Hemilability and structural considerations in com­plexes of platinum(II) com­prising bis­(di­phenyl­phosphan­yl)methane monoxide, mono­sulfide, and monoselenide

The structure of a platinum(II) com­plex containing (R)-(di­methyl­amino)­ethyl­napthyl and bis­(di­phenyl­phosphan­yl)methane mono­sulfide ligands, namely, {(R)-1-[1-(di­methyl­amino)­eth­yl]napthyl-κ²N,C²}[(di­phenyl­phos­phan­yl­meth­yl)di­phenyl­phosphine sulfide-κ²P,S]platinum(II) hexa­fluorido­anti­monate di­chloro­methane monosolvate, [Pt(C₁₄H₁₆N)(C₂₅H₂₂P₂S)][SbF₆]·CH₂Cl₂, was determined. The structural features are com­pared with analogous platinum bis­(di­phenyl­phosphan­yl)methane monoxide [dppm(O)] and bis­(di­phenyl­phosphan­yl)methane monoselenide [dppm(Se)] com­plexes in relation to their potential hemilability and stereochemical nonrigidity.

Computing details

Data collection: PROCESS-AUTO (Rigaku, 1998); cell refinement: PROCESS-AUTO (Rigaku, 1998); data reduction: CrystalStructure (Rigaku and Rigaku Americas, 2010); program(s) used to solve structure: SIR92 (Altomare et al., 1994); program(s) used to refine structure: SHELXL2018 (Sheldrick, 2015); molecular graphics: OLEX2 (Dolomanov et al., 2009); software used to prepare material for publication: OLEX2 (Dolomanov et al., 2009).

{(R)-1-[1-(Dimethylamino)ethyl]napthyl-κ²N,C²}[(diphenylphosphanylmethyl)diphenylphosphine sulfide-κ²P,S]platinum(II) hexafluoridoantimonate dichloromethane monosolvate

Crystal data

[Pt(C14H16N)(C25H22P2S)][SbF6]·CH2Cl2	F(000) = 2200
Mr = 1130.50	Dx = 1.729 Mg m^−3
Orthorhombic, P212121	Mo Kα radiation, λ = 0.71075 Å
Hall symbol: P 2ac 2ab	Cell parameters from 27018 reflections
a = 12.9774 (8) Å	θ = 3.1–27.6°
b = 18.3039 (11) Å	µ = 4.14 mm^−1
c = 18.2877 (11) Å	T = 223 K
V = 4344.0 (5) Å^3	Prism, colourless
Z = 4	0.14 × 0.12 × 0.10 mm

Data collection

Rigaku SCXmini diffractometer	7617 reflections with I > 2σ(I)
Detector resolution: 6.85 pixels mm^-1	Rint = 0.069
ω scans	θmax = 27.5°, θmin = 3.1°
Absorption correction: multi-scan (DIFABS; Jacobson, 1998)	h = −16→16
Tmin = 0.507, Tmax = 0.666	k = −21→23
30288 measured reflections	l = −23→20
9922 independent reflections

Refinement

