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The structure of the 2,2′-bipyridyl adduct poly[(μ2-2,2′-bipyridyl-κ3N,N′:N)di-μ3-cyanido-κ6C:N:N-gold(I)potassium(I)], [AuK(CN)2(C10H8N2)]n, (1) (space group P21), has been redetermined [previous determination: Jones et al. (1980). Acta Cryst. B36, 160–162]. The bipyridyl ligands coordinate only the potassium ion, which has a coordination sphere consisting of seven N-atom donors; gold(I) remains in the form of linear dicyanidoaurate(I) ions. The extended structure consists of layers in which the AuI atoms form chains parallel to the short a axis, with Au...Au contacts of 3.7286 (1) Å, whereas the chains of potassium ions, which are also parallel to a, are bridged by bipyridyl and dicyanidoaurate resi­dues. The analogous 1,10-phenanthroline adduct, namely poly[di-μ3-cyanido-κ6C:N:N-(μ2-1,10-phenanthroline-κ3N,N′:N)gold(I)potassium(I)], [AuK(CN)2(C12H8N2)]n, (2), crystallizes as nonmerohedral twins in the space group C2/c. The packing is closely related to that of (1), but the chains are now parallel to the short b axis and the layers are parallel to (10\overline{1}). The two independent AuI atoms occupy special positions on inversion centres and twofold axes; the Au...Au contacts are 3.6771 (2) Å.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S2053229617016047/ku3210sup1.cif
Contains datablocks 1, 2, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2053229617016047/ku32101sup4.hkl
Contains datablock 1

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2053229617016047/ku32102sup5.hkl
Contains datablock 2

CCDC references: 1584306; 1584305

Computing details top

For both structures, data collection: CrysAlis PRO (Rigaku Oxford Diffraction, 2015); cell refinement: CrysAlis PRO (Rigaku Oxford Diffraction, 2015); data reduction: CrysAlis PRO (Rigaku Oxford Diffraction, 2015); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL2017 (Sheldrick, 2015); molecular graphics: XP (Siemens, 1994). Software used to prepare material for publication: SHELXL97 for (1); SHELXL2017 for (2).

Poly[(µ2-2,2'-bipyridyl-κ3N,N':N)di-µ3-cyanido-κ6C:N:N-gold(I)potassium(I)] (1) top
Crystal data top
[AuK(CN)2(C10H8N2)]F(000) = 412
Mr = 444.29Dx = 2.329 Mg m3
Monoclinic, P21Mo Kα radiation, λ = 0.71073 Å
a = 3.72856 (13) ÅCell parameters from 17376 reflections
b = 18.8381 (4) Åθ = 2.5–30.8°
c = 9.1981 (2) ŵ = 11.93 mm1
β = 101.337 (3)°T = 100 K
V = 633.46 (3) Å3Lath, colourless
Z = 20.20 × 0.05 × 0.03 mm
Data collection top
Oxford Diffraction Xcalibur Eos
diffractometer
3792 independent reflections
Radiation source: fine-focus sealed X-ray tube3671 reflections with I > 2σ(I)
Detector resolution: 16.1419 pixels mm-1Rint = 0.038
ω scanθmax = 30.9°, θmin = 2.2°
Absorption correction: multi-scan
(CrysAlis PRO; Rigaku Oxford Diffraction, 2015)
h = 55
Tmin = 0.569, Tmax = 1.000k = 2726
33810 measured reflectionsl = 1313
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.015H-atom parameters constrained
