Cis–trans isomerism in a square-planar platinum(II) complex bearing bulky fluorinated phosphane ligands

Transition-metal complexes bearing fluorinated phosphane and thiol­ate ligands has been an area of study in recent years and the chemical context of the current work is related to the metal-assisted functionalization of fluorinated derivatives. The cis and trans isomers of the square-planar complex bis­[(penta­fluoro­phen­yl)di­phenyl­phos­phane-κP]bis(2,3,5,6-tetra­fluoro­benzene­thiol­ato-κS)plati­num(II), [Pt(C₆HF₄S)₂{P(C₆H₅)₂(C₆F₅)}₂], have been crystallized from a single chromatographic fraction and characterized by X-ray diffraction analysis. The stabilization of the cis isomer results from weak intra­molecular π-stacking inter­actions and possibly from the formation of a C—F...Pt contact, characterized by an F...Pt separation of 2.957 (6) Å. The natural bond orbital analysis (NBO) for this isomer confirms that the corresponding F → Pt charge transfer accounts for 6.92 kcal mol⁻¹ in the isomer stabilization. Such inter­actions are not present in the centrosymmetric trans isomer.

Computing details

For both compounds, data collection: XSCANS (Bruker, 1997); cell refinement: XSCANS (Bruker, 1997); data reduction: XSCANS (Bruker, 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXL2014 (Sheldrick, 2015).

(trans) Bis[(pentafluorophenyl)diphenylphosphane-κP]bis(2,3,5,6-tetrafluorophenylthiolato-κS)platinum(II)

Crystal data

[Pt(C6HF4S)2(C18H10F5P)2]	Z = 1
Mr = 1261.80	F(000) = 612
Triclinic, P1	Dx = 1.826 Mg m^−3
a = 10.3553 (8) Å	Mo Kα radiation, λ = 0.71073 Å
b = 10.5983 (10) Å	Cell parameters from 81 reflections
c = 12.4594 (8) Å	θ = 4.0–13.8°
α = 114.574 (6)°	µ = 3.33 mm^−1
β = 104.400 (6)°	T = 298 K
γ = 99.442 (5)°	Irregular_block, yellow
V = 1147.61 (17) Å^3	0.6 × 0.5 × 0.4 mm

Data collection

Bruker P4 diffractometer	6346 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube, FN4	Rint = 0.019
Graphite monochromator	θmax = 30.0°, θmin = 1.9°
2θ/ω scans	h = −14→9
Absorption correction: ψ scan (XSCANS; Bruker, 1997)	k = −13→13
Tmin = 0.468, Tmax = 0.730	l = −17→17
11452 measured reflections	3 standard reflections every 97 reflections
6346 independent reflections	intensity decay: 1%

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.022	H-atom parameters constrained
wR(F^2) = 0.057	w = 1/[σ^2(Fo^2) + (0.0356P)^2 + 0.248P] where P = (Fo^2 + 2Fc^2)/3
S = 1.07	(Δ/σ)max < 0.001
6346 reflections	Δρmax = 0.88 e Å^−3
323 parameters	Δρmin = −0.91 e Å^−3
0 restraints	Extinction correction: SHELXL2014 (Sheldrick, 2015), Fc*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
0 constraints	Extinction coefficient: 0.0105 (6)
Primary atom site location: structure-invariant direct methods