Refinement on F^2	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.054	w = 1/[σ^2(Fo^2) + (0.0394P)^2] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.105	(Δ/σ)max = 0.001
S = 1.02	Δρmax = 1.31 e Å^−3
9922 reflections	Δρmin = −0.62 e Å^−3
463 parameters	Absolute structure: Flack x determined using 2448 quotients [(I+)-(I-)]/[(I+)+(I-)] (Parsons et al., 2013)
0 restraints	Absolute structure parameter: 0.011 (5)
Primary atom site location: structure-invariant direct methods

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Large thermal parameters on fluorines indicate disorder. There are apparently two orientations of the SbF6 displaced around the F1—F6 axis. This was not a large enough displacement that it was modelled. Modelling of a disorder in a methylene chloride was problematic. Refinement without the methylene chloride, but using a solvent mask calculated that 160 electrons were found in a volume of 748 A3 in one void in the unit cell. This is consistent with the presence of one CH2Cl2 per formula unit which accounts for 168 electrons per unit cell.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Pt1	0.59581 (3)	0.81059 (2)	0.39453 (2)	0.03826 (12)
Sb1	0.93404 (8)	0.72396 (6)	0.19367 (6)	0.0750 (3)
S1	0.7429 (3)	0.86583 (17)	0.45127 (17)	0.0529 (9)
P1	0.5905 (3)	0.89654 (15)	0.30950 (15)	0.0400 (6)
P2	0.7778 (2)	0.95134 (16)	0.38666 (18)	0.0438 (7)
F1	0.8943 (9)	0.8191 (6)	0.1766 (6)	0.132 (4)
F2	0.8599 (18)	0.7329 (10)	0.2764 (10)	0.273 (11)
F3	1.0469 (11)	0.7597 (6)	0.2409 (10)	0.203 (8)
F4	1.0054 (17)	0.7206 (12)	0.1104 (8)	0.271 (11)
F5	0.8274 (13)	0.6934 (8)	0.1385 (13)	0.290 (12)
F6	0.9791 (10)	0.6290 (6)	0.2162 (7)	0.153 (5)
N1	0.5991 (8)	0.7236 (5)	0.4736 (5)	0.045 (2)
C1	0.7224 (9)	0.9338 (6)	0.3011 (7)	0.050 (3)
H1A	0.765505	0.898814	0.274476	0.060*
H1B	0.720133	0.979179	0.272758	0.060*
C2	0.5628 (9)	0.8720 (6)	0.2146 (6)	0.044 (3)
C3	0.4790 (10)	0.9053 (7)	0.1784 (7)	0.055 (4)
H3	0.434523	0.938943	0.201076	0.067*
C4	0.4678 (12)	0.8821 (9)	0.1012 (9)	0.081 (5)
H4	0.413555	0.901671	0.073368	0.098*
C5	0.5316 (15)	0.8347 (8)	0.0698 (9)	0.078 (5)
H5	0.522268	0.822652	0.020303	0.093*
C6	0.6088 (13)	0.8036 (7)	0.1073 (8)	0.079 (4)
H6	0.653334	0.770580	0.083825	0.095*
C7	0.6237 (11)	0.8204 (7)	0.1823 (7)	0.062 (4)
H7	0.674823	0.796223	0.209516	0.074*
