00146 (19)	0.00199 (18)	−0.00069 (19)
W4	0.0101 (2)	0.0159 (3)	0.0086 (2)	0.00106 (19)	0.00249 (18)	−0.00106 (19)
W5	0.0098 (2)	0.0119 (2)	0.0116 (2)	0.00132 (19)	0.00229 (18)	−0.00048 (19)
W6	0.0117 (2)	0.0147 (3)	0.0099 (2)	0.0007 (2)	0.00424 (18)	0.00230 (19)
W7	0.0129 (2)	0.0145 (3)	0.0100 (2)	0.0024 (2)	0.00471 (18)	−0.00008 (19)
W8	0.0108 (2)	0.0115 (2)	0.0106 (2)	−0.00044 (19)	0.00181 (18)	−0.00087 (19)
W9	0.0102 (2)	0.0155 (3)	0.0088 (2)	−0.0030 (2)	0.00222 (18)	−0.00008 (19)
W10	0.0091 (2)	0.0115 (2)	0.0105 (2)	0.00075 (19)	0.00260 (18)	−0.00007 (18)
W11	0.0092 (2)	0.0125 (2)	0.0106 (2)	−0.00177 (19)	0.00302 (18)	0.00028 (18)

Geometric parameters (Å, º)

C1—C2	1.381 (17)	Cu4—N7	1.998 (10)
C1—N1	1.331 (15)	Cu4—N8	1.985 (9)
C2—C3	1.339 (18)	Cu4—O49	1.956 (9)
C3—C4	1.423 (18)	Cu4—O51	1.978 (8)
C4—C5	1.423 (18)	Cu4—O52	2.205 (11)
C4—C12	1.394 (17)	Dy1—O34	2.314 (8)
C5—C6	1.347 (19)	Dy1—O35	2.297 (8)
C6—C7	1.431 (19)	Dy1—O37	2.346 (8)
C7—C8	1.412 (18)	Dy1—O38	2.341 (8)
C7—C11	1.379 (17)	Dy1—O41	2.406 (9)
C8—C9	1.350 (18)	Dy1—O42	2.413 (8)
C9—C10	1.408 (18)	Dy1—O42^ii	2.517 (7)
C10—N2	1.316 (16)	Dy1—O59^ii	2.434 (8)
C11—C12	1.416 (17)	Dy1—K1^ii	3.986 (4)
C11—N2	1.368 (15)	O1—W1	1.725 (8)
C12—N1	1.348 (15)	O2—W2	1.688 (8)
C13—C14	1.362 (19)	O3—W3	1.701 (8)
C13—N3	1.330 (17)	O4—W2	1.904 (8)
C14—C15	1.41 (2)	O4—W3	1.921 (7)
C15—C16	1.37 (2)	O5—W1	1.933 (8)
C16—C17	1.45 (2)	O5—W2	1.898 (8)
C16—C24	1.390 (19)	O5—K2	2.876 (10)
C17—C18	1.34 (2)	O6—W1	1.892 (8)
C18—C19	1.38 (2)	O6—W3	1.929 (8)
C19—C20	1.41 (2)	O7—W3	1.864 (7)
C19—C23	1.38 (2)	O7—W4	2.012 (8)
C20—C21	1.33 (2)	O8—W3	1.887 (8)
C21—C22	1.40 (2)	O8—W5	1.943 (7)
C22—N4	1.320 (18)	O9—W2	1.910 (8)
C23—C24	1.409 (19)	O9—W6	1.955 (8)
C23—N4	1.380 (17)	O10—W2	1.912 (8)
C24—N3	1.351 (16)	O10—W7	1.972 (8)
C25—C26	1.391 (16)	O10—K2	2.974 (10)
C25—N5	1.337 (14)	O11—W1	1.932 (8)
C26—C27	1.343 (16)	O11—W8	1.917 (8)
C27—C28	1.413 (17)	O11—K2	2.932 (10)
C28—C29	1.466 (18)	O12—W1	1.856 (8)
C28—C36	1.376 (16)	O12—W9	2.032 (8)
C29—C30	1.35 (2)	O13—W4	1.729 (8)
C30—C31	1.448 (19)	O14—W4	1.969 (8)
C31—C32	1.42 (2)	O14—W5	1.895 (7)
C31—C35	1.374 (17)	O15—W5	1.692 (8)
C32—C33	1.367 (19)	O16—W5	1.929 (8)
C33—C34	1.370 (17)	O16—W6	1.901 (8)
C34—N6	1.336 (15)	O17—W6	1.702 (8)
C35—C36	1.424 (17)	O18—W6	1.952 (8)
C35—N6	1.380 (15)	O18—W7	1.912 (8)
C36—N5	1.373 (14)	O19—W7	1.706 (8)
C37—C38	1.403 (17)	O20—W7	1.916 (8)
C37—N7	1.313 (16)	O20—W8	1.918 (8)
C38—C39	1.337 (18)	O20—K2	3.066 (10)
C39—C40	1.431 (18)	O21—W8	1.703 (8)
C40—C41	1.434 (17)	O23—W8	1.916 (7)
C40—C48	1.384 (16)	O23—W9	1.973 (8)
C41—C42	1.342 (18)	O23—K1^ii	3.091 (9)
C42—C43	1.447 (17)	O24—W9	1.713 (8)
C43—C44	1.409 (18)	O25—W4	1.921 (8)
C43—C47	1.399 (16)	O25—W9	1.911 (8)
C44—C45	1.359 (18)	O26—W1	2.419 (7)
C45—C46	1.367 (17)	O26—W8	2.347 (8)
C46—N8	1.312 (15)	O26—W9	2.370 (7)
C47—C48	1.436 (17)	O27—W3	2.410 (7)
C47—N8	1.349 (14)	O27—W4	2.362 (7)
C48—N7	1.371 (15)	O27—W5	2.346 (7)
C49—C50	1.490 (17)	O28—W2	2.377 (7)
C49—O45	1.282 (15)	O28—W6	2.352 (8)
C49—O46	1.264 (15)	O28—W7	2.363 (7)
C50—K1^i	3.408 (14)	O29—W10	2.307 (7)
C51—C52	1.47 (3)	O29—W11	2.343 (7)
C51—O43	1.308 (17)	O30—W5	1.886 (8)
C51—O44	1.268 (17)	O30—W11	1.942 (8)
C53—C54	1.509 (18)	O31—W6	1.834 (8)
C53—O48	1.247 (15)	O31—W11	2.028 (7)
C53—O49	1.254 (15)	O32—W7	1.833 (8)
C54—K2	3.441 (17)	O32—W10	2.024 (7)
C55—C56	1.492 (17)	O33—W8	1.905 (8)
C55—O50	1.268 (14)	O33—W10	1.946 (8)
C55—O51	1.249 (14)	O33—K1^ii	3.016 (8)
C100—C101	1.510 (18)	O34—W9	1.770 (8)
C101—Dy1^ii	2.864 (11)	O34—K1^ii	3.060 (9)
C101—O42	1.268 (14)	O35—W4	1.769 (8)
C101—O59	1.258 (13)	O36—W10	1.717 (8)
As1—O26	1.670 (8)	O37—W10	1.775 (7)
As1—O27	1.675 (7)	O37—K1^ii	2.955 (9)
As1—O28	1.679 (7)	O38—W11	1.769 (7)
As1—O29	1.665 (7)	O39—W11	1.725 (8)
Cu1—Cu2	3.025 (2)	O40—W10	1.942 (8)
Cu1—N1	1.986 (10)	O40—W11	1.944 (8)
Cu1—N2	2.008 (10)	O45—K1^i	2.853 (10)
Cu1—O39	2.244 (8)	O47—K1^i	2.900 (10)
Cu1—O43	1.932 (9)	O48—K2	3.021 (11)
Cu1—O46	1.924 (9)	O58—K1	2.968 (14)
Cu2—N3	1.999 (11)	O59—K1	2.702 (9)
Cu2—N4	2.018 (11)	O60—K2	2.79 (2)
Cu2—O44	1.961 (10)	O62—K1^i	2.936 (12)
Cu2—O45	1.958 (9)	W1—K2	3.839 (6)
Cu2—O47	2.200 (10)	W2—K2	3.781 (6)
Cu2—K1^i	3.966 (4)	W7—K2	4.028 (6)
Cu3—Cu4	2.996 (2)	W8—K1^ii	3.948 (4)
Cu3—N5	1.996 (10)	W8—K2	3.954 (6)
Cu3—N6	1.974 (10)	W9—K1^ii	3.960 (4)
Cu3—O1	2.313 (8)	W10—K1^ii	3.841 (4)
Cu3—O48	1.935 (9)	K2—O0AA^iii	2.92 (3)
Cu3—O50	1.928 (9)
N1—C1—C2	122.5 (11)	O6—W1—O11	155.3 (3)
C3—C2—C1	121.0 (13)	O6—W1—O26	86.0 (3)
C2—C3—C4	118.5 (13)	O6—W1—K2	129.8 (2)
C5—C4—C3	124.6 (13)	O11—W1—O5	84.1 (3)
C12—C4—C3	117.1 (12)	O11—W1—O26	70.9 (3)
C12—C4—C5	118.3 (12)	O11—W1—K2	48.3 (2)
C6—C5—C4	122.3 (14)	O12—W1—O5	154.4 (3)
C5—C6—C7	119.9 (13)	O12—W1—O6	92.7 (3)
C8—C7—C6	124.0 (12)	O12—W1—O11	88.2 (3)
C11—C7—C6	118.4 (12)	O12—W1—O26	71.8 (3)
C11—C7—C8	117.4 (12)	O12—W1—K2	135.7 (3)
C9—C8—C7	120.0 (13)	O26—W1—K2	96.37 (19)
C8—C9—C10	119.3 (13)	O2—W2—O4	103.4 (4)
N2—C10—C9	121.5 (12)	O2—W2—O5	102.1 (4)
C7—C11—C12	121.7 (11)	O2—W2—O9	102.9 (4)
N2—C11—C7	122.0 (11)	O2—W2—O10	100.6 (4)
N2—C11—C12	116.2 (10)	O2—W2—O28	171.1 (3)
C4—C12—C11	119.2 (11)	O2—W2—K2	81.6 (3)
N1—C12—C4	123.3 (11)	O4—W2—O9	87.0 (3)
N1—C12—C11	117.3 (11)	O4—W2—O10	155.9 (3)
N3—C13—C14	122.0 (13)	O4—W2—O28	83.7 (3)
C13—C14—C15	118.7 (15)	O4—W2—K2	132.3 (3)
C16—C15—C14	120.4 (15)	O5—W2—O4	85.4 (3)
C15—C16—C17	125.2 (15)	O5—W2—O9	154.9 (3)
C15—C16—C24	116.4 (14)	O5—W2—O10	88.7 (3)
C24—C16—C17	118.4 (14)	O5—W2—O28	83.7 (3)
C18—C17—C16	118.9 (17)	O5—W2—K2	47.9 (3)
C17—C18—C19	123.6 (18)	O9—W2—O10	88.5 (3)
C18—C19—C20	125.6 (16)	O9—W2—O28	71.7 (3)
C18—C19—C23	118.2 (15)	O9—W2—K2	139.0 (2)
C23—C19—C20	116.1 (14)	O10—W2—O28	72.5 (3)
C21—C20—C19	121.3 (17)	O10—W2—K2	51.0 (3)
C20—C21—C22	120.2 (17)	O28—W2—K2	97.8 (2)
N4—C22—C21	120.8 (15)	O3—W3—O4	102.5 (3)
C19—C23—C24	121.1 (13)	O3—W3—O6	102.8 (4)
N4—C23—C19	122.2 (13)	O3—W3—O7	102.3 (3)
N4—C23—C24	116.7 (12)	O3—W3—O8	100.6 (4)
C16—C24—C23	119.7 (13)	O3—W3—O27	169.5 (3)
N3—C24—C16	123.4 (13)	O4—W3—O6	83.3 (3)
N3—C24—C23	116.9 (12)	O4—W3—O27	84.6 (3)
N5—C25—C26	122.3 (10)	O6—W3—O27	85.6 (3)
C27—C26—C25	120.4 (12)	O7—W3—O4	155.1 (3)
C26—C27—C28	118.6 (12)	O7—W3—O6	88.8 (3)
C27—C28—C29	123.0 (12)	O7—W3—O8	89.7 (3)
C36—C28—C27	118.9 (11)	O7—W3—O27	71.2 (3)
C36—C28—C29	118.0 (12)	O8—W3—O4	88.2 (3)
C30—C29—C28	120.5 (13)	O8—W3—O6	156.3 (3)
C29—C30—C31	120.9 (14)	O8—W3—O27	71.6 (3)
C32—C31—C30	124.4 (13)	O7—W4—O27	70.1 (3)
C35—C31—C30	118.8 (12)	O13—W4—O7	98.9 (3)
C35—C31—C32	116.8 (13)	O13—W4—O14	101.9 (4)
C33—C32—C31	119.3 (14)	O13—W4—O25	102.4 (4)
C32—C33—C34	119.8 (14)	O13—W4—O27	166.8 (3)
N6—C34—C33	123.6 (12)	O13—W4—O35	104.2 (4)
C31—C35—C36	120.6 (11)	O14—W4—O7	83.6 (3)
C31—C35—N6	124.0 (11)	O14—W4—O27	70.3 (3)
N6—C35—C36	115.4 (10)	O25—W4—O7	84.8 (3)
C28—C36—C35	121.2 (11)	O25—W4—O14	154.4 (3)
N5—C36—C28	121.9 (11)	O25—W4—O27	84.3 (3)
N5—C36—C35	116.9 (11)	O35—W4—O7	156.9 (3)
N7—C37—C38	123.3 (12)	O35—W4—O14	91.6 (3)
C39—C38—C37	119.6 (13)	O35—W4—O25	90.2 (3)
C38—C39—C40	119.8 (13)	O35—W4—O27	87.0 (3)
C39—C40—C41	125.5 (12)	O8—W5—O27	72.2 (3)
C48—C40—C39	116.1 (11)	O14—W5—O8	87.3 (3)
C48—C40—C41	118.4 (11)	O14—W5—O16	156.9 (3)
C42—C41—C40	122.4 (13)	O14—W5—O27	71.9 (3)
C41—C42—C43	120.6 (12)	O15—W5—O8	100.9 (4)
C44—C43—C42	126.1 (12)	O15—W5—O14	100.5 (4)
C47—C43—C42	117.6 (11)	O15—W5—O16	102.3 (4)
C47—C43—C44	116.3 (11)	O15—W5—O27	169.6 (3)
C45—C44—C43	119.0 (13)	O15—W5—O30	103.5 (4)
C44—C45—C46	120.2 (13)	O16—W5—O8	84.7 (3)
N8—C46—C45	123.3 (12)	O16—W5—O27	85.1 (3)
C43—C47—C48	121.1 (11)	O30—W5—O8	155.1 (3)
N8—C47—C43	123.6 (11)	O30—W5—O14	93.1 (3)
N8—C47—C48	115.3 (10)	O30—W5—O16	85.3 (3)
C40—C48—C47	119.8 (11)	O30—W5—O27	84.2 (3)
N7—C48—C40	124.0 (11)	O9—W6—O28	71.6 (3)
N7—C48—C47	116.2 (10)	O16—W6—O9	87.7 (3)
O45—C49—C50	115.3 (12)	O16—W6—O18	157.6 (3)
O46—C49—C50	120.2 (12)	O16—W6—O28	85.5 (3)
O46—C49—O45	124.5 (11)	O17—W6—O9	99.7 (4)
C49—C50—K1^i	84.6 (8)	O17—W6—O16	103.0 (4)
O43—C51—C52	118.3 (16)	O17—W6—O18	99.0 (4)
O44—C51—C52	119.3 (16)	O17—W6—O28	167.8 (3)
O44—C51—O43	122.4 (13)	O17—W6—O31	105.2 (4)
O48—C53—C54	118.4 (12)	O18—W6—O9	84.9 (3)
O48—C53—O49	125.8 (11)	O18—W6—O28	72.1 (3)
O49—C53—C54	115.9 (12)	O31—W6—O9	155.0 (3)
C53—C54—K2	84.8 (8)	O31—W6—O16	87.3 (3)
O50—C55—C56	117.5 (11)	O31—W6—O18	90.5 (3)
O51—C55—C56	117.8 (11)	O31—W6—O28	83.6 (3)
O51—C55—O50	124.7 (11)	O10—W7—O28	71.8 (3)
C100—C101—Dy1^ii	174.8 (9)	O10—W7—K2	44.8 (3)
O42—C101—C100	121.0 (10)	O18—W7—O10	85.4 (3)
O42—C101—Dy1^ii	61.4 (6)	O18—W7—O20	156.5 (3)
O59—C101—C100	120.1 (11)	O18—W7—O28	72.5 (3)
O59—C101—Dy1^ii	57.6 (6)	O18—W7—K2	130.1 (3)
O59—C101—O42	118.9 (10)	O19—W7—O10	99.8 (4)
O26—As1—O27	106.9 (4)	O19—W7—O18	100.2 (4)
O26—As1—O28	107.2 (4)	O19—W7—O20	102.8 (4)
O27—As1—O28	108.5 (4)	O19—W7—O28	169.0 (3)
O29—As1—O26	111.1 (4)	O19—W7—O32	105.1 (4)
O29—As1—O27	111.3 (4)	O19—W7—K2	86.9 (3)
O29—As1—O28	111.7 (4)	O20—W7—O10	85.7 (3)
N1—Cu1—Cu2	101.8 (3)	O20—W7—O28	84.0 (3)
N1—Cu1—N2	82.8 (4)	O20—W7—K2	47.2 (2)
N1—Cu1—O39	90.4 (4)	O28—W7—K2	91.7 (2)
N2—Cu1—Cu2	84.2 (3)	O32—W7—O10	155.1 (3)
N2—Cu1—O39	106.1 (4)	O32—W7—O18	91.9 (3)
O39—Cu1—Cu2	165.1 (2)	O32—W7—O20	87.0 (3)
O43—Cu1—Cu2	78.7 (3)	O32—W7—O28	83.7 (3)
O43—Cu1—N1	174.2 (4)	O32—W7—K2	134.2 (3)
O43—Cu1—N2	91.5 (4)	O11—W8—O20	87.4 (3)
O43—Cu1—O39	90.1 (4)	O11—W8—O26	72.8 (3)
O46—Cu1—Cu2	79.5 (3)	O11—W8—K1^ii	138.1 (2)
O46—Cu1—N1	93.1 (4)	O11—W8—K2	45.0 (2)
O46—Cu1—N2	162.0 (4)	O20—W8—O26	86.2 (3)