wR(F2) = 0.030 w = 1/[σ2(Fo2) + (0.0106P)2 + 0.399P]
where P = (Fo2 + 2Fc2)/3
S = 1.06(Δ/σ)max = 0.001
3792 reflectionsΔρmax = 1.13 e Å3
163 parametersΔρmin = 0.75 e Å3
1 restraintAbsolute structure: Flack x determined using 1700 quotients [(I+)-(I-)]/[(I+)+(I-)] (Parsons et al., 2013)
Primary atom site location: structure-invariant direct methodsAbsolute structure parameter: 0.014 (3)
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. CrysAlisPro 1.171.38.43 (Rigaku Oxford Diffraction, 2015) Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Au10.00381 (3)0.25092 (2)0.98032 (2)0.01365 (4)
K10.2679 (3)0.50836 (5)0.75067 (10)0.01257 (17)
N10.1879 (10)0.40128 (19)0.8414 (4)0.0182 (7)
C10.1144 (11)0.3473 (2)0.8962 (4)0.0146 (8)
N20.1704 (10)0.09486 (19)1.0918 (4)0.0176 (7)
C20.1130 (11)0.1525 (2)1.0540 (4)0.0148 (8)
N110.6390 (9)0.48670 (17)0.4907 (4)0.0139 (6)
C120.6661 (10)0.5326 (2)0.3804 (4)0.0121 (7)
C130.5964 (12)0.5116 (3)0.2314 (5)0.0194 (10)
H130.6201670.5445350.1557210.023*
C140.4925 (12)0.4421 (2)0.1956 (4)0.0192 (8)
H140.4488750.4265710.0954480.023*
C150.4535 (11)0.3960 (2)0.3074 (5)0.0183 (8)
H150.3747880.3484960.2856940.022*
C160.5317 (11)0.4202 (2)0.4526 (4)0.0171 (8)
H160.5078420.3878890.5293450.021*
N210.9864 (9)0.61680 (18)0.5568 (4)0.0140 (6)
C220.7697 (11)0.6068 (2)0.4228 (4)0.0120 (7)
C230.6449 (11)0.6628 (2)0.3283 (4)0.0160 (8)
H230.4941360.6540600.2340770.019*
C240.7425 (11)0.7315 (2)0.3726 (5)0.0174 (9)
H240.6582130.7705870.3098960.021*
C250.9645 (10)0.7422 (4)0.5098 (4)0.0160 (11)
H251.0362380.7887070.5434290.019*
C261.0803 (11)0.6835 (2)0.5973 (4)0.0158 (8)
H261.2349600.6909880.6911980.019*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Au10.01722 (7)0.01062 (6)0.01254 (5)0.00043 (9)0.00152 (4)0.00143 (17)
K10.0127 (4)0.0117 (4)0.0128 (4)0.0005 (4)0.0012 (3)0.0008 (3)
N10.0161 (19)0.0161 (17)0.0224 (17)0.0005 (14)0.0038 (13)0.0028 (13)
C10.013 (2)0.0157 (19)0.0152 (17)0.0023 (15)0.0024 (14)0.0023 (14)
N20.0166 (19)0.0168 (17)0.0199 (17)0.0001 (13)0.0049 (13)0.0035 (13)
C20.013 (2)0.0173 (19)0.0141 (17)0.0002 (15)0.0034 (14)0.0003 (14)
N110.0154 (17)0.0127 (16)0.0141 (15)0.0015 (12)0.0037 (12)0.0007 (12)
C120.0081 (18)0.0143 (18)0.0142 (17)0.0006 (14)0.0031 (13)0.0008 (13)
C130.015 (2)0.029 (3)0.013 (2)0.003 (2)0.0023 (17)0.0012 (18)
C140.014 (2)0.028 (2)0.0151 (18)0.0030 (16)0.0019 (15)0.0063 (16)
C150.014 (2)0.020 (2)0.021 (2)0.0011 (16)0.0022 (15)0.0053 (15)
C160.019 (2)0.0173 (19)0.0168 (18)0.0025 (15)0.0069 (15)0.0022 (15)
N210.0132 (17)0.0156 (16)0.0128 (14)0.0008 (13)0.0013 (12)0.0006 (12)
C220.0094 (19)0.0153 (18)0.0119 (16)0.0008 (14)0.0035 (13)0.0014 (13)
C230.012 (2)0.020 (2)0.0157 (18)0.0030 (15)0.0030 (14)0.0042 (15)
C240.014 (2)0.018 (2)0.0217 (18)0.0048 (14)0.0080 (15)0.0068 (13)
C250.0145 (17)0.012 (3)0.0234 (16)0.0005 (17)0.0075 (13)0.0002 (17)
C260.014 (2)0.0192 (19)0.0143 (18)0.0003 (15)0.0020 (14)0.0007 (14)