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Pt1	0.0000	0.0000	0.0000	0.02829 (4)
S1	0.03421 (6)	−0.05262 (6)	0.16714 (5)	0.04019 (11)
P1	0.19274 (5)	0.20958 (6)	0.10904 (5)	0.03178 (9)
C1	−0.0125 (3)	0.0703 (3)	0.2857 (2)	0.0461 (5)
C2	0.0583 (4)	0.1060 (5)	0.4105 (3)	0.0650 (8)
F2	0.1579 (2)	0.0446 (3)	0.4353 (2)	0.0817 (7)
C3	0.0297 (5)	0.2023 (7)	0.5090 (3)	0.0982 (17)
F3	0.1059 (4)	0.2318 (6)	0.6266 (2)	0.1498 (18)
C4	−0.0725 (7)	0.2667 (8)	0.4909 (4)	0.115 (2)
H4A	−0.0905	0.3329	0.5584	0.137*
C5	−0.1465 (5)	0.2292 (6)	0.3690 (4)	0.0885 (14)
F5	−0.2516 (4)	0.2847 (5)	0.3432 (3)	0.1268 (14)
C6	−0.1182 (3)	0.1334 (4)	0.2680 (3)	0.0544 (6)
F6	−0.1969 (2)	0.1017 (2)	0.15250 (17)	0.0601 (4)
C7	0.2938 (2)	0.2328 (3)	0.2635 (2)	0.0418 (5)
C8	0.3523 (3)	0.1231 (3)	0.2635 (3)	0.0508 (6)
F8	0.3361 (2)	0.0103 (2)	0.1539 (2)	0.0627 (4)
C9	0.4262 (4)	0.1256 (4)	0.3736 (4)	0.0707 (10)
F9	0.4791 (3)	0.0165 (4)	0.3672 (3)	0.1100 (10)
C10	0.4413 (5)	0.2366 (5)	0.4876 (4)	0.0830 (13)
F10	0.5074 (4)	0.2374 (4)	0.5942 (3)	0.1328 (15)
C11	0.3849 (5)	0.3451 (4)	0.4919 (3)	0.0738 (11)
F11	0.3970 (4)	0.4534 (3)	0.6030 (2)	0.1135 (12)
C12	0.3114 (3)	0.3428 (3)	0.3809 (2)	0.0544 (6)
F12	0.2578 (3)	0.4521 (2)	0.39420 (18)	0.0784 (6)
C13	0.3279 (2)	0.2361 (3)	0.0427 (2)	0.0400 (4)
C14	0.4620 (3)	0.2315 (4)	0.0897 (4)	0.0657 (9)
H14A	0.4880	0.2162	0.1592	0.079*
C15	0.5581 (4)	0.2500 (6)	0.0323 (6)	0.0942 (16)
H15A	0.6476	0.2454	0.0636	0.113*
C16	0.5244 (5)	0.2743 (6)	−0.0670 (5)	0.0870 (13)
H16A	0.5899	0.2859	−0.1041	0.104*
C17	0.3932 (4)	0.2819 (5)	−0.1133 (4)	0.0788 (11)
H17A	0.3694	0.2990	−0.1820	0.095*
C18	0.2956 (3)	0.2642 (4)	−0.0579 (3)	0.0613 (8)
H18A	0.2072	0.2714	−0.0890	0.074*
C19	0.1348 (2)	0.3693 (2)	0.1374 (2)	0.0351 (4)
C20	0.2282 (3)	0.5031 (3)	0.1751 (3)	0.0493 (5)
H20A	0.3219	0.5118	0.1856	0.059*
C21	0.1806 (3)	0.6235 (3)	0.1970 (3)	0.0538 (6)
H21A	0.2431	0.7133	0.2231	0.065*
C22	0.0423 (3)	0.6110 (3)	0.1804 (3)	0.0519 (6)
H22A	0.0115	0.6922	0.1952	0.062*
C23	−0.0513 (3)	0.4787 (3)	0.1419 (3)	0.0527 (6)
H23A	−0.1450	0.4707	0.1308	0.063*
C24	−0.0055 (3)	0.3573 (3)	0.1196 (2)	0.0428 (5)
H24A	−0.0688	0.2678	0.0928	0.051*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pt1	0.03238 (6)	0.02482 (6)	0.02739 (5)	0.01034 (3)	0.00919 (3)	0.01241 (4)
S1	0.0497 (3)	0.0372 (3)	0.0370 (2)	0.0137 (2)	0.0120 (2)	0.0224 (2)
P1	0.0324 (2)	0.0285 (2)	0.0324 (2)	0.01009 (17)	0.00848 (17)	0.01415 (17)
C1	0.0512 (12)	0.0526 (13)	0.0355 (10)	0.0127 (10)	0.0166 (9)	0.0223 (9)
C2	0.0610 (17)	0.095 (3)	0.0398 (12)	0.0242 (16)	0.0171 (12)	0.0338 (15)
F2	0.0718 (13)	0.134 (2)	0.0564 (11)	0.0433 (14)	0.0199 (9)	0.0576 (13)
C3	0.098 (3)	0.154 (5)	0.0358 (14)	0.054 (3)	0.0247 (17)	0.033 (2)
F3	0.147 (3)	0.255 (5)	0.0391 (11)	0.101 (3)	0.0306 (15)	0.0491 (19)
C4	0.133 (4)	0.164 (6)	0.0507 (19)	0.088 (4)	0.046 (3)	0.032 (3)
C5	0.099 (3)	0.118 (4)	0.0577 (19)	0.066 (3)	0.039 (2)	0.032 (2)
F5	0.146 (3)	0.172 (3)	0.0840 (18)	0.119 (3)	0.0565 (19)	0.046 (2)
C6	0.0622 (16)	0.0645 (17)	0.0420 (12)	0.0261 (13)	0.0223 (11)	0.0255 (12)
F6	0.0706 (11)	0.0722 (11)	0.0492 (8)	0.0377 (9)	0.0231 (8)	0.0325 (8)
C7	0.0400 (10)	0.0398 (11)	0.0370 (10)	0.0059 (8)	0.0035 (8)	0.0186 (8)
C8	0.0435 (12)	0.0508 (14)	0.0547 (14)	0.0114 (10)	0.0045 (10)	0.0305 (11)
F8	0.0654 (11)	0.0580 (10)	0.0738 (12)	0.0347 (9)	0.0230 (9)	0.0346 (9)
C9	0.0613 (17)	0.069 (2)	0.075 (2)	0.0117 (15)	−0.0053 (15)	0.0482 (18)
F9	0.113 (2)	0.107 (2)	0.119 (2)	0.0505 (18)	0.0016 (17)	0.0782 (19)
C10	0.086 (2)	0.074 (2)	0.0580 (18)	−0.0091 (19)	−0.0195 (17)	0.0417 (17)
F10	0.160 (3)	0.108 (2)	0.0763 (16)	−0.003 (2)	−0.0426 (18)	0.0597 (17)
C11	0.094 (3)	0.0574 (17)	0.0368 (12)	−0.0106 (17)	−0.0045 (14)	0.0207 (12)
F11	0.179 (3)	0.0762 (15)	0.0353 (9)	0.0007 (17)	0.0061 (13)	0.0145 (9)
C12	0.0680 (17)	0.0428 (12)	0.0376 (11)	0.0034 (11)	0.0078 (11)	0.0171 (10)
F12	0.127 (2)	0.0553 (11)	0.0442 (9)	0.0364 (12)	0.0261 (11)	0.0147 (8)
C13	0.0351 (9)	0.0382 (10)	0.0454 (11)	0.0107 (8)	0.0148 (8)	0.0185 (8)
C14	0.0433 (13)	0.086 (2)	0.095 (2)	0.0274 (14)	0.0295 (15)	0.063 (2)
C15	0.058 (2)	0.130 (4)	0.159 (5)	0.051 (2)	0.064 (3)	0.103 (4)
C16	0.074 (2)	0.109 (3)	0.120 (4)	0.038 (2)	0.067 (3)	0.070 (3)
C17	0.070 (2)	0.105 (3)	0.078 (2)	0.016 (2)	0.0378 (19)	0.056 (2)
C18	0.0445 (13)	0.086 (2)	0.0656 (17)	0.0137 (13)	0.0196 (12)	0.0488 (17)
C19	0.0385 (9)	0.0281 (9)	0.0375 (9)	0.0120 (7)	0.0115 (7)	0.0151 (7)
C20	0.0493 (13)	0.0339 (11)	0.0621 (15)	0.0101 (9)	0.0204 (11)	0.0211 (10)
C21	0.0694 (17)	0.0317 (11)	0.0635 (16)	0.0150 (11)	0.0276 (13)	0.0233 (11)
C22	0.0755 (18)	0.0395 (12)	0.0534 (13)	0.0307 (12)	0.0282 (13)	0.0255 (10)
C23	0.0528 (14)	0.0510 (14)	0.0602 (15)	0.0280 (12)	0.0223 (12)	0.0261 (12)
C24	0.0412 (10)	0.0348 (10)	0.0508 (12)	0.0131 (8)	0.0160 (9)	0.0184 (9)

Geometric parameters (Å, º)