O46—Cu1—O39	91.4 (3)	O20—W8—K1^ii	132.8 (2)
O46—Cu1—O43	92.7 (4)	O20—W8—K2	49.2 (3)
Cu1—Cu2—K1^i	117.80 (8)	O21—W8—O11	100.6 (4)
N3—Cu2—Cu1	87.9 (3)	O21—W8—O20	102.2 (4)
N3—Cu2—N4	82.2 (4)	O21—W8—O23	99.5 (4)
N3—Cu2—O47	104.2 (4)	O21—W8—O26	169.3 (3)
N3—Cu2—K1^i	102.6 (3)	O21—W8—O33	102.8 (4)
N4—Cu2—Cu1	105.9 (4)	O21—W8—K1^ii	84.2 (3)
N4—Cu2—O47	90.4 (4)	O21—W8—K2	86.0 (3)
N4—Cu2—K1^i	136.1 (4)	O23—W8—O11	88.3 (3)
O44—Cu2—Cu1	77.1 (3)	O23—W8—O20	158.3 (3)
O44—Cu2—N3	162.3 (4)	O23—W8—O26	72.2 (3)
O44—Cu2—N4	92.7 (4)	O23—W8—K1^ii	50.1 (2)
O44—Cu2—O47	92.8 (4)	O23—W8—K2	132.9 (2)
O44—Cu2—K1^i	92.9 (3)	O26—W8—K1^ii	95.08 (19)
O45—Cu2—Cu1	76.0 (3)	O26—W8—K2	94.7 (2)
O45—Cu2—N3	93.7 (4)	O33—W8—O11	156.5 (3)
O45—Cu2—N4	175.3 (4)	O33—W8—O20	85.7 (3)
O45—Cu2—O44	91.9 (4)	O33—W8—O23	89.9 (3)
O45—Cu2—O47	88.5 (4)	O33—W8—O26	84.3 (3)
O45—Cu2—K1^i	42.7 (3)	O33—W8—K1^ii	47.7 (2)
O47—Cu2—Cu1	161.0 (3)	O33—W8—K2	134.8 (2)
O47—Cu2—K1^i	45.8 (3)	K1^ii—W8—K2	170.19 (11)
N5—Cu3—Cu4	97.1 (3)	O12—W9—O26	70.2 (3)
N5—Cu3—O1	86.5 (3)	O12—W9—K1^ii	132.7 (2)
N6—Cu3—Cu4	95.0 (3)	O23—W9—O12	82.8 (3)
N6—Cu3—N5	83.2 (4)	O23—W9—O26	70.8 (3)
N6—Cu3—O1	93.7 (4)	O23—W9—K1^ii	50.1 (2)
O1—Cu3—Cu4	170.89 (19)	O24—W9—O12	98.2 (3)
O48—Cu3—Cu4	77.8 (3)	O24—W9—O23	101.1 (4)
O48—Cu3—N5	93.4 (4)	O24—W9—O25	102.7 (4)
O48—Cu3—N6	171.6 (4)	O24—W9—O26	166.3 (3)
O48—Cu3—O1	93.7 (3)	O24—W9—O34	104.3 (4)
O50—Cu3—Cu4	80.8 (3)	O24—W9—K1^ii	88.2 (3)
O50—Cu3—N5	175.4 (4)	O25—W9—O12	84.4 (3)
O50—Cu3—N6	92.8 (4)	O25—W9—O23	154.3 (3)
O50—Cu3—O1	96.1 (3)	O25—W9—O26	83.9 (3)
O50—Cu3—O48	90.2 (4)	O25—W9—K1^ii	140.0 (2)
N7—Cu4—Cu3	89.1 (3)	O26—W9—K1^ii	94.40 (18)
N7—Cu4—O52	106.3 (4)	O34—W9—O12	157.4 (3)
N8—Cu4—Cu3	97.6 (3)	O34—W9—O23	91.0 (3)
N8—Cu4—N7	82.2 (4)	O34—W9—O25	92.4 (4)
N8—Cu4—O52	96.1 (4)	O34—W9—O26	87.2 (3)
O49—Cu4—Cu3	77.3 (3)	O34—W9—K1^ii	47.6 (3)
O49—Cu4—N7	91.2 (4)	O29—W10—K1^ii	97.58 (19)
O49—Cu4—N8	171.8 (4)	O32—W10—O29	82.8 (3)
O49—Cu4—O51	91.9 (3)	O32—W10—K1^ii	131.9 (2)
O49—Cu4—O52	90.4 (4)	O33—W10—O29	85.4 (3)
O51—Cu4—Cu3	75.3 (3)	O33—W10—O32	81.5 (3)
O51—Cu4—N7	163.0 (4)	O33—W10—K1^ii	50.8 (2)
O51—Cu4—N8	93.1 (4)	O36—W10—O29	172.1 (3)
O51—Cu4—O52	90.4 (4)	O36—W10—O32	96.9 (3)
O52—Cu4—Cu3	160.6 (3)	O36—W10—O33	102.5 (4)
C101^ii—Dy1—K1^ii	60.1 (2)	O36—W10—O37	101.6 (4)
O34—Dy1—C101^ii	74.2 (3)	O36—W10—O40	99.4 (4)
O34—Dy1—O37	79.6 (3)	O36—W10—K1^ii	88.6 (3)
O34—Dy1—O38	126.8 (3)	O37—W10—O29	79.1 (3)
O34—Dy1—O41	144.7 (3)	O37—W10—O32	161.4 (3)
O34—Dy1—O42^ii	77.5 (3)	O37—W10—O33	92.7 (3)
O34—Dy1—O42	129.8 (3)	O37—W10—O40	93.8 (3)
O34—Dy1—O59^ii	75.8 (3)	O37—W10—K1^ii	47.7 (3)
O34—Dy1—K1^ii	49.9 (2)	O40—W10—O29	72.7 (3)
O35—Dy1—C101^ii	111.3 (3)	O40—W10—O32	84.9 (3)
O35—Dy1—O34	71.4 (3)	O40—W10—O33	155.4 (3)
O35—Dy1—O37	126.6 (3)	O40—W10—K1^ii	141.4 (2)
O35—Dy1—O38	83.6 (3)	O30—W11—O29	83.9 (3)
O35—Dy1—O41	143.5 (3)	O30—W11—O31	80.2 (3)
O35—Dy1—O42^ii	88.6 (3)	O30—W11—O40	153.4 (3)
O35—Dy1—O42	73.5 (3)	O31—W11—O29	81.7 (3)
O35—Dy1—O59^ii	133.4 (3)	O38—W11—O29	79.3 (3)
O35—Dy1—K1^ii	121.3 (2)	O38—W11—O30	92.6 (3)
O37—Dy1—C101^ii	102.1 (3)	O38—W11—O31	160.3 (3)
O37—Dy1—O41	78.0 (3)	O38—W11—O40	93.3 (3)
O37—Dy1—O42^ii	127.8 (3)	O39—W11—O29	172.7 (3)
O37—Dy1—O42	150.6 (3)	O39—W11—O30	103.0 (3)
O37—Dy1—O59^ii	77.1 (3)	O39—W11—O31	96.9 (3)
O37—Dy1—K1^ii	47.4 (2)	O39—W11—O38	102.6 (4)
O38—Dy1—C101^ii	158.4 (3)	O39—W11—O40	101.0 (3)
O38—Dy1—O37	79.2 (3)	O40—W11—O29	71.8 (3)
O38—Dy1—O41	74.7 (3)	O40—W11—O31	85.7 (3)
O38—Dy1—O42	82.8 (3)	C50^i—K1—W8^ii	72.5 (2)
O38—Dy1—O42^ii	149.5 (3)	C50^i—K1—W10^ii	119.6 (2)
O38—Dy1—O59^ii	143.0 (3)	O23^ii—K1—C50^i	71.0 (3)
O38—Dy1—K1^ii	126.34 (19)	O23^ii—K1—W8^ii	28.39 (14)
O41—Dy1—C101^ii	84.3 (3)	O23^ii—K1—W10^ii	78.77 (17)
O41—Dy1—O42^ii	95.4 (3)	O33^ii—K1—C50^i	93.9 (3)
O41—Dy1—O42	74.9 (3)	O33^ii—K1—O23^ii	52.4 (2)
O41—Dy1—O59^ii	72.8 (3)	O33^ii—K1—O34^ii	64.9 (2)
O41—Dy1—K1^ii	95.2 (2)	O33^ii—K1—W8^ii	27.86 (15)
O42—Dy1—C101^ii	86.6 (3)	O33^ii—K1—W10^ii	30.01 (15)
O42^ii—Dy1—C101^ii	26.2 (3)	O34^ii—K1—C50^i	120.4 (3)
O42—Dy1—O42^ii	66.8 (3)	O34^ii—K1—O23^ii	51.5 (2)
O42—Dy1—O59^ii	105.3 (3)	O34^ii—K1—W8^ii	64.57 (16)
O42—Dy1—K1^ii	146.32 (19)	O34^ii—K1—W10^ii	67.27 (16)
O42^ii—Dy1—K1^ii	82.64 (19)	O37^ii—K1—C50^i	146.0 (3)
O59^ii—Dy1—C101^ii	25.9 (3)	O37^ii—K1—O23^ii	92.3 (2)
O59^ii—Dy1—O42^ii	52.1 (3)	O37^ii—K1—O33^ii	53.6 (2)
O59^ii—Dy1—K1^ii	41.59 (19)	O37^ii—K1—O34^ii	59.4 (2)
C1—N1—C12	117.6 (11)	O37^ii—K1—O58	124.7 (3)
C1—N1—Cu1	130.2 (8)	O37^ii—K1—W8^ii	78.92 (17)
C12—N1—Cu1	112.1 (8)	O37^ii—K1—W10^ii	26.38 (15)
C10—N2—C11	119.4 (11)	O45^i—K1—C50^i	42.8 (3)
C10—N2—Cu1	129.2 (9)	O45^i—K1—O23^ii	94.5 (3)
C11—N2—Cu1	111.4 (8)	O45^i—K1—O33^ii	80.6 (3)
C13—N3—C24	118.9 (12)	O45^i—K1—O34^ii	141.6 (3)
C13—N3—Cu2	128.1 (9)	O45^i—K1—O37^ii	113.0 (3)
C24—N3—Cu2	112.9 (9)	O45^i—K1—O47^i	60.7 (3)
C22—N4—C23	119.5 (13)	O45^i—K1—O58	71.2 (3)
C22—N4—Cu2	129.2 (10)	O45^i—K1—O62^i	106.2 (3)
C23—N4—Cu2	111.3 (9)	O45^i—K1—W8^ii	77.1 (2)
C25—N5—C36	117.8 (10)	O45^i—K1—W10^ii	91.4 (2)
C25—N5—Cu3	130.5 (8)	O47^i—K1—C50^i	102.3 (3)
C36—N5—Cu3	111.6 (8)	O47^i—K1—O23^ii	134.5 (3)
C34—N6—C35	116.3 (10)	O47^i—K1—O33^ii	84.5 (3)
C34—N6—Cu3	130.8 (8)	O47^i—K1—O34^ii	127.5 (3)
C35—N6—Cu3	112.8 (8)	O47^i—K1—O37^ii	68.1 (3)
C37—N7—C48	117.0 (10)	O47^i—K1—O58	68.4 (3)
C37—N7—Cu4	131.0 (9)	O47^i—K1—O62^i	149.8 (3)
C48—N7—Cu4	111.6 (8)	O47^i—K1—W8^ii	106.1 (2)
C46—N8—C47	117.6 (10)	O47^i—K1—W10^ii	65.6 (2)
C46—N8—Cu4	128.7 (8)	O58—K1—C50^i	76.0 (4)
C47—N8—Cu4	113.4 (8)	O58—K1—O23^ii	143.0 (3)
W1—O1—Cu3	133.9 (4)	O58—K1—O33^ii	147.8 (3)
W2—O4—W3	153.8 (5)	O58—K1—O34^ii	146.3 (3)
W1—O5—K2	104.2 (4)	O58—K1—W8^ii	146.0 (3)
W2—O5—W1	152.6 (5)	O58—K1—W10^ii	133.6 (3)
W2—O5—K2	102.8 (3)	O59—K1—C50^i	149.8 (3)
W1—O6—W3	153.4 (4)	O59—K1—O23^ii	110.3 (3)
W3—O7—W4	126.0 (4)	O59—K1—O33^ii	110.9 (3)
W3—O8—W5	124.9 (4)	O59—K1—O34^ii	60.5 (2)
W2—O9—W6	124.2 (4)	O59—K1—O37^ii	63.3 (2)
W2—O10—W7	123.3 (4)	O59—K1—O45^i	154.9 (3)
W2—O10—K2	99.1 (3)	O59—K1—O47^i	97.2 (3)
W7—O10—K2	107.3 (3)	O59—K1—O58	90.3 (3)
W1—O11—K2	102.3 (3)	O59—K1—O62^i	87.0 (3)
W8—O11—W1	124.8 (4)	O59—K1—W8^ii	123.6 (2)
W8—O11—K2	107.4 (3)	O59—K1—W10^ii	89.4 (2)
W1—O12—W9	125.5 (4)	O62^i—K1—C50^i	64.7 (3)
W5—O14—W4	124.5 (4)	O62^i—K1—O23^ii	69.6 (3)
W6—O16—W5	149.2 (5)	O62^i—K1—O33^ii	122.0 (3)
W7—O18—W6	123.0 (4)	O62^i—K1—O34^ii	80.5 (3)
W7—O20—W8	149.8 (5)	O62^i—K1—O37^ii	137.9 (3)
W7—O20—K2	105.6 (3)	O62^i—K1—O58	81.7 (4)
W8—O20—K2	102.5 (3)	O62^i—K1—W8^ii	96.0 (2)
W8—O23—W9	123.7 (4)	O62^i—K1—W10^ii	144.6 (3)
W8—O23—K1^ii	101.5 (3)	W10^ii—K1—W8^ii	57.64 (6)
W9—O23—K1^ii	100.5 (3)	C54—K2—W1	96.9 (3)
W9—O25—W4	144.4 (4)	C54—K2—W2	151.9 (3)
As1—O26—W1	125.5 (4)	C54—K2—W7	115.8 (3)
As1—O26—W8	122.7 (4)	C54—K2—W8	73.4 (3)
As1—O26—W9	122.5 (4)	O5—K2—C54	125.3 (4)
W8—O26—W1	91.4 (3)	O5—K2—O10	54.1 (2)
W8—O26—W9	93.3 (3)	O5—K2—O11	52.9 (2)
W9—O26—W1	92.4 (2)	O5—K2—O20	63.6 (3)
As1—O27—W3	124.9 (4)	O5—K2—O48	95.5 (3)
As1—O27—W4	123.3 (4)	O5—K2—W1	29.20 (17)
As1—O27—W5	122.6 (4)	O5—K2—W2	29.30 (17)
W4—O27—W3	92.7 (2)	O5—K2—W7	64.6 (2)
W5—O27—W3	91.2 (3)	O5—K2—W8	64.1 (2)
W5—O27—W4	93.2 (3)	O5—K2—O0AA^iii	103.3 (6)
As1—O28—W2	126.3 (4)	O10—K2—C54	143.7 (4)
As1—O28—W6	121.5 (4)	O10—K2—O20	51.9 (2)
As1—O28—W7	122.9 (4)	O10—K2—O48	147.6 (3)
W6—O28—W2	92.5 (3)	O10—K2—W1	80.2 (2)
W6—O28—W7	92.1 (2)	O10—K2—W2	29.96 (16)
W7—O28—W2	92.3 (3)	O10—K2—W7	27.86 (16)
As1—O29—W10	124.0 (4)	O10—K2—W8	76.7 (2)
As1—O29—W11	123.5 (4)	O11—K2—C54	73.4 (3)
W10—O29—W11	93.6 (3)	O11—K2—O10	89.3 (3)
W5—O30—W11	157.2 (5)	O11—K2—O20	52.4 (2)
W6—O31—W11	155.0 (4)	O11—K2—O48	60.3 (3)
W7—O32—W10	154.5 (4)	O11—K2—W1	29.45 (17)
W8—O33—W10	154.4 (5)	O11—K2—W2	78.8 (2)
W8—O33—K1^ii	104.4 (3)	O11—K2—W7	76.2 (2)
W10—O33—K1^ii	99.2 (3)	O11—K2—W8	27.56 (16)
Dy1—O34—K1^ii	94.7 (3)	O20—K2—C54	93.4 (3)
W9—O34—Dy1	158.1 (5)	O20—K2—W1	66.77 (18)
W9—O34—K1^ii	107.1 (4)	O20—K2—W2	65.72 (19)
W4—O35—Dy1	161.6 (5)	O20—K2—W7	27.26 (16)
Dy1—O37—K1^ii	96.9 (3)	O20—K2—W8	28.26 (15)
W10—O37—Dy1	132.0 (4)	O48—K2—C54	42.4 (3)
W10—O37—K1^ii	105.9 (3)	O48—K2—O20	107.8 (3)
W11—O38—Dy1	132.1 (4)	O48—K2—W1	67.8 (2)
W11—O39—Cu1	148.6 (4)	O48—K2—W2	123.8 (2)
W10—O40—W11	121.3 (4)	O48—K2—W7	134.8 (2)
C101—O42—Dy1^ii	92.3 (6)	O48—K2—W8	79.6 (2)
C101—O42—Dy1	130.6 (7)	O60—K2—C54	115.7 (5)
Dy1—O42—Dy1^ii	113.2 (3)	O60—K2—O5	72.9 (5)
C51—O43—Cu1	127.9 (10)	O60—K2—O10	99.2 (5)
C51—O44—Cu2	129.6 (9)	O60—K2—O11	103.6 (5)
C49—O45—Cu2	128.9 (9)	O60—K2—O20	136.3 (5)
C49—O45—K1^i	115.1 (7)	O60—K2—O48	79.2 (5)
Cu2—O45—K1^i	109.6 (4)	O60—K2—W1	77.5 (4)
C49—O46—Cu1	126.4 (8)	O60—K2—W2	74.6 (5)
Cu2—O47—K1^i	101.2 (4)	O60—K2—W7	125.8 (5)
C53—O48—Cu3	126.3 (8)	O60—K2—W8	129.3 (4)
C53—O48—K2	109.4 (7)	O60—K2—O0AA^iii	90.5 (7)
Cu3—O48—K2	124.0 (4)	W1—K2—W7	80.91 (12)
C53—O49—Cu4	126.6 (9)	W1—K2—W8	51.88 (8)
C55—O50—Cu3	123.8 (8)	W2—K2—W1	58.46 (9)
C55—O51—Cu4	130.7 (8)	W2—K2—W7	51.80 (8)
C101—O59—Dy1^ii	96.6 (7)	W2—K2—W8	80.09 (12)
C101—O59—K1	124.3 (7)	W8—K2—W7	55.24 (8)
Dy1^ii—O59—K1	101.7 (3)	O0AA^iii—K2—C54	129.1 (6)
O1—W1—O5	102.3 (3)	O0AA^iii—K2—O10	56.3 (6)
O1—W1—O6	103.9 (3)	O0AA^iii—K2—O11	144.8 (6)
O1—W1—O11	99.9 (4)	O0AA^iii—K2—O20	95.5 (6)
O1—W1—O12	103.1 (3)	O0AA^iii—K2—O48	154.9 (6)
O1—W1—O26	169.2 (3)	O0AA^iii—K2—W1	132.5 (6)
O1—W1—K2	80.7 (3)	O0AA^iii—K2—W2	74.0 (6)
O5—W1—O26	82.7 (3)	O0AA^iii—K2—W7	69.5 (5)
O5—W1—K2	46.6 (3)	O0AA^iii—K2—W8	123.6 (5)
O6—W1—O5	84.5 (3)

Symmetry codes: (i) −x+1/2, −y+3/2, −z+1/2; (ii) −x+1/2, −y+1/2, −z+1/2; (iii) −x, −y, −z.