Geometric parameters (Å, º) top
Au1—C21.988 (4)C13—H130.9500
Au1—C11.989 (4)C14—C151.376 (6)
K1—N21i2.778 (3)C14—H140.9500
K1—N2ii2.819 (4)C15—C161.387 (5)
K1—N12.866 (4)C15—H150.9500
K1—N1iii2.866 (4)C16—H160.9500
K1—N2iv2.891 (4)N21—C261.337 (5)
K1—N113.017 (3)N21—C221.348 (5)
K1—N11i3.030 (3)C22—C231.388 (5)
N1—C11.144 (5)C23—C241.384 (6)
N2—C21.148 (5)C23—H230.9500
N11—C161.340 (5)C24—C251.381 (5)
N11—C121.351 (5)C24—H240.9500
C12—C131.401 (6)C25—C261.386 (7)
C12—C221.482 (5)C25—H250.9500
C13—C141.386 (7)C26—H260.9500
C2—Au1—C1177.03 (16)N11—C12—C13121.8 (4)
N21i—K1—N2ii93.07 (10)N11—C12—C22117.4 (3)
N21i—K1—N1122.25 (11)C13—C12—C22120.9 (4)
N2ii—K1—N1132.88 (11)C14—C13—C12119.2 (4)
N21i—K1—N1iii149.41 (11)C14—C13—H13120.4
N2ii—K1—N1iii81.10 (10)C12—C13—H13120.4
N1—K1—N1iii81.15 (9)C15—C14—C13119.0 (4)
N21i—K1—N2iv74.19 (10)C15—C14—H14120.5
N2ii—K1—N2iv81.53 (9)C13—C14—H14120.5
N1—K1—N2iv79.91 (10)C14—C15—C16118.6 (4)
N1iii—K1—N2iv133.50 (11)C14—C15—H15120.7
N21i—K1—N1176.41 (10)C16—C15—H15120.7
N2ii—K1—N1194.33 (10)N11—C16—C15123.7 (4)
N1—K1—N11121.76 (10)N11—C16—K157.9 (2)
N1iii—K1—N1174.16 (10)C15—C16—K1150.5 (3)
N2iv—K1—N11150.01 (10)N11—C16—H16118.1
N21i—K1—N11i57.06 (9)C15—C16—H16118.1
N2ii—K1—N11i149.88 (10)K1—C16—H1668.9
N1—K1—N11i73.97 (10)C26—N21—C22117.6 (3)
N1iii—K1—N11i121.92 (10)C26—N21—K1iii117.8 (2)
N2iv—K1—N11i92.60 (10)C22—N21—K1iii124.5 (3)
N11—K1—N11i76.14 (8)N21—C22—C23122.2 (4)
C1—N1—K1130.5 (3)N21—C22—C12116.8 (3)
C1—N1—K1i148.0 (3)C23—C22—C12120.9 (3)
K1—N1—K1i81.15 (9)C24—C23—C22119.3 (4)
N1—C1—Au1176.8 (4)C24—C23—H23120.3
C2—N2—K1v141.1 (3)C22—C23—H23120.3
C2—N2—K1vi126.6 (3)C25—C24—C23118.8 (4)
K1v—N2—K1vi81.53 (9)C25—C24—H24120.6
N2—C2—Au1177.7 (4)C23—C24—H24120.6
C16—N11—C12117.6 (3)C24—C25—C26118.5 (5)
C16—N11—K1100.0 (2)C24—C25—H25120.8
C12—N11—K1128.5 (2)C26—C25—H25120.8
C16—N11—K1iii118.5 (3)N21—C26—C25123.6 (4)
C12—N11—K1iii110.2 (2)N21—C26—H26118.2
K1—N11—K1iii76.14 (8)C25—C26—H26118.2
C16—N11—C12—C131.9 (6)C14—C15—C16—K184.2 (7)
K1—N11—C12—C13133.8 (3)C26—N21—C22—C230.0 (6)
K1iii—N11—C12—C13138.1 (3)K1iii—N21—C22—C23178.1 (3)
C16—N11—C12—C22177.5 (3)C26—N21—C22—C12179.5 (3)
K1—N11—C12—C2245.6 (5)K1iii—N21—C22—C122.4 (5)
K1iii—N11—C12—C2242.4 (4)N11—C12—C22—N2130.3 (5)
N11—C12—C13—C140.8 (7)C13—C12—C22—N21150.3 (4)
C22—C12—C13—C14178.6 (4)N11—C12—C22—C23149.2 (4)
C12—C13—C14—C151.3 (7)C13—C12—C22—C2330.2 (6)
C13—C14—C15—C162.1 (6)N21—C22—C23—C240.6 (6)
C12—N11—C16—C151.1 (6)C12—C22—C23—C24179.0 (4)
K1—N11—C16—C15144.8 (4)C22—C23—C24—C250.5 (6)
K1iii—N11—C16—C15135.7 (4)C23—C24—C25—C260.0 (6)
C12—N11—C16—K1143.7 (4)C22—N21—C26—C250.6 (6)
K1iii—N11—C16—K179.58 (19)K1iii—N21—C26—C25178.8 (3)
C14—C15—C16—N111.0 (6)C24—C25—C26—N210.6 (6)
Symmetry codes: (i) x1, y, z; (ii) x+1, y+1/2, z+2; (iii) x+1, y, z; (iv) x, y+1/2, z+2; (v) x+1, y1/2, z+2; (vi) x, y1/2, z+2.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C13—H13···N2vii0.952.723.616 (6)158
Symmetry code: (vii) x+1, y+1/2, z+1.