Pt1—S1^i	2.3318 (5)	C10—C11	1.360 (7)
Pt1—S1	2.3318 (5)	C11—F11	1.339 (5)
Pt1—P1	2.3345 (6)	C11—C12	1.391 (4)
Pt1—P1^i	2.3345 (6)	C12—F12	1.332 (4)
S1—C1	1.753 (3)	C13—C18	1.381 (4)
P1—C19	1.814 (2)	C13—C14	1.384 (4)
P1—C13	1.833 (2)	C14—C15	1.395 (5)
P1—C7	1.838 (2)	C14—H14A	0.9300
C1—C6	1.392 (4)	C15—C16	1.341 (7)
C1—C2	1.397 (4)	C15—H15A	0.9300
C2—F2	1.346 (4)	C16—C17	1.368 (6)
C2—C3	1.369 (5)	C16—H16A	0.9300
C3—F3	1.354 (4)	C17—C18	1.388 (4)
C3—C4	1.372 (7)	C17—H17A	0.9300
C4—C5	1.368 (6)	C18—H18A	0.9300
C4—H4A	0.9300	C19—C24	1.390 (3)
C5—F5	1.352 (5)	C19—C20	1.392 (3)
C5—C6	1.385 (4)	C20—C21	1.389 (4)
C6—F6	1.332 (3)	C20—H20A	0.9300
C7—C12	1.383 (4)	C21—C22	1.371 (5)
C7—C8	1.397 (4)	C21—H21A	0.9300
C8—F8	1.335 (4)	C22—C23	1.378 (4)
C8—C9	1.382 (4)	C22—H22A	0.9300
C9—F9	1.340 (5)	C23—C24	1.387 (4)
C9—C10	1.367 (6)	C23—H23A	0.9300
C10—F10	1.330 (4)	C24—H24A	0.9300
S1^i—Pt1—S1	180.0	F11—C11—C10	120.3 (3)
S1^i—Pt1—P1	85.67 (2)	F11—C11—C12	119.4 (4)
S1—Pt1—P1	94.33 (2)	C10—C11—C12	120.3 (3)
S1^i—Pt1—P1^i	94.33 (2)	F12—C12—C7	121.8 (2)
S1—Pt1—P1^i	85.67 (2)	F12—C12—C11	116.1 (3)
P1—Pt1—P1^i	180.0	C7—C12—C11	122.0 (3)
C1—S1—Pt1	109.92 (9)	C18—C13—C14	118.1 (3)
C19—P1—C13	102.55 (11)	C18—C13—P1	118.7 (2)
C19—P1—C7	107.31 (11)	C14—C13—P1	123.2 (2)
C13—P1—C7	103.00 (11)	C13—C14—C15	119.7 (3)
C19—P1—Pt1	110.04 (7)	C13—C14—H14A	120.1
C13—P1—Pt1	121.48 (8)	C15—C14—H14A	120.1
C7—P1—Pt1	111.35 (8)	C16—C15—C14	121.6 (4)
C6—C1—C2	115.5 (3)	C16—C15—H15A	119.2
C6—C1—S1	126.4 (2)	C14—C15—H15A	119.2
C2—C1—S1	118.1 (2)	C15—C16—C17	119.6 (3)
F2—C2—C3	118.7 (3)	C15—C16—H16A	120.2
F2—C2—C1	119.4 (3)	C17—C16—H16A	120.2
C3—C2—C1	121.9 (4)	C16—C17—C18	120.1 (4)
F3—C3—C2	117.4 (4)	C16—C17—H17A	120.0
F3—C3—C4	120.5 (4)	C18—C17—H17A	120.0
C2—C3—C4	122.1 (4)	C13—C18—C17	120.9 (3)
C5—C4—C3	116.9 (4)	C13—C18—H18A	119.5
C5—C4—H4A	121.5	C17—C18—H18A	119.5
C3—C4—H4A	121.5	C24—C19—C20	119.5 (2)
F5—C5—C4	120.5 (4)	C24—C19—P1	119.44 (16)
F5—C5—C6	117.6 (4)	C20—C19—P1	121.09 (18)
C4—C5—C6	121.9 (4)	C21—C20—C19	119.6 (3)
F6—C6—C5	117.7 (3)	C21—C20—H20A	120.2
F6—C6—C1	120.7 (2)	C19—C20—H20A	120.2
C5—C6—C1	121.5 (3)	C22—C21—C20	120.5 (3)
C12—C7—C8	115.7 (2)	C22—C21—H21A	119.8
C12—C7—P1	127.2 (2)	C20—C21—H21A	119.8
C8—C7—P1	116.92 (19)	C21—C22—C23	120.4 (2)
F8—C8—C9	118.1 (3)	C21—C22—H22A	119.8
F8—C8—C7	119.6 (2)	C23—C22—H22A	119.8
C9—C8—C7	122.4 (3)	C22—C23—C24	119.9 (3)
F9—C9—C10	120.6 (3)	C22—C23—H23A	120.0
F9—C9—C8	119.5 (4)	C24—C23—H23A	120.0
C10—C9—C8	119.9 (3)	C23—C24—C19	120.2 (2)
F10—C10—C11	119.8 (4)	C23—C24—H24A	119.9
F10—C10—C9	120.5 (4)	C19—C24—H24A	119.9
C11—C10—C9	119.7 (3)
Pt1—S1—C1—C6	33.1 (3)	F10—C10—C11—F11	0.7 (7)
Pt1—S1—C1—C2	−149.4 (2)	C9—C10—C11—F11	179.0 (4)
C6—C1—C2—F2	177.1 (3)	F10—C10—C11—C12	−177.8 (4)
S1—C1—C2—F2	−0.7 (5)	C9—C10—C11—C12	0.5 (6)
C6—C1—C2—C3	−3.1 (6)	C8—C7—C12—F12	−178.3 (3)
S1—C1—C2—C3	179.2 (4)	P1—C7—C12—F12	−2.7 (4)
F2—C2—C3—F3	1.1 (8)	C8—C7—C12—C11	1.1 (4)
C1—C2—C3—F3	−178.8 (5)	P1—C7—C12—C11	176.7 (3)
F2—C2—C3—C4	−178.5 (6)	F11—C11—C12—F12	0.3 (5)
C1—C2—C3—C4	1.7 (9)	C10—C11—C12—F12	178.8 (4)
F3—C3—C4—C5	−178.8 (6)	F11—C11—C12—C7	−179.1 (3)
C2—C3—C4—C5	0.7 (11)	C10—C11—C12—C7	−0.6 (6)
C3—C4—C5—F5	178.1 (6)	C19—P1—C13—C18	−51.8 (3)
C3—C4—C5—C6	−1.5 (10)	C7—P1—C13—C18	−163.2 (2)
F5—C5—C6—F6	−0.4 (7)	Pt1—P1—C13—C18	71.4 (3)
C4—C5—C6—F6	179.2 (6)	C19—P1—C13—C14	127.2 (3)
F5—C5—C6—C1	−179.6 (4)	C7—P1—C13—C14	15.8 (3)
C4—C5—C6—C1	0.0 (8)	Pt1—P1—C13—C14	−109.6 (3)
C2—C1—C6—F6	−176.9 (3)	C18—C13—C14—C15	−2.2 (6)
S1—C1—C6—F6	0.6 (4)	P1—C13—C14—C15	178.8 (4)
C2—C1—C6—C5	2.3 (5)	C13—C14—C15—C16	0.9 (8)
S1—C1—C6—C5	179.8 (4)	C14—C15—C16—C17	0.3 (9)
C19—P1—C7—C12	6.2 (3)	C15—C16—C17—C18	−0.2 (8)
C13—P1—C7—C12	114.0 (3)	C14—C13—C18—C17	2.4 (5)
Pt1—P1—C7—C12	−114.3 (2)	P1—C13—C18—C17	−178.6 (3)
C19—P1—C7—C8	−178.2 (2)	C16—C17—C18—C13	−1.2 (7)
C13—P1—C7—C8	−70.4 (2)	C13—P1—C19—C24	144.19 (19)
Pt1—P1—C7—C8	61.3 (2)	C7—P1—C19—C24	−107.7 (2)
C12—C7—C8—F8	177.8 (3)	Pt1—P1—C19—C24	13.6 (2)
P1—C7—C8—F8	1.7 (3)	C13—P1—C19—C20	−35.0 (2)
C12—C7—C8—C9	−1.5 (4)	C7—P1—C19—C20	73.1 (2)
P1—C7—C8—C9	−177.6 (3)	Pt1—P1—C19—C20	−165.59 (19)
F8—C8—C9—F9	0.2 (5)	C24—C19—C20—C21	1.3 (4)
C7—C8—C9—F9	179.6 (3)	P1—C19—C20—C21	−179.5 (2)
F8—C8—C9—C10	−177.9 (3)	C19—C20—C21—C22	−0.7 (5)
C7—C8—C9—C10	1.5 (5)	C20—C21—C22—C23	0.0 (5)
F9—C9—C10—F10	−0.8 (7)	C21—C22—C23—C24	0.0 (5)
C8—C9—C10—F10	177.3 (4)	C22—C23—C24—C19	0.7 (4)
F9—C9—C10—C11	−179.0 (4)	C20—C19—C24—C23	−1.3 (4)
C8—C9—C10—C11	−0.9 (6)	P1—C19—C24—C23	179.5 (2)

Symmetry code: (i) −x, −y, −z.

