Bis(π-allyl-6,7-dihydrohimachalene)-α,α-dichlorodipalladium

El Firdoussi, L.; Allaoud, S.; Karim, A.; Barrero, A.F.; Quirós, M.; Castanet, Y.; Mortreux, A.

doi:10.1107/S0108270196015557

Bis(π-allyl-6,7-dihydrohimachalene)-α,α-dichlorodipalladium

L. El Firdoussi, S. Allaoud, A. Karim, A. F. Barrero, M. Quirós, Y. Castanet and A. Mortreux

Treatment of trans-6,7-dihydrohimachalene [(1R,2R,7R)-2,6,6,9-tetramethylbicyclo[5.4.0]deca-8-ene] with palladium(II) chloride gives bis(chloro)-bridged cyclopalladated dimers [Pd₂Cl₂(C₁₅H₂₅)₂] with high regio- and stereoselectivity. The molecule displays crystallographic twofold symmetry and adopts a butterfly shape (the Pd₂Cl₂ unit is the `body' and the organic ligands are the `wings'). The methyl group on the asymmetric C atom points to the side in which the Pd₂Cl₂ unit is placed.

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Bis(π-allyl-6,7-dihydrohimachalene)-α,α-dichlorodipalladium

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	Crystallographic Information File (CIF) Contains datablocks global, terpala
	Structure factor file (CIF format) Contains datablock terpala