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The minor diastereomer (
adduct) of the tertiary homoallylic alcohols, formed in the Zn-mediated reaction between 2-methyl-1-phenyl-1-propanone (isobutyrophenone) and 3-chloro-1-phenylpropene (cinnamyl chloride) in tetrahydrofuran/NH4Cl(aq), was isolated and crystallized. The structure of the title compound,C19H22O, confirms that the major and minor diastereomers of the
adduct formed in the reaction have syn and anti configurations, respectively.
adduct) of the tertiary homoallylic alcohols, formed in the Zn-mediated reaction between 2-methyl-1-phenyl-1-propanone (isobutyrophenone) and 3-chloro-1-phenylpropene (cinnamyl chloride) in tetrahydrofuran/NH4Cl(aq), was isolated and crystallized. The structure of the title compound,C19H22O, confirms that the major and minor diastereomers of the
adduct formed in the reaction have syn and anti configurations, respectively.
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