C8	0.5114 (10)	0.9761 (6)	0.3328 (6)	0.047 (3)
C9	0.4407 (9)	0.9700 (7)	0.3885 (7)	0.049 (3)
H9	0.433284	0.925849	0.414257	0.059*
C10	0.3823 (10)	1.0286 (9)	0.4054 (9)	0.076 (4)
H10	0.334680	1.023548	0.443814	0.091*
C11	0.3868 (14)	1.0926 (9)	0.3721 (9)	0.078 (5)
H11	0.344101	1.131814	0.385575	0.093*
C12	0.4599 (15)	1.0987 (8)	0.3148 (11)	0.097 (6)
H12	0.467862	1.143798	0.290879	0.116*
C13	0.5187 (12)	1.0412 (7)	0.2936 (8)	0.073 (4)
H13	0.563300	1.045192	0.253287	0.087*
C14	0.9159 (9)	0.9596 (6)	0.3767 (5)	0.041 (3)
C15	0.9640 (11)	0.9112 (7)	0.3338 (8)	0.063 (4)
H15	0.925846	0.876180	0.307698	0.075*
C16	1.0743 (12)	0.9131 (8)	0.3279 (8)	0.074 (4)
H16	1.108552	0.878960	0.298151	0.089*
C17	1.1290 (11)	0.9640 (8)	0.3652 (7)	0.059 (4)
H17	1.201150	0.965587	0.361298	0.071*
C18	1.0792 (12)	1.0117 (8)	0.4074 (9)	0.082 (5)
H18	1.117405	1.047096	0.432908	0.099*
C19	0.9711 (11)	1.0106 (7)	0.4151 (7)	0.063 (4)
H19	0.937614	1.044199	0.445952	0.076*
C20	0.7304 (10)	1.0379 (6)	0.4188 (6)	0.048 (3)
C21	0.6619 (11)	1.0422 (7)	0.4756 (8)	0.064 (4)
H21	0.639641	0.999318	0.499138	0.077*
C22	0.6249 (13)	1.1105 (10)	0.4988 (9)	0.085 (5)
H22	0.580209	1.113329	0.539156	0.102*
C23	0.6523 (15)	1.1707 (10)	0.4643 (11)	0.098 (6)
H23	0.626523	1.216004	0.480055	0.118*
C24	0.7212 (15)	1.1677 (8)	0.4031 (10)	0.097 (6)
H24	0.738671	1.210187	0.376964	0.116*
C25	0.7599 (13)	1.1021 (7)	0.3842 (8)	0.077 (5)
H25	0.808625	1.099679	0.346259	0.092*
C26	0.4715 (9)	0.7545 (6)	0.3617 (6)	0.037 (3)
C27	0.3846 (9)	0.7792 (6)	0.3210 (6)	0.045 (3)
H27	0.385130	0.827201	0.302623	0.054*
C28	0.2999 (9)	0.7359 (7)	0.3074 (6)	0.048 (3)
H28	0.243869	0.755048	0.280955	0.057*
C29	0.2965 (8)	0.6642 (6)	0.3323 (6)	0.038 (3)
C30	0.2109 (9)	0.6178 (8)	0.3199 (7)	0.053 (3)
H30	0.152864	0.637093	0.296067	0.064*
C31	0.2090 (11)	0.5498 (8)	0.3400 (7)	0.063 (4)
H31	0.152397	0.520315	0.327494	0.075*
C32	0.2922 (11)	0.5195 (7)	0.3811 (7)	0.061 (4)
H32	0.289053	0.470850	0.397230	0.073*
C33	0.3775 (9)	0.5620 (6)	0.3970 (7)	0.048 (3)
H33	0.432524	0.541847	0.423682	0.058*
C34	0.3825 (8)	0.6362 (6)	0.3731 (6)	0.042 (3)
C35	0.4653 (7)	0.6825 (6)	0.3880 (6)	0.036 (2)
C36	0.5552 (10)	0.6573 (6)	0.4345 (7)	0.052 (3)
H36	0.531036	0.621134	0.470903	0.062*
C37	0.6379 (10)	0.6231 (7)	0.3866 (8)	0.074 (4)
