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metal-organic compounds
Bis[μ-methylenebis(dicyclohexylphosphine)-P:P']bis[chloropalladium(I)](Pd—Pd) Diacetonitrile Solvate
A dinuclear palladium(I) complex bridged by two diphosphine ligands, bis[μ-methylenebis(dicyclohexylphosphine)- P:P']bis[chloropalladium(I)](Pd—Pd) diacetonitrile solvate, [Pd2Cl2(C25H46P2)2].2CH3CN, has been prepared, and the crystal structure determined. The two, approximately square-planar, ligand arrays show twisting, and the torsion angles are interpreted in terms of the steric factor between the diphosphine ligands.
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