A Star-Shaped Heptanuclear Tetramine Cadmium(II) Complex

Klüfers, P.; Mayer, P.

doi:10.1107/S0108270197019355

A Star-Shaped Heptanuclear Tetramine Cadmium(II) Complex

Colourless rhombohedral crystals of dodekakis[tris(2-aminoethyl)amine]heptacadmium(II) tetradecaperchlorate, [Cd₇(tren)₁₂](ClO₄)₁₄, form from aqueous solutions of the cellulose solvent `Cd–tren' on addition of perchloric acid. The heptanuclear cations are flat star-shaped disks and are composed of Cd(tren) moieties that are linked by further tren ligands, which exhibit the unusual μ³,κ³N,N′,N′′ mode of coordination.

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A Star-Shaped Heptanuclear Tetramine Cadmium(II) Complex

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	Crystallographic Information File (CIF) Contains datablocks cdtren, cd
	Structure factor file (CIF format) Contains datablock cd