H37A	0.671192	0.660895	0.357885	0.111*
H37B	0.606582	0.587570	0.354142	0.111*
H37C	0.688625	0.599083	0.417229	0.111*
C38	0.6992 (10)	0.7078 (7)	0.5056 (7)	0.067 (4)
H38A	0.746735	0.693064	0.467366	0.101*
H38B	0.692324	0.668579	0.540925	0.101*
H38C	0.725372	0.751137	0.529769	0.101*
C39	0.5276 (11)	0.7450 (8)	0.5342 (7)	0.066 (4)
H39A	0.543740	0.794171	0.550291	0.098*
H39B	0.535577	0.711354	0.574741	0.098*
H39C	0.457021	0.743354	0.516699	0.098*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pt1	0.0424 (2)	0.0396 (2)	0.0328 (2)	−0.0039 (2)	−0.0053 (2)	0.0064 (2)
Sb1	0.0658 (7)	0.0821 (7)	0.0772 (7)	0.0113 (5)	−0.0107 (5)	−0.0266 (6)
S1	0.065 (2)	0.0526 (19)	0.0413 (19)	−0.0188 (17)	−0.0173 (15)	0.0129 (14)
P1	0.0468 (16)	0.0404 (15)	0.0328 (15)	−0.0023 (15)	−0.0080 (15)	0.0057 (12)
P2	0.0533 (18)	0.0438 (17)	0.0345 (18)	−0.0096 (14)	−0.0055 (15)	0.0038 (14)
F1	0.166 (11)	0.099 (7)	0.131 (8)	0.027 (9)	−0.053 (8)	−0.002 (6)
F2	0.38 (3)	0.217 (17)	0.221 (18)	0.049 (18)	0.189 (19)	0.015 (14)
F3	0.176 (13)	0.102 (9)	0.33 (2)	0.035 (9)	−0.156 (14)	−0.065 (10)
F4	0.37 (3)	0.32 (2)	0.127 (12)	0.14 (2)	0.085 (15)	−0.042 (14)
F5	0.183 (14)	0.132 (12)	0.55 (3)	0.026 (11)	−0.209 (19)	−0.113 (17)
F6	0.174 (12)	0.081 (7)	0.205 (13)	0.009 (8)	−0.064 (10)	−0.029 (8)
N1	0.051 (6)	0.047 (5)	0.036 (5)	−0.017 (5)	−0.003 (5)	0.003 (4)
C1	0.055 (8)	0.034 (7)	0.061 (8)	−0.001 (6)	−0.002 (7)	0.007 (6)
C2	0.059 (8)	0.043 (7)	0.030 (6)	−0.016 (6)	0.009 (5)	0.000 (5)
C3	0.065 (9)	0.056 (8)	0.046 (8)	−0.001 (7)	−0.034 (7)	0.010 (6)
C4	0.086 (11)	0.098 (12)	0.060 (10)	−0.029 (10)	−0.026 (9)	0.046 (10)
C5	0.107 (14)	0.069 (11)	0.058 (10)	−0.006 (10)	−0.014 (10)	−0.011 (8)
C6	0.105 (12)	0.057 (9)	0.075 (10)	−0.018 (9)	0.018 (11)	−0.011 (9)
C7	0.092 (11)	0.051 (8)	0.043 (7)	0.001 (8)	−0.001 (7)	−0.007 (6)
C8	0.057 (8)	0.041 (7)	0.042 (8)	0.006 (6)	0.007 (6)	0.005 (5)
C9	0.044 (6)	0.060 (8)	0.044 (7)	0.004 (6)	−0.016 (6)	−0.004 (6)
C10	0.048 (9)	0.094 (12)	0.086 (12)	0.013 (8)	0.000 (8)	−0.023 (10)
C11	0.079 (12)	0.074 (11)	0.080 (13)	0.030 (10)	−0.011 (9)	−0.004 (9)
C12	0.132 (16)	0.039 (8)	0.120 (15)	0.028 (10)	−0.037 (14)	0.003 (9)
C13	0.083 (11)	0.055 (9)	0.081 (11)	−0.003 (8)	−0.037 (9)	0.008 (8)
C14	0.046 (7)	0.044 (6)	0.034 (6)	−0.012 (6)	−0.012 (5)	0.009 (5)