(cis) Bis[(pentafluorophenyl)diphenylphosphane-κP]bis(2,3,5,6-tetrafluorophenylthiolato-κS)platinum(II)

Crystal data

[Pt(C6HF4S)2(C18H10F5P)2]	Dx = 1.868 Mg m^−3
Mr = 1261.80	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Pbca	Cell parameters from 84 reflections
a = 20.348 (3) Å	θ = 3.4–13.0°
b = 19.511 (2) Å	µ = 3.40 mm^−1
c = 22.6059 (18) Å	T = 298 K
V = 8974.7 (17) Å^3	Plate, yellow
Z = 8	0.65 × 0.26 × 0.08 mm
F(000) = 4896

Data collection

Bruker P4 diffractometer	4829 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube, FN4	Rint = 0.049
Graphite monochromator	θmax = 25.0°, θmin = 2.0°
ω scans	h = −24→1
Absorption correction: ψ scan (XSCANS; Bruker, 1997)	k = −23→4
Tmin = 0.200, Tmax = 0.339	l = −1→26
10953 measured reflections	3 standard reflections every 97 reflections
7858 independent reflections	intensity decay: 1%

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.055	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.155	H-atom parameters constrained
S = 1.01	w = 1/[σ^2(Fo^2) + (0.0758P)^2 + 28.3359P] where P = (Fo^2 + 2Fc^2)/3
7858 reflections	(Δ/σ)max = 0.002
640 parameters	Δρmax = 1.73 e Å^−3
0 restraints	Δρmin = −2.06 e Å^−3
0 constraints

