Photochemical Reactions of Transition Metal Organyl Complexes with Olefins. 18. Dicarbonylbis(η5-cyclopentadienyl)(μ-1,4-η:4,5-η-1,4-pentadien-1,4-diyl)oxoditungsten(W—W)

Kreiter, C.G.; Schwarz, C.B.; Frank, W.; Reiß, G.J.

doi:10.1107/S0108270197004393

Photochemical Reactions of Transition Metal Organyl Complexes with Olefins. 18. Dicarbonylbis(η⁵-cyclopentadienyl)(μ-1,4-η:4,5-η-1,4-pentadien-1,4-diyl)oxoditungsten(W—W)

C. G. Kreiter, C. B. Schwarz, W. Frank and G. J. Reiß

In the binuclear title complex, [W₂O(C₅H₅)₂(C₅H₆)(CO)₂], the W centres are bridged by a 1,4-pentadien-1,4-diyl ligand. The W—W distance of 2.9426 (5) Å is in accord with a W—W single bond, the W—O distance of 1.678 (5) Å corresponds to a W=O double bond.

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Photochemical Reactions of Transition Metal Organyl Complexes with Olefins. 18. Dicarbonylbis(η⁵-cyclopentadienyl)(μ-1,4-η:4,5-η-1,4-pentadien-1,4-diyl)oxoditungsten(W—W)

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	Crystallographic Information File (CIF) Contains datablock C~17~H~16~W~2~O~3~
	Structure factor file (CIF format) Contains datablock I