C15	0.063 (9)	0.041 (8)	0.085 (11)	−0.007 (7)	−0.016 (8)	0.005 (7)
C16	0.061 (10)	0.079 (11)	0.082 (11)	−0.003 (8)	0.002 (8)	0.002 (8)
C17	0.050 (8)	0.075 (10)	0.053 (9)	−0.010 (7)	−0.002 (6)	−0.002 (7)
C18	0.079 (11)	0.083 (11)	0.084 (12)	−0.041 (10)	−0.004 (10)	0.004 (9)
C19	0.076 (10)	0.071 (9)	0.043 (9)	−0.035 (8)	0.002 (7)	0.000 (6)
C20	0.062 (8)	0.050 (8)	0.033 (7)	0.004 (6)	−0.006 (6)	0.003 (5)
C21	0.066 (10)	0.057 (9)	0.070 (10)	−0.004 (7)	−0.016 (8)	−0.003 (7)
C22	0.080 (12)	0.099 (13)	0.076 (12)	0.012 (11)	−0.009 (9)	−0.041 (10)
C23	0.104 (15)	0.074 (14)	0.117 (17)	0.031 (11)	−0.017 (12)	−0.027 (11)
C24	0.135 (16)	0.063 (11)	0.093 (13)	0.022 (10)	−0.027 (13)	−0.011 (9)
C25	0.122 (13)	0.048 (8)	0.060 (10)	0.009 (9)	0.003 (9)	0.000 (7)
C26	0.051 (7)	0.036 (6)	0.025 (6)	−0.003 (5)	0.006 (5)	−0.003 (4)
C27	0.051 (8)	0.055 (7)	0.030 (6)	0.004 (6)	−0.005 (5)	0.012 (5)
C28	0.043 (7)	0.065 (9)	0.035 (7)	0.004 (6)	−0.004 (6)	−0.008 (6)
C29	0.034 (6)	0.048 (7)	0.033 (7)	0.000 (5)	0.006 (5)	−0.005 (5)
C30	0.037 (7)	0.076 (10)	0.047 (8)	−0.019 (7)	0.000 (6)	−0.019 (7)
C31	0.057 (9)	0.064 (10)	0.067 (10)	−0.026 (8)	0.018 (7)	−0.032 (7)
C32	0.076 (10)	0.041 (7)	0.064 (10)	−0.018 (7)	0.029 (8)	−0.017 (6)
C33	0.058 (8)	0.031 (6)	0.054 (7)	−0.002 (5)	0.010 (7)	−0.005 (6)
C34	0.029 (6)	0.053 (7)	0.043 (7)	0.000 (5)	0.011 (5)	−0.011 (5)
C35	0.035 (5)	0.044 (6)	0.029 (5)	0.003 (5)	−0.004 (5)	0.002 (6)
C36	0.054 (8)	0.047 (7)	0.055 (8)	−0.001 (6)	−0.018 (6)	0.008 (6)
C37	0.058 (8)	0.070 (9)	0.094 (12)	0.016 (7)	−0.013 (9)	−0.040 (9)
C38	0.075 (10)	0.070 (10)	0.057 (9)	−0.012 (8)	−0.035 (7)	0.026 (7)
C39	0.076 (10)	0.076 (10)	0.045 (9)	−0.007 (8)	0.001 (7)	0.006 (7)

Geometric parameters (Å, º)

Pt1—S1	2.397 (3)	C16—H16	0.9400
Pt1—P1	2.213 (3)	C16—C17	1.355 (18)
Pt1—N1	2.151 (8)	C17—H17	0.9400
Pt1—C26	2.004 (11)	C17—C18	1.333 (19)
Sb1—F1	1.843 (10)	C18—H18	0.9400
Sb1—F2	1.800 (14)	C18—C19	1.410 (19)
Sb1—F3	1.822 (11)	C19—H19	0.9400
Sb1—F4	1.784 (15)	C20—C21	1.369 (18)
Sb1—F5	1.802 (13)	C20—C25	1.389 (17)
Sb1—F6	1.880 (11)	C21—H21	0.9400
S1—P2	2.013 (4)	C21—C22	1.406 (19)
P1—C1	1.848 (12)	C22—H22	0.9400
P1—C2	1.829 (11)	C22—C23	1.32 (2)
P1—C8	1.832 (12)	C23—H23	0.9400
P2—C1	1.752 (12)	C23—C24	1.43 (2)