(fhsp24d)

Crystal data

K2{[Cu2(H2O)(C12H8N2)2(C2H3O2)2]4[Ho2(H2O)2(C2H3O2)2 (AsW11O39)2]}·24H2O	F(000) = 16096
Mr = 8870.99	Dx = 2.996 Mg m^−3
Monoclinic, I2/a	Mo Kα radiation, λ = 0.71073 Å
a = 30.4802 (7) Å	Cell parameters from 19107 reflections
b = 14.1130 (3) Å	θ = 2.8–28.3°
c = 48.1160 (13) Å	µ = 14.93 mm^−1
β = 108.169 (3)°	T = 172 K
V = 19665.9 (9) Å^3	Block, blue
Z = 4	0.08 × 0.08 × 0.01 mm

Data collection

Agulent Xcalibur Sapphire3 diffractometer	18640 independent reflections
Radiation source: Enhance (Mo) X-ray Source	13506 reflections with I > 2σ(I)
Detector resolution: 15.9853 pixels mm^-1	Rint = 0.106
ω scans	θmax = 25.7°, θmin = 2.8°
Absorption correction: multi-scan (CrysAlis PRO; Agilent, 2013)	h = −37→37
Tmin = 0.458, Tmax = 1.000	k = −17→17
123225 measured reflections	l = −58→58

Refinement

Refinement on F^2	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.047	w = 1/[σ^2(Fo^2) + (0.0273P)^2 + 248.0512P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.106	(Δ/σ)max = 0.001
S = 1.02	Δρmax = 3.66 e Å^−3
18640 reflections	Δρmin = −1.61 e Å^−3
688 parameters	Extinction correction: SHELXL2017 (Sheldrick, 2015), Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
0 restraints	Extinction coefficient: 0.0000015 (6)
Primary atom site location: structure-invariant direct methods

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
C1	0.2858 (5)	0.6094 (11)	0.1087 (3)	0.030 (4)*
H1	0.264142	0.600821	0.118392	0.036*
C2	0.2707 (5)	0.6236 (11)	0.0784 (3)	0.031 (4)*
H2	0.239201	0.627033	0.068532	0.037*
C3	0.3013 (5)	0.6324 (12)	0.0634 (4)	0.040 (5)*
H3	0.290803	0.641312	0.043272	0.048*
C4	0.3487 (5)	0.6283 (11)	0.0782 (4)	0.033 (4)*
C5	0.3845 (5)	0.6398 (12)	0.0652 (4)	0.038 (4)*
H5	0.376717	0.647280	0.045010	0.045*
C6	0.4292 (5)	0.6399 (11)	0.0815 (4)	0.034 (4)*
H6	0.451763	0.646683	0.072363	0.041*
C7	0.4427 (5)	0.6299 (11)	0.1125 (4)	0.030 (4)*
C8	0.4887 (5)	0.6345 (10)	0.1306 (3)	0.024 (4)*
H8	0.512330	0.645815	0.122596	0.029*
C9	0.4983 (5)	0.6226 (11)	0.1593 (4)	0.035 (4)*
H9	0.528626	0.626042	0.171535	0.042*
C10	0.4621 (5)	0.6048 (11)	0.1709 (4)	0.035 (4)*
H10	0.469084	0.593556	0.190817	0.042*
C11	0.4091 (5)	0.6183 (10)	0.1257 (3)	0.023 (3)*
C12	0.3615 (5)	0.6170 (10)	0.1085 (3)	0.020 (3)*
C13	0.3329 (5)	0.8358 (11)	0.1248 (4)	0.033 (4)*
H13	0.305307	0.822050	0.128318	0.040*
C14	0.3310 (6)	0.8623 (13)	0.0977 (4)	0.048 (5)*
H14	0.302792	0.868658	0.083079	0.058*
C15	0.3739 (6)	0.8808 (12)	0.0919 (4)	0.044 (5)*
H15	0.373939	0.896094	0.073161	0.052*
C16	0.4136 (6)	0.8757 (12)	0.1140 (4)	0.036 (4)*
C17	0.4594 (6)	0.8939 (13)	0.1112 (4)	0.049 (5)*
H17	0.462497	0.908044	0.093013	0.059*
C18	0.4972 (6)	0.8898 (13)	0.1352 (4)	0.052 (5)*
H18	0.525452	0.905696	0.132920	0.062*
C19	0.4971 (6)	0.8637 (12)	0.1632 (4)	0.041 (5)*
C20	0.5349 (6)	0.8548 (13)	0.1882 (4)	0.048 (5)*
H20	0.564428	0.867430	0.187356	0.058*
C21	0.5288 (6)	0.8276 (13)	0.2137 (4)	0.048 (5)*
H21	0.554228	0.823709	0.230451	0.058*
C22	0.4845 (6)	0.8050 (13)	0.2151 (4)	0.048 (5)*
H22	0.481241	0.783803	0.232673	0.058*
C23	0.4526 (5)	0.8424 (12)	0.1658 (4)	0.033 (4)*
C24	0.4124 (5)	0.8481 (12)	0.1411 (4)	0.036 (4)*
C25	0.1012 (5)	−0.2017 (10)	0.1281 (3)	0.019 (3)*
H25	0.123816	−0.213326	0.119279	0.023*
C26	0.1131 (5)	−0.2063 (10)	0.1582 (3)	0.022 (3)*
H26	0.143374	−0.220183	0.169233	0.027*
C27	0.0809 (5)	−0.1907 (10)	0.1719 (3)	0.027 (4)*
H27	0.088632	−0.193545	0.192154	0.032*
C28	0.0358 (5)	−0.1703 (10)	0.1545 (3)	0.024 (4)*
C29	−0.0021 (5)	−0.1543 (12)	0.1669 (4)	0.037 (4)*
H29	0.003930	−0.152541	0.187064	0.044*
C30	−0.0459 (5)	−0.1420 (11)	0.1487 (4)	0.036 (4)*
H30	−0.069892	−0.136117	0.156700	0.043*
C31	−0.0562 (5)	−0.1377 (11)	0.1174 (3)	0.028 (4)*
C32	−0.0997 (6)	−0.1231 (12)	0.0980 (4)	0.041 (5)*
H32	−0.124530	−0.114427	0.105140	0.050*
C33	−0.1068 (5)	−0.1213 (11)	0.0690 (4)	0.033 (4)*
H33	−0.136243	−0.111519	0.055989	0.040*
C34	−0.0683 (5)	−0.1345 (11)	0.0587 (4)	0.029 (4)*
H34	−0.073110	−0.134452	0.038666	0.034*
C35	−0.0197 (5)	−0.1489 (10)	0.1062 (3)	0.022 (3)*
C36	0.0264 (4)	−0.1674 (9)	0.1251 (3)	0.016 (3)*
C37	0.0584 (5)	−0.4137 (10)	0.1168 (3)	0.024 (4)*
H37	0.086648	−0.422139	0.113613	0.029*
C38	0.0571 (5)	−0.4181 (11)	0.1455 (4)	0.035 (4)*
H38	0.083951	−0.428963	0.160927	0.041*
C39	0.0164 (5)	−0.4065 (11)	0.1505 (4)	0.031 (4)*
H39	0.015244	−0.407151	0.169623	0.037*
C40	−0.0251 (5)	−0.3931 (10)	0.1267 (3)	0.019 (3)*
C41	−0.0703 (5)	−0.3821 (11)	0.1295 (4)	0.030 (4)*
H41	−0.073929	−0.381976	0.148005	0.036*
C42	−0.1067 (5)	−0.3721 (10)	0.1062 (3)	0.027 (4)*
H42	−0.135681	−0.366065	0.108544	0.032*
C43	−0.1030 (5)	−0.3703 (11)	0.0772 (3)	0.028 (4)*
C44	−0.1395 (5)	−0.3595 (11)	0.0511 (3)	0.032 (4)*
H44	−0.169561	−0.354119	0.051695	0.038*
C45	−0.1316 (5)	−0.3568 (10)	0.0248 (3)	0.026 (4)*
H45	−0.155911	−0.350998	0.007550	0.031*
C46	−0.0864 (5)	−0.3630 (10)	0.0244 (3)	0.024 (4)*
H46	−0.080940	−0.360686	0.006435	0.029*
C47	−0.0590 (5)	−0.3765 (10)	0.0744 (3)	0.021 (3)*
C48	−0.0197 (5)	−0.3899 (10)	0.0989 (3)	0.021 (3)*
C49	0.2920 (5)	0.6983 (12)	0.1792 (3)	0.030 (4)*
C50	0.2438 (5)	0.7079 (11)	0.1812 (3)	0.030 (4)*
H50A	0.245388	0.718857	0.201211	0.045*
H50B	0.226805	0.650706	0.174371	0.045*
H50C	0.228466	0.760255	0.169402	0.045*
C51	0.4038 (6)	0.6245 (14)	0.2273 (4)	0.046 (5)*
C52	0.4227 (9)	0.587 (2)	0.2574 (6)	0.123 (11)*
H52A	0.418820	0.519908	0.257250	0.184*
H52B	0.406486	0.615691	0.269549	0.184*
H52C	0.454906	0.602672	0.265056	0.184*
C53	0.1058 (5)	−0.2843 (11)	0.0621 (3)	0.024 (3)*
C1AA	0.1561 (5)	−0.2967 (11)	0.0659 (4)	0.034 (4)*
H1AA	0.171053	−0.235964	0.068918	0.052*
H1AB	0.159843	−0.325854	0.048792	0.052*
H1AC	0.169800	−0.336288	0.082637	0.052*
C55	0.0012 (4)	−0.2188 (10)	0.0079 (3)	0.014 (3)*
C56	−0.0071 (5)	−0.1924 (11)	−0.0231 (3)	0.031 (4)*
H56A	−0.038547	−0.206083	−0.034141	0.046*
H56B	0.013238	−0.227962	−0.030903	0.046*
H56C	−0.001308	−0.125883	−0.024373	0.046*
N1	0.3307 (4)	0.6079 (8)	0.1240 (3)	0.024 (3)*
N2	0.4184 (4)	0.6035 (8)	0.1544 (3)	0.024 (3)*
N3	0.3718 (4)	0.8279 (9)	0.1470 (3)	0.029 (3)*
N4	0.4473 (4)	0.8137 (9)	0.1916 (3)	0.031 (3)*
N5	0.0585 (4)	−0.1814 (8)	0.1111 (2)	0.016 (3)*
N6	−0.0256 (4)	−0.1471 (8)	0.0769 (3)	0.023 (3)*
N7	0.0216 (4)	−0.3981 (8)	0.0940 (3)	0.019 (3)*
N8	−0.0513 (4)	−0.3717 (8)	0.0479 (2)	0.017 (3)*
O0AA	0.0539 (3)	−0.0063 (6)	0.07614 (19)	0.015 (2)*
O2	0.1110 (3)	0.1903 (7)	0.0123 (2)	0.022 (2)*
O3	0.0359 (3)	0.3467 (6)	0.0769 (2)	0.018 (2)*
O4	0.1165 (3)	0.2800 (6)	0.06557 (19)	0.017 (2)*
O5	0.1271 (3)	0.0974 (6)	0.0659 (2)	0.018 (2)*
O6	0.0847 (3)	0.1754 (6)	0.09891 (19)	0.017 (2)*
O7	0.0905 (3)	0.3201 (6)	0.13459 (19)	0.017 (2)*
O8	0.1220 (3)	0.4293 (6)	0.1003 (2)	0.018 (2)*
O9	0.1852 (3)	0.3035 (6)	0.04431 (19)	0.016 (2)*
O10	0.1965 (3)	0.1163 (6)	0.04399 (19)	0.017 (2)*
O11	0.1480 (3)	−0.0516 (6)	0.09894 (19)	0.017 (2)*
O12	0.1066 (3)	0.0230 (6)	0.1342 (2)	0.018 (2)*
O13	0.1191 (3)	0.3435 (6)	0.1964 (2)	0.019 (2)*
O14	0.1616 (3)	0.4323 (6)	0.1576 (2)	0.018 (2)*
O15	0.1871 (3)	0.5703 (7)	0.1247 (2)	0.022 (2)*
O16	0.2023 (3)	0.4143 (6)	0.09177 (19)	0.015 (2)*
O17	0.2624 (3)	0.4234 (6)	0.0575 (2)	0.020 (2)*
O18	0.2681 (3)	0.2278 (6)	0.0645 (2)	0.019 (2)*
O19	0.2859 (3)	0.0387 (6)	0.0573 (2)	0.020 (2)*
O20	0.2260 (3)	0.0071 (6)	0.09081 (19)	0.015 (2)*
O21	0.2260 (3)	−0.1624 (7)	0.1211 (2)	0.020 (2)*
O23	0.1889 (3)	−0.0521 (6)	0.15623 (19)	0.015 (2)*
O24	0.1404 (3)	−0.0004 (7)	0.1961 (2)	0.025 (2)*
O25	0.1328 (3)	0.1759 (6)	0.1672 (2)	0.019 (2)*
O26	0.1782 (3)	0.0994 (6)	0.12783 (19)	0.015 (2)*
O27	0.1681 (3)	0.2891 (6)	0.12811 (19)	0.014 (2)*
O28	0.2093 (3)	0.2081 (6)	0.09182 (19)	0.013 (2)*
O29	0.2543 (3)	0.2124 (6)	0.15091 (19)	0.013 (2)*
O30	0.2451 (3)	0.4140 (6)	0.1478 (2)	0.019 (2)*
O31	0.2831 (3)	0.3362 (6)	0.11242 (19)	0.015 (2)*
O32	0.2957 (3)	0.1168 (6)	0.1123 (2)	0.018 (2)*
O33	0.2668 (3)	0.0094 (6)	0.14651 (19)	0.015 (2)*
O34	0.2153 (3)	0.0984 (6)	0.19081 (19)	0.016 (2)*
O35	0.2030 (3)	0.2881 (6)	0.19120 (19)	0.015 (2)*
O36	0.3636 (3)	0.0402 (6)	0.1610 (2)	0.018 (2)*
O37	0.3133 (3)	0.1153 (6)	0.19317 (19)	0.013 (2)*
O38	0.3038 (3)	0.3237 (6)	0.1937 (2)	0.018 (2)*
O39	0.3432 (3)	0.4322 (6)	0.16098 (19)	0.016 (2)*
O40	0.3393 (3)	0.2319 (6)	0.15642 (19)	0.016 (2)*
O41	0.3470 (3)	0.2291 (7)	0.2479 (2)	0.026 (2)*
O42	0.2647 (3)	0.3374 (6)	0.2463 (2)	0.018 (2)*
O43	0.3962 (3)	0.5676 (8)	0.2061 (2)	0.033 (3)*
O44	0.3975 (4)	0.7157 (9)	0.2238 (3)	0.049 (3)*
O45	0.3148 (3)	0.7725 (7)	0.1819 (2)	0.031 (3)*
O46	0.3052 (3)	0.6149 (8)	0.1751 (2)	0.034 (3)*
O47	0.3779 (3)	0.9233 (8)	0.2104 (2)	0.036 (3)*
O48	0.0897 (3)	−0.2036 (7)	0.0614 (2)	0.024 (2)*
O49	0.0833 (3)	−0.3582 (7)	0.0619 (2)	0.026 (2)*
O50	0.0034 (3)	−0.1530 (7)	0.0264 (2)	0.027 (2)*
O51	0.0056 (3)	−0.3047 (7)	0.0142 (2)	0.025 (2)*
O52	0.0174 (4)	−0.5080 (8)	0.0310 (3)	0.050 (3)*
O53	0.4148 (5)	0.2324 (11)	0.2123 (3)	0.086 (5)*
C54	0.2493 (5)	0.4856 (11)	0.2194 (3)	0.032 (4)*
H54A	0.274350	0.526677	0.229444	0.048*
H54B	0.221776	0.522432	0.211402	0.048*
H54C	0.256769	0.453437	0.203879	0.048*
O55	0.1664 (4)	−0.2987 (10)	0.2463 (3)	0.067 (4)*
K1	0.28064 (14)	−0.0715 (3)	0.20715 (9)	0.0040 (9)*	0.6
Cu1	0.36108 (6)	0.58713 (13)	0.16577 (4)	0.0262 (5)
Cu2	0.38064 (6)	0.78841 (14)	0.18780 (4)	0.0306 (5)
Cu3	0.03254 (6)	−0.16538 (12)	0.06790 (4)	0.0192 (4)
Cu4	0.01592 (6)	−0.37035 (12)	0.05217 (4)	0.0197 (4)
As1	0.20376 (4)	0.20274 (9)	0.12525 (3)	0.0090 (3)
Ho1	0.27016 (2)	0.20870 (5)	0.21511 (2)	0.01432 (15)
W1	0.10353 (2)	0.04933 (4)	0.09603 (2)	0.01494 (13)
W2	0.14799 (2)	0.19733 (4)	0.04670 (2)	0.01438 (13)
W3	0.09059 (2)	0.31116 (4)	0.09601 (2)	0.01428 (13)
W4	0.14504 (2)	0.30988 (4)	0.17070 (2)	0.01387 (13)
W5	0.18465 (2)	0.45007 (4)	0.12564 (2)	0.01383 (13)
W6	0.24109 (2)	0.34132 (4)	0.07586 (2)	0.01407 (13)
W7	0.25611 (2)	0.10283 (4)	0.07533 (2)	0.01412 (13)
W8	0.21095 (2)	−0.04768 (4)	0.12315 (2)	0.01397 (13)
W9	0.16066 (2)	0.05389 (4)	0.17053 (2)	0.01439 (13)
W10	0.31469 (2)	0.10570 (4)	0.15672 (2)	0.01274 (13)
W11	0.30267 (2)	0.34411 (4)	0.15706 (2)	0.01301 (13)
C0AA	0.2415 (5)	0.4134 (10)	0.2407 (3)	0.023 (4)*
O1AA	0.2122 (3)	0.4311 (6)	0.2535 (2)	0.021 (2)*
O1	0.250000	0.4913 (12)	0.000000	0.050 (5)*
O2AA	−0.1209 (4)	−0.4809 (8)	−0.0377 (3)	0.046 (3)*
O6AA	0.2057 (4)	0.8539 (9)	0.2255 (3)	0.054 (3)*
O3AA	0.4567 (4)	0.4027 (10)	0.2100 (3)	0.063 (4)*
O5AA	0.250000	0.2797 (15)	0.000000	0.084 (7)*
O4AA	0.1198 (5)	−0.4486 (12)	0.2151 (4)	0.095 (5)*
K0AA	0.1469 (2)	−0.0690 (5)	0.03799 (16)	0.0136 (16)*	0.4
O7AA	0.1773 (5)	−0.4125 (11)	0.0095 (4)	0.091 (5)*
O8AA	0.3670 (5)	0.4153 (12)	0.2503 (4)	0.099 (6)*
O9AA	0.5460 (5)	0.4632 (11)	0.2383 (4)	0.091 (5)*
O0BA	0.0596 (7)	−0.0083 (16)	0.0063 (5)	0.155 (8)*
O1BA	0.1862 (9)	0.0073 (19)	−0.0063 (6)	0.201 (11)*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Cu1	0.0250 (10)	0.0253 (11)	0.0309 (12)	−0.0010 (8)	0.0123 (9)	−0.0018 (9)
Cu2	0.0227 (10)	0.0302 (12)	0.0387 (13)	−0.0017 (9)	0.0093 (9)	−0.0051 (10)
Cu3	0.0209 (9)	0.0190 (10)	0.0160 (10)	−0.0016 (8)	0.0032 (8)	−0.0026 (8)
Cu4	0.0191 (9)	0.0184 (10)	0.0209 (10)	−0.0002 (8)	0.0052 (8)	−0.0025 (8)
As1	0.0100 (6)	0.0078 (7)	0.0091 (7)	−0.0001 (5)	0.0030 (6)	0.0005 (5)
Ho1	0.0153 (3)	0.0163 (4)	0.0114 (3)	−0.0022 (3)	0.0042 (3)	−0.0003 (3)
W1	0.0127 (3)	0.0173 (3)	0.0138 (3)	−0.0036 (2)	0.0026 (2)	−0.0032 (2)
W2	0.0149 (3)	0.0181 (3)	0.0095 (3)	0.0008 (2)	0.0029 (2)	−0.0010 (2)
W3	0.0107 (3)	0.0175 (3)	0.0144 (3)	0.0011 (2)	0.0036 (2)	−0.0014 (2)
W4	0.0126 (3)	0.0177 (3)	0.0115 (3)	0.0005 (2)	0.0040 (2)	−0.0017 (2)
W5	0.0122 (3)	0.0143 (3)	0.0143 (3)	0.0012 (2)	0.0031 (2)	−0.0009 (2)
W6	0.0136 (3)	0.0167 (3)	0.0127 (3)	0.0009 (2)	0.0052 (2)	0.0026 (2)
W7	0.0150 (3)	0.0161 (3)	0.0120 (3)	0.0023 (2)	0.0053 (2)	−0.0003 (2)
W8	0.0143 (3)	0.0137 (3)	0.0128 (3)	−0.0010 (2)	0.0026 (2)	−0.0010 (2)
W9	0.0132 (3)	0.0180 (3)	0.0114 (3)	−0.0042 (2)	0.0031 (2)	0.0000 (2)
W10	0.0118 (3)	0.0131 (3)	0.0130 (3)	0.0007 (2)	0.0035 (2)	−0.0001 (2)
W11	0.0122 (3)	0.0144 (3)	0.0126 (3)	−0.0021 (2)	0.0042 (2)	0.0001 (2)