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Pt1	0.26305 (2)	0.32364 (2)	0.50273 (2)	0.03623 (14)
S1	0.15478 (13)	0.35885 (15)	0.52803 (10)	0.0550 (7)
S2	0.29034 (13)	0.31330 (13)	0.60341 (9)	0.0468 (6)
P1	0.37043 (12)	0.28949 (12)	0.49139 (10)	0.0413 (5)
P2	0.22397 (12)	0.31423 (12)	0.40789 (9)	0.0392 (5)
C1	0.1419 (5)	0.3411 (5)	0.6032 (4)	0.049 (2)
C2	0.1361 (5)	0.2751 (5)	0.6260 (4)	0.052 (2)
F2	0.1439 (3)	0.2211 (3)	0.5893 (2)	0.0713 (17)
C3	0.1280 (5)	0.2630 (5)	0.6860 (4)	0.051 (2)
F3	0.1270 (3)	0.1965 (3)	0.7042 (3)	0.0726 (17)
C4	0.1207 (5)	0.3157 (6)	0.7255 (4)	0.057 (3)
H4A	0.1142	0.3074	0.7655	0.069*
C5	0.1234 (6)	0.3803 (6)	0.7040 (4)	0.064 (3)
F5	0.1163 (4)	0.4329 (3)	0.7414 (3)	0.094 (2)
C6	0.1341 (5)	0.3927 (5)	0.6453 (4)	0.050 (2)
F6	0.1396 (3)	0.4591 (3)	0.6282 (3)	0.0753 (18)
C7	0.3001 (5)	0.3947 (5)	0.6347 (4)	0.052 (2)
C8	0.3125 (6)	0.3967 (7)	0.6951 (5)	0.075 (3)
F8	0.3159 (5)	0.3371 (5)	0.7252 (3)	0.119 (3)
C9	0.3247 (8)	0.4561 (9)	0.7238 (5)	0.102 (5)
F9	0.3368 (7)	0.4541 (6)	0.7826 (4)	0.193 (6)
C10	0.3241 (8)	0.5183 (8)	0.6959 (7)	0.104 (5)
H10A	0.3329	0.5589	0.7160	0.125*
C11	0.3102 (6)	0.5176 (6)	0.6378 (6)	0.079 (4)
F11	0.3085 (4)	0.5774 (4)	0.6063 (4)	0.117 (3)
C12	0.2994 (5)	0.4586 (5)	0.6075 (5)	0.059 (3)
F12	0.2867 (4)	0.4635 (3)	0.5484 (3)	0.0784 (19)
C13	0.4221 (4)	0.3448 (5)	0.5380 (4)	0.044 (2)
C14	0.4516 (5)	0.3260 (6)	0.5908 (5)	0.062 (3)
F14	0.4503 (3)	0.2616 (3)	0.6104 (3)	0.0717 (18)
C15	0.4809 (5)	0.3732 (6)	0.6289 (5)	0.062 (3)
F15	0.5071 (4)	0.3522 (4)	0.6802 (3)	0.102 (3)
C16	0.4810 (5)	0.4416 (6)	0.6142 (5)	0.066 (3)
F16	0.5095 (4)	0.4873 (4)	0.6506 (4)	0.102 (3)
C17	0.4532 (5)	0.4624 (5)	0.5622 (5)	0.057 (3)
F17	0.4529 (3)	0.5290 (3)	0.5481 (3)	0.0813 (19)
C18	0.4253 (5)	0.4147 (5)	0.5264 (4)	0.050 (2)
F18	0.3962 (3)	0.4391 (3)	0.4758 (2)	0.0571 (14)
C19	0.3851 (5)	0.2014 (5)	0.5145 (4)	0.043 (2)
C20	0.3359 (6)	0.1593 (5)	0.5321 (5)	0.068 (3)
H20A	0.2937	0.1768	0.5371	0.081*
C21	0.3478 (7)	0.0907 (6)	0.5429 (5)	0.082 (4)
H21A	0.3140	0.0619	0.5552	0.099*
C22	0.4121 (7)	0.0648 (6)	0.5351 (5)	0.080 (4)
H22A	0.4207	0.0186	0.5416	0.096*
C23	0.4614 (6)	0.1078 (6)	0.5179 (5)	0.068 (3)
H23A	0.5039	0.0909	0.5137	0.081*
C24	0.4493 (6)	0.1743 (5)	0.5070 (4)	0.059 (3)
H24B	0.4832	0.2028	0.4946	0.070*
C25	0.4118 (5)	0.2879 (4)	0.4200 (4)	0.043 (2)
C26	0.3930 (5)	0.2365 (5)	0.3816 (4)	0.055 (3)
H26B	0.3618	0.2046	0.3935	0.066*
C27	0.4205 (6)	0.2318 (6)	0.3247 (5)	0.072 (3)
H27A	0.4070	0.1977	0.2987	0.087*
C28	0.4677 (7)	0.2784 (7)	0.3081 (5)	0.081 (4)
H28A	0.4852	0.2763	0.2702	0.097*
C29	0.4889 (6)	0.3271 (7)	0.3458 (6)	0.079 (4)
H29A	0.5217	0.3573	0.3339	0.095*
C30	0.4624 (5)	0.3328 (5)	0.4024 (5)	0.066 (3)
H30A	0.4780	0.3660	0.4284	0.079*
C31	0.1518 (4)	0.3691 (5)	0.3918 (4)	0.041 (2)
C32	0.1571 (5)	0.4378 (6)	0.4037 (4)	0.054 (3)
F32	0.2117 (3)	0.4642 (3)	0.4288 (3)	0.0704 (16)
C33	0.1096 (6)	0.4858 (6)	0.3878 (4)	0.063 (3)
F33	0.1189 (4)	0.5523 (4)	0.3988 (3)	0.092 (2)
C34	0.0540 (6)	0.4630 (7)	0.3592 (5)	0.076 (4)
F34	0.0078 (4)	0.5082 (4)	0.3440 (4)	0.125 (3)
C35	0.0466 (5)	0.3949 (7)	0.3476 (5)	0.068 (3)
F35	−0.0071 (3)	0.3726 (5)	0.3192 (3)	0.115 (3)
C36	0.0949 (5)	0.3498 (6)	0.3626 (4)	0.060 (3)
F36	0.0857 (3)	0.2837 (4)	0.3474 (3)	0.0768 (19)
C37	0.1969 (4)	0.2253 (5)	0.4026 (4)	0.044 (2)
C38	0.1514 (5)	0.2021 (6)	0.4433 (5)	0.065 (3)
H38A	0.1316	0.2334	0.4687	0.078*
C39	0.1349 (7)	0.1345 (7)	0.4473 (6)	0.089 (4)
H39A	0.1041	0.1196	0.4748	0.106*
C40	0.1651 (8)	0.0882 (7)	0.4092 (7)	0.099 (5)
H40A	0.1545	0.0419	0.4118	0.119*
C41	0.2093 (7)	0.1087 (6)	0.3686 (6)	0.088 (4)
H41A	0.2279	0.0770	0.3428	0.105*
C42	0.2273 (5)	0.1779 (5)	0.3652 (4)	0.056 (3)
H42A	0.2591	0.1921	0.3384	0.067*
C43	0.2708 (4)	0.3379 (5)	0.3423 (4)	0.043 (2)
C44	0.2544 (5)	0.3149 (5)	0.2866 (4)	0.050 (2)
H44A	0.2211	0.2825	0.2826	0.060*
C45	0.2860 (6)	0.3387 (6)	0.2369 (4)	0.063 (3)
H45A	0.2764	0.3207	0.1998	0.075*
C46	0.3330 (5)	0.3904 (6)	0.2436 (5)	0.067 (3)
H46A	0.3542	0.4078	0.2104	0.080*
C47	0.3480 (5)	0.4155 (6)	0.2976 (5)	0.067 (3)
H47A	0.3795	0.4498	0.3013	0.080*
C48	0.3168 (5)	0.3903 (5)	0.3473 (4)	0.052 (2)
H48A	0.3266	0.4085	0.3843	0.062*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pt1	0.0366 (2)	0.0371 (2)	0.03498 (19)	−0.00151 (15)	−0.00225 (14)	0.00068 (15)
S1	0.0498 (15)	0.0742 (18)	0.0411 (12)	0.0151 (14)	0.0052 (11)	0.0123 (12)
S2	0.0508 (14)	0.0511 (15)	0.0385 (11)	−0.0005 (12)	−0.0058 (10)	0.0047 (10)