P2—C14	1.807 (12)	C24—H24	0.9400
P2—C20	1.798 (12)	C24—C25	1.347 (19)
N1—C36	1.519 (14)	C25—H25	0.9400
N1—C38	1.454 (15)	C26—C27	1.425 (15)
N1—C39	1.498 (15)	C26—C35	1.405 (14)
C1—H1A	0.9800	C27—H27	0.9400
C1—H1B	0.9800	C27—C28	1.379 (16)
C2—C3	1.412 (16)	C28—H28	0.9400
C2—C7	1.366 (16)	C28—C29	1.390 (15)
C3—H3	0.9400	C29—C30	1.417 (15)
C3—C4	1.481 (19)	C29—C34	1.437 (15)
C4—H4	0.9400	C30—H30	0.9400
C4—C5	1.33 (2)	C30—C31	1.297 (17)
C5—H5	0.9400	C31—H31	0.9400
C5—C6	1.34 (2)	C31—C32	1.427 (19)
C6—H6	0.9400	C32—H32	0.9400
C6—C7	1.418 (17)	C32—C33	1.383 (16)
C7—H7	0.9400	C33—H33	0.9400
C8—C9	1.375 (16)	C33—C34	1.430 (15)
C8—C13	1.395 (17)	C34—C35	1.395 (14)
C9—H9	0.9400	C35—C36	1.516 (14)
C9—C10	1.351 (17)	C36—H36	0.9900
C10—H10	0.9400	C36—C37	1.519 (17)
C10—C11	1.32 (2)	C37—H37A	0.9700
C11—H11	0.9400	C37—H37B	0.9700
C11—C12	1.42 (2)	C37—H37C	0.9700
C12—H12	0.9400	C38—H38A	0.9700
C12—C13	1.36 (2)	C38—H38B	0.9700
C13—H13	0.9400	C38—H38C	0.9700
C14—C15	1.338 (16)	C39—H39A	0.9700
C14—C19	1.371 (15)	C39—H39B	0.9700
C15—H15	0.9400	C39—H39C	0.9700
C15—C16	1.435 (19)
P1—Pt1—S1	91.66 (11)	C14—C15—C16	119.6 (13)
N1—Pt1—S1	90.3 (3)	C16—C15—H15	120.2
N1—Pt1—P1	177.5 (2)	C15—C16—H16	120.0
C26—Pt1—S1	170.7 (3)	C17—C16—C15	120.0 (15)
C26—Pt1—P1	97.4 (3)	C17—C16—H16	120.0
C26—Pt1—N1	80.7 (4)	C16—C17—H17	120.4
F1—Sb1—F6	176.4 (5)	C18—C17—C16	119.2 (14)
F2—Sb1—F1	84.7 (7)	C18—C17—H17	120.4
F2—Sb1—F3	89.9 (10)	C17—C18—H18	119.0
F2—Sb1—F5	95.1 (11)	C17—C18—C19	122.1 (14)
F2—Sb1—F6	93.7 (7)	C19—C18—H18	119.0
F3—Sb1—F1	88.1 (5)	C14—C19—C18	118.5 (14)
F3—Sb1—F6	88.7 (5)	C14—C19—H19	120.7
F4—Sb1—F1	91.9 (8)	C18—C19—H19	120.7
F4—Sb1—F2	176.6 (9)	C21—C20—P2	121.4 (10)
F4—Sb1—F3	90.0 (10)	C21—C20—C25	118.4 (12)
F4—Sb1—F5	84.8 (10)	C25—C20—P2	120.1 (10)
F4—Sb1—F6	89.7 (8)	C20—C21—H21	119.9
F5—Sb1—F1	89.1 (6)	C20—C21—C22	120.1 (14)
F5—Sb1—F3	174.0 (10)	C22—C21—H21	119.9
F5—Sb1—F6	94.3 (6)	C21—C22—H22	119.8
P2—S1—Pt1	104.66 (15)	C23—C22—C21	120.5 (17)
C1—P1—Pt1	107.0 (4)	C23—C22—H22	119.8
C2—P1—Pt1	119.9 (4)	C22—C23—H23	119.6
C2—P1—C1	101.2 (5)	C22—C23—C24	120.7 (16)
C2—P1—C8	107.8 (6)	C24—C23—H23	119.6
C8—P1—Pt1	114.8 (4)	C23—C24—H24	121.1
C8—P1—C1	104.2 (6)	C25—C24—C23	117.8 (16)
C1—P2—S1	106.8 (4)	C25—C24—H24	121.1
C1—P2—C14	109.4 (6)	C20—C25—H25	118.8