Geometric parameters (Å, º)

C1—C2	1.40 (2)	O9—W6	1.970 (9)
C1—N1	1.335 (17)	O10—W2	1.906 (8)
C2—C3	1.35 (2)	O10—W7	1.975 (9)
C3—C4	1.40 (2)	O10—K0AA	2.990 (11)
C4—C5	1.42 (2)	O11—W1	1.941 (9)
C4—C12	1.40 (2)	O11—W8	1.911 (8)
C5—C6	1.34 (2)	O11—K0AA	2.933 (11)
C6—C7	1.43 (2)	O12—W1	1.846 (9)
C7—C8	1.402 (19)	O12—W9	2.041 (9)
C7—C11	1.371 (19)	O13—W4	1.726 (9)
C8—C9	1.33 (2)	O14—W4	1.959 (9)
C9—C10	1.407 (19)	O14—W5	1.895 (9)
C10—N2	1.319 (18)	O15—W5	1.699 (9)
C11—C12	1.429 (18)	O16—W5	1.936 (8)
C11—N2	1.336 (17)	O16—W6	1.899 (8)
C12—N1	1.377 (16)	O17—W6	1.703 (9)
C13—C14	1.34 (2)	O18—W6	1.956 (9)
C13—N3	1.330 (18)	O18—W7	1.908 (9)
C14—C15	1.44 (2)	O19—W7	1.699 (9)
C15—C16	1.34 (2)	O20—W7	1.911 (8)
C16—C17	1.47 (2)	O20—W8	1.916 (8)
C16—C24	1.37 (2)	O20—K0AA	3.098 (11)
C17—C18	1.36 (2)	O21—W8	1.695 (9)
C18—C19	1.40 (2)	O23—K1	3.103 (10)
C19—C20	1.39 (2)	O23—W8	1.912 (8)
C19—C23	1.43 (2)	O23—W9	1.955 (9)
C20—C21	1.35 (2)	O24—W9	1.719 (9)
C21—C22	1.41 (2)	O25—W4	1.925 (9)
C22—N4	1.34 (2)	O25—W9	1.904 (9)
C23—C24	1.42 (2)	O26—As1	1.675 (9)
C23—N4	1.366 (19)	O26—W1	2.420 (8)
C24—N3	1.386 (18)	O26—W8	2.344 (9)
C25—C26	1.382 (18)	O26—W9	2.368 (8)
C25—N5	1.334 (16)	O27—As1	1.667 (8)
C26—C27	1.359 (18)	O27—W3	2.406 (8)
C27—C28	1.399 (19)	O27—W4	2.383 (8)
C28—C29	1.471 (19)	O27—W5	2.338 (9)
C28—C36	1.354 (18)	O28—As1	1.670 (8)
C29—C30	1.36 (2)	O28—W2	2.387 (8)
C30—C31	1.44 (2)	O28—W6	2.352 (8)
C31—C32	1.38 (2)	O28—W7	2.362 (8)
C31—C35	1.388 (18)	O29—As1	1.652 (8)
C32—C33	1.35 (2)	O29—W10	2.328 (8)
C33—C34	1.421 (19)	O29—W11	2.334 (8)
C34—N6	1.336 (17)	O30—W5	1.888 (9)
C35—C36	1.440 (18)	O30—W11	1.940 (9)
C35—N6	1.368 (17)	O31—W6	1.826 (9)
C36—N5	1.364 (15)	O31—W11	2.045 (9)
C37—C38	1.39 (2)	O32—W7	1.821 (9)
C37—N7	1.319 (17)	O32—W10	2.041 (9)
C38—C39	1.346 (19)	O33—K1	3.038 (10)
C39—C40	1.431 (19)	O33—W8	1.902 (8)
C40—C41	1.433 (18)	O33—W10	1.942 (8)
C40—C48	1.399 (18)	O34—K1	3.060 (9)
C41—C42	1.318 (19)	O34—Ho1	2.317 (9)
C42—C43	1.43 (2)	O34—W9	1.762 (8)
C43—C44	1.40 (2)	O35—Ho1	2.303 (8)
C43—C47	1.394 (18)	O35—W4	1.760 (8)
C44—C45	1.356 (19)	O36—W10	1.710 (8)
C45—C46	1.387 (18)	O37—K1	2.968 (9)
C46—N8	1.297 (17)	O37—Ho1	2.334 (8)
C47—C48	1.407 (19)	O37—W10	1.773 (8)
C47—N8	1.367 (16)	O38—Ho1	2.324 (9)
C48—N7	1.357 (16)	O38—W11	1.778 (9)
C49—C50	1.510 (19)	O39—Cu1	2.248 (9)
C49—O45	1.239 (17)	O39—W11	1.721 (8)
C49—O46	1.279 (17)	O40—W10	1.935 (9)
C50—K1^i	3.411 (16)	O40—W11	1.943 (9)
C51—C52	1.48 (3)	O41—Ho1	2.397 (9)
C51—O43	1.260 (19)	O42—Ho1	2.395 (9)
C51—O44	1.30 (2)	O42—Ho1^ii	2.495 (9)
C53—C1AA	1.496 (18)	O42—C0AA	1.266 (16)
C53—O48	1.237 (16)	O43—Cu1	1.923 (11)
C53—O49	1.248 (16)	O44—Cu2	1.938 (12)
C1AA—K0AA	3.461 (18)	O45—K1^i	2.863 (11)
C55—C56	1.480 (18)	O45—Cu2	1.951 (10)
C55—O50	1.274 (15)	O46—Cu1	1.931 (10)
C55—O51	1.248 (15)	O47—K1^i	2.920 (11)
N1—Cu1	1.957 (12)	O47—Cu2	2.207 (11)
N2—Cu1	2.002 (11)	O48—Cu3	1.940 (9)
N3—Cu2	1.975 (13)	O48—K0AA	3.024 (12)
N4—Cu2	2.013 (12)	O49—Cu4	1.967 (9)
N5—Cu3	1.994 (11)	O50—Cu3	1.925 (10)
N6—Cu3	1.966 (11)	O51—Cu4	1.982 (10)
N7—Cu4	2.005 (11)	O52—Cu4	2.201 (12)
N8—Cu4	1.995 (10)	C54—C0AA	1.516 (19)
O0AA—Cu3	2.337 (9)	O55—K1^iii	2.952 (14)
O0AA—W1	1.709 (8)	K1—W9	3.948 (4)
O2—W2	1.692 (9)	K1—W10	3.846 (4)
O3—W3	1.708 (9)	K1—O1AA^ii	2.702 (10)
O4—W2	1.911 (8)	K1—O6AA^iv	2.893 (12)
O4—W3	1.919 (8)	Cu1—Cu2	3.026 (3)
O5—W1	1.929 (9)	Cu3—Cu4	2.993 (2)
O5—W2	1.902 (9)	Ho1—C0AA^ii	2.844 (15)
O5—K0AA	2.864 (11)	Ho1—O1AA^ii	2.441 (9)
O6—W1	1.889 (9)	W1—K0AA	3.826 (7)
O6—W3	1.933 (9)	W2—K0AA	3.781 (7)
O7—W3	1.861 (9)	W7—K0AA	4.056 (7)
O7—W4	2.000 (9)	W8—K0AA	3.962 (7)
O8—W3	1.901 (9)	C0AA—O1AA	1.257 (15)
O8—W5	1.942 (9)	K0AA—O0BA	2.76 (2)
O9—W2	1.904 (9)	K0AA—O1BA	2.95 (3)
N1—C1—C2	121.8 (14)	O29—As1—O26	111.3 (4)
C3—C2—C1	120.7 (15)	O29—As1—O27	111.0 (4)
C2—C3—C4	120.1 (17)	O29—As1—O28	111.5 (4)
C3—C4—C5	125.7 (16)	O34—Ho1—O37	79.2 (3)
C12—C4—C3	116.2 (14)	O34—Ho1—O38	126.5 (3)
C12—C4—C5	118.0 (14)	O34—Ho1—O41	144.7 (3)
C6—C5—C4	121.2 (17)	O34—Ho1—O42	130.2 (3)
C5—C6—C7	121.4 (15)	O34—Ho1—O42^ii	78.0 (3)
C8—C7—C6	123.5 (14)	O34—Ho1—K1	49.7 (2)
C11—C7—C6	118.8 (14)	O34—Ho1—C0AA^ii	74.4 (4)
C11—C7—C8	117.7 (15)	O34—Ho1—O1AA^ii	75.8 (3)
C9—C8—C7	119.5 (14)	O35—Ho1—O34	71.6 (3)
C8—C9—C10	119.3 (15)	O35—Ho1—O37	126.0 (3)
N2—C10—C9	122.2 (16)	O35—Ho1—O38	83.5 (3)
C7—C11—C12	120.2 (14)	O35—Ho1—O41	143.5 (3)
N2—C11—C7	123.2 (14)	O35—Ho1—O42	73.7 (3)
N2—C11—C12	116.6 (13)	O35—Ho1—O42^ii	88.9 (3)
C4—C12—C11	120.5 (13)	O35—Ho1—K1	121.2 (2)
N1—C12—C4	124.1 (13)	O35—Ho1—C0AA^ii	111.7 (4)
N1—C12—C11	115.4 (13)	O35—Ho1—O1AA^ii	133.8 (3)
N3—C13—C14	124.4 (16)	O37—Ho1—O41	78.0 (3)
C13—C14—C15	118.0 (17)	O37—Ho1—O42	150.6 (3)
C16—C15—C14	119.2 (17)	O37—Ho1—O42^ii	128.3 (3)
C15—C16—C17	124.7 (17)	O37—Ho1—K1	47.5 (2)
C15—C16—C24	118.8 (16)	O37—Ho1—C0AA^ii	102.4 (4)
C24—C16—C17	116.4 (16)	O37—Ho1—O1AA^ii	77.1 (3)
C18—C17—C16	119.6 (18)	O38—Ho1—O37	78.8 (3)
C17—C18—C19	125.3 (18)	O38—Ho1—O41	74.4 (3)
C18—C19—C23	115.1 (17)	O38—Ho1—O42^ii	149.3 (3)
C20—C19—C18	127.4 (17)	O38—Ho1—O42	82.8 (3)
C20—C19—C23	117.5 (16)	O38—Ho1—K1	126.1 (2)
C21—C20—C19	120.0 (18)	O38—Ho1—C0AA^ii	158.3 (4)
C20—C21—C22	120.9 (18)	O38—Ho1—O1AA^ii	142.7 (3)
N4—C22—C21	120.8 (17)	O41—Ho1—O42^ii	95.6 (3)
C24—C23—C19	120.7 (15)	O41—Ho1—K1	95.2 (2)
N4—C23—C19	121.7 (15)	O41—Ho1—C0AA^ii	84.6 (4)
N4—C23—C24	117.6 (14)	O41—Ho1—O1AA^ii	73.1 (3)
C16—C24—C23	122.7 (15)	O42—Ho1—O41	75.0 (3)
C16—C24—N3	123.1 (15)	O42—Ho1—O42^ii	66.6 (4)
N3—C24—C23	114.1 (15)	O42—Ho1—K1	146.5 (2)
N5—C25—C26	122.6 (13)	O42^ii—Ho1—K1	83.0 (2)
C27—C26—C25	120.4 (14)	O42—Ho1—C0AA^ii	86.7 (4)
C26—C27—C28	118.0 (15)	O42^ii—Ho1—C0AA^ii	26.4 (3)
C27—C28—C29	122.7 (14)	O42—Ho1—O1AA^ii	105.7 (3)
C36—C28—C27	118.6 (13)	C0AA^ii—Ho1—K1	60.3 (3)
C36—C28—C29	118.8 (13)	O1AA^ii—Ho1—O42^ii	52.5 (3)
C30—C29—C28	119.7 (16)	O1AA^ii—Ho1—K1	41.5 (2)
C29—C30—C31	121.9 (15)	O1AA^ii—Ho1—C0AA^ii	26.1 (3)
C32—C31—C30	124.4 (15)	O0AA—W1—O5	102.3 (4)
C32—C31—C35	118.2 (15)	O0AA—W1—O6	103.7 (4)
C35—C31—C30	117.4 (14)	O0AA—W1—O11	100.4 (4)
C33—C32—C31	121.0 (16)	O0AA—W1—O12	103.1 (4)
C32—C33—C34	118.4 (16)	O0AA—W1—O26	169.5 (4)
N6—C34—C33	122.3 (15)	O0AA—W1—K0AA	80.7 (3)
C31—C35—C36	121.2 (14)	O5—W1—O11	84.1 (4)
N6—C35—C31	122.5 (13)	O5—W1—O26	82.8 (3)
N6—C35—C36	116.3 (12)	O5—W1—K0AA	46.5 (3)
C28—C36—C35	120.8 (12)	O6—W1—O5	85.2 (4)
C28—C36—N5	124.1 (12)	O6—W1—O11	155.3 (4)
N5—C36—C35	115.0 (12)	O6—W1—O26	85.8 (3)
N7—C37—C38	123.6 (14)	O6—W1—K0AA	130.4 (3)
C39—C38—C37	118.9 (16)	O11—W1—O26	70.8 (3)
C38—C39—C40	120.4 (15)	O11—W1—K0AA	48.7 (3)
C39—C40—C41	125.0 (13)	O12—W1—O5	154.3 (4)
C48—C40—C39	115.6 (12)	O12—W1—O6	92.2 (4)
C48—C40—C41	119.4 (13)	O12—W1—O11	87.8 (4)
C42—C41—C40	120.6 (15)	O12—W1—O26	71.5 (3)
C41—C42—C43	122.1 (14)	O12—W1—K0AA	135.7 (3)
C44—C43—C42	126.5 (14)	O26—W1—K0AA	96.8 (2)
C47—C43—C42	117.6 (14)	O2—W2—O4	102.7 (4)
C47—C43—C44	115.8 (14)	O2—W2—O5	102.2 (4)
C45—C44—C43	121.1 (14)	O2—W2—O9	102.4 (4)
C44—C45—C46	118.6 (15)	O2—W2—O10	101.1 (4)
N8—C46—C45	123.0 (14)	O2—W2—O28	171.3 (3)
C43—C47—C48	121.3 (13)	O2—W2—K0AA	81.6 (3)
N8—C47—C43	122.6 (13)	O4—W2—O28	84.0 (3)
N8—C47—C48	116.1 (12)	O4—W2—K0AA	132.2 (3)
C40—C48—C47	118.9 (12)	O5—W2—O4	85.8 (4)
N7—C48—C40	123.7 (13)	O5—W2—O9	155.3 (4)
N7—C48—C47	117.4 (13)	O5—W2—O10	88.5 (4)
O45—C49—C50	116.2 (14)	O5—W2—O28	83.7 (3)
O45—C49—O46	126.9 (14)	O5—W2—K0AA	47.5 (3)
O46—C49—C50	116.9 (14)	O9—W2—O4	86.8 (4)
C49—C50—K1^i	83.7 (9)	O9—W2—O10	88.8 (4)
O43—C51—C52	119 (2)	O9—W2—O28	72.1 (3)
O43—C51—O44	122.8 (18)	O9—W2—K0AA	139.5 (3)
O44—C51—C52	118.2 (19)	O10—W2—O4	156.1 (4)
O48—C53—C1AA	119.7 (13)	O10—W2—O28	72.3 (3)
O48—C53—O49	123.8 (13)	O10—W2—K0AA	51.4 (3)
O49—C53—C1AA	116.3 (13)	O28—W2—K0AA	98.1 (2)
C53—C1AA—K0AA	83.5 (9)	O3—W3—O4	102.8 (4)
O50—C55—C56	118.4 (13)	O3—W3—O6	103.4 (4)
O51—C55—C56	117.6 (12)	O3—W3—O7	102.3 (4)
O51—C55—O50	124.0 (13)	O3—W3—O8	100.0 (4)
C1—N1—C12	117.0 (13)	O3—W3—O27	168.9 (4)
C1—N1—Cu1	130.1 (10)	O4—W3—O6	84.2 (4)
C12—N1—Cu1	112.8 (9)	O4—W3—O27	84.6 (3)
C10—N2—C11	118.0 (13)	O6—W3—O27	85.5 (3)
C10—N2—Cu1	129.7 (11)	O7—W3—O4	154.9 (4)
C11—N2—Cu1	112.3 (9)	O7—W3—O6	88.0 (4)
C13—N3—C24	116.5 (14)	O7—W3—O8	89.4 (4)
C13—N3—Cu2	129.3 (11)	O7—W3—O27	71.0 (3)
C24—N3—Cu2	114.2 (10)	O8—W3—O4	88.3 (4)
C22—N4—C23	119.1 (14)	O8—W3—O6	156.4 (4)
C22—N4—Cu2	129.0 (12)	O8—W3—O27	71.6 (3)
C23—N4—Cu2	111.9 (10)	O7—W4—O27	69.5 (3)
C25—N5—C36	116.2 (12)	O13—W4—O7	99.2 (4)
C25—N5—Cu3	131.0 (9)	O13—W4—O14	102.1 (4)
C36—N5—Cu3	112.7 (9)	O13—W4—O25	102.3 (4)
C34—N6—C35	117.6 (12)	O13—W4—O27	166.4 (4)
C34—N6—Cu3	129.6 (10)	O13—W4—O35	104.5 (4)
C35—N6—Cu3	112.8 (9)	O14—W4—O7	83.3 (4)
C37—N7—C48	117.6 (12)	O14—W4—O27	69.9 (3)
C37—N7—Cu4	130.8 (10)	O25—W4—O7	84.8 (4)
C48—N7—Cu4	111.2 (9)	O25—W4—O14	154.2 (4)
C46—N8—C47	118.9 (12)	O25—W4—O27	84.5 (3)
C46—N8—Cu4	129.0 (10)	O35—W4—O7	156.3 (4)
C47—N8—Cu4	111.9 (9)	O35—W4—O14	91.2 (4)
W1—O0AA—Cu3	133.4 (5)	O35—W4—O25	90.6 (4)
W2—O4—W3	152.8 (5)	O35—W4—O27	87.0 (3)
W1—O5—K0AA	104.3 (4)	O8—W5—O27	72.5 (3)
W2—O5—W1	152.3 (5)	O14—W5—O8	87.0 (4)
W2—O5—K0AA	103.2 (4)	O14—W5—O16	156.8 (4)
W1—O6—W3	153.0 (5)	O14—W5—O27	71.9 (3)
W3—O7—W4	127.1 (4)	O15—W5—O8	100.2 (4)