P1	0.0386 (13)	0.0376 (13)	0.0476 (13)	−0.0030 (11)	−0.0040 (10)	0.0017 (11)
P2	0.0414 (14)	0.0416 (13)	0.0346 (11)	−0.0047 (11)	−0.0030 (9)	−0.0009 (10)
C1	0.042 (6)	0.066 (7)	0.039 (5)	0.005 (5)	0.008 (4)	−0.004 (5)
C2	0.056 (7)	0.044 (6)	0.055 (6)	0.009 (5)	0.004 (5)	−0.005 (5)
F2	0.094 (5)	0.058 (4)	0.062 (3)	0.004 (4)	0.005 (3)	−0.006 (3)
C3	0.051 (6)	0.044 (6)	0.056 (6)	−0.006 (5)	0.000 (5)	0.015 (5)
F3	0.076 (4)	0.064 (4)	0.078 (4)	−0.004 (3)	−0.007 (3)	0.016 (3)
C4	0.061 (7)	0.072 (8)	0.039 (5)	0.001 (6)	0.004 (5)	−0.005 (5)
C5	0.088 (9)	0.052 (7)	0.053 (6)	0.008 (6)	0.011 (6)	−0.006 (5)
F5	0.135 (7)	0.082 (5)	0.063 (4)	0.013 (5)	0.016 (4)	−0.020 (4)
C6	0.055 (6)	0.042 (6)	0.053 (6)	0.000 (5)	0.012 (5)	0.008 (5)
F6	0.100 (5)	0.059 (4)	0.067 (4)	0.010 (4)	0.010 (3)	0.003 (3)
C7	0.049 (6)	0.064 (7)	0.042 (5)	0.002 (5)	0.001 (4)	−0.005 (5)
C8	0.092 (9)	0.081 (9)	0.052 (6)	−0.010 (8)	−0.014 (6)	−0.011 (6)
F8	0.173 (9)	0.133 (7)	0.050 (4)	−0.028 (6)	−0.032 (5)	0.014 (4)
C9	0.137 (14)	0.117 (12)	0.053 (7)	−0.020 (11)	−0.024 (8)	−0.029 (8)
F9	0.291 (15)	0.221 (11)	0.067 (5)	−0.069 (11)	−0.047 (7)	−0.045 (6)
C10	0.113 (12)	0.101 (12)	0.099 (11)	−0.004 (10)	−0.021 (9)	−0.057 (10)
C11	0.078 (9)	0.049 (8)	0.109 (10)	−0.002 (7)	−0.005 (7)	−0.012 (7)
F11	0.127 (7)	0.063 (5)	0.161 (8)	−0.003 (5)	−0.021 (6)	−0.030 (5)
C12	0.061 (7)	0.047 (6)	0.068 (7)	0.001 (5)	−0.013 (5)	−0.010 (5)
F12	0.105 (5)	0.057 (4)	0.073 (4)	−0.002 (4)	−0.015 (4)	0.000 (3)
C13	0.028 (5)	0.049 (6)	0.056 (5)	−0.004 (4)	−0.006 (4)	0.003 (4)
C14	0.052 (7)	0.054 (7)	0.080 (7)	0.003 (6)	−0.015 (6)	0.006 (6)
F14	0.075 (4)	0.061 (4)	0.079 (4)	0.011 (3)	−0.032 (3)	0.006 (3)
C15	0.052 (7)	0.068 (8)	0.065 (6)	−0.006 (6)	−0.023 (5)	0.000 (6)
F15	0.113 (6)	0.104 (6)	0.088 (5)	0.002 (5)	−0.060 (4)	−0.003 (4)
C16	0.048 (6)	0.072 (8)	0.079 (7)	−0.013 (6)	−0.006 (6)	−0.022 (6)
F16	0.098 (6)	0.091 (5)	0.117 (6)	−0.023 (5)	−0.047 (4)	−0.034 (4)
C17	0.046 (6)	0.046 (6)	0.079 (7)	−0.008 (5)	−0.008 (5)	−0.001 (5)
F17	0.090 (5)	0.054 (4)	0.100 (5)	−0.017 (4)	−0.008 (4)	−0.005 (3)
C18	0.038 (5)	0.052 (6)	0.059 (6)	−0.006 (5)	−0.010 (5)	0.010 (5)
F18	0.058 (4)	0.048 (3)	0.065 (3)	−0.001 (3)	−0.002 (3)	0.009 (3)
C19	0.049 (6)	0.040 (5)	0.040 (4)	−0.004 (5)	−0.003 (4)	0.001 (4)
C20	0.075 (8)	0.046 (7)	0.082 (8)	−0.014 (6)	0.012 (6)	0.007 (6)
C21	0.114 (11)	0.043 (7)	0.090 (9)	−0.018 (7)	0.017 (8)	0.015 (6)
C22	0.111 (11)	0.054 (8)	0.075 (8)	0.024 (8)	0.007 (8)	0.015 (6)
C23	0.073 (8)	0.061 (8)	0.070 (7)	0.027 (7)	−0.007 (6)	0.003 (6)
C24	0.051 (6)	0.049 (6)	0.077 (7)	0.007 (5)	−0.009 (5)	0.005 (6)
C25	0.044 (6)	0.033 (5)	0.053 (5)	−0.003 (5)	−0.007 (4)	0.004 (4)
C26	0.045 (6)	0.055 (7)	0.065 (6)	−0.003 (5)	−0.008 (5)	−0.003 (5)
C27	0.073 (8)	0.080 (9)	0.064 (7)	0.005 (7)	−0.014 (6)	−0.023 (6)
C28	0.085 (10)	0.091 (10)	0.066 (7)	0.014 (8)	0.016 (7)	−0.006 (7)
C29	0.065 (8)	0.076 (9)	0.096 (9)	0.003 (7)	0.038 (7)	0.015 (8)
C30	0.055 (7)	0.051 (7)	0.092 (8)	−0.003 (6)	0.008 (6)	0.003 (6)
C31	0.036 (5)	0.048 (6)	0.039 (5)	−0.002 (5)	0.006 (4)	0.002 (4)
C32	0.060 (7)	0.067 (7)	0.035 (5)	−0.001 (6)	−0.001 (5)	0.005 (5)
F32	0.082 (4)	0.054 (4)	0.075 (4)	−0.004 (4)	−0.004 (3)	0.002 (3)
C33	0.074 (9)	0.062 (8)	0.054 (6)	0.013 (7)	0.016 (6)	0.012 (5)
F33	0.118 (6)	0.075 (5)	0.083 (4)	0.030 (4)	0.012 (4)	0.014 (4)
C34	0.062 (8)	0.092 (10)	0.073 (7)	0.036 (8)	0.011 (6)	0.026 (7)
F34	0.100 (6)	0.143 (8)	0.133 (7)	0.068 (6)	−0.001 (5)	0.036 (6)
C35	0.044 (7)	0.098 (10)	0.063 (6)	0.007 (7)	−0.007 (5)	0.010 (7)
F35	0.066 (5)	0.165 (8)	0.115 (6)	0.024 (5)	−0.033 (4)	−0.012 (6)
C36	0.059 (7)	0.074 (8)	0.045 (5)	−0.005 (7)	−0.002 (5)	0.001 (5)
F36	0.051 (4)	0.096 (5)	0.083 (4)	−0.012 (4)	−0.019 (3)	−0.013 (4)
C37	0.037 (5)	0.047 (6)	0.049 (5)	−0.011 (5)	−0.010 (4)	0.006 (4)
C38	0.066 (7)	0.060 (7)	0.068 (7)	−0.023 (6)	−0.005 (6)	0.000 (6)
C39	0.099 (11)	0.081 (10)	0.087 (9)	−0.031 (9)	0.010 (8)	0.010 (8)
C40	0.101 (12)	0.060 (9)	0.137 (13)	−0.021 (9)	−0.014 (10)	0.014 (9)
C41	0.087 (10)	0.049 (7)	0.126 (12)	−0.003 (7)	−0.021 (9)	−0.017 (8)
C42	0.061 (7)	0.052 (6)	0.056 (6)	0.004 (6)	−0.012 (5)	−0.006 (5)
C43	0.038 (6)	0.050 (6)	0.041 (5)	0.002 (5)	−0.006 (4)	−0.001 (4)
C44	0.049 (6)	0.056 (6)	0.045 (5)	0.001 (5)	−0.002 (4)	0.000 (4)
C45	0.076 (8)	0.075 (8)	0.037 (5)	0.013 (7)	0.007 (5)	−0.001 (5)
C46	0.061 (7)	0.083 (8)	0.056 (6)	−0.008 (7)	0.007 (5)	0.027 (6)
C47	0.056 (7)	0.077 (8)	0.067 (7)	−0.012 (6)	0.000 (5)	0.014 (6)
C48	0.053 (6)	0.052 (6)	0.050 (5)	0.003 (5)	−0.013 (5)	0.004 (5)