C1—P2—C20	108.3 (6)	C24—C25—C20	122.3 (16)
C14—P2—S1	110.3 (4)	C24—C25—H25	118.8
C20—P2—S1	114.6 (4)	C27—C26—Pt1	129.1 (8)
C20—P2—C14	107.4 (6)	C35—C26—Pt1	115.1 (8)
C36—N1—Pt1	105.5 (6)	C35—C26—C27	115.5 (10)
C38—N1—Pt1	115.8 (7)	C26—C27—H27	118.5
C38—N1—C36	111.4 (10)	C28—C27—C26	122.9 (11)
C38—N1—C39	107.9 (9)	C28—C27—H27	118.5
C39—N1—Pt1	106.9 (7)	C27—C28—H28	119.7
C39—N1—C36	108.9 (10)	C27—C28—C29	120.6 (11)
P1—C1—H1A	109.2	C29—C28—H28	119.7
P1—C1—H1B	109.2	C28—C29—C30	122.6 (11)
P2—C1—P1	112.0 (7)	C28—C29—C34	118.9 (10)
P2—C1—H1A	109.2	C30—C29—C34	118.5 (11)
P2—C1—H1B	109.2	C29—C30—H30	118.5
H1A—C1—H1B	107.9	C31—C30—C29	123.1 (13)
C3—C2—P1	119.4 (10)	C31—C30—H30	118.5
C7—C2—P1	117.8 (10)	C30—C31—H31	119.8
C7—C2—C3	122.8 (11)	C30—C31—C32	120.4 (12)
C2—C3—H3	123.3	C32—C31—H31	119.8
C2—C3—C4	113.5 (13)	C31—C32—H32	120.0
C4—C3—H3	123.3	C33—C32—C31	119.9 (12)
C3—C4—H4	118.7	C33—C32—H32	120.0
C5—C4—C3	122.5 (14)	C32—C33—H33	119.8
C5—C4—H4	118.7	C32—C33—C34	120.4 (12)
C4—C5—H5	119.3	C34—C33—H33	119.8
C4—C5—C6	121.4 (16)	C33—C34—C29	117.6 (10)
C6—C5—H5	119.3	C35—C34—C29	118.9 (10)
C5—C6—H6	119.9	C35—C34—C33	123.5 (10)
C5—C6—C7	120.3 (15)	C26—C35—C36	115.7 (9)
C7—C6—H6	119.9	C34—C35—C26	123.2 (10)
C2—C7—C6	119.3 (13)	C34—C35—C36	121.2 (10)
C2—C7—H7	120.4	N1—C36—H36	109.7
C6—C7—H7	120.4	C35—C36—N1	108.0 (9)
C9—C8—P1	118.8 (9)	C35—C36—H36	109.7
C9—C8—C13	119.7 (12)	C35—C36—C37	110.3 (10)
C13—C8—P1	121.5 (11)	C37—C36—N1	109.6 (10)
C8—C9—H9	120.7	C37—C36—H36	109.7
C10—C9—C8	118.7 (13)	C36—C37—H37A	109.5
C10—C9—H9	120.7	C36—C37—H37B	109.5
C9—C10—H10	117.5	C36—C37—H37C	109.5
C11—C10—C9	125.0 (16)	H37A—C37—H37B	109.5
C11—C10—H10	117.5	H37A—C37—H37C	109.5
C10—C11—H11	121.9	H37B—C37—H37C	109.5
C10—C11—C12	116.1 (15)	N1—C38—H38A	109.5
C12—C11—H11	121.9	N1—C38—H38B	109.5
C11—C12—H12	119.1	N1—C38—H38C	109.5
C13—C12—C11	121.8 (16)	H38A—C38—H38B	109.5
C13—C12—H12	119.1	H38A—C38—H38C	109.5
C8—C13—H13	120.7	H38B—C38—H38C	109.5
C12—C13—C8	118.5 (16)	N1—C39—H39A	109.5
C12—C13—H13	120.7	N1—C39—H39B	109.5
C15—C14—P2	117.8 (9)	N1—C39—H39C	109.5
C15—C14—C19	120.5 (12)	H39A—C39—H39B	109.5
C19—C14—P2	121.5 (10)	H39A—C39—H39C	109.5
C14—C15—H15	120.2	H39B—C39—H39C	109.5
Pt1—P1—C1—P2	−45.8 (7)	C13—C8—C9—C10	−2.3 (19)
Pt1—P1—C2—C3	123.4 (8)	C14—P2—C1—P1	162.2 (6)