W3—O8—W5	124.3 (5)	O15—W5—O14	100.6 (4)
W2—O9—W6	123.7 (5)	O15—W5—O16	102.2 (4)
W2—O10—W7	123.7 (5)	O15—W5—O27	169.5 (4)
W2—O10—K0AA	98.7 (3)	O15—W5—O30	104.0 (4)
W7—O10—K0AA	107.8 (4)	O16—W5—O8	84.8 (4)
W1—O11—K0AA	101.5 (4)	O16—W5—O27	84.9 (3)
W8—O11—W1	124.6 (5)	O30—W5—O8	155.5 (4)
W8—O11—K0AA	107.9 (4)	O30—W5—O14	92.9 (4)
W1—O12—W9	125.9 (4)	O30—W5—O16	85.7 (4)
W5—O14—W4	125.2 (5)	O30—W5—O27	84.1 (3)
W6—O16—W5	148.4 (5)	O9—W6—O28	71.9 (3)
W7—O18—W6	123.1 (4)	O16—W6—O9	87.7 (4)
W7—O20—W8	150.2 (5)	O16—W6—O18	157.9 (4)
W7—O20—K0AA	105.7 (4)	O16—W6—O28	86.0 (3)
W8—O20—K0AA	101.8 (3)	O17—W6—O9	99.4 (4)
W8—O23—K1	101.3 (3)	O17—W6—O16	103.1 (4)
W8—O23—W9	125.1 (5)	O17—W6—O18	98.6 (4)
W9—O23—K1	100.2 (3)	O17—W6—O28	167.4 (4)
W9—O25—W4	144.3 (5)	O17—W6—O31	105.0 (4)
As1—O26—W1	125.1 (5)	O18—W6—O9	84.3 (4)
As1—O26—W8	122.9 (4)	O18—W6—O28	71.9 (3)
As1—O26—W9	122.4 (4)	O31—W6—O9	155.5 (4)
W8—O26—W1	91.4 (3)	O31—W6—O16	88.3 (4)
W8—O26—W9	93.5 (3)	O31—W6—O18	90.4 (4)
W9—O26—W1	92.7 (3)	O31—W6—O28	83.7 (3)
As1—O27—W3	125.2 (4)	O10—W7—O28	71.8 (3)
As1—O27—W4	122.4 (4)	O10—W7—K0AA	44.6 (3)
As1—O27—W5	123.3 (4)	O18—W7—O10	84.9 (4)
W4—O27—W3	92.4 (3)	O18—W7—O20	156.5 (4)
W5—O27—W3	91.5 (3)	O18—W7—O28	72.4 (3)
W5—O27—W4	92.9 (3)	O18—W7—K0AA	129.2 (3)
As1—O28—W2	126.0 (4)	O19—W7—O10	100.0 (4)
As1—O28—W6	121.7 (4)	O19—W7—O18	100.0 (4)
As1—O28—W7	123.2 (4)	O19—W7—O20	102.8 (4)
W6—O28—W2	92.2 (3)	O19—W7—O28	169.0 (4)
W6—O28—W7	92.2 (3)	O19—W7—O32	104.9 (4)
W7—O28—W2	92.2 (3)	O19—W7—K0AA	87.2 (3)
As1—O29—W10	123.7 (4)	O20—W7—O10	85.8 (4)
As1—O29—W11	124.5 (4)	O20—W7—O28	84.2 (3)
W10—O29—W11	93.1 (3)	O20—W7—K0AA	47.3 (3)
W5—O30—W11	157.0 (5)	O28—W7—K0AA	91.5 (2)
W6—O31—W11	153.7 (5)	O32—W7—O10	155.0 (4)
W7—O32—W10	154.1 (5)	O32—W7—O18	92.4 (4)
W8—O33—K1	103.8 (3)	O32—W7—O20	87.1 (4)
W8—O33—W10	155.5 (5)	O32—W7—O28	83.7 (3)
W10—O33—K1	98.7 (3)	O32—W7—K0AA	134.4 (3)
Ho1—O34—K1	95.0 (3)	O11—W8—O20	88.0 (4)
W9—O34—K1	106.8 (4)	O11—W8—O23	87.7 (4)
W9—O34—Ho1	158.1 (5)	O11—W8—O26	73.0 (3)
W4—O35—Ho1	161.0 (5)	O11—W8—K1	137.6 (3)
Ho1—O37—K1	97.1 (3)	O11—W8—K0AA	44.8 (3)
W10—O37—K1	105.6 (4)	O20—W8—O26	86.4 (3)
W10—O37—Ho1	133.0 (4)	O20—W8—K1	132.6 (3)
W11—O38—Ho1	132.6 (5)	O20—W8—K0AA	49.9 (3)
W11—O39—Cu1	149.0 (5)	O21—W8—O11	100.1 (4)
W10—O40—W11	121.6 (4)	O21—W8—O20	101.5 (4)
Ho1—O42—Ho1^ii	113.4 (4)	O21—W8—O23	101.0 (4)
C0AA—O42—Ho1	130.7 (9)	O21—W8—O26	169.5 (4)
C0AA—O42—Ho1^ii	92.3 (8)	O21—W8—O33	103.3 (4)
C51—O43—Cu1	128.9 (12)	O21—W8—K1	84.8 (3)
C51—O44—Cu2	128.7 (12)	O21—W8—K0AA	85.5 (3)
C49—O45—K1^i	115.4 (9)	O23—W8—O20	157.5 (4)
C49—O45—Cu2	129.0 (10)	O23—W8—O26	71.3 (3)
Cu2—O45—K1^i	110.0 (4)	O23—W8—K1	50.4 (3)
C49—O46—Cu1	124.4 (10)	O23—W8—K0AA	132.1 (3)
Cu2—O47—K1^i	100.9 (4)	O26—W8—K1	94.9 (2)
C53—O48—Cu3	128.4 (9)	O26—W8—K0AA	94.6 (2)
C53—O48—K0AA	108.5 (8)	O33—W8—O11	156.4 (4)
Cu3—O48—K0AA	122.5 (4)	O33—W8—O20	85.0 (4)
C53—O49—Cu4	127.3 (10)	O33—W8—O23	90.2 (4)
C55—O50—Cu3	124.4 (9)	O33—W8—O26	84.1 (3)
C55—O51—Cu4	130.9 (9)	O33—W8—K1	48.3 (3)
C50^iv—K1—W9	95.3 (3)	O33—W8—K0AA	134.8 (3)
C50^iv—K1—W10	119.1 (3)	K1—W8—K0AA	170.33 (12)
O23—K1—C50^iv	71.3 (3)	O12—W9—O26	69.8 (3)
O23—K1—W9	29.16 (16)	O12—W9—K1	132.4 (3)
O23—K1—W10	78.38 (18)	O23—W9—O12	82.0 (4)
O33—K1—C50^iv	93.5 (3)	O23—W9—O26	70.0 (3)
O33—K1—O23	52.2 (2)	O23—W9—K1	50.7 (3)
O33—K1—O34	64.8 (2)	O24—W9—O12	98.3 (4)
O33—K1—W9	64.59 (17)	O24—W9—O23	101.9 (4)
O33—K1—W10	29.95 (17)	O24—W9—O25	102.3 (4)
O34—K1—C50^iv	120.5 (3)	O24—W9—O26	166.1 (4)
O34—K1—O23	51.2 (2)	O24—W9—O34	104.5 (4)
O34—K1—W9	25.29 (16)	O24—W9—K1	88.3 (3)
O34—K1—W10	67.07 (17)	O25—W9—O12	84.3 (4)
O37—K1—C50^iv	145.4 (3)	O25—W9—O23	153.6 (4)
O37—K1—O23	91.5 (3)	O25—W9—O26	84.1 (3)
O37—K1—O33	53.4 (2)	O25—W9—K1	140.3 (3)
O37—K1—O34	58.9 (2)	O26—W9—K1	94.6 (2)
O37—K1—W9	80.22 (18)	O34—W9—O12	157.1 (4)
O37—K1—W10	26.35 (17)	O34—W9—O23	91.4 (4)
O45^iv—K1—C50^iv	42.7 (3)	O34—W9—O25	92.5 (4)
O45^iv—K1—O23	95.1 (3)	O34—W9—O26	87.3 (3)
O45^iv—K1—O33	80.9 (3)	O34—W9—K1	47.9 (3)
O45^iv—K1—O34	141.9 (3)	O29—W10—K1	97.9 (2)
O45^iv—K1—O37	113.3 (3)	O32—W10—O29	82.5 (3)
O45^iv—K1—O47^iv	60.4 (3)	O32—W10—K1	131.9 (3)
O45^iv—K1—O55^iii	70.1 (3)	O33—W10—O29	85.3 (3)
O45^iv—K1—W9	124.3 (2)	O33—W10—O32	81.0 (4)
O45^iv—K1—W10	91.6 (2)	O33—W10—K1	51.3 (3)
O45^iv—K1—O6AA^iv	106.0 (3)	O36—W10—O29	172.4 (4)
O47^iv—K1—C50^iv	102.1 (3)	O36—W10—O32	96.9 (4)
O47^iv—K1—O23	134.0 (3)	O36—W10—O33	102.2 (4)
O47^iv—K1—O33	84.0 (3)	O36—W10—O37	102.1 (4)
O47^iv—K1—O34	127.1 (3)	O36—W10—O40	100.0 (4)
O47^iv—K1—O37	68.2 (3)	O36—W10—K1	88.2 (3)
O47^iv—K1—O55^iii	68.8 (3)	O37—W10—O29	78.9 (3)
O47^iv—K1—W9	145.0 (2)	O37—W10—O32	160.9 (3)
O47^iv—K1—W10	65.3 (2)	O37—W10—O33	93.2 (4)
O55^iii—K1—C50^iv	75.6 (4)	O37—W10—O40	93.8 (4)
O55^iii—K1—O23	142.9 (3)	O37—W10—K1	48.0 (3)
O55^iii—K1—O33	147.2 (3)	O40—W10—O29	72.4 (3)
O55^iii—K1—O34	147.1 (3)	O40—W10—O32	84.6 (4)
O55^iii—K1—O37	125.5 (3)	O40—W10—O33	154.8 (4)
O55^iii—K1—W9	145.8 (3)	O40—W10—K1	141.7 (3)
O55^iii—K1—W10	133.7 (3)	O30—W11—O29	83.4 (3)
W10—K1—W9	79.73 (8)	O30—W11—O31	80.8 (4)
O1AA^ii—K1—C50^iv	150.5 (3)	O30—W11—O40	153.4 (4)
O1AA^ii—K1—O23	110.2 (3)	O31—W11—O29	81.8 (3)
O1AA^ii—K1—O33	110.8 (3)	O38—W11—O29	79.2 (4)
O1AA^ii—K1—O34	60.6 (3)	O38—W11—O30	92.8 (4)
O1AA^ii—K1—O37	63.2 (3)	O38—W11—O31	160.6 (4)
O1AA^ii—K1—O45^iv	154.3 (3)	O38—W11—O40	92.9 (4)
O1AA^ii—K1—O47^iv	97.0 (3)	O39—W11—O29	173.2 (3)
O1AA^ii—K1—O55^iii	91.0 (4)	O39—W11—O30	103.0 (4)
O1AA^ii—K1—W9	81.1 (2)	O39—W11—O31	96.8 (4)
O1AA^ii—K1—W10	89.3 (2)	O39—W11—O38	102.5 (4)
O1AA^ii—K1—O6AA^iv	87.2 (3)	O39—W11—O40	101.2 (4)
O6AA^iv—K1—C50^iv	65.0 (3)	O40—W11—O29	72.1 (3)
O6AA^iv—K1—O23	70.7 (3)	O40—W11—O31	85.4 (4)
O6AA^iv—K1—O33	122.9 (3)	O42—C0AA—C54	121.2 (13)
O6AA^iv—K1—O34	81.4 (3)	O42—C0AA—Ho1^ii	61.3 (7)
O6AA^iv—K1—O37	138.2 (3)	C54—C0AA—Ho1^ii	174.5 (11)
O6AA^iv—K1—O47^iv	149.2 (4)	O1AA—C0AA—O42	119.9 (13)
O6AA^iv—K1—O55^iii	80.7 (4)	O1AA—C0AA—C54	118.8 (13)
O6AA^iv—K1—W9	65.8 (3)	O1AA—C0AA—Ho1^ii	58.8 (7)
O6AA^iv—K1—W10	145.5 (3)	Ho1^ii—O1AA—K1^ii	101.8 (3)
N1—Cu1—N2	82.8 (5)	C0AA—O1AA—K1^ii	125.1 (9)
N1—Cu1—O39	91.0 (4)	C0AA—O1AA—Ho1^ii	95.1 (8)
N1—Cu1—Cu2	101.4 (4)	C1AA—K0AA—W1	97.2 (3)
N2—Cu1—O39	106.8 (4)	C1AA—K0AA—W2	152.0 (3)
N2—Cu1—Cu2	83.9 (3)	C1AA—K0AA—W7	115.3 (3)
O39—Cu1—Cu2	164.6 (2)	C1AA—K0AA—W8	73.4 (3)
O43—Cu1—N1	174.8 (4)	O5—K0AA—C1AA	125.6 (4)
O43—Cu1—N2	92.0 (5)	O5—K0AA—O10	53.9 (3)
O43—Cu1—O39	90.3 (4)	O5—K0AA—O11	53.1 (3)
O43—Cu1—O46	92.8 (4)	O5—K0AA—O20	63.5 (3)
O43—Cu1—Cu2	78.1 (3)	O5—K0AA—O48	96.3 (3)
O46—Cu1—N1	92.3 (5)	O5—K0AA—W1	29.25 (19)
O46—Cu1—N2	161.5 (5)	O5—K0AA—W2	29.33 (19)
O46—Cu1—O39	91.0 (4)	O5—K0AA—W7	64.3 (2)
O46—Cu1—Cu2	79.6 (3)	O5—K0AA—W8	63.9 (2)
N3—Cu2—N4	82.1 (5)	O5—K0AA—O1BA	103.4 (6)
N3—Cu2—O47	103.4 (5)	O10—K0AA—C1AA	142.9 (4)
N3—Cu2—K1^i	102.4 (4)	O10—K0AA—O20	51.5 (3)
N3—Cu2—Cu1	88.1 (4)	O10—K0AA—O48	147.8 (4)
N4—Cu2—O47	89.7 (4)	O10—K0AA—W1	80.0 (2)
N4—Cu2—K1^i	135.6 (4)	O10—K0AA—W2	29.89 (17)
N4—Cu2—Cu1	106.3 (4)	O10—K0AA—W7	27.61 (18)
O44—Cu2—N3	162.2 (5)	O10—K0AA—W8	76.3 (2)
O44—Cu2—N4	91.8 (5)	O11—K0AA—C1AA	73.4 (4)
O44—Cu2—O45	92.5 (5)	O11—K0AA—O10	89.0 (3)
O44—Cu2—O47	93.2 (5)	O11—K0AA—O20	52.2 (3)
O44—Cu2—K1^i	93.7 (3)	O11—K0AA—O48	60.5 (3)
O44—Cu2—Cu1	77.5 (4)	O11—K0AA—W1	29.80 (18)
O45—Cu2—N3	94.1 (5)	O11—K0AA—W2	79.0 (2)
O45—Cu2—N4	175.4 (5)	O11—K0AA—W7	75.9 (2)
O45—Cu2—O47	88.6 (4)	O11—K0AA—W8	27.31 (17)
O45—Cu2—K1^i	42.5 (3)	O11—K0AA—O1BA	144.1 (6)
O45—Cu2—Cu1	76.1 (3)	O20—K0AA—C1AA	93.2 (4)
O47—Cu2—K1^i	46.1 (3)	O20—K0AA—W1	66.9 (2)
O47—Cu2—Cu1	161.6 (3)	O20—K0AA—W2	65.6 (2)
Cu1—Cu2—K1^i	117.83 (8)	O20—K0AA—W7	26.96 (17)
N5—Cu3—O0AA	86.2 (4)	O20—K0AA—W8	28.26 (17)
N5—Cu3—Cu4	97.8 (3)	O48—K0AA—C1AA	42.1 (3)
N6—Cu3—N5	83.0 (5)	O48—K0AA—O20	107.7 (3)
N6—Cu3—O0AA	93.3 (4)	O48—K0AA—W1	68.4 (2)
N6—Cu3—Cu4	95.1 (3)	O48—K0AA—W2	124.7 (3)
O0AA—Cu3—Cu4	171.0 (2)	O48—K0AA—W7	134.4 (3)
O48—Cu3—N5	93.0 (4)	O48—K0AA—W8	79.5 (2)
O48—Cu3—N6	171.0 (5)	W1—K0AA—W7	80.70 (14)
O48—Cu3—O0AA	94.5 (3)	W1—K0AA—W8	51.90 (9)
O48—Cu3—Cu4	77.3 (3)	W2—K0AA—W1	58.54 (10)
O50—Cu3—N5	175.9 (4)	W2—K0AA—W7	51.62 (9)
O50—Cu3—N6	93.4 (4)	W2—K0AA—W8	79.95 (14)
O50—Cu3—O0AA	95.9 (4)	W8—K0AA—W7	54.91 (9)
O50—Cu3—O48	90.3 (4)	O0BA—K0AA—C1AA	116.7 (6)
O50—Cu3—Cu4	80.7 (3)	O0BA—K0AA—O5	72.3 (5)
N7—Cu4—O52	106.5 (5)	O0BA—K0AA—O10	98.8 (5)
N7—Cu4—Cu3	88.9 (3)	O0BA—K0AA—O11	103.6 (5)
N8—Cu4—N7	82.3 (4)	O0BA—K0AA—O20	135.6 (6)
N8—Cu4—O52	96.5 (4)	O0BA—K0AA—O48	80.3 (5)
N8—Cu4—Cu3	97.0 (3)	O0BA—K0AA—W1	77.0 (5)
O49—Cu4—N7	91.2 (4)	O0BA—K0AA—W2	74.1 (5)
O49—Cu4—N8	171.3 (4)	O0BA—K0AA—W7	125.2 (5)
O49—Cu4—O51	91.9 (4)	O0BA—K0AA—W8	128.8 (5)
O49—Cu4—O52	91.0 (4)	O0BA—K0AA—O1BA	91.5 (7)
O49—Cu4—Cu3	76.9 (3)	O1BA—K0AA—C1AA	128.1 (6)
O51—Cu4—N7	162.8 (4)	O1BA—K0AA—O10	56.2 (6)
O51—Cu4—N8	92.7 (4)	O1BA—K0AA—O20	94.5 (6)
O51—Cu4—O52	90.4 (4)	O1BA—K0AA—O48	155.3 (6)
O51—Cu4—Cu3	75.4 (3)	O1BA—K0AA—W1	132.7 (6)
O52—Cu4—Cu3	160.7 (3)	O1BA—K0AA—W2	74.1 (5)
O27—As1—O26	107.5 (4)	O1BA—K0AA—W7	68.9 (5)
O27—As1—O28	108.1 (4)	O1BA—K0AA—W8	122.6 (5)
O28—As1—O26	107.4 (4)

Symmetry codes: (i) x, y+1, z; (ii) −x+1/2, −y+1/2, −z+1/2; (iii) −x+1/2, −y−1/2, −z+1/2; (iv) x, y−1, z.