Poly[di-µ3-cyanido-κ6C:N:N-(µ2-1,10-phenanthroline-κ3N,N':N)gold(I)potassium(I)] (2) top
Crystal data top
[AuK(CN)2(C12H8N2)]F(000) = 1744
Mr = 468.31Dx = 2.336 Mg m3
Monoclinic, C2/cMo Kα radiation, λ = 0.71073 Å
a = 41.202 (3) ÅCell parameters from 9090 reflections
b = 3.67714 (16) Åθ = 3.0–28.5°
c = 19.5967 (14) ŵ = 11.35 mm1
β = 116.232 (9)°T = 105 K
V = 2663.2 (3) Å3Needle, colourless
Z = 80.24 × 0.02 × 0.01 mm
Data collection top
Oxford Diffraction Xcalibur Eos
diffractometer
6294 independent reflections
Radiation source: fine-focus sealed X-ray tube3789 reflections with I > 2σ(I)
Detector resolution: 16.1419 pixels mm-1θmax = 29.4°, θmin = 2.2°
ω–scanh = 5655
Absorption correction: multi-scan
(CrysAlis PRO; Rigaku Oxford Diffraction, 2015)
k = 55
Tmin = 0.847, Tmax = 1.000l = 2626
6294 measured reflections
Refinement top
Refinement on F296 restraints
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.033H-atom parameters constrained
wR(F2) = 0.037 w = 1/[σ2(Fo2) + (0.0075P)2]
where P = (Fo2 + 2Fc2)/3
S = 0.74(Δ/σ)max = 0.002
6294 reflectionsΔρmax = 2.47 e Å3
184 parametersΔρmin = 1.12 e Å3
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refined as a 2-component twin

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Au10.2500000.2500000.5000000.01367 (8)
Au20.5000000.43336 (7)0.7500000.01282 (8)
K10.37760 (3)0.1119 (3)0.48572 (6)0.0138 (3)
N10.32425 (10)0.3712 (10)0.4944 (2)0.0178 (11)
C10.29712 (13)0.3306 (12)0.4951 (3)0.0169 (13)
N20.42846 (10)0.4119 (10)0.5972 (2)0.0168 (10)
C20.45444 (13)0.4240 (13)0.6526 (3)0.0147 (12)
N110.41286 (10)0.3757 (10)0.4134 (2)0.0126 (10)
N210.34013 (10)0.5067 (10)0.3440 (2)0.0104 (10)
C30.44829 (13)0.3181 (12)0.4463 (3)0.0152 (14)
H30.4614800.3686450.4990390.018*
C40.46732 (12)0.1863 (12)0.4070 (3)0.0169 (13)
H40.4927730.1521040.4326350.020*
C50.44855 (12)0.1085 (12)0.3315 (3)0.0150 (12)
H50.4609900.0146620.3044980.018*
C60.41127 (12)0.1651 (12)0.2935 (3)0.0121 (12)
C70.39000 (12)0.0889 (12)0.2152 (3)0.0164 (12)
H70.4014380.0057200.1862410.020*
C80.35438 (13)0.1465 (12)0.1812 (3)0.0173 (13)
H80.3409480.0892470.1288510.021*
C90.33601 (12)0.2935 (12)0.2225 (3)0.0126 (12)
C100.29883 (12)0.3652 (12)0.1885 (3)0.0174 (13)
H100.2845510.3136250.1360570.021*
C110.28326 (12)0.5087 (12)0.2307 (3)0.0163 (13)
H110.2581850.5655220.2080110.020*
C120.30485 (13)0.5711 (13)0.3081 (3)0.0156 (13)
H120.2934350.6665010.3370240.019*