Pt1—P1—C2—C7	−55.1 (10)	C14—P2—C20—C21	−133.4 (11)
Pt1—P1—C8—C9	−17.4 (11)	C14—P2—C20—C25	49.2 (12)
Pt1—P1—C8—C13	165.1 (9)	C14—C15—C16—C17	0 (2)
Pt1—N1—C36—C35	−40.2 (11)	C15—C14—C19—C18	1.1 (19)
Pt1—N1—C36—C37	80.0 (10)	C15—C16—C17—C18	0 (2)
Pt1—C26—C27—C28	−174.3 (8)	C16—C17—C18—C19	0 (2)
Pt1—C26—C35—C34	177.7 (8)	C17—C18—C19—C14	−1 (2)
Pt1—C26—C35—C36	−2.4 (13)	C19—C14—C15—C16	−0.3 (19)
S1—P2—C1—P1	42.8 (7)	C20—P2—C1—P1	−81.1 (7)
S1—P2—C14—C15	74.0 (10)	C20—P2—C14—C15	−160.5 (9)
S1—P2—C14—C19	−101.9 (10)	C20—P2—C14—C19	23.6 (11)
S1—P2—C20—C21	−10.5 (12)	C20—C21—C22—C23	3 (2)
S1—P2—C20—C25	172.1 (10)	C21—C20—C25—C24	−2 (2)
P1—C2—C3—C4	178.1 (8)	C21—C22—C23—C24	−1 (3)
P1—C2—C7—C6	−175.8 (9)	C22—C23—C24—C25	−3 (3)
P1—C8—C9—C10	−179.8 (10)	C23—C24—C25—C20	4 (3)
P1—C8—C13—C12	−178.3 (12)	C25—C20—C21—C22	−1 (2)
P2—C14—C15—C16	−176.2 (10)	C26—C27—C28—C29	−1.2 (17)
P2—C14—C19—C18	176.9 (10)	C26—C35—C36—N1	29.9 (14)
P2—C20—C21—C22	−178.9 (11)	C26—C35—C36—C37	−89.8 (12)
P2—C20—C25—C24	175.4 (13)	C27—C26—C35—C34	2.9 (15)
C1—P1—C2—C3	−119.4 (10)	C27—C26—C35—C36	−177.2 (10)
C1—P1—C2—C7	62.1 (10)	C27—C28—C29—C30	179.7 (11)
C1—P1—C8—C9	−134.0 (10)	C27—C28—C29—C34	0.5 (16)
C1—P1—C8—C13	48.4 (12)	C28—C29—C30—C31	176.7 (12)
C1—P2—C14—C15	−43.2 (11)	C28—C29—C34—C33	−179.0 (10)
C1—P2—C14—C19	140.9 (10)	C28—C29—C34—C35	1.8 (15)
C1—P2—C20—C21	108.5 (11)	C29—C30—C31—C32	4.5 (19)
C1—P2—C20—C25	−68.9 (12)	C29—C34—C35—C26	−3.7 (15)
C2—P1—C1—P2	−172.0 (6)	C29—C34—C35—C36	176.4 (10)
C2—P1—C8—C9	119.0 (10)	C30—C29—C34—C33	1.7 (15)
C2—P1—C8—C13	−58.5 (12)	C30—C29—C34—C35	−177.4 (9)
C2—C3—C4—C5	−0.3 (19)	C30—C31—C32—C33	−2.7 (19)
C3—C2—C7—C6	5.8 (19)	C31—C32—C33—C34	0.5 (18)
C3—C4—C5—C6	2 (2)	C32—C33—C34—C29	−0.1 (16)
C4—C5—C6—C7	1 (2)	C32—C33—C34—C35	179.0 (11)
C5—C6—C7—C2	−4 (2)	C33—C34—C35—C26	177.2 (10)
C7—C2—C3—C4	−3.5 (17)	C33—C34—C35—C36	−2.7 (16)
C8—P1—C1—P2	76.2 (7)	C34—C29—C30—C31	−4.1 (17)
C8—P1—C2—C3	−10.4 (10)	C34—C35—C36—N1	−150.2 (10)
C8—P1—C2—C7	171.1 (9)	C34—C35—C36—C37	90.1 (13)
C8—C9—C10—C11	0 (2)	C35—C26—C27—C28	−0.5 (16)
C9—C8—C13—C12	4 (2)	C38—N1—C36—C35	−166.7 (9)
C9—C10—C11—C12	0 (2)	C38—N1—C36—C37	−46.6 (13)
C10—C11—C12—C13	3 (2)	C39—N1—C36—C35	74.3 (11)
C11—C12—C13—C8	−4 (2)	C39—N1—C36—C37	−165.5 (10)