(fhsp25c)

Crystal data

K2{[Cu2(H2O)(C12H8N2)2(C2H3O2)2]4[Eu2(H2O)2(C2H3O2)2 (AsW11O39)2]}·24H2O	F(000) = 16076
Mr = 8868.59	Dx = 2.965 Mg m^−3
Monoclinic, I2/a	Mo Kα radiation, λ = 0.71073 Å
a = 30.581 (2) Å	Cell parameters from 5360 reflections
b = 14.1638 (6) Å	θ = 2.9–24.5°
c = 48.299 (3) Å	µ = 14.83 mm^−1
β = 108.273 (7)°	T = 140 K
V = 19865 (2) Å^3	Block, blue
Z = 4	0.09 × 0.07 × 0.01 mm

Data collection

Agulent Xcalibur Sapphire3 diffractometer	18853 independent reflections
Radiation source: Enhance (Mo) X-ray Source	9768 reflections with I > 2σ(I)
Detector resolution: 15.9853 pixels mm^-1	Rint = 0.247
ω scans	θmax = 25.7°, θmin = 2.9°
Absorption correction: multi-scan (CrysAlis PRO; Agilent, 2013)	h = −37→37
Tmin = 0.664, Tmax = 1.000	k = −17→17
126680 measured reflections	l = −58→58

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.087	H-atom parameters constrained
wR(F^2) = 0.183	w = 1/[σ^2(Fo^2) + (0.0242P)^2 + 52.5653P] where P = (Fo^2 + 2Fc^2)/3
S = 1.06	(Δ/σ)max = 0.001
18853 reflections	Δρmax = 3.76 e Å^−3
690 parameters	Δρmin = −2.33 e Å^−3

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
C1	0.2859 (10)	0.609 (2)	0.1094 (6)	0.034 (8)*
H1	0.263962	0.604289	0.118957	0.041*
C2	0.2723 (11)	0.620 (2)	0.0798 (6)	0.037 (8)*
H2	0.240900	0.622187	0.069832	0.045*
C3	0.3022 (11)	0.629 (2)	0.0641 (7)	0.049 (10)*
H3	0.291601	0.636779	0.043966	0.059*
C4	0.3486 (11)	0.626 (2)	0.0790 (7)	0.044 (9)*
C5	0.3837 (11)	0.641 (2)	0.0672 (7)	0.041 (9)*
H5	0.375621	0.656057	0.047527	0.049*
C6	0.4256 (11)	0.636 (2)	0.0812 (7)	0.041 (9)*
H6	0.446704	0.638027	0.070969	0.050*
C7	0.4428 (10)	0.627 (2)	0.1127 (6)	0.035 (8)*
C8	0.4897 (11)	0.634 (2)	0.1304 (7)	0.047 (9)*
H8	0.513712	0.645295	0.122885	0.056*
C9	0.4960 (11)	0.621 (2)	0.1589 (7)	0.047 (9)*
H9	0.526332	0.621977	0.171135	0.057*
C10	0.4617 (10)	0.606 (2)	0.1723 (7)	0.041 (9)*
H10	0.469094	0.600804	0.192389	0.049*
C11	0.4088 (11)	0.616 (2)	0.1257 (7)	0.044 (9)*
C12	0.3616 (11)	0.613 (2)	0.1091 (7)	0.046 (9)*
C13	0.3328 (9)	0.8365 (18)	0.1252 (6)	0.023 (7)*
H13	0.305091	0.825404	0.128853	0.028*
C14	0.3298 (12)	0.860 (2)	0.0959 (7)	0.051 (10)*
H14	0.302030	0.861618	0.080764	0.061*
C15	0.3717 (12)	0.880 (2)	0.0919 (8)	0.056 (10)*
H15	0.371614	0.895768	0.073171	0.067*
C16	0.4141 (12)	0.877 (2)	0.1139 (7)	0.053 (10)*
C17	0.4584 (11)	0.896 (2)	0.1103 (7)	0.044 (9)*
H17	0.461815	0.911150	0.092400	0.052*
C18	0.4958 (12)	0.889 (2)	0.1358 (7)	0.056 (10)*
H18	0.523816	0.905644	0.133320	0.067*
C19	0.4992 (13)	0.864 (3)	0.1632 (8)	0.060 (11)*
C20	0.5352 (14)	0.857 (3)	0.1888 (8)	0.070 (12)*
H20	0.564793	0.873617	0.189183	0.084*
C21	0.5281 (13)	0.828 (3)	0.2123 (8)	0.068 (12)*
H21	0.553605	0.825453	0.228981	0.082*
C22	0.4858 (11)	0.800 (2)	0.2153 (7)	0.047 (9)*
H22	0.483754	0.773413	0.232373	0.056*
C23	0.4541 (12)	0.841 (2)	0.1658 (7)	0.051 (10)*
C24	0.4110 (10)	0.849 (2)	0.1402 (7)	0.036 (8)*
C25	0.1016 (9)	−0.2041 (18)	0.1285 (6)	0.024 (7)*
H25	0.124728	−0.215844	0.120218	0.029*
C26	0.1118 (9)	−0.2082 (19)	0.1580 (6)	0.026 (7)*
H26	0.141770	−0.223011	0.169223	0.031*
C27	0.0807 (9)	−0.192 (2)	0.1713 (6)	0.031 (8)*
H27	0.089472	−0.192394	0.191568	0.038*
C28	0.0372 (8)	−0.1755 (17)	0.1560 (5)	0.013 (6)*
C29	−0.0023 (11)	−0.154 (2)	0.1663 (8)	0.054 (10)*
H29	0.003366	−0.149799	0.186374	0.065*
C30	−0.0461 (10)	−0.141 (2)	0.1488 (6)	0.031 (8)*
H30	−0.069269	−0.132887	0.157336	0.038*
C31	−0.0577 (9)	−0.1392 (18)	0.1185 (5)	0.017 (6)*
C32	−0.1014 (12)	−0.119 (2)	0.0968 (7)	0.051 (10)*
H32	−0.126646	−0.104009	0.102750	0.061*
C33	−0.1060 (10)	−0.1228 (19)	0.0684 (6)	0.032 (8)*
H33	−0.135382	−0.117477	0.055006	0.038*
C34	−0.0692 (9)	−0.1340 (18)	0.0580 (6)	0.020 (7)*
H34	−0.073867	−0.131344	0.038005	0.024*
C35	−0.0185 (8)	−0.1487 (16)	0.1065 (5)	0.009 (5)*
C36	0.0254 (8)	−0.1678 (17)	0.1245 (5)	0.011 (6)*
C37	0.0555 (9)	−0.4141 (18)	0.1173 (5)	0.020 (7)*
H37	0.084080	−0.422691	0.114663	0.024*
C38	0.0555 (10)	−0.4204 (19)	0.1461 (6)	0.028 (7)*
H38	0.082059	−0.433849	0.161393	0.034*
C39	0.0142 (10)	−0.406 (2)	0.1503 (7)	0.037 (8)*
H39	0.012806	−0.404617	0.169261	0.045*
C40	−0.0247 (10)	−0.393 (2)	0.1280 (6)	0.034 (8)*
C41	−0.0708 (10)	−0.382 (2)	0.1290 (7)	0.041 (9)*
H41	−0.074901	−0.383132	0.147304	0.049*
C42	−0.1063 (9)	−0.3698 (18)	0.1073 (6)	0.023 (7)*
H42	−0.134665	−0.363068	0.110295	0.028*
C43	−0.1040 (10)	−0.366 (2)	0.0766 (6)	0.032 (8)*
C44	−0.1419 (10)	−0.359 (2)	0.0502 (6)	0.033 (8)*
H44	−0.172131	−0.356804	0.050540	0.039*
C45	−0.1322 (10)	−0.3562 (19)	0.0249 (6)	0.029 (7)*
H45	−0.156051	−0.351540	0.007411	0.035*
C46	−0.0878 (9)	−0.3600 (19)	0.0245 (6)	0.029 (7)*
H46	−0.082288	−0.356845	0.006678	0.035*
C47	−0.0596 (10)	−0.378 (2)	0.0748 (6)	0.027 (7)*
C48	−0.0186 (10)	−0.386 (2)	0.0989 (6)	0.028 (7)*
C49	0.2912 (9)	0.698 (2)	0.1792 (6)	0.023 (7)*
C50	0.2430 (9)	0.709 (2)	0.1811 (6)	0.034 (8)*
H50A	0.244745	0.732420	0.200126	0.051*
H50B	0.227435	0.649671	0.177813	0.051*
H50C	0.226278	0.753812	0.166613	0.051*
C51	0.4033 (12)	0.626 (3)	0.2268 (7)	0.051 (10)*
C52	0.4199 (12)	0.587 (3)	0.2571 (7)	0.072 (12)*
H52A	0.412405	0.521265	0.256680	0.108*
H52B	0.405296	0.620168	0.269198	0.108*
H52C	0.452693	0.594933	0.264945	0.108*
C53	0.1046 (10)	−0.290 (2)	0.0632 (6)	0.030 (7)*
C1AA	0.1549 (10)	−0.305 (2)	0.0666 (7)	0.049 (9)*
H1AA	0.159086	−0.306269	0.047709	0.074*	0.5
H1AB	0.165059	−0.363828	0.076385	0.074*
H1AC	0.172602	−0.254232	0.077863	0.074*
C55	0.0010 (9)	−0.217 (2)	0.0082 (6)	0.022 (7)*
C56	−0.0057 (11)	−0.191 (2)	−0.0229 (6)	0.047 (9)*
H56A	−0.026402	−0.138257	−0.028256	0.071*
H56B	−0.018433	−0.243728	−0.035271	0.071*
H56C	0.023426	−0.174118	−0.025105	0.071*
N1	0.3304 (7)	0.6057 (15)	0.1246 (5)	0.025 (6)*
N2	0.4169 (7)	0.6010 (15)	0.1545 (5)	0.025 (6)*
N3	0.3710 (8)	0.8290 (17)	0.1480 (5)	0.035 (7)*
N4	0.4471 (9)	0.8155 (18)	0.1912 (5)	0.041 (7)*
N5	0.0595 (7)	−0.1835 (14)	0.1113 (4)	0.014 (5)*
N6	−0.0255 (8)	−0.1491 (17)	0.0768 (5)	0.036 (7)*
N7	0.0209 (7)	−0.3975 (15)	0.0930 (5)	0.023 (6)*
N8	−0.0523 (7)	−0.3678 (15)	0.0486 (5)	0.024 (6)*
O1	0.0536 (6)	−0.0092 (14)	0.0766 (4)	0.036 (5)*
O1AA	0.1101 (6)	0.1903 (13)	0.0122 (4)	0.030 (5)*
O3	0.0345 (6)	0.3453 (12)	0.0772 (4)	0.023 (4)*
O4	0.1164 (6)	0.2788 (12)	0.0662 (3)	0.020 (4)*
O5	0.1266 (6)	0.1010 (13)	0.0658 (4)	0.032 (5)*
O6	0.0830 (6)	0.1740 (12)	0.0995 (4)	0.024 (5)*
O7	0.0898 (6)	0.3189 (13)	0.1349 (4)	0.032 (5)*
O8	0.1205 (6)	0.4271 (12)	0.1004 (4)	0.022 (4)*
O9	0.1838 (6)	0.3035 (12)	0.0439 (4)	0.025 (5)*
O10	0.1978 (6)	0.1172 (12)	0.0447 (4)	0.025 (5)*
O11	0.1468 (6)	−0.0524 (13)	0.0988 (4)	0.030 (5)*
O12	0.1063 (6)	0.0226 (12)	0.1350 (4)	0.022 (4)*
O13	0.1192 (6)	0.3457 (13)	0.1966 (4)	0.029 (5)*
O14	0.1609 (6)	0.4316 (12)	0.1578 (4)	0.026 (5)*
O15	0.1851 (6)	0.5708 (12)	0.1241 (4)	0.026 (5)*
O16	0.2026 (5)	0.4158 (11)	0.0928 (3)	0.016 (4)*
O17	0.2616 (6)	0.4220 (12)	0.0571 (4)	0.024 (5)*
O18	0.2682 (6)	0.2285 (12)	0.0652 (4)	0.022 (4)*
O19	0.2855 (6)	0.0414 (14)	0.0583 (4)	0.037 (5)*
O20	0.2251 (6)	0.0054 (12)	0.0923 (4)	0.023 (5)*
O21	0.2259 (6)	−0.1656 (12)	0.1221 (3)	0.020 (4)*
O23	0.1891 (6)	−0.0518 (12)	0.1564 (4)	0.024 (5)*
O24	0.1408 (6)	−0.0038 (12)	0.1957 (4)	0.025 (5)*
O25	0.1324 (5)	0.1737 (11)	0.1673 (3)	0.014 (4)*
O26	0.1779 (6)	0.0980 (12)	0.1281 (3)	0.020 (4)*
O27	0.1678 (5)	0.2858 (12)	0.1287 (3)	0.018 (4)*
O28	0.2086 (5)	0.2082 (11)	0.0926 (3)	0.017 (4)*
O29	0.2538 (6)	0.2117 (12)	0.1510 (4)	0.024 (5)*
O30	0.2444 (6)	0.4118 (13)	0.1484 (4)	0.027 (5)*
O31	0.2827 (6)	0.3370 (12)	0.1128 (4)	0.026 (5)*
O32	0.2959 (6)	0.1171 (13)	0.1133 (4)	0.028 (5)*
O33	0.2662 (5)	0.0099 (11)	0.1470 (3)	0.015 (4)*
O34	0.2151 (6)	0.0968 (12)	0.1914 (4)	0.023 (4)*
O35	0.2041 (6)	0.2848 (12)	0.1915 (3)	0.019 (4)*
O36	0.3632 (6)	0.0406 (12)	0.1613 (4)	0.022 (4)*
O37	0.3119 (5)	0.1155 (11)	0.1929 (3)	0.015 (4)*
O38	0.3017 (5)	0.3241 (11)	0.1934 (3)	0.014 (4)*
O39	0.3436 (6)	0.4303 (12)	0.1614 (4)	0.025 (5)*
O40	0.3386 (6)	0.2336 (12)	0.1569 (4)	0.022 (4)*
O41	0.3467 (6)	0.2288 (12)	0.2467 (4)	0.025 (5)*
O42	0.2644 (6)	0.3343 (12)	0.2467 (4)	0.022 (4)*
O43	0.3957 (7)	0.5624 (14)	0.2063 (4)	0.037 (5)*
O44	0.3989 (7)	0.7116 (15)	0.2241 (4)	0.045 (6)*
O45	0.3155 (6)	0.7707 (13)	0.1826 (4)	0.030 (5)*
O46	0.3056 (7)	0.6165 (15)	0.1762 (4)	0.044 (6)*
O47	0.3776 (8)	0.9231 (16)	0.2105 (5)	0.058 (7)*
O48	0.0893 (6)	−0.2055 (12)	0.0620 (3)	0.019 (4)*
O49	0.0812 (6)	−0.3629 (12)	0.0617 (4)	0.023 (4)*
O50	0.0028 (6)	−0.1561 (13)	0.0264 (4)	0.029 (5)*
O51	0.0046 (6)	−0.3032 (13)	0.0145 (4)	0.029 (5)*
O52	0.0150 (8)	−0.5117 (16)	0.0306 (5)	0.064 (7)*
O53	0.4157 (11)	0.229 (2)	0.2119 (7)	0.119 (11)*
C54	0.2504 (10)	0.484 (2)	0.2184 (6)	0.032 (8)*
O55	0.1671 (8)	−0.2990 (17)	0.2458 (5)	0.069 (8)*
O57	0.1770 (11)	0.582 (2)	0.0083 (7)	0.126 (12)*
O58	0.250000	0.274 (3)	0.000000	0.103 (14)*
Cu1	0.36064 (13)	0.5861 (3)	0.16601 (8)	0.0353 (10)
Cu2	0.38036 (12)	0.7876 (3)	0.18802 (9)	0.0377 (10)
Cu3	0.03243 (12)	−0.1672 (2)	0.06828 (7)	0.0267 (9)
Cu4	0.01488 (12)	−0.3706 (2)	0.05221 (8)	0.0275 (9)
As1	0.20334 (9)	0.20159 (18)	0.12542 (5)	0.0128 (6)
Er	0.26968 (4)	0.20833 (9)	0.21523 (3)	0.0218 (3)
W1	0.10328 (4)	0.04847 (8)	0.09643 (2)	0.0213 (3)
W2	0.14750 (4)	0.19623 (8)	0.04700 (2)	0.0213 (3)
W3	0.09006 (4)	0.30972 (8)	0.09633 (2)	0.0206 (3)
W4	0.14479 (4)	0.30882 (8)	0.17095 (2)	0.0200 (3)
W5	0.18393 (4)	0.44908 (8)	0.12575 (2)	0.0204 (3)
W6	0.24042 (4)	0.34045 (8)	0.07607 (2)	0.0206 (3)
W7	0.25578 (4)	0.10210 (8)	0.07566 (2)	0.0212 (3)
W8	0.21080 (4)	−0.04854 (8)	0.12342 (2)	0.0209 (3)
W9	0.16058 (4)	0.05321 (8)	0.17084 (2)	0.0206 (3)
W10	0.31432 (4)	0.10542 (8)	0.15694 (2)	0.0188 (3)
W11	0.30201 (4)	0.34313 (8)	0.15717 (2)	0.0196 (3)
O0AA	0.2126 (6)	0.4287 (13)	0.2533 (4)	0.034 (5)*
C2AA	0.2424 (9)	0.415 (2)	0.2414 (6)	0.026 (7)*
K1	0.2196 (3)	0.5710 (6)	0.29295 (17)	0.0126 (19)*	0.6667
K2	0.1473 (5)	−0.0705 (10)	0.0397 (3)	0.003 (3)*	0.3333
O2AA	0.250000	0.488 (2)	0.000000	0.051 (9)*
O3AA	0.2065 (8)	0.8573 (16)	0.2258 (5)	0.059 (7)*
O4AA	0.4583 (8)	0.4031 (16)	0.2105 (5)	0.058 (7)*
O5AA	−0.1182 (8)	−0.4761 (16)	−0.0383 (5)	0.061 (7)*
O6AA	0.3668 (10)	0.415 (2)	0.2511 (6)	0.108 (11)*
O7AA	0.1843 (14)	0.012 (3)	−0.0066 (9)	0.048 (12)*	0.5
O8AA	0.1128 (19)	−0.230 (4)	−0.0036 (12)	0.097 (19)*	0.5
O9AA	0.1224 (10)	−0.448 (2)	0.2148 (6)	0.098 (10)*
O2	0.4535 (10)	0.963 (2)	0.2611 (6)	0.106 (10)*
O0BA	−0.0583 (11)	0.009 (2)	−0.0075 (7)	0.128 (12)*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Cu1	0.035 (2)	0.030 (2)	0.046 (3)	0.002 (2)	0.020 (2)	0.004 (2)
Cu2	0.026 (2)	0.036 (2)	0.053 (3)	−0.002 (2)	0.016 (2)	−0.010 (2)
Cu3	0.029 (2)	0.025 (2)	0.027 (2)	−0.0035 (18)	0.0088 (17)	−0.0064 (17)
Cu4	0.028 (2)	0.022 (2)	0.035 (2)	0.0008 (18)	0.0137 (18)	−0.0041 (18)
As1	0.0135 (14)	0.0105 (15)	0.0146 (14)	−0.0009 (12)	0.0049 (12)	−0.0002 (12)
Er	0.0222 (7)	0.0213 (8)	0.0234 (7)	−0.0028 (6)	0.0093 (6)	−0.0012 (6)
W1	0.0199 (6)	0.0204 (7)	0.0230 (7)	−0.0023 (6)	0.0060 (5)	−0.0030 (6)
W2	0.0233 (6)	0.0216 (7)	0.0197 (6)	0.0003 (6)	0.0078 (5)	−0.0007 (5)
W3	0.0184 (6)	0.0214 (7)	0.0224 (7)	0.0019 (6)	0.0069 (5)	−0.0006 (5)
W4	0.0200 (6)	0.0219 (7)	0.0181 (6)	0.0006 (6)	0.0058 (5)	−0.0017 (5)
W5	0.0198 (6)	0.0176 (7)	0.0239 (7)	−0.0001 (6)	0.0071 (5)	0.0002 (5)
W6	0.0234 (6)	0.0185 (7)	0.0221 (7)	0.0018 (6)	0.0103 (5)	0.0014 (5)
W7	0.0219 (6)	0.0210 (7)	0.0220 (7)	0.0033 (6)	0.0089 (5)	−0.0002 (5)
W8	0.0203 (6)	0.0187 (7)	0.0236 (7)	−0.0001 (6)	0.0069 (5)	0.0006 (6)
W9	0.0208 (6)	0.0202 (7)	0.0216 (7)	−0.0046 (6)	0.0076 (5)	−0.0014 (6)
W10	0.0200 (6)	0.0149 (7)	0.0222 (7)	0.0009 (5)	0.0079 (5)	0.0008 (5)
W11	0.0206 (6)	0.0172 (7)	0.0221 (7)	−0.0020 (5)	0.0083 (5)	0.0008 (5)