Geometric parameters (Å, º)

Pt1—P2	2.294 (2)	C21—H21A	0.9300
Pt1—P1	2.299 (2)	C22—C23	1.365 (16)
Pt1—S2	2.352 (2)	C22—H22A	0.9300
Pt1—S1	2.377 (3)	C23—C24	1.344 (14)
S1—C1	1.753 (9)	C23—H23A	0.9300
S2—C7	1.749 (10)	C24—H24B	0.9300
P1—C25	1.821 (9)	C25—C26	1.380 (12)
P1—C19	1.821 (9)	C25—C30	1.408 (13)
P1—C13	1.840 (9)	C26—C27	1.405 (14)
P2—C43	1.822 (9)	C26—H26B	0.9300
P2—C37	1.825 (9)	C27—C28	1.374 (16)
P2—C31	1.853 (9)	C27—H27A	0.9300
C1—C2	1.393 (13)	C28—C29	1.347 (17)
C1—C6	1.394 (13)	C28—H28A	0.9300
C2—F2	1.349 (10)	C29—C30	1.393 (15)
C2—C3	1.386 (13)	C29—H29A	0.9300
C3—F3	1.362 (10)	C30—H30A	0.9300
C3—C4	1.370 (13)	C31—C32	1.373 (13)
C4—C5	1.350 (13)	C31—C36	1.384 (13)
C4—H4A	0.9300	C32—F32	1.349 (11)
C5—F5	1.337 (11)	C32—C33	1.392 (15)
C5—C6	1.368 (13)	C33—F33	1.336 (13)
C6—F6	1.355 (11)	C33—C34	1.376 (17)
C7—C8	1.390 (13)	C34—F34	1.334 (12)
C7—C12	1.391 (14)	C34—C35	1.364 (17)
C8—F8	1.350 (13)	C35—F35	1.340 (12)
C8—C9	1.351 (17)	C35—C36	1.361 (15)
C9—F9	1.352 (14)	C36—F36	1.348 (12)
C9—C10	1.368 (19)	C37—C38	1.383 (13)
C10—C11	1.343 (17)	C37—C42	1.396 (13)
C10—H10A	0.9300	C38—C39	1.365 (16)
C11—C12	1.358 (15)	C38—H38A	0.9300
C11—F11	1.366 (14)	C39—C40	1.392 (18)
C12—F12	1.363 (11)	C39—H39A	0.9300
C13—C14	1.385 (13)	C40—C41	1.346 (18)
C13—C18	1.390 (13)	C40—H40A	0.9300
C14—F14	1.333 (11)	C41—C42	1.400 (15)
C14—C15	1.394 (14)	C41—H41A	0.9300
C15—F15	1.340 (11)	C42—H42A	0.9300
C15—C16	1.375 (15)	C43—C44	1.377 (12)
C16—F16	1.346 (11)	C43—C48	1.391 (13)
C16—C17	1.368 (14)	C44—C45	1.376 (13)
C17—F17	1.337 (11)	C44—H44A	0.9300
C17—C18	1.358 (13)	C45—C46	1.399 (14)
C18—F18	1.372 (10)	C45—H45A	0.9300
C19—C20	1.354 (14)	C46—C47	1.350 (14)
C19—C24	1.419 (15)	C46—H46A	0.9300
C20—C21	1.383 (15)	C47—C48	1.382 (13)
C20—H20A	0.9300	C47—H47A	0.9300
C21—C22	1.413 (17)	C48—H48A	0.9300
P2—Pt1—P1	101.66 (8)	C22—C21—H21A	120.5
P2—Pt1—S2	168.40 (9)	C23—C22—C21	119.8 (11)
P1—Pt1—S2	81.87 (8)	C23—C22—H22A	120.1
P2—Pt1—S1	85.80 (8)	C21—C22—H22A	120.1
P1—Pt1—S1	172.47 (8)	C24—C23—C22	120.7 (12)
S2—Pt1—S1	90.61 (8)	C24—C23—H23A	119.6
C1—S1—Pt1	108.3 (3)	C22—C23—H23A	119.6
C7—S2—Pt1	109.9 (3)	C23—C24—C19	120.5 (11)
C25—P1—C19	99.4 (4)	C23—C24—H24B	119.8
C25—P1—C13	104.6 (4)	C19—C24—H24B	119.8
C19—P1—C13	107.2 (4)	C26—C25—C30	118.4 (9)
C25—P1—Pt1	122.9 (3)	C26—C25—P1	116.2 (7)
C19—P1—Pt1	113.4 (3)	C30—C25—P1	125.4 (8)
C13—P1—Pt1	108.0 (3)	C25—C26—C27	120.8 (10)
C43—P2—C37	110.2 (4)	C25—C26—H26B	119.6
C43—P2—C31	96.2 (4)	C27—C26—H26B	119.6
C37—P2—C31	107.3 (4)	C28—C27—C26	119.0 (10)
C43—P2—Pt1	124.0 (3)	C28—C27—H27A	120.5
C37—P2—Pt1	104.0 (3)	C26—C27—H27A	120.5
C31—P2—Pt1	114.3 (3)	C29—C28—C27	121.2 (11)
C2—C1—C6	113.9 (8)	C29—C28—H28A	119.4
C2—C1—S1	123.6 (7)	C27—C28—H28A	119.4
C6—C1—S1	122.4 (8)	C28—C29—C30	120.8 (12)
F2—C2—C3	118.8 (9)	C28—C29—H29A	119.6
F2—C2—C1	119.0 (8)	C30—C29—H29A	119.6
C3—C2—C1	122.0 (9)	C29—C30—C25	119.6 (11)
F3—C3—C4	121.1 (9)	C29—C30—H30A	120.2
F3—C3—C2	117.4 (9)	C25—C30—H30A	120.2
C4—C3—C2	121.5 (9)	C32—C31—C36	115.2 (10)
C5—C4—C3	117.5 (9)	C32—C31—P2	117.6 (8)
C5—C4—H4A	121.2	C36—C31—P2	126.8 (8)
C3—C4—H4A	121.2	F32—C32—C31	121.3 (9)
F5—C5—C4	119.0 (9)	F32—C32—C33	115.1 (10)
F5—C5—C6	119.6 (10)	C31—C32—C33	123.4 (11)
C4—C5—C6	121.4 (9)	F33—C33—C34	121.1 (11)
F6—C6—C5	117.4 (9)	F33—C33—C32	120.4 (11)
F6—C6—C1	119.0 (8)	C34—C33—C32	118.4 (11)
C5—C6—C1	123.5 (9)	F34—C34—C35	121.1 (13)
C8—C7—C12	114.2 (10)	F34—C34—C33	119.2 (13)
C8—C7—S2	116.4 (8)	C35—C34—C33	119.7 (11)
C12—C7—S2	129.4 (7)	F35—C35—C36	119.9 (12)
F8—C8—C9	119.2 (11)	F35—C35—C34	119.8 (12)
F8—C8—C7	118.7 (10)	C36—C35—C34	120.2 (11)
C9—C8—C7	122.0 (12)	F36—C36—C35	117.0 (10)
C8—C9—F9	118.6 (15)	F36—C36—C31	119.9 (10)
C8—C9—C10	122.5 (11)	C35—C36—C31	123.1 (11)
F9—C9—C10	118.8 (14)	C38—C37—C42	118.9 (9)
C11—C10—C9	116.3 (12)	C38—C37—P2	117.9 (8)
C11—C10—H10A	121.8	C42—C37—P2	122.5 (7)
C9—C10—H10A	121.8	C39—C38—C37	121.6 (11)
C10—C11—C12	122.5 (13)	C39—C38—H38A	119.2
C10—C11—F11	120.3 (12)	C37—C38—H38A	119.2
C12—C11—F11	117.1 (12)	C38—C39—C40	118.6 (12)
C11—C12—F12	117.8 (10)	C38—C39—H39A	120.7
C11—C12—C7	122.4 (10)	C40—C39—H39A	120.7
F12—C12—C7	119.8 (9)	C41—C40—C39	121.6 (13)
C14—C13—C18	113.8 (9)	C41—C40—H40A	119.2
C14—C13—P1	125.9 (8)	C39—C40—H40A	119.2
C18—C13—P1	119.6 (7)	C40—C41—C42	119.9 (13)
F14—C14—C13	121.8 (9)	C40—C41—H41A	120.0
F14—C14—C15	115.2 (9)	C42—C41—H41A	120.0
C13—C14—C15	122.9 (10)	C37—C42—C41	119.4 (11)
F15—C15—C16	120.3 (10)	C37—C42—H42A	120.3
F15—C15—C14	120.2 (10)	C41—C42—H42A	120.3
C16—C15—C14	119.5 (10)	C44—C43—C48	118.5 (9)
F16—C16—C17	120.4 (11)	C44—C43—P2	122.3 (7)
F16—C16—C15	119.8 (10)	C48—C43—P2	118.2 (7)
C17—C16—C15	119.7 (10)	C45—C44—C43	121.5 (10)
F17—C17—C18	121.5 (9)	C45—C44—H44A	119.2
F17—C17—C16	119.7 (10)	C43—C44—H44A	119.2
C18—C17—C16	118.8 (10)	C44—C45—C46	118.4 (9)