C130.35579 (12)0.3739 (12)0.3007 (3)0.0108 (12)
C140.39434 (12)0.3044 (12)0.3381 (3)0.0109 (12)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Au10.01307 (17)0.01568 (19)0.01347 (18)0.00033 (13)0.00698 (14)0.00015 (15)
Au20.01261 (18)0.01431 (19)0.01240 (18)0.0000.00631 (15)0.000
K10.0151 (6)0.0113 (7)0.0157 (6)0.0011 (5)0.0074 (5)0.0015 (5)
N10.021 (3)0.014 (3)0.023 (3)0.0015 (19)0.014 (2)0.002 (2)
C10.020 (2)0.013 (2)0.016 (2)0.0007 (17)0.0068 (18)0.0014 (17)
N20.019 (2)0.014 (2)0.014 (3)0.0013 (19)0.004 (2)0.001 (2)
C20.017 (2)0.011 (2)0.020 (2)0.0001 (18)0.0112 (18)0.0001 (19)
N110.0124 (18)0.0112 (19)0.015 (2)0.0002 (15)0.0067 (15)0.0008 (16)
N210.0103 (18)0.006 (2)0.0137 (19)0.0004 (14)0.0042 (15)0.0009 (15)
C30.017 (2)0.013 (2)0.015 (2)0.0012 (17)0.0061 (18)0.0009 (18)
C40.012 (2)0.016 (2)0.024 (2)0.0017 (16)0.0090 (18)0.0030 (18)
C50.018 (2)0.013 (2)0.019 (2)0.0001 (17)0.0121 (18)0.0007 (18)
C60.015 (2)0.009 (2)0.016 (2)0.0015 (16)0.0091 (17)0.0020 (17)
C70.025 (2)0.013 (2)0.015 (2)0.0019 (18)0.0119 (18)0.0018 (18)
C80.025 (2)0.014 (2)0.012 (2)0.0069 (17)0.0079 (18)0.0016 (17)
C90.016 (2)0.007 (2)0.014 (2)0.0032 (17)0.0065 (17)0.0013 (18)
C100.020 (2)0.012 (2)0.015 (2)0.0038 (17)0.0029 (18)0.0009 (18)
C110.014 (2)0.014 (2)0.018 (2)0.0014 (17)0.0033 (17)0.0028 (18)
C120.018 (2)0.013 (2)0.016 (2)0.0017 (17)0.0080 (18)0.0001 (19)
C130.012 (2)0.007 (2)0.013 (2)0.0004 (16)0.0064 (17)0.0013 (17)
C140.013 (2)0.007 (2)0.013 (2)0.0012 (16)0.0062 (17)0.0008 (17)
Geometric parameters (Å, º) top
Au1—C12.008 (5)C3—H30.9500
Au1—C1i2.008 (5)C4—C51.363 (6)
Au2—C2ii2.000 (5)C4—H40.9500
Au2—C22.000 (5)C5—C61.395 (6)
K1—N2iii2.861 (4)C5—H50.9500
K1—N21iii2.876 (4)C6—C71.419 (6)
K1—N12.889 (4)C6—C141.431 (6)
K1—N1iii2.967 (4)C7—C81.333 (6)
K1—N22.971 (4)C7—H70.9500
K1—N113.025 (4)C8—C91.435 (6)
K1—N11iii3.080 (4)C8—H80.9500
K1—N213.388 (4)C9—C101.399 (6)
N1—C11.134 (5)C9—C131.413 (6)
N2—C21.140 (5)C10—C111.358 (6)
N11—C31.327 (5)C10—H100.9500
N11—C141.355 (6)C11—C121.397 (6)
N21—C121.327 (5)C11—H110.9500
N21—C131.364 (6)C12—H120.9500
C3—C41.405 (6)C13—C141.448 (6)
C1—Au1—C1i180.0K1—N11—K1iv74.06 (9)
C2ii—Au2—C2178.0 (3)C12—N21—C13116.2 (4)
N2iii—K1—N21iii109.76 (12)C12—N21—K1iv114.9 (3)
N2iii—K1—N1130.62 (12)C13—N21—K1iv125.2 (3)
N21iii—K1—N1105.02 (11)C12—N21—K1123.4 (3)
N2iii—K1—N1iii82.84 (11)C13—N21—K195.8 (3)
N21iii—K1—N1iii69.38 (11)K1iv—N21—K171.37 (9)
N1—K1—N1iii77.78 (10)N11—C3—C4123.4 (5)