Geometric parameters (Å, º)

C1—C2	1.37 (4)	O10—K2	3.05 (2)
C1—N1	1.33 (3)	O11—W1	1.932 (18)
C2—C3	1.37 (4)	O11—W8	1.944 (18)
C3—C4	1.37 (4)	O11—K2	2.87 (2)
C4—C5	1.38 (4)	O12—W1	1.874 (16)
C4—C12	1.40 (4)	O12—W9	2.033 (17)
C5—C6	1.25 (4)	O13—W4	1.743 (17)
C6—C7	1.45 (4)	O14—W4	1.967 (17)
C7—C8	1.42 (4)	O14—W5	1.908 (16)
C7—C11	1.38 (4)	O15—W5	1.726 (18)
C8—C9	1.34 (4)	O16—W5	1.911 (15)
C9—C10	1.41 (4)	O16—W6	1.928 (15)
C10—N2	1.37 (3)	O17—W6	1.720 (17)
C11—C12	1.42 (4)	O18—W6	1.947 (17)
C11—N2	1.35 (3)	O18—W7	1.929 (17)
C12—N1	1.39 (3)	O19—W7	1.658 (18)
C13—C14	1.43 (4)	O20—W7	1.968 (17)
C13—N3	1.33 (3)	O20—W8	1.857 (16)
C14—C15	1.38 (4)	O20—K2	3.08 (2)
C15—C16	1.40 (4)	O21—W8	1.728 (17)
C16—C17	1.45 (4)	O23—W8	1.908 (16)
C16—C24	1.36 (4)	O23—W9	1.960 (17)
C17—C18	1.39 (4)	O23—K1^ii	3.094 (19)
C18—C19	1.34 (4)	O24—W9	1.708 (16)
C19—C20	1.38 (5)	O25—W4	1.948 (16)
C19—C23	1.46 (4)	O25—W9	1.896 (16)
C20—C21	1.29 (4)	O26—As1	1.684 (17)
C21—C22	1.40 (4)	O26—W1	2.419 (17)
C22—N4	1.39 (4)	O26—W8	2.348 (17)
C23—C24	1.50 (4)	O26—W9	2.374 (16)
C23—N4	1.36 (4)	O27—As1	1.654 (16)
C24—N3	1.42 (3)	O27—W3	2.425 (16)
C25—C26	1.36 (3)	O27—W4	2.381 (15)
C25—N5	1.33 (3)	O27—W5	2.378 (16)
C26—C27	1.33 (3)	O28—As1	1.647 (15)
C27—C28	1.33 (3)	O28—W2	2.406 (16)
C28—C29	1.47 (4)	O28—W6	2.361 (16)
C28—C36	1.45 (3)	O28—W7	2.397 (16)
C29—C30	1.36 (4)	O29—As1	1.653 (17)
C30—C31	1.40 (3)	O29—W10	2.334 (17)
C31—C32	1.44 (4)	O29—W11	2.335 (17)
C31—C35	1.49 (3)	O30—W5	1.906 (18)
C32—C33	1.34 (4)	O30—W11	1.938 (18)
C33—C34	1.38 (3)	O31—W6	1.840 (17)
C34—N6	1.38 (3)	O31—W11	2.036 (17)
C35—C36	1.38 (3)	O32—W7	1.860 (18)
C35—N6	1.38 (3)	O32—W10	2.010 (17)
C36—N5	1.40 (3)	O33—W8	1.909 (16)
C37—C38	1.39 (3)	O33—W10	1.946 (16)
C37—N7	1.33 (3)	O33—K1^ii	3.020 (17)
C38—C39	1.36 (3)	O34—Er	2.323 (17)
C39—C40	1.34 (4)	O34—W9	1.764 (17)
C40—C41	1.44 (4)	O34—K1^ii	3.043 (19)
C40—C48	1.48 (4)	O35—Er	2.251 (17)
C41—C42	1.26 (4)	O35—W4	1.806 (16)
C42—C43	1.51 (3)	O36—W10	1.710 (17)
C43—C44	1.43 (4)	O37—Er	2.330 (15)
C43—C47	1.40 (3)	O37—W10	1.769 (15)
C44—C45	1.35 (3)	O37—K1^ii	2.965 (18)
C45—C46	1.36 (3)	O38—Er	2.327 (15)
C46—N8	1.32 (3)	O38—W11	1.772 (15)
C47—C48	1.42 (4)	O39—Cu1	2.262 (18)
C47—N8	1.36 (3)	O39—W11	1.738 (17)
C48—N7	1.34 (3)	O40—W10	1.961 (17)
C49—C50	1.52 (3)	O40—W11	1.915 (17)
C49—O45	1.25 (3)	O41—Er	2.389 (17)
C49—O46	1.25 (3)	O42—Er^ii	2.454 (16)
C50—K1^i	3.41 (3)	O42—Er	2.384 (17)
C51—C52	1.50 (4)	O42—C2AA	1.31 (3)
C51—O43	1.31 (4)	O43—Cu1	1.935 (19)
C51—O44	1.22 (4)	O44—Cu2	1.97 (2)
C53—C1AA	1.51 (4)	O45—Cu2	1.932 (18)
C53—O48	1.29 (3)	O45—K1^i	2.893 (19)
C53—O49	1.24 (3)	O46—Cu1	1.94 (2)
C55—C56	1.50 (3)	O47—Cu2	2.22 (2)
C55—O50	1.22 (3)	O47—K1^i	2.93 (2)
C55—O51	1.25 (3)	O48—Cu3	1.935 (16)
N1—Cu1	1.94 (2)	O48—K2	3.03 (2)
N2—Cu1	1.98 (2)	O49—Cu4	1.938 (17)
N3—Cu2	1.95 (2)	O50—Cu3	1.947 (18)
N4—Cu2	2.04 (2)	O51—Cu4	1.992 (18)
N5—Cu3	1.994 (19)	O52—Cu4	2.26 (2)
N6—Cu3	1.96 (2)	C54—C2AA	1.55 (4)
N7—Cu4	1.96 (2)	O55—K1^iii	2.98 (3)
N8—Cu4	2.01 (2)	Cu1—Cu2	3.039 (5)
O1—Cu3	2.33 (2)	Cu2—K1^i	3.995 (8)
O1—W1	1.727 (19)	Cu3—Cu4	2.988 (5)
O1AA—W2	1.714 (18)	Er—O0AA^ii	2.420 (19)
O3—W3	1.734 (17)	Er—C2AA^ii	2.84 (3)
O4—W2	1.920 (16)	Er—K1^ii	4.000 (8)
O4—W3	1.922 (15)	W1—K2	3.803 (14)
O5—W1	1.979 (17)	W2—K2	3.794 (14)
O5—W2	1.848 (18)	W7—K2	4.047 (14)
O5—K2	2.89 (2)	W8—K1^ii	3.944 (8)
O6—W1	1.904 (17)	W8—K2	3.909 (14)
O6—W3	1.946 (17)	W9—K1^ii	3.945 (8)
O7—W3	1.872 (17)	W10—K1^ii	3.841 (8)
O7—W4	2.009 (18)	O0AA—C2AA	1.24 (3)
O8—W3	1.886 (17)	O0AA—K1	2.74 (2)
O8—W5	1.966 (17)	K1—O3AA^i	2.87 (2)
O9—W2	1.916 (17)	K2—O7AA	3.04 (4)
O9—W6	2.000 (17)	K2—O8AA	3.04 (6)
O10—W2	1.934 (17)	K2—O0BA^iv	2.82 (4)
O10—W7	1.939 (17)
N1—C1—C2	120 (3)	O12—W1—O26	71.7 (6)
C1—C2—C3	124 (3)	O12—W1—K2	135.4 (6)
C2—C3—C4	118 (3)	O26—W1—K2	96.1 (4)
C3—C4—C5	126 (3)	O1AA—W2—O4	103.1 (8)
C3—C4—C12	117 (3)	O1AA—W2—O5	102.6 (8)
C5—C4—C12	116 (3)	O1AA—W2—O9	100.7 (8)
C6—C5—C4	125 (3)	O1AA—W2—O10	102.3 (8)
C5—C6—C7	123 (3)	O1AA—W2—O28	171.5 (7)
C8—C7—C6	126 (3)	O1AA—W2—K2	83.1 (6)
C11—C7—C6	114 (3)	O4—W2—O10	154.6 (7)
C11—C7—C8	120 (3)	O4—W2—O28	82.8 (6)
C9—C8—C7	114 (3)	O4—W2—K2	131.7 (5)
C8—C9—C10	127 (3)	O5—W2—O4	84.7 (7)
N2—C10—C9	118 (3)	O5—W2—O9	156.4 (8)
C7—C11—C12	122 (3)	O5—W2—O10	90.6 (8)
N2—C11—C7	124 (3)	O5—W2—O28	83.8 (7)
N2—C11—C12	114 (3)	O5—W2—K2	47.8 (6)
C4—C12—C11	119 (3)	O9—W2—O4	86.7 (7)
N1—C12—C4	123 (3)	O9—W2—O10	87.9 (7)
N1—C12—C11	117 (3)	O9—W2—O28	73.3 (6)
N3—C13—C14	127 (3)	O9—W2—K2	140.0 (5)
C15—C14—C13	114 (3)	O10—W2—O28	71.9 (6)
C14—C15—C16	125 (3)	O10—W2—K2	52.9 (6)
C15—C16—C17	126 (3)	O28—W2—K2	97.6 (4)
C24—C16—C15	114 (3)	O3—W3—O4	103.6 (7)
C24—C16—C17	120 (3)	O3—W3—O6	102.4 (8)
C18—C17—C16	115 (3)	O3—W3—O7	101.7 (8)
C19—C18—C17	132 (4)	O3—W3—O8	99.7 (8)
C18—C19—C20	134 (4)	O3—W3—O27	169.2 (7)
C18—C19—C23	111 (3)	O4—W3—O6	85.3 (7)
C20—C19—C23	114 (3)	O4—W3—O27	84.1 (6)
C21—C20—C19	121 (4)	O6—W3—O27	85.5 (6)
C20—C21—C22	127 (4)	O7—W3—O4	154.6 (8)
N4—C22—C21	116 (3)	O7—W3—O6	87.4 (7)
C19—C23—C24	121 (3)	O7—W3—O8	89.5 (7)
N4—C23—C19	124 (3)	O7—W3—O27	71.1 (7)
N4—C23—C24	115 (3)	O8—W3—O4	88.2 (7)
C16—C24—C23	119 (3)	O8—W3—O6	157.8 (7)
C16—C24—N3	128 (3)	O8—W3—O27	72.7 (6)
N3—C24—C23	112 (3)	O7—W4—O27	70.1 (6)
N5—C25—C26	122 (2)	O13—W4—O7	98.9 (8)
C27—C26—C25	122 (3)	O13—W4—O14	100.3 (8)
C26—C27—C28	121 (3)	O13—W4—O25	103.9 (7)
C27—C28—C29	129 (3)	O13—W4—O27	166.2 (7)
C27—C28—C36	118 (2)	O13—W4—O35	105.3 (8)
C36—C28—C29	112 (2)	O14—W4—O7	83.4 (7)
C30—C29—C28	125 (3)	O14—W4—O27	70.9 (6)
C29—C30—C31	122 (3)	O25—W4—O7	84.6 (7)
C30—C31—C32	129 (3)	O25—W4—O14	154.3 (6)
C30—C31—C35	116 (2)	O25—W4—O27	83.6 (6)
C32—C31—C35	114 (2)	O35—W4—O7	155.8 (7)
C33—C32—C31	121 (3)	O35—W4—O14	91.9 (7)
C32—C33—C34	123 (3)	O35—W4—O25	89.9 (7)
N6—C34—C33	121 (2)	O35—W4—O27	85.9 (6)
C36—C35—C31	121 (2)	O8—W5—O27	72.6 (6)
C36—C35—N6	117 (2)	O14—W5—O8	86.7 (7)
N6—C35—C31	121 (2)	O14—W5—O16	158.0 (7)
C35—C36—C28	123 (2)	O14—W5—O27	71.9 (6)
C35—C36—N5	117 (2)	O15—W5—O8	99.2 (8)
N5—C36—C28	119 (2)	O15—W5—O14	100.7 (8)
N7—C37—C38	130 (3)	O15—W5—O16	101.0 (7)
C39—C38—C37	116 (3)	O15—W5—O27	169.0 (7)
C40—C39—C38	122 (3)	O15—W5—O30	105.8 (8)
C39—C40—C41	128 (3)	O16—W5—O8	86.3 (7)
C39—C40—C48	115 (3)	O16—W5—O27	86.1 (6)
C41—C40—C48	116 (3)	O30—W5—O8	154.7 (7)
C42—C41—C40	126 (3)	O30—W5—O14	92.1 (7)
C41—C42—C43	122 (3)	O30—W5—O16	85.4 (7)
C44—C43—C42	127 (3)	O30—W5—O27	83.0 (7)
C47—C43—C42	114 (3)	O9—W6—O28	73.0 (6)
C47—C43—C44	119 (3)	O16—W6—O9	89.1 (7)
C45—C44—C43	117 (3)	O16—W6—O18	159.0 (7)
C44—C45—C46	121 (3)	O16—W6—O28	86.2 (6)
N8—C46—C45	123 (3)	O17—W6—O9	98.1 (7)
C43—C47—C48	126 (3)	O17—W6—O16	103.1 (7)
N8—C47—C43	119 (3)	O17—W6—O18	97.8 (7)
N8—C47—C48	114 (2)	O17—W6—O28	167.2 (7)
C47—C48—C40	116 (3)	O17—W6—O31	105.3 (8)
N7—C48—C40	126 (3)	O18—W6—O9	85.5 (7)
N7—C48—C47	117 (2)	O18—W6—O28	72.9 (6)
O45—C49—C50	117 (2)	O31—W6—O9	156.6 (7)
O45—C49—O46	124 (3)	O31—W6—O16	86.7 (7)
O46—C49—C50	119 (3)	O31—W6—O18	90.3 (7)
C49—C50—K1^i	84.4 (16)	O31—W6—O28	83.8 (7)
O43—C51—C52	114 (3)	O10—W7—O20	87.3 (7)
O44—C51—C52	118 (3)	O10—W7—O28	72.0 (6)
O44—C51—O43	128 (3)	O10—W7—K2	46.2 (6)
O48—C53—C1AA	118 (3)	O18—W7—O10	84.5 (7)
O49—C53—C1AA	116 (3)	O18—W7—O20	155.6 (7)
O49—C53—O48	125 (3)	O18—W7—O28	72.3 (6)
O50—C55—C56	120 (3)	O18—W7—K2	130.6 (5)
O50—C55—O51	122 (2)	O19—W7—O10	100.4 (8)
O51—C55—C56	117 (2)	O19—W7—O18	99.5 (8)
C1—N1—C12	117 (2)	O19—W7—O20	104.7 (8)
C1—N1—Cu1	130 (2)	O19—W7—O28	169.0 (7)
C12—N1—Cu1	112.3 (19)	O19—W7—O32	104.8 (8)
C10—N2—Cu1	128.1 (19)	O19—W7—K2	88.6 (7)
C11—N2—C10	117 (2)	O20—W7—O28	83.3 (6)
C11—N2—Cu1	114.3 (19)	O20—W7—K2	47.4 (5)
C13—N3—C24	112 (2)	O28—W7—K2	91.4 (4)
C13—N3—Cu2	131 (2)	O32—W7—O10	154.8 (7)
C24—N3—Cu2	116.9 (19)	O32—W7—O18	91.5 (7)
C22—N4—Cu2	127 (2)	O32—W7—O20	86.2 (7)
C23—N4—C22	118 (3)	O32—W7—O28	83.0 (7)
C23—N4—Cu2	115 (2)	O32—W7—K2	133.6 (6)
C25—N5—C36	118 (2)	O11—W8—O26	72.8 (7)
C25—N5—Cu3	132.9 (17)	O11—W8—K1^ii	137.7 (5)
C36—N5—Cu3	109.4 (15)	O11—W8—K2	44.6 (5)
C34—N6—C35	119 (2)	O20—W8—O11	87.9 (7)
C34—N6—Cu3	129.5 (19)	O20—W8—O23	156.6 (7)
C35—N6—Cu3	111.3 (17)	O20—W8—O26	86.0 (6)
C37—N7—C48	111 (2)	O20—W8—O33	85.1 (7)
C37—N7—Cu4	136.1 (18)	O20—W8—K1^ii	132.4 (5)
C48—N7—Cu4	112.7 (18)	O20—W8—K2	50.3 (6)
C46—N8—C47	120 (2)	O21—W8—O11	100.3 (8)
C46—N8—Cu4	128.0 (19)	O21—W8—O20	103.4 (7)
C47—N8—Cu4	112.2 (18)	O21—W8—O23	100.0 (7)
W1—O1—Cu3	134.3 (10)	O21—W8—O26	168.3 (7)
W2—O4—W3	153.3 (10)	O21—W8—O33	104.0 (7)
W1—O5—K2	100.9 (8)	O21—W8—K1^ii	84.0 (6)
W2—O5—W1	154.5 (11)	O21—W8—K2	86.4 (6)
W2—O5—K2	104.1 (7)	O23—W8—O11	87.8 (7)
W1—O6—W3	150.4 (9)	O23—W8—O26	70.7 (6)
W3—O7—W4	126.5 (9)	O23—W8—O33	89.3 (7)
W3—O8—W5	124.3 (9)	O23—W8—K1^ii	50.2 (5)
W2—O9—W6	121.9 (9)	O23—W8—K2	132.2 (6)
W2—O10—W7	124.8 (9)	O26—W8—K1^ii	94.8 (4)
W2—O10—K2	96.7 (7)	O26—W8—K2	94.6 (4)
W7—O10—K2	106.4 (7)	O33—W8—O11	155.7 (7)
W1—O11—W8	124.0 (10)	O33—W8—O26	83.5 (6)
W1—O11—K2	103.0 (8)	O33—W8—K1^ii	48.0 (5)
W8—O11—K2	107.0 (7)	O33—W8—K2	135.4 (5)