C17—C18—F18	116.1 (9)	C44—C45—H45A	120.8
C17—C18—C13	125.4 (9)	C46—C45—H45A	120.8
F18—C18—C13	118.5 (8)	C47—C46—C45	120.9 (9)
C20—C19—C24	119.3 (10)	C47—C46—H46A	119.6
C20—C19—P1	122.4 (8)	C45—C46—H46A	119.6
C24—C19—P1	117.9 (7)	C46—C47—C48	120.2 (10)
C19—C20—C21	120.6 (12)	C46—C47—H47A	119.9
C19—C20—H20A	119.7	C48—C47—H47A	119.9
C21—C20—H20A	119.7	C47—C48—C43	120.3 (9)
C20—C21—C22	119.1 (12)	C47—C48—H48A	119.9
C20—C21—H21A	120.5	C43—C48—H48A	119.9
Pt1—S1—C1—C2	−69.7 (9)	C24—C19—C20—C21	0.1 (16)
Pt1—S1—C1—C6	112.7 (8)	P1—C19—C20—C21	172.6 (9)
C6—C1—C2—F2	−178.9 (9)	C19—C20—C21—C22	−0.2 (18)
S1—C1—C2—F2	3.3 (14)	C20—C21—C22—C23	0.9 (19)
C6—C1—C2—C3	−4.3 (15)	C21—C22—C23—C24	−1.5 (18)
S1—C1—C2—C3	177.9 (8)	C22—C23—C24—C19	1.4 (16)
F2—C2—C3—F3	−1.4 (14)	C20—C19—C24—C23	−0.6 (15)
C1—C2—C3—F3	−176.1 (9)	P1—C19—C24—C23	−173.5 (8)
F2—C2—C3—C4	179.2 (9)	C19—P1—C25—C26	53.1 (8)
C1—C2—C3—C4	4.6 (16)	C13—P1—C25—C26	163.8 (7)
F3—C3—C4—C5	179.0 (10)	Pt1—P1—C25—C26	−72.8 (8)
C2—C3—C4—C5	−1.7 (16)	C19—P1—C25—C30	−124.3 (9)
C3—C4—C5—F5	179.8 (10)	C13—P1—C25—C30	−13.6 (10)
C3—C4—C5—C6	−1.0 (18)	Pt1—P1—C25—C30	109.8 (8)
F5—C5—C6—F6	2.7 (16)	C30—C25—C26—C27	−4.2 (15)
C4—C5—C6—F6	−176.5 (10)	P1—C25—C26—C27	178.2 (8)
F5—C5—C6—C1	−179.8 (10)	C25—C26—C27—C28	1.4 (16)
C4—C5—C6—C1	1.1 (18)	C26—C27—C28—C29	1.7 (19)
C2—C1—C6—F6	179.1 (9)	C27—C28—C29—C30	−2 (2)
S1—C1—C6—F6	−3.1 (14)	C28—C29—C30—C25	−1.2 (18)
C2—C1—C6—C5	1.6 (15)	C26—C25—C30—C29	4.2 (15)
S1—C1—C6—C5	179.4 (9)	P1—C25—C30—C29	−178.5 (8)
Pt1—S2—C7—C8	176.3 (8)	C43—P2—C31—C32	−78.3 (7)
Pt1—S2—C7—C12	−6.1 (11)	C37—P2—C31—C32	168.3 (7)
C12—C7—C8—F8	−178.2 (11)	Pt1—P2—C31—C32	53.5 (7)
S2—C7—C8—F8	−0.2 (16)	C43—P2—C31—C36	93.8 (8)
C12—C7—C8—C9	−1.9 (19)	C37—P2—C31—C36	−19.6 (9)
S2—C7—C8—C9	176.1 (12)	Pt1—P2—C31—C36	−134.4 (7)
F8—C8—C9—F9	−3 (2)	C36—C31—C32—F32	−175.9 (8)
C7—C8—C9—F9	−179.5 (13)	P2—C31—C32—F32	−2.9 (12)
F8—C8—C9—C10	178.0 (15)	C36—C31—C32—C33	−0.4 (14)
C7—C8—C9—C10	2 (3)	P2—C31—C32—C33	172.6 (7)
C8—C9—C10—C11	0 (3)	F32—C32—C33—F33	−1.7 (13)
F9—C9—C10—C11	−178.4 (14)	C31—C32—C33—F33	−177.5 (9)
C9—C10—C11—C12	−2 (2)	F32—C32—C33—C34	176.7 (9)
C9—C10—C11—F11	−180.0 (14)	C31—C32—C33—C34	0.9 (15)
C10—C11—C12—F12	−179.0 (12)	F33—C33—C34—F34	−2.0 (16)
F11—C11—C12—F12	−1.2 (17)	C32—C33—C34—F34	179.6 (9)
C10—C11—C12—C7	2 (2)	F33—C33—C34—C35	178.7 (10)
F11—C11—C12—C7	179.8 (10)	C32—C33—C34—C35	0.3 (16)
C8—C7—C12—C11	0.1 (17)	F34—C34—C35—F35	1.6 (18)
S2—C7—C12—C11	−177.6 (9)	C33—C34—C35—F35	−179.2 (9)
C8—C7—C12—F12	−178.9 (10)	F34—C34—C35—C36	178.7 (10)
S2—C7—C12—F12	3.5 (16)	C33—C34—C35—C36	−2.0 (17)
C25—P1—C13—C14	−121.6 (9)	F35—C35—C36—F36	0.1 (15)
C19—P1—C13—C14	−16.7 (10)	C34—C35—C36—F36	−177.0 (10)
Pt1—P1—C13—C14	105.8 (9)	F35—C35—C36—C31	179.8 (9)
C25—P1—C13—C18	69.3 (9)	C34—C35—C36—C31	2.7 (17)
C19—P1—C13—C18	174.1 (8)	C32—C31—C36—F36	178.3 (8)
Pt1—P1—C13—C18	−63.3 (8)	P2—C31—C36—F36	6.0 (13)
C18—C13—C14—F14	176.6 (9)	C32—C31—C36—C35	−1.4 (14)
P1—C13—C14—F14	7.0 (15)	P2—C31—C36—C35	−173.7 (8)
C18—C13—C14—C15	0.7 (16)	C43—P2—C37—C38	−169.1 (7)
P1—C13—C14—C15	−169.0 (9)	C31—P2—C37—C38	−65.4 (8)
F14—C14—C15—F15	2.0 (16)	Pt1—P2—C37—C38	56.1 (8)
C13—C14—C15—F15	178.2 (10)	C43—P2—C37—C42	20.7 (9)
F14—C14—C15—C16	−176.0 (10)	C31—P2—C37—C42	124.4 (8)
C13—C14—C15—C16	0.2 (18)	Pt1—P2—C37—C42	−114.1 (7)
F15—C15—C16—F16	2.4 (18)	C42—C37—C38—C39	−1.0 (15)
C14—C15—C16—F16	−179.6 (10)	P2—C37—C38—C39	−171.5 (9)
F15—C15—C16—C17	−179.0 (10)	C37—C38—C39—C40	0.2 (19)
C14—C15—C16—C17	−1.0 (18)	C38—C39—C40—C41	−1 (2)
F16—C16—C17—F17	−1.8 (16)	C39—C40—C41—C42	2 (2)
C15—C16—C17—F17	179.6 (10)	C38—C37—C42—C41	2.2 (14)
F16—C16—C17—C18	179.4 (10)	P2—C37—C42—C41	172.3 (8)
C15—C16—C17—C18	0.9 (17)	C40—C41—C42—C37	−2.6 (18)
F17—C17—C18—F18	−1.1 (15)	C37—P2—C43—C44	37.8 (9)
C16—C17—C18—F18	177.7 (9)	C31—P2—C43—C44	−73.3 (8)
F17—C17—C18—C13	−178.6 (10)	Pt1—P2—C43—C44	161.7 (6)
C16—C17—C18—C13	0.2 (17)	C37—P2—C43—C48	−154.2 (7)
C14—C13—C18—C17	−0.9 (15)	C31—P2—C43—C48	94.8 (8)
P1—C13—C18—C17	169.5 (8)	Pt1—P2—C43—C48	−30.2 (9)
C14—C13—C18—F18	−178.4 (8)	C48—C43—C44—C45	5.2 (14)
P1—C13—C18—F18	−8.0 (13)	P2—C43—C44—C45	173.2 (8)
C25—P1—C19—C20	−127.4 (9)	C43—C44—C45—C46	−4.0 (15)
C13—P1—C19—C20	124.0 (9)	C44—C45—C46—C47	1.4 (16)
Pt1—P1—C19—C20	4.8 (9)	C45—C46—C47—C48	−0.3 (17)
C25—P1—C19—C24	45.3 (8)	C46—C47—C48—C43	1.6 (16)
C13—P1—C19—C24	−63.3 (8)	C44—C43—C48—C47	−4.0 (14)
Pt1—P1—C19—C24	177.5 (6)	P2—C43—C48—C47	−172.5 (8)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C4—H4A···F36^i	0.93	2.63	3.444 (12)	147
C30—H30A···F17^ii	0.93	2.54	3.391 (13)	152
C30—H30A···F18	0.93	2.44	2.979 (12)	117
C38—H38A···S1	0.93	2.83	3.608 (12)	142
C48—H48A···F18	0.93	2.58	3.457 (11)	158

Symmetry codes: (i) x, −y+1/2, z+1/2; (ii) −x+1, −y+1, −z+1.