N2iii—K1—N278.16 (10)N11—C3—H3118.3
N21iii—K1—N2158.31 (12)C4—C3—H3118.3
N1—K1—N282.30 (11)C5—C4—C3118.7 (5)
N1iii—K1—N2132.29 (12)C5—C4—H4120.6
N2iii—K1—N11112.27 (11)C3—C4—H4120.6
N21iii—K1—N1190.04 (11)C4—C5—C6120.7 (5)
N1—K1—N11101.46 (11)C4—C5—H5119.6
N1iii—K1—N11158.09 (12)C6—C5—H5119.6
N2—K1—N1168.37 (11)C5—C6—C7123.8 (4)
N2iii—K1—N11iii68.99 (11)C5—C6—C14116.5 (4)
N21iii—K1—N11iii54.45 (10)C7—C6—C14119.7 (4)
N1—K1—N11iii158.28 (12)C8—C7—C6121.8 (5)
N1iii—K1—N11iii98.42 (11)C8—C7—H7119.1
N2—K1—N11iii114.32 (11)C6—C7—H7119.1
N11—K1—N11iii74.06 (9)C7—C8—C9121.1 (5)
N2iii—K1—N21162.07 (11)C7—C8—H8119.4
N21iii—K1—N2171.37 (9)C9—C8—H8119.4
N1—K1—N2163.42 (11)C10—C9—C13117.5 (4)
N1iii—K1—N21113.35 (10)C10—C9—C8122.8 (4)
N2—K1—N2194.89 (10)C13—C9—C8119.7 (4)
N11—K1—N2150.02 (9)C11—C10—C9119.7 (5)
N11iii—K1—N2199.81 (11)C11—C10—H10120.1
C1—N1—K1134.4 (3)C9—C10—H10120.1
C1—N1—K1iv147.6 (3)C10—C11—C12118.7 (5)
K1—N1—K1iv77.78 (10)C10—C11—H11120.7
N1—C1—Au1178.0 (5)C12—C11—H11120.7
C2—N2—K1iv140.0 (4)N21—C12—C11124.7 (5)
C2—N2—K1141.8 (4)N21—C12—H12117.6
K1iv—N2—K178.16 (10)C11—C12—H12117.6
N2—C2—Au2178.7 (5)N21—C13—C9123.1 (4)
C3—N11—C14117.8 (4)N21—C13—C14117.6 (4)
C3—N11—K1109.4 (3)C9—C13—C14119.3 (4)
C14—N11—K1103.9 (3)N11—C14—C6122.8 (4)
C3—N11—K1iv121.1 (3)N11—C14—C13118.7 (4)
C14—N11—K1iv117.8 (3)C6—C14—C13118.5 (4)
C14—N11—C3—C40.3 (7)C12—N21—C13—C14179.4 (4)
K1—N11—C3—C4117.9 (4)K1iv—N21—C13—C1422.4 (5)
K1iv—N11—C3—C4159.4 (3)K1—N21—C13—C1448.8 (4)
N11—C3—C4—C50.9 (7)C10—C9—C13—N211.9 (7)
C3—C4—C5—C61.2 (7)C8—C9—C13—N21178.6 (4)
C4—C5—C6—C7179.7 (4)C10—C9—C13—C14179.9 (4)
C4—C5—C6—C140.4 (6)C8—C9—C13—C140.4 (6)
C5—C6—C7—C8179.8 (4)C3—N11—C14—C61.1 (7)
C14—C6—C7—C80.6 (7)K1—N11—C14—C6120.0 (4)
C6—C7—C8—C90.8 (7)K1iv—N11—C14—C6160.9 (3)
C7—C8—C9—C10178.6 (4)C3—N11—C14—C13178.5 (4)
C7—C8—C9—C130.9 (7)K1—N11—C14—C1360.4 (4)
C13—C9—C10—C110.3 (6)K1iv—N11—C14—C1318.7 (5)
C8—C9—C10—C11179.2 (4)C5—C6—C14—N110.8 (7)
C9—C10—C11—C121.9 (7)C7—C6—C14—N11178.5 (4)
C13—N21—C12—C110.8 (7)C5—C6—C14—C13178.8 (4)
K1iv—N21—C12—C11160.1 (4)C7—C6—C14—C131.9 (6)
K1—N21—C12—C11116.5 (5)N21—C13—C14—N110.4 (6)
C10—C11—C12—N211.4 (7)C9—C13—C14—N11178.7 (4)
C12—N21—C13—C92.4 (6)N21—C13—C14—C6180.0 (4)
K1iv—N21—C13—C9159.4 (3)C9—C13—C14—C61.7 (6)
K1—N21—C13—C9129.4 (4)
Symmetry codes: (i) x+1/2, y+1/2, z+1; (ii) x+1, y, z+3/2; (iii) x, y1, z; (iv) x, y+1, z.
 

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