W1—O12—W9	125.2 (8)	K2—W8—K1^ii	170.4 (2)
W5—O14—W4	124.7 (9)	O12—W9—O26	70.3 (6)
W5—O16—W6	149.4 (9)	O12—W9—K1^ii	132.8 (5)
W7—O18—W6	123.2 (8)	O23—W9—O12	82.6 (7)
W7—O20—K2	104.6 (7)	O23—W9—O26	69.3 (6)
W8—O20—W7	151.6 (10)	O23—W9—K1^ii	50.5 (5)
W8—O20—K2	102.0 (7)	O24—W9—O12	97.1 (7)
W8—O23—W9	126.1 (9)	O24—W9—O23	100.8 (7)
W8—O23—K1^ii	101.5 (7)	O24—W9—O25	103.7 (7)
W9—O23—K1^ii	100.2 (6)	O24—W9—O26	164.5 (7)
W9—O25—W4	143.7 (9)	O24—W9—O34	104.5 (8)
As1—O26—W1	124.8 (9)	O24—W9—K1^ii	87.8 (6)
As1—O26—W8	122.8 (8)	O25—W9—O12	83.6 (7)
As1—O26—W9	122.3 (8)	O25—W9—O23	153.1 (7)
W8—O26—W1	91.7 (6)	O25—W9—O26	84.3 (6)
W8—O26—W9	93.8 (6)	O25—W9—K1^ii	140.8 (5)
W9—O26—W1	92.8 (6)	O26—W9—K1^ii	94.3 (4)
As1—O27—W3	125.4 (8)	O34—W9—O12	158.3 (7)
As1—O27—W4	124.1 (8)	O34—W9—O23	91.0 (7)
As1—O27—W5	122.8 (8)	O34—W9—O25	93.4 (7)
W4—O27—W3	92.3 (5)	O34—W9—O26	88.1 (7)
W5—O27—W3	90.3 (6)	O34—W9—K1^ii	47.5 (6)
W5—O27—W4	92.3 (6)	O29—W10—K1^ii	97.8 (4)
As1—O28—W2	126.5 (8)	O32—W10—O29	82.4 (6)
As1—O28—W6	123.1 (8)	O32—W10—K1^ii	132.2 (5)
As1—O28—W7	123.0 (8)	O33—W10—O29	84.8 (6)
W6—O28—W2	91.8 (5)	O33—W10—O32	81.8 (7)
W6—O28—W7	91.5 (5)	O33—W10—O40	154.3 (7)
W7—O28—W2	91.3 (5)	O33—W10—K1^ii	50.9 (5)
As1—O29—W10	123.7 (9)	O36—W10—O29	172.3 (7)
As1—O29—W11	124.7 (9)	O36—W10—O32	96.9 (7)
W10—O29—W11	93.0 (6)	O36—W10—O33	102.8 (7)
W5—O30—W11	156.4 (10)	O36—W10—O37	103.0 (7)
W6—O31—W11	153.9 (10)	O36—W10—O40	100.4 (7)
W7—O32—W10	153.9 (10)	O36—W10—K1^ii	88.3 (6)
W8—O33—W10	155.5 (9)	O37—W10—O29	78.0 (6)
W8—O33—K1^ii	104.0 (6)	O37—W10—O32	160.0 (7)
W10—O33—K1^ii	99.1 (6)	O37—W10—O33	92.1 (7)
Er—O34—K1^ii	95.4 (6)	O37—W10—O40	93.3 (7)
W9—O34—Er	157.3 (10)	O37—W10—K1^ii	48.0 (5)
W9—O34—K1^ii	107.3 (7)	O40—W10—O29	71.9 (6)
W4—O35—Er	162.0 (9)	O40—W10—O32	84.6 (7)
Er—O37—K1^ii	97.4 (5)	O40—W10—K1^ii	141.2 (5)
W10—O37—Er	134.4 (8)	O30—W11—O29	83.0 (7)
W10—O37—K1^ii	105.7 (7)	O30—W11—O31	81.2 (7)
W11—O38—Er	133.5 (8)	O31—W11—O29	82.5 (6)
W11—O39—Cu1	147.3 (9)	O38—W11—O29	78.8 (6)
W11—O40—W10	121.9 (8)	O38—W11—O30	90.4 (7)
Er—O42—Er^ii	115.0 (7)	O38—W11—O31	160.3 (7)
C2AA—O42—Er^ii	92.9 (15)	O38—W11—O40	93.8 (7)
C2AA—O42—Er	131.3 (16)	O39—W11—O29	172.3 (7)
C51—O43—Cu1	123 (2)	O39—W11—O30	104.5 (8)
C51—O44—Cu2	129 (2)	O39—W11—O31	96.5 (7)
C49—O45—Cu2	131.3 (18)	O39—W11—O38	102.9 (7)
C49—O45—K1^i	114.4 (16)	O39—W11—O40	99.7 (8)
Cu2—O45—K1^i	110.2 (8)	O40—W11—O29	72.6 (6)
C49—O46—Cu1	126.5 (19)	O40—W11—O30	153.8 (7)
Cu2—O47—K1^i	101.0 (8)	O40—W11—O31	86.4 (7)
C53—O48—Cu3	126.0 (17)	Er^ii—O0AA—K1	101.3 (7)
C53—O48—K2	111.2 (16)	C2AA—O0AA—Er^ii	96.5 (17)
Cu3—O48—K2	122.3 (8)	C2AA—O0AA—K1	122.3 (18)
C53—O49—Cu4	127.0 (19)	O42—C2AA—C54	120 (2)
C55—O50—Cu3	126.3 (19)	O42—C2AA—Er^ii	59.7 (13)
C55—O51—Cu4	131.5 (18)	C54—C2AA—Er^ii	178 (2)
N1—Cu1—N2	82.6 (9)	O0AA—C2AA—O42	117 (2)
N1—Cu1—O39	91.0 (8)	O0AA—C2AA—C54	122 (3)
N1—Cu1—Cu2	101.8 (7)	O0AA—C2AA—Er^ii	57.9 (14)
N2—Cu1—O39	105.7 (8)	C50^i—K1—W8^ii	71.7 (5)
N2—Cu1—Cu2	84.4 (6)	C50^i—K1—W10^ii	119.1 (5)
O39—Cu1—Cu2	164.8 (4)	O23^ii—K1—C50^i	71.0 (6)
O43—Cu1—N1	174.6 (9)	O23^ii—K1—W8^ii	28.3 (3)
O43—Cu1—N2	92.6 (9)	O23^ii—K1—W10^ii	78.4 (4)
O43—Cu1—O39	88.2 (8)	O33^ii—K1—C50^i	93.6 (6)
O43—Cu1—O46	92.0 (8)	O33^ii—K1—O23^ii	52.0 (4)
O43—Cu1—Cu2	79.9 (6)	O33^ii—K1—O34^ii	65.1 (4)
O46—Cu1—N1	93.3 (9)	O33^ii—K1—W8^ii	28.0 (3)
O46—Cu1—N2	161.0 (9)	O33^ii—K1—W10^ii	30.0 (3)
O46—Cu1—O39	92.9 (8)	O34^ii—K1—C50^i	120.2 (6)
O46—Cu1—Cu2	78.2 (6)	O34^ii—K1—O23^ii	51.4 (5)
N3—Cu2—N4	81.3 (10)	O34^ii—K1—W8^ii	65.2 (3)
N3—Cu2—O44	161.7 (9)	O34^ii—K1—W10^ii	67.7 (3)
N3—Cu2—O47	102.0 (9)	O37^ii—K1—C50^i	145.4 (6)
N3—Cu2—Cu1	89.1 (7)	O37^ii—K1—O23^ii	91.0 (5)
N3—Cu2—K1^i	101.1 (7)	O37^ii—K1—O33^ii	53.1 (4)
N4—Cu2—O47	89.2 (9)	O37^ii—K1—O34^ii	58.8 (5)
N4—Cu2—Cu1	107.0 (7)	O37^ii—K1—O55^v	126.2 (6)
N4—Cu2—K1^i	134.9 (7)	O37^ii—K1—W8^ii	78.6 (3)
O44—Cu2—N4	92.0 (9)	O37^ii—K1—W10^ii	26.3 (3)
O44—Cu2—O47	94.8 (8)	O45^i—K1—C50^i	43.0 (6)
O44—Cu2—Cu1	76.6 (6)	O45^i—K1—O23^ii	95.9 (5)
O44—Cu2—K1^i	95.7 (6)	O45^i—K1—O33^ii	82.0 (5)
O45—Cu2—N3	94.4 (9)	O45^i—K1—O34^ii	143.3 (5)
O45—Cu2—N4	174.8 (9)	O45^i—K1—O37^ii	114.0 (5)
O45—Cu2—O44	93.0 (8)	O45^i—K1—O47^i	60.0 (6)
O45—Cu2—O47	88.8 (8)	O45^i—K1—O55^v	69.7 (6)
O45—Cu2—Cu1	75.7 (6)	O45^i—K1—W8^ii	78.1 (4)
O45—Cu2—K1^i	42.8 (6)	O45^i—K1—W10^ii	92.2 (4)
O47—Cu2—Cu1	161.7 (6)	O47^i—K1—C50^i	102.3 (7)
O47—Cu2—K1^i	46.0 (6)	O47^i—K1—O23^ii	134.1 (6)
Cu1—Cu2—K1^i	117.96 (17)	O47^i—K1—O33^ii	84.4 (5)
N5—Cu3—O1	86.0 (7)	O47^i—K1—O34^ii	127.7 (6)
N5—Cu3—Cu4	98.1 (6)	O47^i—K1—O37^ii	68.9 (6)
N6—Cu3—N5	84.4 (9)	O47^i—K1—O55^v	69.2 (6)
N6—Cu3—O1	93.3 (8)	O47^i—K1—W8^ii	105.8 (5)
N6—Cu3—Cu4	94.6 (7)	O47^i—K1—W10^ii	65.4 (5)
O1—Cu3—Cu4	171.4 (5)	O55^v—K1—C50^i	75.9 (7)
O48—Cu3—N5	91.8 (7)	O55^v—K1—O23^ii	142.8 (6)
O48—Cu3—N6	170.9 (9)	O55^v—K1—O33^ii	148.2 (6)
O48—Cu3—O1	94.7 (7)	O55^v—K1—O34^ii	145.9 (6)
O48—Cu3—O50	90.5 (7)	O55^v—K1—W8^ii	145.3 (5)
O48—Cu3—Cu4	77.7 (5)	O55^v—K1—W10^ii	134.2 (5)
O50—Cu3—N5	176.4 (8)	W10^ii—K1—W8^ii	57.84 (11)
O50—Cu3—N6	92.9 (9)	O0AA—K1—C50^i	150.4 (6)
O50—Cu3—O1	96.7 (7)	O0AA—K1—O23^ii	110.0 (6)
O50—Cu3—Cu4	79.6 (6)	O0AA—K1—O33^ii	110.4 (6)
N7—Cu4—N8	82.1 (9)	O0AA—K1—O34^ii	60.1 (5)
N7—Cu4—O51	162.1 (8)	O0AA—K1—O37^ii	63.0 (5)
N7—Cu4—O52	106.2 (9)	O0AA—K1—O45^i	153.8 (6)
N7—Cu4—Cu3	88.5 (6)	O0AA—K1—O47^i	97.2 (6)
N8—Cu4—O52	97.3 (9)	O0AA—K1—O55^v	90.8 (6)
N8—Cu4—Cu3	95.7 (6)	O0AA—K1—W8^ii	123.7 (5)
O49—Cu4—N7	90.7 (8)	O0AA—K1—W10^ii	89.1 (4)
O49—Cu4—N8	170.7 (8)	O0AA—K1—O3AA^i	86.4 (6)
O49—Cu4—O51	92.4 (7)	O3AA^i—K1—C50^i	65.6 (6)
O49—Cu4—O52	90.3 (8)	O3AA^i—K1—O23^ii	71.1 (6)
O49—Cu4—Cu3	78.2 (5)	O3AA^i—K1—O33^ii	123.1 (6)
O51—Cu4—N8	92.7 (8)	O3AA^i—K1—O34^ii	80.5 (6)
O51—Cu4—O52	91.4 (8)	O3AA^i—K1—O37^ii	137.1 (6)
O51—Cu4—Cu3	74.9 (5)	O3AA^i—K1—O45^i	106.5 (6)
O52—Cu4—Cu3	161.5 (6)	O3AA^i—K1—O47^i	149.1 (7)
O27—As1—O26	106.8 (8)	O3AA^i—K1—O55^v	80.2 (7)
O28—As1—O26	108.1 (8)	O3AA^i—K1—W8^ii	97.2 (5)
O28—As1—O27	108.5 (8)	O3AA^i—K1—W10^ii	145.5 (5)
O28—As1—O29	111.4 (8)	O5—K2—O10	53.7 (5)
O29—As1—O26	111.3 (8)	O5—K2—O20	64.3 (6)
O29—As1—O27	110.7 (8)	O5—K2—O48	98.2 (6)
O34—Er—O37	78.7 (6)	O5—K2—W1	30.7 (4)
O34—Er—O38	126.4 (5)	O5—K2—W2	28.2 (4)
O34—Er—O41	144.1 (6)	O5—K2—W7	64.5 (4)
O34—Er—O42^ii	78.3 (6)	O5—K2—W8	65.8 (4)
O34—Er—O42	130.0 (6)	O5—K2—O7AA	100.3 (9)
O34—Er—O0AA^ii	75.6 (6)	O5—K2—O8AA	147.9 (12)
O34—Er—C2AA^ii	73.1 (7)	O10—K2—O20	52.3 (5)
O34—Er—K1^ii	49.2 (4)	O10—K2—W1	80.9 (4)
O35—Er—O34	71.8 (6)	O10—K2—W2	30.4 (3)
O35—Er—O37	124.8 (6)	O10—K2—W7	27.4 (3)
O35—Er—O38	82.2 (6)	O10—K2—W8	76.9 (4)
O35—Er—O41	144.0 (6)	O11—K2—O5	54.8 (6)
O35—Er—O42^ii	88.9 (6)	O11—K2—O10	90.2 (6)
O35—Er—O42	74.7 (6)	O11—K2—O20	52.6 (5)
O35—Er—O0AA^ii	133.9 (6)	O11—K2—O48	61.1 (5)
O35—Er—C2AA^ii	111.7 (7)	O11—K2—W1	29.7 (4)
O35—Er—K1^ii	120.9 (4)	O11—K2—W2	79.6 (5)
O37—Er—O41	77.5 (6)	O11—K2—W7	77.2 (5)
O37—Er—O42	151.2 (6)	O11—K2—W8	28.4 (4)
O37—Er—O42^ii	129.3 (6)	O11—K2—O7AA	144.7 (10)
O37—Er—O0AA^ii	77.9 (6)	O11—K2—O8AA	130.0 (12)
O37—Er—C2AA^ii	102.4 (7)	O20—K2—W1	66.9 (4)
O37—Er—K1^ii	47.3 (4)	O20—K2—W2	66.3 (4)
O38—Er—O37	79.3 (5)	O20—K2—W7	28.1 (3)
O38—Er—O41	74.4 (6)	O20—K2—W8	27.7 (3)
O38—Er—O42^ii	148.3 (5)	O48—K2—O10	149.6 (7)
O38—Er—O42	83.4 (5)	O48—K2—O20	108.4 (6)
O38—Er—O0AA^ii	143.8 (6)	O48—K2—W1	69.2 (4)
O38—Er—C2AA^ii	159.9 (7)	O48—K2—W2	125.5 (5)
O38—Er—K1^ii	126.4 (4)	O48—K2—W7	136.3 (5)
O41—Er—O42^ii	96.8 (6)	O48—K2—W8	80.7 (4)
O41—Er—O0AA^ii	73.4 (6)	O48—K2—O7AA	154.1 (10)
O41—Er—C2AA^ii	86.3 (7)	O48—K2—O8AA	70.1 (11)
O41—Er—K1^ii	95.1 (4)	W1—K2—W7	81.5 (3)
O42—Er—O41	75.7 (6)	W1—K2—W8	52.67 (18)
O42—Er—O42^ii	65.0 (7)	W2—K2—W1	58.9 (2)
O42—Er—O0AA^ii	104.2 (6)	W2—K2—W7	51.81 (18)
O42—Er—C2AA^ii	86.4 (7)	W2—K2—W8	80.8 (3)
O42^ii—Er—C2AA^ii	27.4 (6)	W8—K2—W7	55.54 (19)
O42^ii—Er—K1^ii	84.1 (4)	O7AA—K2—O10	54.9 (9)
O42—Er—K1^ii	145.9 (4)	O7AA—K2—O20	95.9 (9)
O0AA^ii—Er—O42^ii	52.8 (6)	O7AA—K2—W1	131.0 (9)
O0AA^ii—Er—C2AA^ii	25.6 (6)	O7AA—K2—W2	72.2 (8)
O0AA^ii—Er—K1^ii	42.3 (5)	O7AA—K2—W7	68.8 (8)
C2AA^ii—Er—K1^ii	59.9 (6)	O7AA—K2—W8	123.5 (9)
O1—W1—O5	102.9 (8)	O8AA—K2—O10	139.6 (11)
O1—W1—O6	103.5 (8)	O8AA—K2—O20	147.2 (12)
O1—W1—O11	98.9 (8)	O8AA—K2—W1	134.5 (11)
O1—W1—O12	102.6 (8)	O8AA—K2—W2	142.6 (11)
O1—W1—O26	168.5 (8)	O8AA—K2—W7	143.7 (11)
O1—W1—K2	80.8 (6)	O8AA—K2—W8	136.5 (11)
O5—W1—O26	82.8 (6)	O8AA—K2—O7AA	84.8 (13)
O5—W1—K2	48.4 (6)	O0BA^iv—K2—O5	71.0 (8)
O6—W1—O5	84.8 (7)	O0BA^iv—K2—O10	98.8 (9)
O6—W1—O11	157.1 (8)	O0BA^iv—K2—O11	102.5 (8)
O6—W1—O26	86.9 (6)	O0BA^iv—K2—O20	135.3 (9)
O6—W1—K2	131.9 (5)	O0BA^iv—K2—O48	79.6 (8)
O11—W1—O5	85.4 (7)	O0BA^iv—K2—W1	76.2 (7)
O11—W1—O26	71.3 (7)	O0BA^iv—K2—W2	73.5 (7)
O11—W1—K2	47.4 (6)	O0BA^iv—K2—W7	124.8 (8)
O12—W1—O5	154.3 (7)	O0BA^iv—K2—W8	128.8 (8)
O12—W1—O6	91.2 (7)	O0BA^iv—K2—O7AA	89.6 (11)
O12—W1—O11	88.7 (7)	O0BA^iv—K2—O8AA	77.4 (13)

Symmetry codes: (i) −x+1/2, −y+3/2, −z+1/2; (ii) −x+1/2, −y+1/2, −z+1/2; (iii) x, y−1, z; (iv) −x, −y, −z; (v) x, y+1, z.